DE69122591T2 - Verfahren zum entfernen von sox aus rauchgasen und anderen gasströmen unter verwendung von sorbentien - Google Patents

Verfahren zum entfernen von sox aus rauchgasen und anderen gasströmen unter verwendung von sorbentien

Info

Publication number
DE69122591T2
DE69122591T2 DE69122591T DE69122591T DE69122591T2 DE 69122591 T2 DE69122591 T2 DE 69122591T2 DE 69122591 T DE69122591 T DE 69122591T DE 69122591 T DE69122591 T DE 69122591T DE 69122591 T2 DE69122591 T2 DE 69122591T2
Authority
DE
Germany
Prior art keywords
sorbents
gas flows
smoke gases
removing sox
ldh
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69122591T
Other languages
English (en)
Other versions
DE69122591D1 (de
Inventor
Thomas Pinnavaia
Jayantha Amarasekera
Christine Polansky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michigan State University MSU
Original Assignee
Michigan State University MSU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michigan State University MSU filed Critical Michigan State University MSU
Publication of DE69122591D1 publication Critical patent/DE69122591D1/de
Application granted granted Critical
Publication of DE69122591T2 publication Critical patent/DE69122591T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/78—Compounds containing aluminium and two or more other elements, with the exception of oxygen and hydrogen
    • C01F7/784—Layered double hydroxide, e.g. comprising nitrate, sulfate or carbonate ions as intercalating anions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/20—Two-dimensional structures
    • C01P2002/22—Two-dimensional structures layered hydroxide-type, e.g. of the hydrotalcite-type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/78—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by stacking-plane distances or stacking sequences

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
DE69122591T 1990-06-08 1991-05-28 Verfahren zum entfernen von sox aus rauchgasen und anderen gasströmen unter verwendung von sorbentien Expired - Fee Related DE69122591T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/535,147 US5114691A (en) 1990-01-18 1990-06-08 Process using sorbents for the removal of SOx from flue gas
PCT/US1991/003642 WO1991018667A1 (en) 1990-06-08 1991-05-28 PROCESS USING SORBENTS FOR THE REMOVAL OF SOx FROM FLUE GAS AND OTHER GAS STREAMS

Publications (2)

Publication Number Publication Date
DE69122591D1 DE69122591D1 (de) 1996-11-14
DE69122591T2 true DE69122591T2 (de) 1997-02-13

Family

ID=24133032

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69122591T Expired - Fee Related DE69122591T2 (de) 1990-06-08 1991-05-28 Verfahren zum entfernen von sox aus rauchgasen und anderen gasströmen unter verwendung von sorbentien

Country Status (12)

Country Link
US (1) US5114691A (de)
EP (1) EP0486676B1 (de)
JP (1) JPH0722678B2 (de)
KR (1) KR950011824B1 (de)
CN (1) CN1057211A (de)
AT (1) ATE143827T1 (de)
CA (1) CA2064715A1 (de)
DE (1) DE69122591T2 (de)
IE (1) IE911685A1 (de)
MX (1) MX171531B (de)
MY (1) MY106394A (de)
WO (1) WO1991018667A1 (de)

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US5334564A (en) * 1990-07-16 1994-08-02 Board Of Trustees Operating Michigan State University Method for the preparation of highly reactive clay composites for the removal of SOx from flue gas streams
US5364568A (en) * 1992-07-08 1994-11-15 Georgetown University Compounds and methods for separation and molecular encapsulation of metal ions
US5358701A (en) * 1992-11-16 1994-10-25 Board Of Trustees Operating Michigan State University Process of using layered double hydroxides as low temperature recyclable sorbents for the removal of SOx from flue gas and other gas streams
US5785938A (en) * 1992-11-16 1998-07-28 Board Of Trustees Operating Michigan State University Process using recyclable sorbents for the removal of sox from flue gases and other gas streams
US5302709A (en) * 1992-11-25 1994-04-12 Board Of Trustees Operating Michigan State University Polyaryl-metallic complex intercalated layered double hydroxides
US5415850A (en) * 1993-02-24 1995-05-16 The Research Foundation Of State Univeristy Of New York Pillared interlayered clay catalysts for the selective reduction of nitrogen oxides with ammonia
HU221182B1 (en) * 1994-06-09 2002-08-28 Alstom Power Inc Improved entrainment separator for high velocity gases and reheating of scrubber gases
US5928496A (en) * 1996-06-20 1999-07-27 Contract Materials Processing, Inc. Hydrotalcite sulfer oxide sorption
US6028023A (en) 1997-10-20 2000-02-22 Bulldog Technologies U.S.A., Inc. Process for making, and use of, anionic clay materials
US6074437A (en) * 1998-12-23 2000-06-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Bleaching with polyoxometalates and air or molecular oxygen
US20030049191A1 (en) * 1999-12-11 2003-03-13 Twigg Martyn Vincent Process for treating exhaust gas including sox
AU2001286831A1 (en) * 2000-08-25 2002-03-04 Apyron Technologies, Inc. Adsorbent and/or catalyst compounds promoted with halide ions and methods of making and using thereof
US6662951B1 (en) * 2000-09-27 2003-12-16 Basic Resources, Inc. Process for extracting and purifying naturally occurring zeolite
JP4574884B2 (ja) * 2001-03-27 2010-11-04 住友重機械工業株式会社 排ガス処理システムの硫酸回収方法及び硫酸回収装置
CN1245079C (zh) * 2002-12-13 2006-03-15 北京化工大学 一种超分子结构草甘膦缓释剂及其制备方法
US20050100493A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050161410A1 (en) * 2003-11-06 2005-07-28 Wilson Gregg L. System, method and composition for treatment of wastewater
US20050100494A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US6998100B2 (en) * 2003-11-19 2006-02-14 Toll Processing And Consulting, Llc Sulfur oxide sorption with layered chlorite-type contact solids
US7304011B2 (en) * 2004-04-15 2007-12-04 W.R. Grace & Co. -Conn. Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US20050232839A1 (en) * 2004-04-15 2005-10-20 George Yaluris Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US7238288B1 (en) 2004-08-13 2007-07-03 Sandia Corporation Method for absorbing an ion from a fluid
WO2006104612A2 (en) * 2005-03-24 2006-10-05 W.R. Grace & Co.-Conn. Method for controlling nox emissions in the fccu
CN101166574B (zh) 2005-04-27 2011-09-21 格雷斯公司 用于减少流化催化裂化过程中的NOx排放物的组合物和方法
JP4535016B2 (ja) * 2006-03-28 2010-09-01 住友ベークライト株式会社 塩化ビニル樹脂組成物、それを用いて作製した塩化ビニル樹脂シートおよび成形体
CN101631844A (zh) * 2006-10-31 2010-01-20 英特卡有限公司 用于部分氧化条件下的氧化硫移除添加剂及方法
US20100135884A1 (en) * 2009-06-26 2010-06-03 Manuela Serban Process for Desulfurization of Hot Fuel Gases
US20100327224A1 (en) * 2009-06-26 2010-12-30 Manuela Serban Compounds for Desulfurization of Hot Fuel Gases
CN103589450B (zh) * 2012-08-14 2015-11-04 中国科学院大连化学物理研究所 一种柴油的超深度氧化脱硫方法
US9951196B2 (en) 2012-10-24 2018-04-24 J.M. Huber Corporation Cationic polyoxometalate-coated alumina trihydrate dispersants
CN103041769B (zh) * 2012-12-31 2015-01-28 东南大学 高温脱氯剂及其制备方法
CN105771619A (zh) * 2016-04-25 2016-07-20 张锐 一种复合脱硫剂及其制备方法
WO2018050799A1 (en) * 2016-09-15 2018-03-22 Paris Sciences Et Lettres - Quartier Latin A method for exchanging interlayer anions of a layered double hydroxide
CA3075118A1 (en) * 2017-09-08 2019-03-14 Commonwealth Scientific And Industrial Research Organisation Water treatment process
CN108754203A (zh) * 2018-07-10 2018-11-06 上海大学 一种抗退化的铝硅系合金细化剂及其制备方法和应用
KR102558233B1 (ko) * 2019-04-19 2023-07-21 쿠리타 고교 가부시키가이샤 산성 배기가스 처리제, 산성 배기가스 처리방법 및 산성 배기가스 처리설비
JP6898625B2 (ja) * 2019-04-19 2021-07-07 栗田工業株式会社 酸性排ガス処理剤、酸性排ガス処理方法、及び酸性排ガス処理設備
JP6898627B2 (ja) * 2019-12-10 2021-07-07 栗田工業株式会社 炭酸型層状複水酸化物の再生方法、及び酸性排ガス処理設備
CN113416585B (zh) * 2021-07-09 2022-11-01 深圳灏权环保有限公司 一种吸附焦炉煤气中h2s的方法
CN114452811B (zh) * 2021-12-27 2023-03-17 深圳华明环保科技有限公司 一种脱硫脱硝剂及其制备方法
CN115999499A (zh) * 2022-12-27 2023-04-25 国家电投集团远达环保工程有限公司 一种用于脱除烟气中so3的吸附剂及其制备方法

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US3879523A (en) * 1969-12-12 1975-04-22 Kyowa Chem Ind Co Ltd Composite metal hydroxides
US3699037A (en) * 1970-10-28 1972-10-17 Chevron Res Catalytic cracking
US3835031A (en) * 1973-05-23 1974-09-10 Standard Oil Co Catalytic cracking with reduced emission of sulfur oxides
US4153534A (en) * 1975-12-19 1979-05-08 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
JPS5456089A (en) * 1977-10-12 1979-05-04 Kyowa Kagaku Kougiyou Kk Desulfurizing agent
US4472532A (en) * 1982-11-29 1984-09-18 Atlantic Richfield Company Preparative process for alkaline earth metal, aluminum-containing spinels
US4454244A (en) * 1983-03-28 1984-06-12 Ashland Oil, Inc. New compositions
US4492678A (en) * 1984-05-17 1985-01-08 Atlantic Richfield Company Preparative process for alkaline earth metal, aluminum-containing spinels and their use for reducing sulfur oxide content in gases
US4866019A (en) * 1987-01-13 1989-09-12 Akzo N.V. Catalyst composition and absorbent which contain an anionic clay
US4774212A (en) * 1987-12-22 1988-09-27 Amoco Corporation Pillared hydrotalcites
US5116587A (en) * 1990-01-18 1992-05-26 Board Of Trustees Operating Michigan State University Layered double hydroxide sorbents for the removal of sox from flue gas resulting from coal combustion
US5075089A (en) * 1990-03-20 1991-12-24 Aluminum Company Of America Method of making pillared hydrotalcites and associated products
US5079203A (en) * 1990-05-25 1992-01-07 Board Of Trustees Operating Michigan State University Polyoxometalate intercalated layered double hydroxides

Also Published As

Publication number Publication date
JPH0722678B2 (ja) 1995-03-15
KR950011824B1 (ko) 1995-10-11
MX171531B (es) 1993-11-03
EP0486676A4 (en) 1992-11-25
DE69122591D1 (de) 1996-11-14
JPH04506932A (ja) 1992-12-03
KR920702248A (ko) 1992-09-03
EP0486676B1 (de) 1996-10-09
EP0486676A1 (de) 1992-05-27
CN1057211A (zh) 1991-12-25
US5114691A (en) 1992-05-19
IE911685A1 (en) 1991-12-18
MY106394A (en) 1995-05-30
WO1991018667A1 (en) 1991-12-12
CA2064715A1 (en) 1991-12-09
ATE143827T1 (de) 1996-10-15

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee