MX2007002981A - Proceso para la isomerizacion de alfa olefinas a olefinas internas. - Google Patents

Proceso para la isomerizacion de alfa olefinas a olefinas internas.

Info

Publication number
MX2007002981A
MX2007002981A MX2007002981A MX2007002981A MX2007002981A MX 2007002981 A MX2007002981 A MX 2007002981A MX 2007002981 A MX2007002981 A MX 2007002981A MX 2007002981 A MX2007002981 A MX 2007002981A MX 2007002981 A MX2007002981 A MX 2007002981A
Authority
MX
Mexico
Prior art keywords
isomerization
olefins
internal
mixture
alkenes
Prior art date
Application number
MX2007002981A
Other languages
English (en)
Inventor
Jian Jian Zhang
Original Assignee
Hercules Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hercules Inc filed Critical Hercules Inc
Publication of MX2007002981A publication Critical patent/MX2007002981A/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C07C5/2562—Catalytic processes with hydrides or organic compounds
    • C07C5/2568—Catalytic processes with hydrides or organic compounds with ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invencion se refiere a modalidades de un proceso para la isomerizacion de por lo menos una alfa olefina a una olefina interna a traves de un proceso multi-etapa que resulta en una mezcla que comprende isomeros de alqueno y un bajo nivel de oligomeros. De acuerdo con la presente invencion un compuesto de alquilaluminio es utilizado en combinacion con la sal de metal de transicion del Grupo VIII para interaccion con esta ultima, y generar de esta manera especies cataliticamente activas para la isomerizacion de 1-alquenos a alquenos internos, en donde esta mezcla es combinada subsecuentemente con una arcilla lavada con acido.
MX2007002981A 2004-10-19 2005-10-17 Proceso para la isomerizacion de alfa olefinas a olefinas internas. MX2007002981A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/968,608 US7271308B2 (en) 2004-10-19 2004-10-19 Process for isomerization of alpha olefins to internal olefins
PCT/US2005/037357 WO2006044852A1 (en) 2004-10-19 2005-10-17 Process for isomerization of alpha olefins to internal olefins

Publications (1)

Publication Number Publication Date
MX2007002981A true MX2007002981A (es) 2007-05-16

Family

ID=35708471

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2007002981A MX2007002981A (es) 2004-10-19 2005-10-17 Proceso para la isomerizacion de alfa olefinas a olefinas internas.

Country Status (17)

Country Link
US (1) US7271308B2 (es)
EP (1) EP1807381B1 (es)
JP (1) JP2008517062A (es)
KR (1) KR101202486B1 (es)
CN (1) CN101044105B (es)
AT (1) ATE391705T1 (es)
AU (1) AU2005295433C1 (es)
BR (1) BRPI0517310A (es)
CA (1) CA2579310A1 (es)
DE (1) DE602005006011T2 (es)
ES (1) ES2301076T3 (es)
MX (1) MX2007002981A (es)
PL (1) PL1807381T3 (es)
PT (1) PT1807381E (es)
RU (1) RU2007118534A (es)
WO (1) WO2006044852A1 (es)
ZA (1) ZA200704107B (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112006002434A5 (de) * 2005-07-11 2008-06-19 Carbo Tec Gmbh Verfahren und Vorrichtung zum Aufbereiten von Kohlenwasserstoffhaltigen Produkten
US20080146856A1 (en) * 2006-12-19 2008-06-19 Leyshon David W Propylene production
US8178737B2 (en) 2007-06-14 2012-05-15 Lyondell Chemical Technology, L.P. Propylene production
US7816572B2 (en) * 2007-08-07 2010-10-19 Lyondell Chemical Technology, L.P. Propylene and isoprene production
US8119849B2 (en) * 2008-12-29 2012-02-21 Lyondell Chemical Technology, L.P. Propylene production
CA2785608A1 (en) * 2009-12-29 2011-07-07 Dow Global Technologies Llc Producing alpha-olefins
EP2186786A3 (en) * 2010-01-27 2010-09-01 Shell Internationale Research Maatschappij B.V. Process for the separation of olefins from paraffins
US8440871B2 (en) 2010-03-30 2013-05-14 Uop Llc Tetramer production apparatus and process relating thereto
US9486296B2 (en) * 2010-07-08 2016-11-08 Warsaw Orthopedic, Inc. Surgical assembly with flexible arm
US8395005B2 (en) 2010-10-13 2013-03-12 Equistar Chemicals, Lp Production of 1-butene and propylene from ethylene
CN104557398B (zh) * 2013-10-28 2017-08-11 中国石油化工股份有限公司 碳五生产丙烯的方法
US9708236B2 (en) 2014-01-09 2017-07-18 San Diego State University Research Foundation Terminal alkene monoisomerization catalysts and methods
US10364204B2 (en) 2015-06-22 2019-07-30 Lyondell Chemical Technology, L.P. Process for manufacturing methyl tertiary-butyl ether (MTBE) and other hydrocarbons
US10125062B2 (en) 2015-11-06 2018-11-13 Lyondell Chemical Technology, L.P. Propylene production processes and catalyst systems for use therein
CN114685234B (zh) * 2020-12-31 2024-05-14 上海昶法新材料有限公司 一种生产内烯烃的系统和方法
ES2929364B2 (es) * 2021-05-28 2024-03-18 Consejo Superior Investigacion Procedimiento de obtencion de alquenos lineales de cadena larga
CN113735805A (zh) * 2021-07-06 2021-12-03 上海昶法新材料有限公司 烯基琥珀酸酐的制备方法
WO2023042898A1 (ja) 2021-09-17 2023-03-23 花王株式会社 内部オレフィンの製造方法
CN115650939B (zh) * 2022-11-15 2024-06-14 上海昶法新材料有限公司 一种α-烯烃异构化制备ASA原料的方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3439054A (en) * 1966-12-08 1969-04-15 Exxon Research Engineering Co Metal carbonyl catalyst and hydrogenation process therefor
US3641184A (en) * 1969-12-16 1972-02-08 Phillips Petroleum Co Olefin isomerization
DE3022821A1 (de) 1980-06-19 1982-01-14 EC Erdölchemie GmbH, 5000 Köln Verfahren zur stellungsisomerisierung von endstaendigen doppelbindungen in olefinen
FR2555570B1 (fr) * 1983-11-29 1986-10-03 Inst Francais Du Petrole Nouvelle composition du nickel bivalent soluble dans les hydrocarbures
US4587374A (en) * 1984-03-26 1986-05-06 Ethyl Corporation Olefin isomerization process
JPH0633598B2 (ja) * 1984-11-16 1994-05-02 三菱石油株式会社 製紙用サイズ剤
US5030606A (en) * 1985-10-15 1991-07-09 E. I. Du Pont De Nemours And Company Nickel-catalyzed copolymerization of ethylene
US4876314A (en) * 1988-11-09 1989-10-24 Shell Oil Company Hydrogenation process
US5252754A (en) * 1991-11-18 1993-10-12 Hercules Incorporated Fluorinated aldoketene dimer structures and their use as combination oil and water resistant sizes for cellulosic materials
EP0646413B1 (fr) * 1993-09-22 2000-03-01 Institut Français du Pétrole Nouvelle composition contenant du nickel pour la catalyse et procédé de dimérisation et d'oligomérisation des oléfines
US5545792A (en) * 1994-11-21 1996-08-13 Amoco Corporation Isomerization catalyst and process
FR2736562B1 (fr) * 1995-07-11 1997-09-19 Inst Francais Du Petrole Nouvelle composition catalytique pour catalyse biphasique, en particulier a base de complexes du nickel et procede pour l'oligomerisation des olefines
US6355855B1 (en) * 2000-02-29 2002-03-12 Hercules Incorporated Process for the isomerization of 1-alkenes to internal alkenes and catalyst therefor
US6348132B1 (en) * 2000-05-30 2002-02-19 Hercules Incorporated Alkenyl succinic anhydride compositons and the use thereof
JP2004285000A (ja) 2003-03-24 2004-10-14 Idemitsu Petrochem Co Ltd 内部オレフィンの製造方法

Also Published As

Publication number Publication date
BRPI0517310A (pt) 2008-10-07
KR101202486B1 (ko) 2012-11-16
ZA200704107B (en) 2009-01-28
US7271308B2 (en) 2007-09-18
CN101044105B (zh) 2011-03-30
US20060084831A1 (en) 2006-04-20
KR20070068378A (ko) 2007-06-29
CA2579310A1 (en) 2006-04-27
JP2008517062A (ja) 2008-05-22
RU2007118534A (ru) 2008-11-27
PT1807381E (pt) 2008-05-27
WO2006044852A1 (en) 2006-04-27
ES2301076T3 (es) 2008-06-16
DE602005006011T2 (de) 2009-05-07
EP1807381A1 (en) 2007-07-18
AU2005295433A1 (en) 2006-04-27
AU2005295433B2 (en) 2009-02-12
DE602005006011D1 (de) 2008-05-21
CN101044105A (zh) 2007-09-26
AU2005295433C1 (en) 2009-07-30
ATE391705T1 (de) 2008-04-15
EP1807381B1 (en) 2008-04-09
PL1807381T3 (pl) 2008-09-30

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