MX171531B - Proceso para eliminar los oxidos de azufre de los gases de combustion y de otras corrientes de gases, usando sorbentes - Google Patents

Proceso para eliminar los oxidos de azufre de los gases de combustion y de otras corrientes de gases, usando sorbentes

Info

Publication number
MX171531B
MX171531B MX026026A MX2602691A MX171531B MX 171531 B MX171531 B MX 171531B MX 026026 A MX026026 A MX 026026A MX 2602691 A MX2602691 A MX 2602691A MX 171531 B MX171531 B MX 171531B
Authority
MX
Mexico
Prior art keywords
sorbents
sulfur oxides
gas flows
combustion gases
eliminate sulfur
Prior art date
Application number
MX026026A
Other languages
English (en)
Inventor
Thomas J Pinnavaia
Jayantha Amaresekera
Christine A Polansky
Original Assignee
Univ Michigan State
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Michigan State filed Critical Univ Michigan State
Publication of MX171531B publication Critical patent/MX171531B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/78—Compounds containing aluminium and two or more other elements, with the exception of oxygen and hydrogen
    • C01F7/784—Layered double hydroxide, e.g. comprising nitrate, sulfate or carbonate ions as intercalating anions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/20—Two-dimensional structures
    • C01P2002/22—Two-dimensional structures layered hydroxide-type, e.g. of the hydrotalcite-type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/78—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by stacking-plane distances or stacking sequences

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

La presente invención se refiere a un proceso para eliminar los componentes de los SOx de los gases de combustión y de otras corrientes de gases, caracterizado en que comprende el contacto de la corriente de gases con una composición sorbente calentada, en la cual el sorbente se selecciona del grupo consistente en una estructura en capas de un doble hidróxido de la fórmula: (M1-xIIMxIII(OH)2)(An-)x/n.yH2O) en la cual MII es un catión de metal divalente y MIII es un catión de metal trivalente seleccionados del grupo consistente en cationes de metales que forman óxidos metálicos y que son capaces de reaccionar con el SO2 para formar sulfitos metálicos y con el SO3 para formar sulfatos metálicos; A es un anión de capa intermedia de carga n- que comprende, cuando menos, un átomo de metal que provee la oxidación del bióxido de azufre en trióxido de azufre en una proporción suficiente para que la estructura en capas del doble hidróxido intersifique la oxidación del bióxido de azufre en trióxido de azufre bajo las condiciones de oxidación del bióxido de azufre; x es un valor comprendido entre 0.8 y 0.12 y un derivado termotratado del doble hidróxido.
MX026026A 1990-06-08 1991-05-31 Proceso para eliminar los oxidos de azufre de los gases de combustion y de otras corrientes de gases, usando sorbentes MX171531B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/535,147 US5114691A (en) 1990-01-18 1990-06-08 Process using sorbents for the removal of SOx from flue gas

Publications (1)

Publication Number Publication Date
MX171531B true MX171531B (es) 1993-11-03

Family

ID=24133032

Family Applications (1)

Application Number Title Priority Date Filing Date
MX026026A MX171531B (es) 1990-06-08 1991-05-31 Proceso para eliminar los oxidos de azufre de los gases de combustion y de otras corrientes de gases, usando sorbentes

Country Status (12)

Country Link
US (1) US5114691A (es)
EP (1) EP0486676B1 (es)
JP (1) JPH0722678B2 (es)
KR (1) KR950011824B1 (es)
CN (1) CN1057211A (es)
AT (1) ATE143827T1 (es)
CA (1) CA2064715A1 (es)
DE (1) DE69122591T2 (es)
IE (1) IE911685A1 (es)
MX (1) MX171531B (es)
MY (1) MY106394A (es)
WO (1) WO1991018667A1 (es)

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US5334564A (en) * 1990-07-16 1994-08-02 Board Of Trustees Operating Michigan State University Method for the preparation of highly reactive clay composites for the removal of SOx from flue gas streams
US5364568A (en) * 1992-07-08 1994-11-15 Georgetown University Compounds and methods for separation and molecular encapsulation of metal ions
US5785938A (en) * 1992-11-16 1998-07-28 Board Of Trustees Operating Michigan State University Process using recyclable sorbents for the removal of sox from flue gases and other gas streams
US5358701A (en) * 1992-11-16 1994-10-25 Board Of Trustees Operating Michigan State University Process of using layered double hydroxides as low temperature recyclable sorbents for the removal of SOx from flue gas and other gas streams
US5302709A (en) * 1992-11-25 1994-04-12 Board Of Trustees Operating Michigan State University Polyaryl-metallic complex intercalated layered double hydroxides
US5415850A (en) * 1993-02-24 1995-05-16 The Research Foundation Of State Univeristy Of New York Pillared interlayered clay catalysts for the selective reduction of nitrogen oxides with ammonia
AU2700295A (en) * 1994-06-09 1996-01-04 Abb Environmental Systems Improved entrainment separator for high velocity gases and reheating of scrubber gases
US5928496A (en) * 1996-06-20 1999-07-27 Contract Materials Processing, Inc. Hydrotalcite sulfer oxide sorption
US6028023A (en) * 1997-10-20 2000-02-22 Bulldog Technologies U.S.A., Inc. Process for making, and use of, anionic clay materials
US6074437A (en) * 1998-12-23 2000-06-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Bleaching with polyoxometalates and air or molecular oxygen
US20030049191A1 (en) * 1999-12-11 2003-03-13 Twigg Martyn Vincent Process for treating exhaust gas including sox
WO2002016026A2 (en) * 2000-08-25 2002-02-28 Apyron Technologies, Inc. Adsorbent and/or catalyst compounds promoted with halide ions and methods of making and using thereof
US6662951B1 (en) * 2000-09-27 2003-12-16 Basic Resources, Inc. Process for extracting and purifying naturally occurring zeolite
JP4574884B2 (ja) * 2001-03-27 2010-11-04 住友重機械工業株式会社 排ガス処理システムの硫酸回収方法及び硫酸回収装置
CN1245079C (zh) * 2002-12-13 2006-03-15 北京化工大学 一种超分子结构草甘膦缓释剂及其制备方法
US20050161410A1 (en) * 2003-11-06 2005-07-28 Wilson Gregg L. System, method and composition for treatment of wastewater
US20050100493A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050100494A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US6998100B2 (en) * 2003-11-19 2006-02-14 Toll Processing And Consulting, Llc Sulfur oxide sorption with layered chlorite-type contact solids
US7304011B2 (en) * 2004-04-15 2007-12-04 W.R. Grace & Co. -Conn. Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US20050232839A1 (en) * 2004-04-15 2005-10-20 George Yaluris Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US7238288B1 (en) 2004-08-13 2007-07-03 Sandia Corporation Method for absorbing an ion from a fluid
MX2007011531A (es) * 2005-03-24 2007-11-16 Grace W R & Co Metodo para controlar emisiones de nox en la fccu.
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JP4535016B2 (ja) * 2006-03-28 2010-09-01 住友ベークライト株式会社 塩化ビニル樹脂組成物、それを用いて作製した塩化ビニル樹脂シートおよび成形体
MX2009004594A (es) * 2006-10-31 2009-09-18 Intercat Inc Aditivos de remocion de oxido de azufre y metodos para condiciones de oxidacion parcial.
US20100327224A1 (en) * 2009-06-26 2010-12-30 Manuela Serban Compounds for Desulfurization of Hot Fuel Gases
US20100135884A1 (en) * 2009-06-26 2010-06-03 Manuela Serban Process for Desulfurization of Hot Fuel Gases
CN103589450B (zh) * 2012-08-14 2015-11-04 中国科学院大连化学物理研究所 一种柴油的超深度氧化脱硫方法
US9951196B2 (en) 2012-10-24 2018-04-24 J.M. Huber Corporation Cationic polyoxometalate-coated alumina trihydrate dispersants
CN103041769B (zh) * 2012-12-31 2015-01-28 东南大学 高温脱氯剂及其制备方法
CN105771619A (zh) * 2016-04-25 2016-07-20 张锐 一种复合脱硫剂及其制备方法
WO2018050799A1 (en) * 2016-09-15 2018-03-22 Paris Sciences Et Lettres - Quartier Latin A method for exchanging interlayer anions of a layered double hydroxide
JP2020533163A (ja) * 2017-09-08 2020-11-19 コモンウェルス サイエンティフィック アンド インダストリアル リサーチ オーガナイゼーション 水処理工程
CN108754203A (zh) * 2018-07-10 2018-11-06 上海大学 一种抗退化的铝硅系合金细化剂及其制备方法和应用
JP6898625B2 (ja) * 2019-04-19 2021-07-07 栗田工業株式会社 酸性排ガス処理剤、酸性排ガス処理方法、及び酸性排ガス処理設備
WO2020213281A1 (ja) * 2019-04-19 2020-10-22 栗田工業株式会社 酸性排ガス処理剤、酸性排ガス処理方法、及び酸性排ガス処理設備
JP6898627B2 (ja) * 2019-12-10 2021-07-07 栗田工業株式会社 炭酸型層状複水酸化物の再生方法、及び酸性排ガス処理設備
CN113416585B (zh) * 2021-07-09 2022-11-01 深圳灏权环保有限公司 一种吸附焦炉煤气中h2s的方法
CN114452811B (zh) * 2021-12-27 2023-03-17 深圳华明环保科技有限公司 一种脱硫脱硝剂及其制备方法
CN115999499A (zh) * 2022-12-27 2023-04-25 国家电投集团远达环保工程有限公司 一种用于脱除烟气中so3的吸附剂及其制备方法

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Also Published As

Publication number Publication date
IE911685A1 (en) 1991-12-18
KR920702248A (ko) 1992-09-03
US5114691A (en) 1992-05-19
EP0486676A4 (en) 1992-11-25
EP0486676A1 (en) 1992-05-27
EP0486676B1 (en) 1996-10-09
CN1057211A (zh) 1991-12-25
DE69122591D1 (de) 1996-11-14
MY106394A (en) 1995-05-30
WO1991018667A1 (en) 1991-12-12
ATE143827T1 (de) 1996-10-15
CA2064715A1 (en) 1991-12-09
KR950011824B1 (ko) 1995-10-11
JPH0722678B2 (ja) 1995-03-15
JPH04506932A (ja) 1992-12-03
DE69122591T2 (de) 1997-02-13

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