ECSP088664A - Proceso para la producción de fracciones altamente enriquecidas de compuestos naturales provenientes de aceite de palma con fluidos supercríticos y casi críticos - Google Patents

Proceso para la producción de fracciones altamente enriquecidas de compuestos naturales provenientes de aceite de palma con fluidos supercríticos y casi críticos

Info

Publication number
ECSP088664A
ECSP088664A EC2008008664A ECSP088664A ECSP088664A EC SP088664 A ECSP088664 A EC SP088664A EC 2008008664 A EC2008008664 A EC 2008008664A EC SP088664 A ECSP088664 A EC SP088664A EC SP088664 A ECSP088664 A EC SP088664A
Authority
EC
Ecuador
Prior art keywords
enrichment
separation
supercritical
tocochromanols
carotenoids
Prior art date
Application number
EC2008008664A
Other languages
English (en)
Inventor
Gerd Brunner
Kai Gast
Meng-Han Chuang
Sendil Kumar
Philip Chan
Wan Ping Chan
Original Assignee
Carotech Sdn Bhd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carotech Sdn Bhd filed Critical Carotech Sdn Bhd
Publication of ECSP088664A publication Critical patent/ECSP088664A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0403—Solvent extraction of solutions which are liquid with a supercritical fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0403—Solvent extraction of solutions which are liquid with a supercritical fluid
    • B01D11/0407—Solvent extraction of solutions which are liquid with a supercritical fluid the supercritical fluid acting as solvent for the solute
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0426—Counter-current multistage extraction towers in a vertical or sloping position
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0492—Applications, solvents used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00—Production of fats or fatty oils from raw materials
    • C11B1/10—Production of fats or fatty oils from raw materials by extracting
    • C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Fats And Perfumes (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)

Abstract

A partir de aceite de palma se pueden derivar compuestos valiosos similares a tococromanoles, carotenoides, fitoesteroles, y otros. El enriquecimiento a fracciones altamente concentradas se obstaculiza por el inmenso número de componentes implicados, la muy baja volatilidad, la muy baja solubilidad de muchos de los compuestos en solventes orgánicos, y la alta viscosidad de las mezclas que serán procesadas. Los materiales de partida para el proceso novedoso son fracciones enriquecidas de tococromanoles (entre aproximadamente 20 hasta aproximadamente 50% en peso) y/o carotenoides (entre aproximadamente 10 hasta 30% en peso) de aceite de palma obtenido mediante procesos convencionales, o mediante procesos de etapas múltiples a contracorriente con dióxido de carbono supercrítico. Estos procesos, no consignados aquí, pueden comprender: la eliminación de ácidos grasos libres, la transesterificación de triglicéridos a ésteres de metilo o etilo, la eliminación de los ésteres, por ejemplo, mediante destilación de trayectoria corta, separación de la fracción de tococromanol a partir de la fracción de carotenoides mediante enfriamiento. En el proceso novedoso, las fracciones derivadas del aceite de palma crudo, ya enriquecido a algún grado en tococromanoles, carotenoides, fitoesteroles, y otros, se tratará mediante tecnología de fluidos supercríticos en una combinación única de separación a contracorriente con adsorción y desorción selectiva utilizando fluidos supercríticos. Un primer enriquecimiento, que comprende uno o más pasos de separación mediante la aplicación de un fluido casi crítico o uno supercrítico en un proceso de separación de etapa individual o múltiple (contracorriente) se combina adecuadamente con un segundo paso de enriquecimiento en donde el producto del primer paso de enriquecimiento se adsorbe directamente en un adsorbente (gel de sílice) al hacer pasar el flujo del producto sobre un lecho fijo de adsorbente sin cambio de presión sustancial, y la posterior desorción con el mismo (u otro) fluido casi crítico o supercrítico a la misma o una presión diferente como en la primera separación, o mediante una secuencia pre-designada de presiones y temperaturas. Para el enriquecimiento con tococromanol, se utiliza dióxido de carbono a condiciones casi críticas superiores a la temperatura crítica del dióxido de carbono. Para el enriquecimiento con carotenoides, se utiliza propano a condiciones casi críticas por debajo de la temperatura crítica del propano.
EC2008008664A 2006-02-10 2008-08-07 Proceso para la producción de fracciones altamente enriquecidas de compuestos naturales provenientes de aceite de palma con fluidos supercríticos y casi críticos ECSP088664A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06002687A EP1818388B1 (en) 2006-02-10 2006-02-10 Process for production of highly enriched fractions of natural compounds from Palm Oil with supercritical and near critical fluids

Publications (1)

Publication Number Publication Date
ECSP088664A true ECSP088664A (es) 2008-11-27

Family

ID=36694365

Family Applications (1)

Application Number Title Priority Date Filing Date
EC2008008664A ECSP088664A (es) 2006-02-10 2008-08-07 Proceso para la producción de fracciones altamente enriquecidas de compuestos naturales provenientes de aceite de palma con fluidos supercríticos y casi críticos

Country Status (14)

Country Link
US (1) US8048462B2 (es)
EP (1) EP1818388B1 (es)
JP (1) JP5189991B2 (es)
CN (1) CN101379174B (es)
AT (1) ATE466065T1 (es)
BR (1) BRPI0706288B8 (es)
DE (1) DE602006013933D1 (es)
EC (1) ECSP088664A (es)
ES (1) ES2345396T3 (es)
HK (1) HK1130280A1 (es)
MX (1) MX2008010219A (es)
MY (1) MY144049A (es)
NI (1) NI200800212A (es)
WO (1) WO2007090545A1 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY148321A (en) * 2007-10-02 2013-03-29 Malaysian Palm Oil Board Mpob Vitamin e supplementation to tetanus toxoid
DE102007061436A1 (de) * 2007-12-20 2009-06-25 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Gewinnung von Fettbegleitstoffen aus Kraftstoffen und Verwendung dieses Verfahrens
US8747673B2 (en) * 2008-09-25 2014-06-10 Battelle Energy Alliance, Llc Methods for recovering a solvent from a fluid volume and methods of removing at least one compound from a nonpolar solvent
ITTO20080797A1 (it) * 2008-10-29 2010-04-30 Leonardo Boschetti Applicazione della tecnologia di estrazione in fase supercritica a diverse materie prime al fine di ottenere principi attivi altamente purificati.
MY188429A (en) * 2009-01-08 2021-12-08 Sime Darby Plantation Berhad Refining of edible oil
US9078850B2 (en) 2009-07-30 2015-07-14 The Thailand Research Fund System and method for extracting vitamin E from fatty acid distillates
CN102061130A (zh) * 2009-11-13 2011-05-18 天津市食品研究所有限公司 一种从辣椒中提取辣椒油树脂的方法
FR2989373B1 (fr) * 2012-04-16 2016-05-06 Roquette Freres Procede de raffinage du squalene produit par microalgues
WO2013156720A2 (fr) * 2012-04-16 2013-10-24 Roquette Freres Procédé de raffinage du squalène produit par microalgues
CN102660378B (zh) * 2012-04-28 2013-11-06 青岛佰福得科技有限公司 一种用棕榈渣提取天然辅酶q10的方法
US10123986B2 (en) 2012-12-24 2018-11-13 Qualitas Health, Ltd. Eicosapentaenoic acid (EPA) formulations
US9629820B2 (en) 2012-12-24 2017-04-25 Qualitas Health, Ltd. Eicosapentaenoic acid (EPA) formulations
US10144874B2 (en) * 2013-03-15 2018-12-04 Terrapower, Llc Method and system for performing thermochemical conversion of a carbonaceous feedstock to a reaction product
TW201623271A (zh) 2014-02-11 2016-07-01 贏創薄膜萃取技術公司 從天然油製造富含維生素ｅ，尤其是富含生育三烯醇，之組成物的方法
EP3002327A1 (en) 2014-10-02 2016-04-06 Sensient Flavors Limited Process for modifying the composition of essential oils
US11154795B2 (en) 2016-10-21 2021-10-26 Novasep Equipment Solutions Use of compressed gas for moving eluent applied to chromatography
WO2018176026A1 (en) 2017-03-24 2018-09-27 Terrapower, Llc Method and system for recycling pyrolysis tail gas through conversion into formic acid
US10787610B2 (en) 2017-04-11 2020-09-29 Terrapower, Llc Flexible pyrolysis system and method
US10050677B1 (en) * 2017-05-23 2018-08-14 Nxp B.V. Antenna coil tuning mechanism for magnetic communication
CN113509746B (zh) * 2021-03-29 2022-08-09 艾斯普瑞(广州)食品有限公司 一种类胡萝卜素芝麻油扯动式浸料系统及其浸料方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6048981A (ja) * 1983-08-29 1985-03-16 Showa Denko Kk 高純度トコフェロ−ルの製造方法
DE3783502T2 (de) 1986-04-15 1993-05-13 Lion Corp Verfahren zur reinigung eines caroten enthaltenden konzentrats.
US5157142A (en) 1986-06-17 1992-10-20 Hoechst Celanese Corporation Thiocarbamates and their derivatives
DE3834988A1 (de) 1988-10-14 1990-04-19 Sueddeutsche Kalkstickstoff Verfahren zur entfernung von terpenen aus etherischen oelen
US5157132A (en) 1990-05-18 1992-10-20 Carotech Associates Integrated process for recovery of carotenoids and tocotrienols from oil
JP2968893B2 (ja) * 1992-10-26 1999-11-02 株式会社神戸製鋼所 油脂の精製方法
DE4241487C2 (de) * 1992-12-09 1996-07-25 Indena Spa Neue Extrakte von Cucurbita sp., Verfahren zu deren Herstellung und deren Verwendung in Arzneimitteln und in der Kosmetik
AU694134B2 (en) 1994-03-18 1998-07-16 Malaysian Palm Oil Board Recovery of carotenes
DE4429506B4 (de) 1994-08-19 2007-09-13 Degussa Gmbh Verfahren zur Extraktion natürlicher Carotinoid-Farbstoffe
DE4447116A1 (de) * 1994-12-29 1996-07-04 Sueddeutsche Kalkstickstoff Verfahren zur Fraktionierung bzw. Raffination von lipiden Naturstoffen
DE19638459A1 (de) 1996-09-19 1998-03-26 Peter Siegfried Verfahren zur Reinigung von Fetten und Ölen tierischen oder vegetabilischen Ursprungs
US6833149B2 (en) * 1999-01-14 2004-12-21 Cargill, Incorporated Method and apparatus for processing vegetable oil miscella, method for conditioning a polymeric microfiltration membrane, membrane, and lecithin product
MY127451A (en) * 1999-11-04 2006-12-29 Malaysian Palm Oil Board A method of chromatographic isolation for vitamin e isomers
MY127954A (en) * 1999-11-04 2007-01-31 Malaysian Palm Oil Board A method of chromatographic isolation for non-glyceride components
US6629256B1 (en) 2000-04-04 2003-09-30 Texas Instruments Incorporated Apparatus for and method of generating a clock from an available clock of arbitrary frequency
FR2830760B1 (fr) * 2001-10-12 2004-06-04 Pf Medicament Procede de preparation d'un compose d'interaction de substances actives avec un support poreux par fluide supercritique
MY136397A (en) 2002-08-20 2008-09-30 Malaysian Palm Oil Board Mpob Recovery of palm phytonutrients
US7455797B2 (en) * 2003-02-28 2008-11-25 Ferro Corporation Method and apparatus for producing particles using supercritical fluid
MY138963A (en) * 2003-08-27 2009-08-28 Malaysian Palm Oil Board One-stage and two-stage supercritical fluid extractions of carotenes concentrate, vitamin e concentrate and other minor components concentrates
ES2238183B1 (es) * 2004-02-09 2006-12-16 Consejo Sup. Investig. Cientificas Procedimiento para obtener compuestos de alto valor añadido a partir de hoja de olivo.
MY146635A (en) * 2004-09-01 2012-09-14 Malaysian Palm Oil Board Specialty palm oil products and other specialty vegetable oil products

Also Published As

Publication number Publication date
ES2345396T3 (es) 2010-09-22
BRPI0706288A2 (pt) 2011-03-22
MY144049A (en) 2011-07-29
US8048462B2 (en) 2011-11-01
DE602006013933D1 (de) 2010-06-10
WO2007090545A1 (en) 2007-08-16
US20090155434A1 (en) 2009-06-18
MX2008010219A (es) 2008-10-31
CN101379174B (zh) 2013-01-16
ATE466065T1 (de) 2010-05-15
EP1818388B1 (en) 2010-04-28
BRPI0706288B8 (pt) 2017-10-31
JP5189991B2 (ja) 2013-04-24
HK1130280A1 (en) 2009-12-24
EP1818388A1 (en) 2007-08-15
JP2009530426A (ja) 2009-08-27
CN101379174A (zh) 2009-03-04
NI200800212A (es) 2011-12-15

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