MA64622A1 - Agent de pré-lithiation de batterie au lithium-ion, son procédé de préparation et application - Google Patents

Agent de pré-lithiation de batterie au lithium-ion, son procédé de préparation et application

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Publication number
MA64622A1
MA64622A1 MA64622A MA64622A MA64622A1 MA 64622 A1 MA64622 A1 MA 64622A1 MA 64622 A MA64622 A MA 64622A MA 64622 A MA64622 A MA 64622A MA 64622 A1 MA64622 A1 MA 64622A1
Authority
MA
Morocco
Prior art keywords
sub
sup
particles
ion battery
lithiation agent
Prior art date
Application number
MA64622A
Other languages
English (en)
Inventor
Dingshan Ruan
Changdong LI
Yong Cai
Weijian Liu
Jianlin MIAO
Original Assignee
Guangdong Brunp Recycling Technology Co., Ltd.
Hunan Brunp Recycling Technology Co., Ltd.
Hunan Brunp Ev Recycling Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Brunp Recycling Technology Co., Ltd., Hunan Brunp Recycling Technology Co., Ltd., Hunan Brunp Ev Recycling Co., Ltd. filed Critical Guangdong Brunp Recycling Technology Co., Ltd.
Publication of MA64622A1 publication Critical patent/MA64622A1/fr

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/168After-treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00Compounds of iron
    • C01G49/0018Mixed oxides or hydroxides
    • C01G49/0027Mixed oxides or hydroxides containing one alkali metal
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00Compounds of iron
    • C01G49/02Oxides; Hydroxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/56Treatment of carbon black ; Purification
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0438Processes of manufacture in general by electrochemical processing
    • H01M4/0459Electrochemical doping, intercalation, occlusion or alloying
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1391Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1395Processes of manufacture of electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/50Agglomerated particles
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente demande divulgue un agent de pré-lithiation de batterie au lithium-ion, son procédé de préparation et une application. La formule chimique de l'agent de pré-lithiation de batterie au lithium-ion est : Li<sub>5</sub>FeO<sub>4</sub>@C, et une structure de celui-ci est des particules secondaires formées par l'agglomération de particules primaires de Li<sub>5</sub>FeO<sub>4</sub>, avec un revêtement en carbone de la surface des particules primaires de Li<sub>5</sub>FeO<sub>4</sub>. Dans la présente demande, une source de carbone est mélangée avec un sel soluble de Fe, amenant des ions Fe à se fixer à la source de carbone ; après que de l'eau ammoniacale a été ajoutée, de l'hydroxyde présentant de petites particules et une bonne dispersion peut être formé, puis un oxyde à l'échelle nanométrique est obtenu au moyen d'une réaction solvothermique, et la source de carbone permet en outre d'obtenir un effet d'obstruction entre des particules dans un processus de frittage ultérieur, une croissance de particules primaires est ralentie, et de grandes particules cristallines uniques sont empêchées de croître. L'agent de pré-lithiation préparé à l'aide du présent procédé présente des particules primaires plus petites, un trajet de désintercalation de Li<sup>+</sup> plus court pendant la charge, et une bonne capacité de débit. L'agent de pré-lithiation peut fournir suffisamment de Li<sup>+</sup> lors de la charge d'une batterie pour la première fois pour amener un film de SEI à être généré sur une surface d'une électrode négative, la perte de Li<sup>+</sup> dans un matériau d'électrode positive est réduite, et l'efficacité coulombienne et la capacité d'une batterie au lithium-ion sont améliorées.
MA64622A 2022-01-27 2022-12-01 Agent de pré-lithiation de batterie au lithium-ion, son procédé de préparation et application MA64622A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202210101748.5A CN114551812A (zh) 2022-01-27 2022-01-27 锂离子电池预锂化剂及其制备方法和应用
PCT/CN2022/135781 WO2023142666A1 (fr) 2022-01-27 2022-12-01 Agent de pré-lithiation de batterie au lithium-ion, son procédé de préparation et application

Publications (1)

Publication Number Publication Date
MA64622A1 true MA64622A1 (fr) 2025-04-30

Family

ID=81674572

Family Applications (1)

Application Number Title Priority Date Filing Date
MA64622A MA64622A1 (fr) 2022-01-27 2022-12-01 Agent de pré-lithiation de batterie au lithium-ion, son procédé de préparation et application

Country Status (8)

Country Link
US (1) US20240336493A1 (fr)
CN (1) CN114551812A (fr)
DE (1) DE112022004705T5 (fr)
ES (1) ES2988957A2 (fr)
GB (1) GB2620047A (fr)
HU (1) HU231687B1 (fr)
MA (1) MA64622A1 (fr)
WO (1) WO2023142666A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114551812A (zh) * 2022-01-27 2022-05-27 广东邦普循环科技有限公司 锂离子电池预锂化剂及其制备方法和应用
CN115172700A (zh) * 2022-07-20 2022-10-11 广东邦普循环科技有限公司 一种核壳结构富锂氧化物及制备方法和应用
CN115108589B (zh) * 2022-07-21 2024-05-10 广东邦普循环科技有限公司 一种碳包覆富锂氧化物及其制备方法和应用
CN115763781B (zh) * 2022-11-15 2025-09-30 广东邦普循环科技有限公司 凝胶混合物制取高倍率单晶正极材料的方法及其应用
CN116598499A (zh) * 2023-05-04 2023-08-15 深圳技术大学 一种锂离子电池预锂化剂及其制备方法和应用
CN116741986B (zh) * 2023-08-07 2023-12-19 合肥国轩高科动力能源有限公司 锂离子电池正极补锂复合材料及其制备方法和应用
CN117317415A (zh) * 2023-11-15 2023-12-29 银贮(宁波)科技有限公司 一种碳包覆高铁酸锂补锂添加剂及其制备方法
WO2025102344A1 (fr) * 2023-11-17 2025-05-22 广东邦普循环科技有限公司 Matériau de phosphate ferrique modifié, son procédé de préparation et son utilisation
CN119703066B (zh) * 2024-12-23 2025-11-18 中国科学院长春应用化学研究所 一种双层碳包覆储氢合金及其制备方法和应用

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CN110498449A (zh) * 2019-09-06 2019-11-26 湖北融通高科先进材料有限公司 一种铁酸锂材料及其制备方法

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CN114551812A (zh) * 2022-01-27 2022-05-27 广东邦普循环科技有限公司 锂离子电池预锂化剂及其制备方法和应用
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CN110498449A (zh) * 2019-09-06 2019-11-26 湖北融通高科先进材料有限公司 一种铁酸锂材料及其制备方法

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Publication number Publication date
CN114551812A (zh) 2022-05-27
HUP2400293A1 (hu) 2024-08-28
GB202314792D0 (en) 2023-11-08
ES2988957A2 (es) 2024-11-22
HU231687B1 (hu) 2025-09-28
WO2023142666A1 (fr) 2023-08-03
DE112022004705T5 (de) 2024-07-11
GB2620047A (en) 2023-12-27
US20240336493A1 (en) 2024-10-10

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