MX166301B - Procedimiento para preparar un copolimero de bloque - Google Patents

Procedimiento para preparar un copolimero de bloque

Info

Publication number
MX166301B
MX166301B MX005578A MX557887A MX166301B MX 166301 B MX166301 B MX 166301B MX 005578 A MX005578 A MX 005578A MX 557887 A MX557887 A MX 557887A MX 166301 B MX166301 B MX 166301B
Authority
MX
Mexico
Prior art keywords
stage
monomer
polymerization
conjugated diene
monovinylaromatic
Prior art date
Application number
MX005578A
Other languages
English (en)
Inventor
Alonzo Gene Kitichen
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of MX166301B publication Critical patent/MX166301B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerization Catalysts (AREA)
  • Catching Or Destruction (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

La presente invención se refiere a un procedimiento para preparar un copolímero de bloque mediante el modo en secuencia de copolimerización de caracterizado porque consiste de: polimerizar bajo condiciones de polimerización de solución, por lo menos un monómero monovinilaromático que contiene de 8 a 12 átomos de carbono y por lo menos un monómero de dieno conjugado que contiene de 4 a 6 átomos de carbono, en una relación de aproximadamente 55 por ciento a 95 por ciento en peso del monómero monovinilaromático y de 45 por ciento a 5 por ciento en peso del monómero de dieno conjugado, mediante un procedimiento de polimerización de carga en secuencia, en donde por lo menos dos cargas separadas que consiste del monómero monovinilaromático y un iniciador de metal organomonoalcalino preceden una carga separada del monómero de dieno conjugado seguido por la carga adicional separada del monómero monovinilaromático y el iniciador antes de las cargas individuales consecutivas del dieno conjugado y de los monómeros monovinilaromáticos; cada carga monomérica se polimeriza hasta completarse esencialmente antes de la adición de cualquier carga subsecuente. en donde procedimiento de polimerización de carga en secuencia emplea una secuencia de carga de 6 etapas: Etapa 1: (Si); Etapa 2: (Si); Etapa 3: (B); Etapa 4: (Si); Etapa 5: (B); Etapa 6: (S) en donde (Si) representa el iniciador y el monómero monovinilaromático, (B) representa el monómero e dieno conjugado y (S) representa el monómero monovinilaromático, produciendo de esta manera los copolímeros de bloque lineales transparentes de poco color polimodales, resistentes al agrietamiento con bloques resinosos terminales.
MX005578A 1986-03-24 1987-03-13 Procedimiento para preparar un copolimero de bloque MX166301B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/843,490 US4704435A (en) 1986-03-24 1986-03-24 Craze-resistant polymodal linear block copolymers with resinous terminal blocks

Publications (1)

Publication Number Publication Date
MX166301B true MX166301B (es) 1992-12-29

Family

ID=25290147

Family Applications (1)

Application Number Title Priority Date Filing Date
MX005578A MX166301B (es) 1986-03-24 1987-03-13 Procedimiento para preparar un copolimero de bloque

Country Status (13)

Country Link
US (1) US4704435A (es)
EP (1) EP0242612B1 (es)
JP (1) JPH0730143B2 (es)
KR (1) KR940003365B1 (es)
CN (1) CN86108591A (es)
AT (1) ATE95526T1 (es)
CA (1) CA1255829A (es)
DE (1) DE3787664T2 (es)
ES (1) ES2059318T3 (es)
HK (1) HK82894A (es)
IN (1) IN168084B (es)
MX (1) MX166301B (es)
ZA (1) ZA871596B (es)

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IT1227901B (it) * 1988-12-23 1991-05-14 Enichem Elastomers Composizioni polimeriche e loro metodo di preparazione
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US5227419A (en) * 1990-12-20 1993-07-13 Phillips Petroleum Company Tapered block styrene/butadiene copolymers
US5290875A (en) * 1992-11-30 1994-03-01 Phillips Petroleum Company Conjugated diene/monovinylarene block copolymers with multiple tapered blocks
US5296547A (en) * 1993-01-28 1994-03-22 Minnesota Mining And Manufacturing Company Block copolymer having mixed molecular weight endblocks
CA2117708C (en) * 1993-09-30 2002-10-22 William J. Trepka Block copolymers of monovinylarenes and conjugated dienes and preparation thereof
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US6835778B2 (en) * 1995-08-29 2004-12-28 Chevron Phillips Chemical Company Lp Conjugated diene/monovinylarene block copolymers blends
DE69941620D1 (de) * 1998-08-03 2009-12-17 Asahi Chemical Ind Lineares blockcopolymer und harzzusammensetzung die dieses enthält
US6630531B1 (en) 2000-02-02 2003-10-07 3M Innovative Properties Company Adhesive for bonding to low surface energy surfaces
US20030211308A1 (en) * 2001-02-02 2003-11-13 Khandpur Ashish K Adhesive for bonding to low surface energy surfaces
KR100425243B1 (ko) * 2001-11-14 2004-03-30 주식회사 엘지화학 선형의 블록 공중합체의 제조방법
US7977428B2 (en) 2003-03-19 2011-07-12 Denki Kagaku Kogyo Kabushiki Kaisha Linear block copolymer composition
JP4138578B2 (ja) * 2003-05-26 2008-08-27 奇美實業股▲分▼有限公司 ブロック共重合体
US20050090587A1 (en) * 2003-10-28 2005-04-28 Dunn John E. Ultraviolet light stability of monovinylarene-conjugated diene copolymer compositions
US7037980B2 (en) * 2003-11-10 2006-05-02 Chevron Phillips Chemical Company, Lp Monovinylarene/conjugated diene copolymers having lower glass transition temperatures
US20050166551A1 (en) * 2004-02-02 2005-08-04 Keane J. A. Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer
US7351767B2 (en) * 2004-02-20 2008-04-01 Chevron Phillips Chemical Company, Lp Composition for monovinylrenic-based shrink label films
US20060235118A1 (en) * 2005-04-18 2006-10-19 Selby Larry M Antiblock additives for monovinylarene-conjugated diene block copolymers
US20070269670A1 (en) * 2006-05-17 2007-11-22 Ronald Wilmer Multilayered structures and their use as optical storage media
US8415429B2 (en) * 2006-12-11 2013-04-09 Chervron Phillips Chemical Company LP Styrene butadiene block copolymers for film applications
CN102558466B (zh) * 2012-01-10 2013-08-14 宁波科元塑胶有限公司 透明型嵌段共聚物的合成方法
US20150166710A1 (en) 2012-06-26 2015-06-18 Styrolution Europe Gmbh Method for producing polymers of vinyl aromatics, as well as vinyl aromatic-diene block copolymers
US10023676B2 (en) * 2016-02-24 2018-07-17 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
EP3752561B1 (en) 2018-02-16 2023-05-24 INEOS Styrolution Group GmbH High heat resistant abs molding composition
WO2019201782A1 (en) 2018-04-16 2019-10-24 Ineos Styrolution Group Gmbh Ultra-high flow styrene acrylonitrile copolymer compositions
US11390736B2 (en) 2018-04-16 2022-07-19 Ineos Styrolution Group Gmbh Ultra-high flow acrylonitrile butadiene styrene copolymer compositions

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Also Published As

Publication number Publication date
CA1255829A (en) 1989-06-13
EP0242612A3 (en) 1989-06-14
EP0242612B1 (en) 1993-10-06
ES2059318T3 (es) 1994-11-16
IN168084B (es) 1991-02-02
KR940003365B1 (ko) 1994-04-21
ZA871596B (en) 1987-08-26
US4704435A (en) 1987-11-03
JPH0730143B2 (ja) 1995-04-05
DE3787664D1 (de) 1993-11-11
CN86108591A (zh) 1987-10-07
ATE95526T1 (de) 1993-10-15
DE3787664T2 (de) 1994-02-03
HK82894A (en) 1994-08-26
KR870008924A (ko) 1987-10-22
JPS62232418A (ja) 1987-10-12
EP0242612A2 (en) 1987-10-28

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