MX171229B - Fibra elastica mejorada, hilada en seco con segmentos blandos de copolimero y procedimiento para su fabricacion - Google Patents

Fibra elastica mejorada, hilada en seco con segmentos blandos de copolimero y procedimiento para su fabricacion

Info

Publication number
MX171229B
MX171229B MX016185A MX1618589A MX171229B MX 171229 B MX171229 B MX 171229B MX 016185 A MX016185 A MX 016185A MX 1618589 A MX1618589 A MX 1618589A MX 171229 B MX171229 B MX 171229B
Authority
MX
Mexico
Prior art keywords
diamine
elastic fiber
copolymer
procedure
manufacture
Prior art date
Application number
MX016185A
Other languages
English (en)
Inventor
Richard Lewis Dreibelbis
Nathan Eli Houser
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of MX171229B publication Critical patent/MX171229B/es

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4858—Polyethers containing oxyalkylene groups having more than four carbon atoms in the alkylene group
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

La presente invención se refiere a una fibra elástica hilada en seco, mejorada, de polímero spandex de poliuretano-urea a base de poliéter, que tiene segmentos blandos y duros, polímero que es el producto de un copolímero terminado en hidroxilo de tetrahidrofurano y 3-metiltetrahidrofurano, que se terminó en un extremo con diisocianato orgánico y después se le extendió la cadena con la diamina, en donde la mejora comprende, que los extendedores de cadena sean una mezcla de dos diaminas, seleccionándose la primera diamina de etilendiamina, 1,3-propilendiamina y 1,4-ciclohexillendiamina y la segunda diamina es un coextendedor que se selecciona de 2-metilpentametilendiamina, m-fenilendiamina hidrogenada y 1,2-propilendiamina, el coextendedor es de 20 a 50 por ciento molar de la mezcla de diamina, y el segmento duro es de 5.5 a 9 por ciento molar del polímero.
MX016185A 1988-05-26 1989-05-25 Fibra elastica mejorada, hilada en seco con segmentos blandos de copolimero y procedimiento para su fabricacion MX171229B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/199,088 US5000899A (en) 1988-05-26 1988-05-26 Spandex fiber with copolymer soft segment

Publications (1)

Publication Number Publication Date
MX171229B true MX171229B (es) 1993-10-12

Family

ID=22736159

Family Applications (1)

Application Number Title Priority Date Filing Date
MX016185A MX171229B (es) 1988-05-26 1989-05-25 Fibra elastica mejorada, hilada en seco con segmentos blandos de copolimero y procedimiento para su fabricacion

Country Status (9)

Country Link
US (1) US5000899A (es)
EP (1) EP0343985B1 (es)
JP (1) JP2897254B2 (es)
KR (1) KR970007430B1 (es)
CN (1) CN1038318A (es)
BR (1) BR8902408A (es)
CA (1) CA1318048C (es)
DE (1) DE68917212T2 (es)
MX (1) MX171229B (es)

Families Citing this family (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4973647A (en) * 1989-05-31 1990-11-27 E. I. Du Pont De Nemours And Company Fiber from polyether-based spandex
US5094914A (en) * 1990-12-20 1992-03-10 E. I. Du Pont De Nemours And Company Microporous elastic segmented polyurethane shaped structure
US5126181A (en) * 1991-09-23 1992-06-30 E. I. Du Pont De Nemours And Company Microporous discs of elastic segmented polyurethane
DE4228884A1 (de) * 1992-08-29 1994-03-03 Basf Ag Verfahren zur Herstellung von Reduktionsprodukten von Derivaten der 4-Hydroxybuttersäure
US5391343A (en) * 1992-10-26 1995-02-21 E. I. Du Pont De Nemours And Company Thin-walled articles of polyurethaneurea
US5728340A (en) * 1992-10-26 1998-03-17 E. I. Du Pont De Nemours And Company Process for polyesterurethaneurea thin-walled articles
US5354837A (en) * 1992-12-22 1994-10-11 Hodogaya Chemical Co., Ltd. Low-temperature liquid urethane prepolymer
JP3213744B2 (ja) * 1993-03-17 2001-10-02 保土谷化学工業株式会社 ポリウレア及びポリウレタンウレア樹脂の製造方法
US5362432A (en) * 1993-04-02 1994-11-08 E. I. Du Pont De Nemours And Company Process for dry spinning spandex
US5539037A (en) * 1993-09-30 1996-07-23 E. I. Du Pont De Nemours And Company Spandex containing certain alkali metal salts
US5962130A (en) * 1995-01-03 1999-10-05 Dupont-Toray Co., Ltd. Durable polyurethane fiber and method for the manufacture thereof
US5800920A (en) * 1994-03-04 1998-09-01 Dupont Toray Durable polyurethane fiber and method for the manufacture thereof
JP3422857B2 (ja) * 1994-04-04 2003-06-30 保土谷化学工業株式会社 広いゴム領域を有する熱可塑性ポリウレタン樹脂及びその製造法
KR100239204B1 (ko) * 1995-06-23 2000-01-15 야마모토 카즈모토 폴리우레탄 탄성 섬유 및 그의 제조 방법
US5626960A (en) * 1995-09-07 1997-05-06 E. I. Du Pont De Nemours And Company Spandex containing a huntite and hydromagnesite additive
EP0907771B1 (en) * 1996-06-24 2003-02-12 E.I. Du Pont De Nemours And Company Polyurethane fibers and films
US6248197B1 (en) * 1996-07-02 2001-06-19 E. I. Du Pont De Nemours And Company Method for producing a shaped multifilament, non-thermoplastic, elastomeric yarn
US5644015A (en) * 1996-07-24 1997-07-01 Hyosung T & C Co., Ltd. Process of manufacturing improved polyurethane fiber polymer
US5691441A (en) * 1996-10-11 1997-11-25 Arco Chemical Technology, L.P. Spandex elastomers
US5708118A (en) * 1996-10-11 1998-01-13 Arco Chemical Technology, L.P. Spandex elastomers
US5723563A (en) * 1996-10-11 1998-03-03 Arco Chemical Technology, L.P. Spandex elastomers
WO1998033962A1 (en) * 1997-01-31 1998-08-06 E.I. Du Pont De Nemours And Company Spandex with low tackiness and process for making same
KR100495019B1 (ko) * 1997-03-05 2005-06-14 듀폰 도레이 컴파니, 리미티드 안정한 폴리우레탄우레아 용액
US6225435B1 (en) 1997-03-05 2001-05-01 Dupont Toray Co. Ltd. Stable polyurethaneurea solutions
JPH10279573A (ja) * 1997-04-02 1998-10-20 Mitsubishi Gas Chem Co Inc ３−メチルテトラヒドロフランの製造方法
US5959059A (en) * 1997-06-10 1999-09-28 The B.F. Goodrich Company Thermoplastic polyether urethane
GB9721588D0 (en) 1997-10-10 1997-12-10 Du Pont Textile treatment
US6096252A (en) * 1998-01-29 2000-08-01 Dupont Toray Co., Ltd. Process of making polyurethane fiber
US5948875A (en) * 1998-03-26 1999-09-07 E. I. Du Pont De Nemours And Company Polyurethaneureas and spandex made therefrom
US6300463B1 (en) 1999-01-29 2001-10-09 E. I. Du Pont De Nemours And Company Thermoplastic elastomers
US6337384B1 (en) * 2000-01-18 2002-01-08 Sandia Corporation Method of making thermally removable epoxies
US6472494B2 (en) 2000-04-26 2002-10-29 E. I. Du Pont De Nemours And Company Spandex with high heat-set efficiency
TW589421B (en) * 2000-04-26 2004-06-01 Du Pont Spandex with high heat-set efficiency
US20040019146A1 (en) * 2000-12-20 2004-01-29 Hiroshi Nishikawa Elastomeric polyurethane fiber with high heat-set efficiency
WO2002086208A1 (en) * 2001-04-19 2002-10-31 Kolon Industries, Inc A polyurethane type elastic fiber, and a process of preparing for the same
KR100710737B1 (ko) 2001-07-24 2007-04-23 라디시스판덱스 코포레이션 개선된 스판덱스 조성물
US6503996B1 (en) 2001-11-14 2003-01-07 Dupont Dow Elastomers L.L.C. High-uniformity spandex and process for making spandex
US6984708B2 (en) 2002-10-04 2006-01-10 Invista North America S.A.R.L. Spandex of a particular composition and process for making same
US6720403B1 (en) 2002-11-01 2004-04-13 E.I. Dupont De Nemours And Co. Polyurethaneurea and spandex comprising same
US7357889B2 (en) 2003-04-09 2008-04-15 Lubrizol Advanced Materials, Inc. Melt spun TPU fibers and process
US6916896B2 (en) * 2003-05-05 2005-07-12 Invista North America S.A.R.L. High productivity spandex fiber process and product
US7838617B2 (en) * 2003-05-05 2010-11-23 Invista North America S.àr.l. Dyeable spandex
KR100524323B1 (ko) * 2003-09-01 2005-10-26 주식회사 효성 높은 모듈러스, 내알칼리성 및 내열성을 가진 탄성사 제조방법
KR100598870B1 (ko) * 2003-11-25 2006-07-10 태광산업주식회사 내열성과 세트성이 우수한 폴리우레탄우레아 탄성섬유 및그의 제조방법
DE602005023978D1 (de) * 2004-04-15 2010-11-18 Textronics Inc Elektrisch leitende elastomere, verfahren zu ihrer herstellung und artikel damit
JP4905132B2 (ja) 2004-10-20 2012-03-28 旭硝子株式会社 ウレタン樹脂溶液、その製造方法及びウレタン樹脂の製造方法
JP4539656B2 (ja) * 2004-10-21 2010-09-08 旭硝子株式会社 ポリウレタン樹脂およびポリウレタン樹脂溶液の製造方法
US20060135724A1 (en) * 2004-12-20 2006-06-22 Lawrey Bruce D Spandex having low heat-set temperature and materials for their production
US7300331B2 (en) * 2005-10-11 2007-11-27 Invista North America S.Ar.L. Brassiere construction using multiple layers of fabric
US20070174972A1 (en) * 2005-11-14 2007-08-02 Invista North America S.A R.I. Spandex having enhanced whiteness, and fabrics and garments comprising the same
KR100711644B1 (ko) * 2006-07-31 2007-04-25 주식회사 효성 열세트성이 향상된 폴리우레탄 탄성사
US8765832B2 (en) 2011-10-14 2014-07-01 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked compositions and methods of making them
US7867433B2 (en) * 2008-05-30 2011-01-11 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked articles
EP2687625B2 (en) 2011-03-14 2022-04-27 Asahi Kasei Kabushiki Kaisha Polyurethane elastic fibers
US8524919B2 (en) 2011-10-18 2013-09-03 Empire Technology Development Llc Active polymeric filters
KR101426208B1 (ko) * 2013-08-20 2014-08-01 주식회사 효성 균일성과 열세트성이 우수한 폴리우레탄우레아 탄성사
CN104353776A (zh) * 2014-10-27 2015-02-18 大丰市洪联铸钢有限责任公司 一种轧钢机机架的铸造工艺
US20180305842A1 (en) * 2015-06-30 2018-10-25 Invista North America S.A R.L. Polyurethane fiber including copolymer polyol
EP3724248B1 (en) * 2017-12-15 2022-08-10 The LYCRA Company UK Limited Polymers with engineered segment molecular weights
WO2019209348A1 (en) 2018-04-28 2019-10-31 Liang Wang Polyurethane elastomer with high ultimate elongation
US10945501B2 (en) 2019-05-30 2021-03-16 Alfonso Aguayo González Stretchable reusable bag
CN116261581A (zh) 2020-12-17 2023-06-13 巴斯夫欧洲公司 从含己内酰胺的聚合物和含聚氨酯的聚合物，特别是聚氨酯嵌段共聚物的混合物选择性解聚聚酰胺6以得到己内酰胺
KR20240024997A (ko) 2021-06-28 2024-02-26 바스프 에스이 폴리우레탄 우레아 섬유 또는 필름 및 그의 제조 방법
WO2023169913A1 (en) 2022-03-10 2023-09-14 Basf Se Polyurethane urea and its preparation method
JP2024076480A (ja) 2022-11-25 2024-06-06 東レ・オペロンテックス株式会社 ポリウレタン弾性繊維
WO2024175671A1 (en) 2023-02-22 2024-08-29 Basf Se Process for depolymerizing polyamide prepared from caprolactam

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2929804A (en) * 1955-01-31 1960-03-22 Du Pont Elastic filaments of linear segmented polymers
US3180854A (en) * 1961-06-14 1965-04-27 Polythane Corp Double diamine modification of urethane prepolymers
US3499040A (en) * 1964-06-29 1970-03-03 Eastman Kodak Co Copolymeric ether glycol and process for its manufacture
US3428711A (en) * 1966-02-01 1969-02-18 Du Pont Hindered polymeric tertiary amines as stabilizers for polyurethanes
US3642703A (en) * 1967-08-29 1972-02-15 Asahi Chemical Ind Method of improving the stability of polyurethane solutions
USRE29623E (en) * 1972-05-04 1978-05-02 Bayer Aktiengesellschaft Polyurethane-ureas based on cis-trans-1,4-diaminocyclohexane
US4296174A (en) * 1980-08-08 1981-10-20 E. I. Du Pont De Nemours And Company Spandex filaments containing certain metallic soaps
US4590285A (en) * 1983-06-08 1986-05-20 E. I. Du Pont De Nemours And Company Process for preparing a mixture of tetrahydrofuran and 3-alkyl tetrahydrofuran and copolymers thereof
US4590312A (en) * 1983-06-08 1986-05-20 E. I. Du Pont De Nemours And Company Process for preparing 2-alkyl-1,4-butanediols
CA1280232C (en) * 1986-09-30 1991-02-12 Gary Arthur Lodoen Polyester-based spandex filament
DE3641703A1 (de) * 1986-12-06 1988-06-16 Bayer Ag Hochdehnbare elasthanfasern mit verbesserten eigenschaften
US4798880A (en) * 1987-12-30 1989-01-17 E. I. Du Pont De Nemours And Company Spandex formed with a mixture of diamines

Also Published As

Publication number Publication date
EP0343985A2 (en) 1989-11-29
JP2897254B2 (ja) 1999-05-31
JPH0219511A (ja) 1990-01-23
EP0343985A3 (en) 1990-11-28
US5000899A (en) 1991-03-19
DE68917212T2 (de) 1995-02-16
CA1318048C (en) 1993-05-18
CN1038318A (zh) 1989-12-27
BR8902408A (pt) 1990-01-16
EP0343985B1 (en) 1994-08-03
KR890017396A (ko) 1989-12-16
KR970007430B1 (ko) 1997-05-08
DE68917212D1 (de) 1994-09-08

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