MX167040B - Catalizador de zeolita l mejorado para reformacion - Google Patents
Catalizador de zeolita l mejorado para reformacionInfo
- Publication number
- MX167040B MX167040B MX008492A MX849283A MX167040B MX 167040 B MX167040 B MX 167040B MX 008492 A MX008492 A MX 008492A MX 849283 A MX849283 A MX 849283A MX 167040 B MX167040 B MX 167040B
- Authority
- MX
- Mexico
- Prior art keywords
- zeolite
- catalyst
- group
- time
- period
- Prior art date
Links
- 229910021536 Zeolite Inorganic materials 0.000 title abstract 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 7
- 239000010457 zeolite Substances 0.000 title abstract 7
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 238000002407 reforming Methods 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract 1
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
- B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
- B01J29/62—Noble metals
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La presente invención se refiere a un catalizador para reformación de hidrocarburos, que comprende; una zeolita teniendo cationes intercambiables de los cuales al menos 90 por ciento son iones metálicos seleccionados del grupo que consiste de sodio, bario, litio, potadio, rubidio y cesio y conteniendo al menos un metal seleccionadl del grupo que consiste en el Grupo VIII de la Tabla Periódica de los elementos y teniendo un efecto deshidrociclizador, la zeolita producida por inmersión de una zeolita tipo L antes de calcinar el metal de deshidrociclización cargado en la zeolita L en una solución alcalina teniendo un pH de al menos 11 por un tiempo y a una temperatura efectivos para incrmentar el periódo de un tiempo en que se mantiene la actividad catalítica del catalizador bajo condiciones de reformación. Una zeolita tipo L en una solución de álcali teniendo un pH al menos de 11 bajo una temperatura y por un periódo de tiempo efectivos para incrementar el periódo de tiempo en el cual se mantiene la actividad catalítica. Un proceso de reformación para producir hidrocarburos, conteniendo parafinas al menos C6, que comprende, poner en contacto la alimentación de hidrocarburos en presencia de hidrógeno a temperaturas elevadas con un catalizador que comprende una zeolita tipo L teniendo cationes intercambiables de los cuales al menos un 90 por ciento son iones de metal alcalino y conteniendo al menos un metal seleccionado del grupo que consiste en el Grupo VIII:
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/426,211 US4448891A (en) | 1982-09-28 | 1982-09-28 | Zeolite L catalyst for reforming |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX167040B true MX167040B (es) | 1993-02-26 |
Family
ID=23689806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX008492A MX167040B (es) | 1982-09-28 | 1983-09-28 | Catalizador de zeolita l mejorado para reformacion |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4448891A (es) |
| EP (1) | EP0107389B1 (es) |
| JP (1) | JPS5980333A (es) |
| AU (1) | AU563412B2 (es) |
| BR (1) | BR8305312A (es) |
| CA (1) | CA1202017A (es) |
| DE (1) | DE3378729D1 (es) |
| EG (1) | EG16078A (es) |
| ES (2) | ES8600372A1 (es) |
| MX (1) | MX167040B (es) |
| NO (1) | NO157966C (es) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4517306A (en) * | 1982-02-01 | 1985-05-14 | Chevron Research Company | Composition and a method for its use in dehydrocyclization of alkanes |
| US4595670A (en) * | 1983-11-10 | 1986-06-17 | Exxon Research And Engineering Co. | Zeolite catalyst |
| US4552856A (en) * | 1983-11-10 | 1985-11-12 | Exxon Research And Engineering Co. | Zeolite catalyst and preparation thereof |
| US4623632A (en) * | 1984-11-05 | 1986-11-18 | Uop Inc. | Catalytic composite for conversion of hydrocarbons and the method of preparation and use thereof |
| US4568656A (en) * | 1984-12-07 | 1986-02-04 | Exxon Research & Engineering Co. | Process for loading platinum into Zeolite-L |
| US4698322A (en) * | 1985-04-17 | 1987-10-06 | Chevron Research Company | Highly active and highly selective aromatization catalyst |
| JPH0780798B2 (ja) * | 1985-11-06 | 1995-08-30 | 東ソー株式会社 | 改良ゼオライト触媒によるハロゲン化ベンゼン誘導体の製造法 |
| JPH0829255B2 (ja) * | 1986-10-04 | 1996-03-27 | 出光興産株式会社 | 芳香族炭化水素製造用触媒およびこれを用いた芳香族炭化水素の製造方法 |
| JPH083098B2 (ja) * | 1987-12-19 | 1996-01-17 | 出光興産株式会社 | 芳香族炭化水素の製造方法 |
| US4990710A (en) * | 1988-06-24 | 1991-02-05 | Mobil Oil Corporation | Tin-containing microporous crystalline materials and their use as dehydrogenation, dehydrocyclization and reforming catalysts |
| US4830729A (en) * | 1987-12-28 | 1989-05-16 | Mobil Oil Corporation | Dewaxing over crystalline indium silicates containing groups VIII means |
| US4935566A (en) * | 1987-11-17 | 1990-06-19 | Mobil Oil Corporation | Dehydrocyclization and reforming process |
| US4849567A (en) * | 1987-12-28 | 1989-07-18 | Mobil Oil Corporation | Catalytic dehydrogenation of hydrocarbons over indium-containing crystalline microporous materials |
| US5013423A (en) * | 1987-11-17 | 1991-05-07 | Mobil Oil Corporation | Reforming and dehydrocyclization |
| US4886926A (en) * | 1988-06-24 | 1989-12-12 | Mobil Oil Corporation | Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials |
| US4982028A (en) * | 1987-12-28 | 1991-01-01 | Mobil Oil Corporation | Dehydrogenation and dehydrocyclization catalyst |
| US4822942A (en) * | 1987-12-28 | 1989-04-18 | Mobil Oil Corporation | Styrene production |
| US4922050A (en) * | 1987-12-28 | 1990-05-01 | Mobil Oil Corporation | Catalytic dehydrogenation of hydrocarbons over indium-containing crystalline microporous materials |
| GB8801067D0 (en) * | 1988-01-19 | 1988-02-17 | Exxon Chemical Patents Inc | Zeolite l preparation |
| US4897177A (en) * | 1988-03-23 | 1990-01-30 | Exxon Chemical Patents Inc. | Process for reforming a hydrocarbon fraction with a limited C9 + content |
| DE68917627T2 (de) * | 1988-03-31 | 1995-01-26 | Exxon Chemical Patents Inc | Verfahren zum Reformieren einer dimethylbutanfreien Kohlenwasserstofffraktion. |
| US5192728A (en) * | 1988-06-24 | 1993-03-09 | Mobil Oil Corporation | Tin-colating microporous crystalline materials and their use as dehydrogenation, dehydrocyclization reforming catalysts |
| US4910357A (en) * | 1988-06-24 | 1990-03-20 | Mobil Oil Corporation | Alkylate upgrading |
| US4931416A (en) * | 1988-06-24 | 1990-06-05 | Mobil Oil Corporation | Thallium or lead-containing microporous crystalline materials and their use as dehydrogenation dehydrocyclization and reforming catalysts |
| US4892645A (en) * | 1988-06-24 | 1990-01-09 | Mobil Oil Corporation | Dewaxing catalyst based on tin containing materials |
| US4882040A (en) * | 1988-06-24 | 1989-11-21 | Mobil Oil Corporation | Reforming process |
| US4851599A (en) * | 1988-06-24 | 1989-07-25 | Mobil Oil Corporation | Styrene production |
| US4987109A (en) * | 1988-10-19 | 1991-01-22 | Exxon Chemical Patents Inc. | Zeolites for reforming catalysts |
| US5152884A (en) * | 1988-10-19 | 1992-10-06 | Exxon Chemicals Patents Inc. | Zeolites for reforming catalysts |
| US5124497A (en) * | 1989-10-11 | 1992-06-23 | Mobil Oil Corporation | Production of mono-substituted alkylaromatics from C8 +N-paraffins |
| US5037529A (en) * | 1989-12-29 | 1991-08-06 | Mobil Oil Corp. | Integrated low pressure aromatization process |
| US5122489A (en) * | 1990-10-15 | 1992-06-16 | Mobil Oil Corporation | Non-acidic dehydrogenation catalyst of enhanced stability |
| US5147837A (en) * | 1990-10-22 | 1992-09-15 | Mobil Oil Corporation | Titania containing dehydrogenation catalysts |
| US5103066A (en) * | 1990-12-10 | 1992-04-07 | Mobil Oil Corp. | Dehydrogenation of alcohols over non-acidic metal-zeolite catalysts |
| US5294579A (en) * | 1991-02-05 | 1994-03-15 | Idemitsu Kosan Co., Ltd. | L-type zeolite and catalyst for the production of aromatic hydrocarbons |
| US5354933A (en) * | 1991-02-05 | 1994-10-11 | Idemitsu Kosan Co., Ltd. | Process for producing aromatic hydrocarbons |
| KR100236809B1 (ko) * | 1991-09-30 | 2000-01-15 | 벤 씨. 카덴헤드 | 제올라이트의 미세여과 |
| JP2606991B2 (ja) * | 1991-10-03 | 1997-05-07 | 出光興産株式会社 | 失活触媒の再生方法 |
| US5736478A (en) * | 1995-03-24 | 1998-04-07 | Wisconsin Alumni Research Foundation | Catalyst to dehydrogenate paraffin hydrocarbons |
| US5897846A (en) * | 1997-01-27 | 1999-04-27 | Asec Manufacturing | Catalytic converter having a catalyst with noble metal on molecular sieve crystal surface and method of treating diesel engine exhaust gas with same |
| US5898011A (en) * | 1997-08-28 | 1999-04-27 | Phillips Petroleum Company | Hydrocarbon conversion catalyst composition and processes therefor and therewith |
| US6004452A (en) * | 1997-11-14 | 1999-12-21 | Chevron Chemical Company Llc | Process for converting hydrocarbon feed to high purity benzene and high purity paraxylene |
| US6207042B1 (en) | 1998-01-08 | 2001-03-27 | Chevron Chemical Company Llc | Reforming using a bound halided zeolite catalyst |
| MXPA00009407A (es) * | 2000-09-26 | 2004-12-08 | Mexicano Inst Petrol | Procedimiento para la preparacion de un catalizador monometalico de tipo zeolitico para la obtencion de gasolinas de alto octando mediante reformacion de naftas. |
| JP4537091B2 (ja) * | 2004-03-01 | 2010-09-01 | エヌ・イーケムキャット株式会社 | 水素ガス中の一酸化炭素除去用触媒 |
| US9153356B2 (en) * | 2010-02-27 | 2015-10-06 | Empire Technology Development Llc | High dielectric permittivity materials from composites of low dimensional metallic systems |
| US10226761B2 (en) * | 2016-12-20 | 2019-03-12 | Chevron Phillips Chemical Company, Lp | Aromatization catalyst preparation with alkali metal present during a washing step |
| CN113856742B (zh) * | 2020-06-30 | 2023-07-11 | 中国石油化工股份有限公司 | 固体酸催化剂及其制备方法和烷基化反应的方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3326797A (en) * | 1964-05-22 | 1967-06-20 | Union Oil Co | Hydrocarbon conversion process and catalyst comprising a crystalline alumino-silicate leached with sodium hydroxide |
| US3418256A (en) * | 1965-05-26 | 1968-12-24 | Exxon Research Engineering Co | Catalyst regeneration |
| US3631120A (en) * | 1969-06-13 | 1971-12-28 | Exxon Research Engineering Co | Alkylation of aromatic hydrocarbons |
| US3867512A (en) * | 1969-09-10 | 1975-02-18 | Union Oil Co | Method of preparing crystalline {37 l{38 {0 zeolite |
| US4048111A (en) * | 1975-06-12 | 1977-09-13 | Uop Inc. | Method for manufacturing an adsorbent useful for olefin separation |
| FR2323664A1 (fr) * | 1975-09-10 | 1977-04-08 | Erap | Procede de deshydrocyclisation d'hydrocarbures aliphatiques |
| ZA805231B (en) * | 1980-05-19 | 1981-08-26 | Mobil Oil Corp | Low acidity alkali metal containing zeolites |
-
1982
- 1982-09-28 US US06/426,211 patent/US4448891A/en not_active Expired - Lifetime
-
1983
- 1983-09-27 BR BR8305312A patent/BR8305312A/pt not_active IP Right Cessation
- 1983-09-27 ES ES525973A patent/ES8600372A1/es not_active Expired
- 1983-09-27 NO NO833484A patent/NO157966C/no unknown
- 1983-09-27 AU AU19624/83A patent/AU563412B2/en not_active Ceased
- 1983-09-27 CA CA000437673A patent/CA1202017A/en not_active Expired
- 1983-09-28 JP JP58180099A patent/JPS5980333A/ja active Pending
- 1983-09-28 MX MX008492A patent/MX167040B/es unknown
- 1983-09-28 DE DE8383305853T patent/DE3378729D1/de not_active Expired
- 1983-09-28 EP EP83305853A patent/EP0107389B1/en not_active Expired
- 1983-09-28 EG EG605/83A patent/EG16078A/xx active
-
1985
- 1985-04-16 ES ES542275A patent/ES542275A0/es active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| NO833484L (no) | 1984-03-29 |
| DE3378729D1 (en) | 1989-01-26 |
| ES525973A0 (es) | 1985-10-01 |
| ES8603292A1 (es) | 1985-12-16 |
| EP0107389A3 (en) | 1986-05-14 |
| ES542275A0 (es) | 1985-12-16 |
| EP0107389B1 (en) | 1988-12-21 |
| EG16078A (en) | 1986-12-30 |
| BR8305312A (pt) | 1984-05-08 |
| CA1202017A (en) | 1986-03-18 |
| US4448891A (en) | 1984-05-15 |
| JPS5980333A (ja) | 1984-05-09 |
| AU563412B2 (en) | 1987-07-09 |
| ES8600372A1 (es) | 1985-10-01 |
| EP0107389A2 (en) | 1984-05-02 |
| NO157966B (no) | 1988-03-14 |
| NO157966C (no) | 1988-06-22 |
| AU1962483A (en) | 1984-04-05 |
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