MX174069B - Composiciones para moldear nylon que muestran una proteccion mejorada contra la degradacion producida por la luz ultravioleta - Google Patents
Composiciones para moldear nylon que muestran una proteccion mejorada contra la degradacion producida por la luz ultravioletaInfo
- Publication number
- MX174069B MX174069B MX023424A MX2342490A MX174069B MX 174069 B MX174069 B MX 174069B MX 023424 A MX023424 A MX 023424A MX 2342490 A MX2342490 A MX 2342490A MX 174069 B MX174069 B MX 174069B
- Authority
- MX
- Mexico
- Prior art keywords
- molding compositions
- nylon molding
- protection against
- improved protection
- light degradation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/527—Cyclic esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
Abstract
La presente invención se refiere a una composición para moldeo de nylon, caracterizada porque comprende una resina básica de nylon y un sistema de estabilización, el cual incluye: i) un antioxidante fenólico obstruído o impedido, ii) un compuesto de fosfito, iii) un estabilizador de la luz, de amina obstruída, y opcionalmente, iv) un absorbente de la luz UV de benzotriazol este sistema de estabilización está presnte en la composición en una cantidad suficiente para lograr una diferencia de color, según se calcula en unidades CIELab bajo el iluminante "D-65", de acuerdo con la Norma D-2244 de ASTM, de menos de aproximadamente 1.5, cuando se expone a una irradiación de 601.6 kJ/m2, en un medidor ambiental de arco Xenon, operado de acuerdo con la norma J1885 de la SAE y que exhibe al menos 75 por ciento de retención superficial de brillo, aproximadamente, despues de la irradiación.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/441,959 US5380774A (en) | 1989-11-28 | 1989-11-28 | Nylon molding compositions exhibiting improved protection against UV-light degradation |
Publications (1)
Publication Number | Publication Date |
---|---|
MX174069B true MX174069B (es) | 1994-04-19 |
Family
ID=23754981
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX023424A MX174069B (es) | 1989-11-28 | 1990-11-22 | Composiciones para moldear nylon que muestran una proteccion mejorada contra la degradacion producida por la luz ultravioleta |
Country Status (8)
Country | Link |
---|---|
US (1) | US5380774A (es) |
EP (1) | EP0430650B1 (es) |
JP (1) | JP3295079B2 (es) |
AT (1) | ATE134207T1 (es) |
BR (1) | BR9006003A (es) |
CA (1) | CA2027802C (es) |
DE (1) | DE69025379T2 (es) |
MX (1) | MX174069B (es) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2707339B1 (fr) * | 1993-07-08 | 1996-10-31 | Volkswagen Ag | Came, en particulier pour commander une soupape de changement de charge. |
EP0675160A3 (en) * | 1994-03-29 | 1995-11-29 | Gen Electric | Polyamide compositions stabilized against UV light. |
DE4441429A1 (de) | 1994-11-22 | 1996-07-18 | Schulman A Gmbh | Stabilisiertes Polyamid und Verfahren zu seiner Herstellung |
US5733497A (en) * | 1995-03-31 | 1998-03-31 | Dtm Corporation | Selective laser sintering with composite plastic material |
WO1997042267A1 (en) * | 1996-05-03 | 1997-11-13 | Alliedsignal Inc. | Novel nylon compositions |
CA2259308C (en) | 1996-06-28 | 2007-04-24 | Alan V. Bray | High density composite material |
RU2156264C2 (ru) * | 1996-07-09 | 2000-09-20 | Емс-Инвента АГ | Устойчивый к атмосферным воздействиям полиамид и способ его получения (варианты) |
US5969014A (en) * | 1997-09-23 | 1999-10-19 | Clariant Finance (Bvi) Limited | Synergistic polyamide stabilization method |
JP4108175B2 (ja) * | 1998-03-26 | 2008-06-25 | 旭化成ケミカルズ株式会社 | 耐候性に優れた黒着色ポリアミド系樹脂組成物 |
WO2000032693A1 (fr) * | 1998-11-27 | 2000-06-08 | Unitika Ltd. | Composition de resine de polyamide et partie de support de retroviseur comprenant ladite composition |
NL1012176C2 (nl) * | 1999-05-28 | 2000-11-30 | Dsm Nv | Halogeenvrije brandvertragende samenstelling. |
DE10148702A1 (de) * | 2001-10-02 | 2003-04-10 | Basf Ag | Stabilisatorengemisch und stabilisiete Polyurethane |
US7081213B2 (en) | 2002-05-14 | 2006-07-25 | Clariant Finance (Bvi) Limited | Stabilizer mixtures for the protection of polymer substrates |
GB0219260D0 (en) * | 2002-08-19 | 2002-09-25 | Clariant Gmbh | Improvements in or relating to organic compounds |
FR2890969A1 (fr) * | 2005-09-16 | 2007-03-23 | Arkema Sa | Copolymeres a blocs polyamides et blocs polyethers resistants au vieillissement |
KR100848531B1 (ko) * | 2005-09-16 | 2008-07-25 | 아르끄마 프랑스 | 폴리아미드 블록 및 폴리에테르 블록을 함유하는 노화방지공중합체 |
US7462670B2 (en) * | 2005-09-22 | 2008-12-09 | Ciba Specialty Chemicals Corporation | Scratch resistant polymer compositions |
EP1950238A3 (en) | 2008-02-22 | 2008-09-03 | Solvay Advanced Polymers, L.L.C. | Flame resistant polymer composition with improved color stability |
US20110039470A1 (en) * | 2009-07-30 | 2011-02-17 | E.I. Du Pont De Nemours And Company | Overmolded heat resistant polyamide composite structures and processes for their preparation |
JP6035066B2 (ja) * | 2012-07-04 | 2016-11-30 | 旭化成株式会社 | ポリアミド組成物及び成形品 |
PL221727B1 (pl) | 2012-07-23 | 2016-05-31 | Splast Spółka Z Ograniczoną Odpowiedzialnością Spółka Komandytowa | Kompozycja zawierająca poliamid |
CN106536632B (zh) * | 2014-07-25 | 2019-06-11 | 帝斯曼知识产权资产管理有限公司 | 热稳定的聚酰胺组合物 |
Family Cites Families (74)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2493597A (en) * | 1946-03-05 | 1950-01-03 | Rohm & Haas | Use of phosphite esters in the stabilization of linear polyamides |
US2849414A (en) * | 1954-09-21 | 1958-08-26 | Polymer Corp | Nylon-carbon black composition and article |
US2847443A (en) * | 1956-05-02 | 1958-08-12 | Shea Chemical Corp | Pentaerythritol products |
US3004896A (en) * | 1956-12-14 | 1961-10-17 | Geigy Ag J R | Ultra-violet light-absorbing composition of matter |
US3644482A (en) * | 1961-10-30 | 1972-02-22 | Geigy Ag J R | (4-hydroxy-5-alkylphenyl) alkanoic acid esters of polyols |
US3282886A (en) * | 1962-07-27 | 1966-11-01 | Du Pont | Polycarbonamides of improved photostability and dye lightfastness |
US3324072A (en) * | 1963-08-12 | 1967-06-06 | Monsanto Co | Nylon filled with carbon black |
US3322718A (en) * | 1963-08-23 | 1967-05-30 | Nat Distillers Chem Corp | Polyolefins stabilized with phosphites, phenols, and benzotriazoles |
NL6514124A (es) * | 1964-11-02 | 1966-05-03 | ||
US3285855A (en) * | 1965-03-11 | 1966-11-15 | Geigy Chem Corp | Stabilization of organic material with esters containing an alkylhydroxy-phenyl group |
GB1163086A (en) * | 1966-03-07 | 1969-09-04 | Ici Ltd | Polyamides. |
DE1694156B2 (de) * | 1967-06-09 | 1975-11-06 | Bayer Ag, 5090 Leverkusen | Lichtstabilisierte Polyamide |
US3531423A (en) * | 1968-03-07 | 1970-09-29 | Gen Mills Inc | Thermal and oxidative stabilized polyamides |
US3595829A (en) * | 1968-03-11 | 1971-07-27 | Ici Ltd | Polyamides |
US3839392A (en) * | 1970-04-14 | 1974-10-01 | G Follows | Polyamides |
CH540954A (de) * | 1970-12-07 | 1973-08-31 | Ciba Geigy Ag | Stabilisatorsystem für Polyamide |
US3872055A (en) * | 1972-08-19 | 1975-03-18 | Toyo Boseki | Polyamide composition having decreased gel-forming property in molten state |
US4044200A (en) * | 1972-12-04 | 1977-08-23 | Union Carbide Corporation | Insulated wire or cable |
US3935163A (en) * | 1973-03-08 | 1976-01-27 | Ciba-Geigy Corporation | Light stabilized polymer compositions |
US3935164A (en) * | 1973-03-08 | 1976-01-27 | Ciba-Geigy Corporation | Light stabilized polymer compositions |
US3904705A (en) * | 1973-11-30 | 1975-09-09 | Ici Ltd | Thermally stabilized synthetic polyamides |
USB512373I5 (es) * | 1974-10-07 | 1976-02-10 | ||
US3960809A (en) * | 1973-12-28 | 1976-06-01 | Ciba-Geigy Corporation | Compositions stabilized with hindered piperidine carboxylic acids |
US4001181A (en) * | 1973-12-28 | 1977-01-04 | Ciba-Geigy Corporation | Hindered piperidine carboxamide acids, metal salts thereof, and stabilized compositions |
US3939163A (en) * | 1973-12-28 | 1976-02-17 | Ciba-Geigy Corporation | Metal salts of hindered piperidine carboxylic acids and stabilized compositions |
US3997505A (en) * | 1974-01-02 | 1976-12-14 | Michigan Chemical Corporation | Flame retardant polymeric compositions containing pentaerythritol cyclic diphosphates or diphosphoramidates |
US4017557A (en) * | 1974-11-13 | 1977-04-12 | E. I. Du Pont De Nemours And Company | Novel elastomeric graft copolymers |
JPS51125451A (en) * | 1975-04-03 | 1976-11-01 | Asahi Chem Ind Co Ltd | Polyamide composition |
DE2647452A1 (de) * | 1975-11-07 | 1977-05-18 | Ciba Geigy Ag | Neue hydroxybenzylmalonsaeure-derivate |
DE2656769A1 (de) * | 1975-12-29 | 1977-07-14 | Ciba Geigy Ag | Neue phenol-stabilisatoren |
US4069277A (en) * | 1976-03-02 | 1978-01-17 | Phillips Fibers Corporation | Dyeable polyamides containing an antistatic agent |
GB1526603A (en) * | 1976-03-04 | 1978-09-27 | Borg Warner | Preparation of organic phosphites |
US4174385A (en) * | 1976-10-08 | 1979-11-13 | Robert Reid | Method of identification of surface proteins of cancer cells, clinical test and method of immunization |
US4185004A (en) * | 1977-04-27 | 1980-01-22 | Phillips Petroleum Company | Multi-component stabilizing system for pigmented polyolefins |
US4206111A (en) * | 1977-05-06 | 1980-06-03 | Borg-Warner Corporation | Stabilized polyolefins |
DE2963604D1 (en) * | 1978-06-21 | 1982-10-28 | Ciba Geigy Ag | Light stabilization of acid catalysed stoving enamels |
US4226763A (en) * | 1978-06-26 | 1980-10-07 | Ciba-Geigy Corporation | 2-[2-Hydroxy-3,5-di-(.alpha.,α-dimethylbenzyl)-phenyl]-2H-benzotriazole and stabilized compositions |
DE2837027A1 (de) * | 1978-08-24 | 1980-03-06 | Bayer Ag | Neue phosphorigsaeureester und ihre verwendung zur stabilisierung von polyamiden |
US4477614A (en) * | 1979-01-25 | 1984-10-16 | Ciba-Geigy Corporation | 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-benzotriazole stabilized compositions |
US4283502A (en) * | 1979-04-30 | 1981-08-11 | E. I. Du Pont De Nemours And Company | Polyamide resins |
JPS55165952A (en) * | 1979-06-14 | 1980-12-24 | Unitika Ltd | Polyamide composition |
DE2926778A1 (de) * | 1979-07-03 | 1981-01-15 | Bayer Ag | Mit fasern verstaerkte polyamid-formmassen |
US4377651A (en) * | 1979-10-05 | 1983-03-22 | Phillips Petroleum Company | Polyolefin stabilization |
US4291093A (en) * | 1979-10-05 | 1981-09-22 | Phillips Petroleum Co. | Stabilized polyolefin substrate overcoated with an ethoxylated lubricant and a phosphate ester |
US4346194A (en) * | 1980-01-22 | 1982-08-24 | E. I. Du Pont De Nemours And Company | Toughened polyamide blends |
US4302383A (en) * | 1980-05-19 | 1981-11-24 | Borg-Warner Chemicals, Inc. | Stabilized olefin polymers |
US4310638A (en) * | 1980-08-20 | 1982-01-12 | Monsanto Company | Nylon modified acrylic copolymer rubber |
US4478978A (en) * | 1980-10-20 | 1984-10-23 | E. I. Du Pont De Nemours And Company | Toughened polyamide blends |
US4707513A (en) * | 1980-11-03 | 1987-11-17 | Monsanto Company | Tough thermoplastic nylon compositions |
US4339374A (en) * | 1980-11-28 | 1982-07-13 | Skf Kugellagerfabriken Gmbh | Novel molding composition providing shaped articles of improved strength and heat and age resistance |
NL193426C (nl) * | 1981-03-16 | 1999-10-04 | Hunter Douglas Ind Bv | Werkwijze voor het aanbrengen van een moffellaklaag op een voorwerp. |
US4544691A (en) * | 1981-11-05 | 1985-10-01 | Ciba-Geigy Corporation | Compositions containing ultraviolet-absorbing stabilizing substituted by an aliphatic hydroxyl group |
US4391943A (en) * | 1982-01-04 | 1983-07-05 | The Polymer Corporation | UV Stabilized nylon 6 |
DE3204334A1 (de) * | 1982-02-09 | 1983-08-11 | Bayer Ag, 5090 Leverkusen | Witterungsstabile polyamide |
US4464496A (en) * | 1982-03-26 | 1984-08-07 | Uniroyal, Inc. | Non-yellowing polymer composition |
DE3220380A1 (de) * | 1982-05-29 | 1983-12-01 | Basf Ag, 6700 Ludwigshafen | Schlagzaehe polyamid-formmassen |
US4540727A (en) * | 1982-10-29 | 1985-09-10 | Raychem Corporation | Polyamide compositions |
US4446263A (en) * | 1982-12-28 | 1984-05-01 | Celanese Corporation | UV-Stabilization of oxymethylene copolymers |
GB8317223D0 (en) * | 1983-06-24 | 1983-07-27 | Ici Plc | Polyamide articles |
JPS6049060A (ja) * | 1983-08-26 | 1985-03-18 | Toray Ind Inc | ポリアミドエラストマ組成物 |
US4495324A (en) * | 1983-10-24 | 1985-01-22 | Allied Corporation | Glass reinforced polyamide composition containing acrylic core/shell polymer |
US4537929A (en) * | 1984-01-20 | 1985-08-27 | Plastic Specialties And Technologies, Inc. | High impact nylon composition |
DE3403576A1 (de) * | 1984-02-02 | 1985-08-08 | Basf Ag, 6700 Ludwigshafen | Elastomere thermoplastische formmassen und deren herstellung |
US4536541A (en) * | 1984-02-27 | 1985-08-20 | E. I. Du Pont De Nemours And Company | High impact resistant polyamide |
EP0155912A3 (de) * | 1984-03-20 | 1986-06-04 | Ciba-Geigy Ag | Strahlenstabilisierte polymere Zusammensetzungen |
JPS6136339A (ja) * | 1984-07-27 | 1986-02-21 | Polyplastics Co | 耐候性ポリアセタ−ル樹脂組成物 |
DE3436362A1 (de) * | 1984-10-04 | 1986-04-10 | Basf Ag, 6700 Ludwigshafen | Schlagzaehe polyamid-formmassen mit verminderter spannungsrissanfaelligkeit |
JPS61140566A (ja) * | 1984-12-11 | 1986-06-27 | Sumitomo Chem Co Ltd | ピペリジン誘導体、その製造方法およびこれを有効成分とする有機物質用安定剤 |
US4851473A (en) * | 1985-01-15 | 1989-07-25 | E. I. Du Pont De Nemours And Company | High impact resistant polyamide |
JPH0635538B2 (ja) * | 1985-04-04 | 1994-05-11 | 住友化学工業株式会社 | ポリウレタン組成物 |
US4785076A (en) * | 1985-09-03 | 1988-11-15 | General Electric Company | Polyphenylene ether resin blends having improved ultraviolet light stability |
US4724247A (en) * | 1986-07-18 | 1988-02-09 | Ethyl Corporation | Antioxidant aromatic diphosphites |
DE3700330A1 (de) * | 1987-01-08 | 1988-07-21 | Basf Ag | Schlagzaehe polyamid-formmassen |
JPH07103330B2 (ja) * | 1987-07-22 | 1995-11-08 | ダイセル・ヒュルス株式会社 | ポリアミド樹脂組成物 |
-
1989
- 1989-11-28 US US07/441,959 patent/US5380774A/en not_active Expired - Lifetime
-
1990
- 1990-10-17 CA CA002027802A patent/CA2027802C/en not_active Expired - Fee Related
- 1990-11-22 MX MX023424A patent/MX174069B/es unknown
- 1990-11-27 BR BR909006003A patent/BR9006003A/pt not_active IP Right Cessation
- 1990-11-27 AT AT90312887T patent/ATE134207T1/de not_active IP Right Cessation
- 1990-11-27 EP EP90312887A patent/EP0430650B1/en not_active Expired - Lifetime
- 1990-11-27 DE DE69025379T patent/DE69025379T2/de not_active Expired - Fee Related
- 1990-11-28 JP JP32881790A patent/JP3295079B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69025379T2 (de) | 1996-07-04 |
CA2027802A1 (en) | 1991-05-29 |
EP0430650A1 (en) | 1991-06-05 |
JP3295079B2 (ja) | 2002-06-24 |
DE69025379D1 (de) | 1996-03-28 |
JPH03181561A (ja) | 1991-08-07 |
EP0430650B1 (en) | 1996-02-14 |
BR9006003A (pt) | 1991-09-24 |
CA2027802C (en) | 2003-04-08 |
US5380774A (en) | 1995-01-10 |
ATE134207T1 (de) | 1996-02-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX174069B (es) | Composiciones para moldear nylon que muestran una proteccion mejorada contra la degradacion producida por la luz ultravioleta | |
CA2330422A1 (en) | Methods and compositions for protecting polymers from uv light | |
ES2159866T3 (es) | Composiciones estabilizantes. | |
ES2172586T3 (es) | Mejoras por copolimero-1 en composiciones de copolimeros. | |
MXPA01004635A (es) | Una pelicula con propiedades de proteccion contra uv | |
ATE284918T1 (de) | Polycarbonatzusammensetzungen, die cyanacrylsäuresterverbindungen enthalten | |
AR011040A1 (es) | Composiciones de moldeo termoplasticas y un procedimiento para su obtencion | |
HUP9700538A2 (hu) | Polipropilén random kopolimer kompozíciók | |
ES2138926A1 (es) | Mezcla estabilizadora para materiales organicos. | |
ES2179091T3 (es) | Barniz de proteccion para madera. | |
KR900007947A (ko) | Uv-광안정성 폴리옥시메틸렌 성형 조성물 및 그들로 구성된 성형품 | |
MX169560B (es) | Composicion estabilizadora para polimeros organicos | |
CA2048067A1 (en) | Method for recycling discolored polyolefins | |
EP1371358A3 (de) | Kosmetische und dermatologische Lichtschutzzubereitungen enthaltend UV-Absorber und synthetische organische Polymere | |
AU1816500A (en) | Bleaching compositions | |
CA2028222A1 (en) | Polymeric additives | |
AU2001237058A1 (en) | Carbonate polymer compositions comprising low volatile uv absorbing compounds | |
DE68920705T2 (de) | Gegen UV-Strahlung stabilisierte Polyester-Formmassen. | |
US3335108A (en) | Stabilization of polyolefins with n, n-disubstituted glycine | |
MX173652B (es) | Composicion de polipropileno estabilizado contra la degradacion oxidante con mezclas de derivados de diarilamina y fenoles impedidos estericamente | |
GR3025438T3 (en) | Stabilizing composition for organic polymers | |
EP1028142A3 (en) | Synergistic stabilizer system | |
AR021334A1 (es) | [pirrol]naftopiranos, su preparacion, composiciones y matrices (co)polimericas que los contienen | |
DE59503949D1 (de) | Witterungsstabile polyoxymethylenformmassen | |
US3418272A (en) | Stabilization of polyolefins with n,n'-tetra-substituted alkylenediamines and oxyalkylenediamines |