LV10213B - The compound of transition metal and catalist for producing of stereoregular polymer - Google Patents
The compound of transition metal and catalist for producing of stereoregular polymer Download PDFInfo
- Publication number
- LV10213B LV10213B LVP-92-216A LV920216A LV10213B LV 10213 B LV10213 B LV 10213B LV 920216 A LV920216 A LV 920216A LV 10213 B LV10213 B LV 10213B
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- 229910052723 transition metal Inorganic materials 0.000 title claims 2
- 150000003624 transition metals Chemical class 0.000 title claims 2
- 150000001875 compounds Chemical class 0.000 title abstract description 3
- 229920000576 tactic polymer Polymers 0.000 title 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract 8
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims abstract 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052732 germanium Inorganic materials 0.000 claims abstract 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052735 hafnium Inorganic materials 0.000 claims abstract 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract 3
- 125000005843 halogen group Chemical group 0.000 claims abstract 3
- 229910052710 silicon Inorganic materials 0.000 claims abstract 3
- 239000010703 silicon Substances 0.000 claims abstract 3
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims abstract 3
- 150000003623 transition metal compounds Chemical class 0.000 claims abstract 3
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 3
- 239000003054 catalyst Substances 0.000 claims abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 7
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 101150115538 nero gene Proteins 0.000 description 13
- 102100026639 MICOS complex subunit MIC60 Human genes 0.000 description 7
- 101100168745 Emericella nidulans (strain FGSC A4 / ATCC 38163 / CBS 112.46 / NRRL 194 / M139) csnG gene Proteins 0.000 description 3
- 241001553014 Myrsine salicina Species 0.000 description 3
- 101150078969 acoB gene Proteins 0.000 description 3
- 0 C*[C@@](C)CCCC*(C)CCCN=C Chemical compound C*[C@@](C)CCCC*(C)CCCN=C 0.000 description 2
- 241001026509 Kata Species 0.000 description 2
- 101100366940 Mus musculus Stom gene Proteins 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 125000004188 dichlorophenyl group Chemical group 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- ZRVIYEJYXIDATJ-UHFFFAOYSA-N 4-Heptyloxybenzoic acid Chemical compound CCCCCCCOC1=CC=C(C(O)=O)C=C1 ZRVIYEJYXIDATJ-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 241001646765 Apini Species 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 241001454694 Clupeiformes Species 0.000 description 1
- 101000622004 Crotalus atrox Snake venom metalloproteinase atrolysin-C Proteins 0.000 description 1
- 240000007052 Cynometra cauliflora Species 0.000 description 1
- 101150096839 Fcmr gene Proteins 0.000 description 1
- 241001481828 Glyptocephalus cynoglossus Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241001236294 Hebe Species 0.000 description 1
- 101000671676 Homo sapiens U3 small nucleolar RNA-associated protein 4 homolog Proteins 0.000 description 1
- 101150096418 Mepe gene Proteins 0.000 description 1
- 101100288133 Mus musculus Klk7 gene Proteins 0.000 description 1
- 101150016983 NFIA gene Proteins 0.000 description 1
- 102100035193 Phosphatidylinositol N-acetylglucosaminyltransferase subunit Q Human genes 0.000 description 1
- 101710109719 Phosphatidylinositol N-acetylglucosaminyltransferase subunit Q Proteins 0.000 description 1
- 101100222207 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) TIS11 gene Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 101150095510 TMEM35A gene Proteins 0.000 description 1
- 102100040072 U3 small nucleolar RNA-associated protein 4 homolog Human genes 0.000 description 1
- 101150083305 acsA2 gene Proteins 0.000 description 1
- 101150081706 acsAB gene Proteins 0.000 description 1
- 235000019513 anchovy Nutrition 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 102220257221 rs41294988 Human genes 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
LV 10213
COEflKHEHKE IIEPSCOJOīiOrO METAJUA, KATAJM3AT0P nOJEraiilfl CTEPSOFiiyifiHOrO IMHHEPA
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Kpotie Toro b Ka^ecTBe npuMepoB nojiy^eH0H οοθλεηθηεζ ne-pexo#Horo MeTajuia, οοΛβρκβιρχ jniraim, 0 EcnoJii30BaHEeM saivie- meHHHK Β33ΚΛΟΠΘΗΤ3Λ2ΘΚΗΛΒΗΗΧ ΚΟΛΘΙΪ, 0dpa3yEXIļ2X ΠΟΠθρβ^ΙΘ CBH3H C ΚρβΜΗΗβΜ, MOaHO ΠρΕΒβΟΤΕ AByZ^IOpHCTUfi ΛΗϋΘT0JlC0JI0Jld0c/LI8T0JII1U— KjioneHTa^KeHBJi/raTaH / ffcrft'BA , β/te/U- 112, 887-897 /1981//, ΓΗΛΡΗΛ OTAieTHjicam)idBc/TpeT-dyTiijnĻHKJioneHTaABeHBji/cKaHflBj3/ j/. CIm- ČAm/' Sut- 1988, IIO, 976-978/,. οοθλβηθηβη runa Me2i'/!Je4Cū/-:,[CH/^,3eĒ/2/*'J = Eci· ! Ί V-Jm- Χ985, 107 , 8X03-8110/ 2 I.K..
Oahhko, b cjiyuae πρΗΜβΗΟΗΚίϊ οοθαεηθηεη ιρφκοηηη ujw coe-AilHeHEH TBTSHa Π3ΒΘΟΤΘΗ πρΒΜβρ ΟΟΘ^ΒΗβΗΕΕ, CO^epsaiiļHZ AEMGTEJI-ΟΒΛΙίαίόΜο/τβΤρθΒίΘΤΒΛίρίΚΛΟΠΘΗΤεΛΚβΗΗΛ/ΛΒΓβΙΙΛ, / CftCU/ < β)&Ζ . 119, 1750-1754 /1986//, ho πρπ 3tom ne coodmajiocL o npBMepe nojiy- - 3 - LV 10213
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TpeT-dyTiumnKJioneKTaflueHJw/cjyi3H /3,9 r, 15 i&ioJieE/ b πθητ^ηθ . /50 m/t nocjie ^ero no ksujihm MejvieRHo zočaBJUum pacTEop /20 ία/ H-0yTHjmiT2ji /1,6 14/ b reKcane npn 6xnasweHaa jibaom, i nepeLieiiiiiBaind oiy cmcjob npa κοίίΗβτΗοη īeraepaTj/pe b Te^enue 2 ^acoB, oTroafuin pacTBOpKTenL c odpaeoBaHHeM dejioro TBep^oro BemecTBa / /īie-OgHg//f-B^-CgH^/, a ώτβΜ floČaEJLE- jm ic Hewy TeTparjs#poģ:ypaH /50 m/9 ητο πο3βολβλο nojiy*njTB npo3pa^Hyio εθλτ^κ) bs/ikoctb, B CTGKJLHiiHOivi peaKunoHHOLi cocy,ne θμκοοτββ 500 m ojuiasjiajiii ^θΤΗρβχχπορυοτίώ ηϋρκοΗΐώ /3,5 r, 15 mojiež/ ao -78°C, nocjie ^ero'AotfamiiīALJ TeTparuflpO(ryp£H /200 ιαι/9 no «aiimi μθαπθηηο AodaEUBJin nojiyhohkjio εηζιθ npo3pa^Hyio sojitj» sotoctb, naxo-AfliuyiocH npn TeMriepaType -78°C, 'nepeaseiaHBainī 3Ty ciaecB npn kom-HaTHoū TGMnepaType b τθ^οηηθ 18 ^acos, Harpesajm c odpaTHKM ΧΟΛΟΛΚΛΒΗΖΚΟΜ B ΤΘΗΘΗΒΘ 4 ^aCOB, ΟΟΤΘΒΟΙΛΠΒ MSI 05UiaS£eHIJff, οτγοηλιμ pacTEopBTejiB iī3 dne^oneJiToro pacTEopa, coAepKamero čejmn ocsaok, &o6aBJwm MeTHJieauiopM /200 wi/, a 3aTeu pas-daBjieHHyio ^Jiopnc to Bo#opo£Hy & K2CJioTy /100 but/, oT^ejumn sha-koctl, EHcyundBajin cjiož ijeīiuieHXJiopiwa naa <5θ3βοαηκμ cyjn4aT0M HaTpBfl, OTrOHaHH ΜΘΤΜΘΗΧΕΟρΒΛ, A0daBJL®I2 ΠΘΗΤ£Η 2 φΗΛΒΤρΟΒβΛΗ, HTO Π03Β0Λ1ΗΙ0 HO^HUTB djie AHO-E6JĪTN3 KpHCTaJLHH /0,37 r/23 <taeAHo-&ejiToro giDiiTpara. &aqeH2H &232*iecKEX ceohctb βτογο coeABHeHun πρεβθαθηη ηβεθ. Kpoue τογο npoE3EOĀium onpeflejieHBe BHOpaKpaCIlHX ΟΠΘΚΤρΟΒ B COOTBeTCTBKU C ΜΘΤΟΛΟΜ, OCIiOEaiIHH?.! Ha HCn0JTB30 B£H22 K3^ , 2 0IIp9AejiBJI3 CIĪOKTpH %-ΗίΰΡ C BCn0JIB30Ea-HBeii CDCĪg b KanecTBe pacTEopETeju*.
GtianeHBH 3Jier,-eHTapnoro anaīB3a: ΒυοΌίτεηΗΟθ 3imeHne /%/: C 48,73 H 5,78 - 25 LV 10213 Π0Λ3ΙΗΘΗΗ0Θ 3Η&ΗβΗϋδ J%j\ C 48,81 H 5,82.
IlH^paKpacHijie οποκτρυ: EOK&saKu Ha pnc.7 Οπβκτρκ HMP: noKa3SHH na piic.8. Πρβμθρ 9 IIojroMepn3aiiHg · • B aBTOKJiaB ŠVS etiKocTB» 1,5 ji, χοροιιιο προ^τωΐ ra3oo<5-pa3HKil a30T0M, no cjie.no ββτ&ζιβηο jiotiaBJumi onniļeKHKfi mnyoji /500 mji/, MerajiajiKMHEOKcaH, usroToaneHHnfl $aptīofi "To&o G?Taygep κθμηκβλ komisku, λμτ," /mJieņ/jurpHm Beo: 770/ /4,0 mmojm/ h £ByxjiopBCTH& AmiQTiwciijn5Ji/ueTimņjKJioneuTaweHi!iJi//TņeT-0ytm-UBKHoneiiTa^īiGHMJi/-iņypKOHMS /0,005 mmojlh/» nocjie ^ero HoBHHiaJiH Tei/niepaTypy ao 30°C npii HenpeptiEHoS nojiane npommeHa c τθμ, "ΊΤ00Η coxpaHUTL odinee AaaJieHBe, pasnoe 3 κγ/cm^ Γ, u ocyG>e-ctejibjib nojmwepH3au^io b TeneiiKe 2 ^aceš, saieu nocjie okoh^shbh peaKiņja hpob3boajiīih pa3Jio:ieHiie κομποηθκτοβ i?aTajūī3aTopa c no-modilk)-LffiTaHoijia a BHcyuniBajffl odpasoBaBnraSca nojuniponuneH' c iļejrsED noJiy*ieKiifi Η3οτ£κτβκθοκογο nojusnpoimjieHa /59 r/. Aktebhoctb KaTajnj3aTopa cocTaBTMJia 65 κγ/γ Eto moJieKyjiBpHKH Beo paEHBJiCH 6400. npmgep 10
JiByxjīopūCTKii OT^TiwiciiJiiūidEo/TpeT-<SyTHjriņiibioneHTa- ΛΒΘΗΙ·υΐ/-ΊίΙ3ρΚ0ΗΒβ
Bce peaKpuM ocymecTEJiHjiE b aTMocpepe īrnepruoro ra3a.‘ Kpowe τογο pac TBopBTejiL peaKnjiH npcABapnτθλβηο BHcyuiEaajiH αω npiīMeue~ ΗΒΗ B 3TOM ΠρΟΕζθΟΟβ. B ΟΤΘΚΠΚΗΚΟΜ ρββΚΙζΠΟΗΗΟΜ C0Cy£e eMKOCTLB 200 mji pacTBOpHJiH AEMeTBJidEc/TpeT-dyTHina-iKJioneHTi^iieHEJī/cMaii /4,6 r, 15 Mī.meh/ b neHTaHe /50 m/, eocjig ^ero no KaiumM mga-λθηκο AodasjīBJm pacTBop /21 mh/ H^mraniTM /1,6 Iv/ b reKcane — 26 — npn oxjias,neHHi3 λβαομ, nepeMemHBara 3Ty cm3CB πρυ κοιιηβτηοΜ Tei/nepaTjpe b τθηθημθ 4 nacoB, οτγοηλλη pacTEopBTejiL c odpa3o~ Baūmi dejioro τβθραογο BemecTBa / ^5^3/3// u AodaBJi&iu TeTparuflpoiifpaH /50 ιω/, ητο ικοβοαηαο πολ^βτβ npo3panHyio sejrTyio smakoctb. B ΟΤΘΚΛΗΗΗΟΜ peaKUMOHHOM C0CyA9 ΘΙΰΚΟΦΤΒΕ) 500 UTĪ OXJiaSaSJIU Ηθίπρβχχ^οριιοτΗϋ ipipKOHiiS /3,5 r, 15 maojieR/ ao -78°C, nocjie AodaBJiBJiu TeTparMApopypaH /250 m/9 no KaruiaM ικααθηηο AodaB-jiBJia πολ^ηθηη^κ) ΒΗΠθ npo3pa«Hyio nevil·yo suakoctb npH TeMnepa-Type -78°, ocTaBJiasi! 3iy cmbcb aeh εηοτεμββημη, αοβοαηλη’τθμ-nepaTypy ao KOMHaTHoii, HarpesaAM 3Ty cuecL· c odpaTHKM xojio-ABjilhbkom b τθηθημθ 84 EacoB, ocTaBJinra odpa30Ba.BueecH EeiiļecTBo AAH oxjiaj5weHiw, οτγοηαππ paciBopHTejiB H3 npo3panHoro sejiToro pacTBOpa, AodaBismi κθτιϊλθηχλορμα /300 wi/t a. oaneu pa3daBJieH-Eyio xjiopuctoboAopoAHyK) Knosos /100 m/ npu oxaasņieHBH αςαομ , οταθαηαμ smakoctb, BHcynndBa;iH cjioē MemiemiopKAa HaA de3E0A-' ΕΗΓ.1 CyAB$aTOM HETpilB, OOTOHHJIM ΜδΤΗΑΘΗΧΛΟρΗΑ, AOdaBlBAH ΠΘΗΤ3Η M $MJILTpOBaJIH, STO ΠΟ3ΒΟΛ0ΑΟ HO^EMTL SeATOBaTO-deJIHe KpMCTaAJIH /2,35 r/ 03 sejraoro $MJiLTpaTa. SEaneHas $03βεθοκβχ cboSctb dto- ΓΟ ΟΟΘΑΗΗΘΗΠΒ ΠρΗΒΘΑβΗΗ ΗΚΚβ. ΚρΟΜΘ ΤΟΓΟ, ΠρθΗ3Ε0ΑΕ£Μ ΟΠρβΑβ- ΛΘΗΕΘ MHtļ:paKpaCHHX CneKTpOB Β ΟΟΟΤΒΘΤΟΤΒΚΗ C ΜβΤΟΑΟΜ, OCHOBaiI- τ ΗΗΜ Ea MCII0AB30BaHUH ΚΒ t', 0 ΟΠρβΑβΑΒΟΠΙ ΟΠΘΚΤρϋ ΑΗ-ΗΙ»ίΡ C BC-H0JiL30BaHiieM CPCI3 Β KanecTBe pacTBopMTejia. SHaseHHs 3JieMeHTapHoro aHaiM3a: /¾¾)0½ * LHCHMTaHHoe BHaEBHMe !%ļ\ C 52,15- H’6,56 UojiyHeKHoe 3KaH8HMe ļ%/\ C 52,01 H 6,58 ΠκρρεκρβοΗΗθ οπθκτρκ: anaKa3aHH Ha puc.9.
CneKTpH HmP; noKa3aHH Ha pzc.IO. - 27 - LV 10213
ļlmaep II Πθ^ΙΚ?γ·ΘΏΗ35ΜΙ.Α B aBTOKvias &μκοοτβιο 1,5 ji, χοροπιο προ^τώί ra3oodpa3-HHlvi a30T0M, ΠΟΟΛβΑΟΕδΤβΛΒΗΟ AOdaBJIHJM ΟΗΜίΙΘΗΗϋϋ TOJQ?OJI /500 I.Bl/, ueτιβί&οοιλ]hokgeū, Μ3ΓοτοΒτιβκΐϋίίΙ £l'jx:ož "ToKo CTay£ep Ker.niioji KOMnaHii, jimt." Ameicyjwpmrii bgc: 770/ /4,0 im.cjih/ a flByxao-
pUCTHfi ΑΚΕΘΤΜΟΙ1ΊΙ12Ι0Βθ/TpGT-dyTI-BJIpKJīOneHTa^IieHliVBiJPKOIInS /0,005 mmojih/, nocjie ^ero nouimajin TemiepaTypy &o 3Q°C npa
HenpepHBHoii nogana nponaneHa c τβΜ, 'līodii coxpghistl odmee asa- p jieiii'je, paEKoe 3 κτ/civi Γ, n ocy>uecTiaTiHJiii nojiiiuepusaiņiio b Teqe~ Hne 2 nscoE, 3£TeM nocjre οκοιπεκΕΗ' peaKipg προ23Βο;αΜΗ pa3Jio-seHiie icoiviHOKOKTOB Kaī2JiK3aTopa c ποεοήβιο Meiancuia u EHC^mssa-jm O(5pa3OB£B01I]SCH HOJIEIiponBJieH, HTO nO3BOJHUI0 ΠΟλ^’ώΙΤΒ 230TaK-TinecKnS nojninponiijieii /3,1 r/· /iktbbhocti» KaTam3aTopa cocīac-jlhāsl 3,4 κγ/γ2Γ .'jac. Ero MojieK^jiapnuS Beo paBnaJiCjT 9600. npmsei) 12 to’jaopBCTHii ^MeTiuirepivnuidL'c/i'jeTiiJiipiuioneHTa^BeHmī/ ΐίϋρκοΗΐιϋ
Bce peaKiĢiH ocymecTB&ajffi b aTEocgepe līHepTHoro ra3a. Kpowe τογο pacTBopBTejiL peai-^iJH npe^Bapatsjibho BHcyut0Bajm ro ero UCnOJiBSOBaiiJIH B 3T0M ΠρΟΙίθΟΟΘ. B CCfEK)I£HHOE peaKlļBOHKOM COC^^G eMKOCTBD 200 m pacTBopam TeTpari^j-m RmeTKsdnc/L'etujuj^kjio-neHTa^neESJi/repteaHiiH /1,2 r, 8 εεο,τιθη/ b εοητβηθ /50 m/, nocjie ^ero no KanjiHivi ne^jieHHO EodaEjaEia paciBop /II m/ η-^γβχτητβη /1,6 M/ b reicaaiie πρπ οχΛίε^εκηιι jherom, nepeneiajBajni 3Ty c^eci. npH KoiviHaTHOH TGraiepaType b To^eKBe 2 ^scce, οτγοιι&ίιϊ pacTBo-pHTejiL c odpa30BaniiGE dcjioro TEep^oro BemecTEa / b\
Lfe-CgHg/S//, flodaEJuura κ eci^ TGrparii^poa^paii /50 m/ c 0dpa- - 27α.- 30£&ΗΰΘΜ npOSpa^HOB SCJITOH KUAKOCTii. ' B CTeKJiHHHOM peaKiosoHHOM cocyjļe θμκοοτβιο 500 vai oxaesBa-jm neτκρβχχΛορϋοTHii ςυρκοΗυϋ /1.8 r, 2 mojieii/ ao - 78°C, saieM ppčasaisum TeTparn^po^ypaHjyi50 wi/9 no KamiaM Me^zreimo fl.o6$.ojuum npo3pa^Hyio KejiTyio skākocīl, πολ^ηθηη^ιο βηώθ η Ha-xonHmyiDCH npi! TeMicpaType -78°C, nepeMeiiiHBSJnj 3Ty cmccb npa KOMHaTHofi TewnepaType b τθηθηηθ 14 nacoB, HarpeEao ee c 0(5paTHHLI ΧΟΛΟΛΒΛΒΗΜΚΟΚ B ΤΘ^ΘΗΚΘ 2 HaCOB, OCTaBJUDIB 0(5pS30EaB-tuiiiiCH προ^κτ oxjias%eniyif ottohjūib pacTBopuTejiB B3 npo-spatmoro sojiToro paoTBopa, flodaiuiHJiH μθτηλθηχλορηλ /200 vai/§ a saiets pa3<jaBjieHHyK) zjiopac τοBO£opo;aHyκ> KucjioTy /100 vai/ npii ox~ jiasaeKUM jorom, omejuum sbukootb, BKcyinuB2jm cjioS ΜβτΕΛβΗχκο-pn^a Hafl 0θ3βοληημ cyjtBgaTOM HSTpnn, οτγοηηλβ μθτμθηχλορβλ, R06aBJlSUll] neHTSE» ^ΕΛΒΤρΟΒΘΛΠ H KOHlieKTpBpOB3JD& DOJiynOHHHS προ-Λyi<T c odpasoBaHiīeM £cejiTOBaTO-dejmx KpucmiDioB /0,31 r/ B3 ctaefl-HO-sanToro cpajīBTpaTā'. aianeHun $H3B^ecKHx cbohctb θτογο οοθλιϊ-ΗΘΕΕΒ ΙΐρΒΒΘΛβΗΗ HHH8* ΚρΟΜΘ 3Τ0Γ0, np0H3B0&BjHi ΟΠρθ£&ΛΘΗΙΙΘ HH-5pSKpaCHKX ΟΠΗΚΤρΟΒ Β COOTBGTCTBHB C ΜΘΤΟΛΟΜ, OOHOBaHHKM Ha HCE0JIB3OBaHHB ΚΒί^, Η ΟΠρβΛΘΛΗΛΗ ΟΠΘΚΤρΗ %-ΗΜΡ C ECn0vTL30Ba-ΗΒ6Μ C_DCI3 β KanecTBe pacTBopuTejiH.
Saa^eHZB ajieMeiiTapHoro aHajru3a; /C^HjgCI^Oo ΪΛ/ Buc^KTaHHoe SHa^eHue /#/ : C 39,94 H 4,31 Iīo;iy3eKHoe sHa^enise /%/: C 40,38 H 4,38
Ku^paīgpacHīie -cnetcTpu: nogaaaHH·· hčtpao.~"II "
CneKTpa HMP: noKa3SHH Ha pisc.12. ΠΡΗΜβΡ 13 Πθ·ΠΗΜΘΡΗ32ΙΓΜΗ B aBTOKJiaB SK eMKocTLio 1,5 ji, χοροιυο προγκώ ra30o<5pa3- - 28 - LV 10213 HHM a30T0L·!, ΠΟΟΛΘΛΟΒδΤβΛΒΙΙΟ Λ0 <5a2JUUIII OOimeHHHŽ TOJĪJOJI /500 Ml/» KeTMJiainofvniHOKceH, H3roToaneKHHŪ ģtapMoft "Tofio CTay£ep κθμεκθλ KOMnamj, jUvīt.” AmeKyjwpHHii bgc: 770/ /4,0 mmojis/ h flByxjio-,ρκοτίώ ^ūeTiuirepMPjidiic/MeTHJiiīBKJionoHTa^BeiiBvīi/^PKOKnS /0,005 mmojīb/, nocjie ^ero noBuuasu Tei»inepaaypy no 30°C npn hg~ npepiiBHofi nojiane npoimjiena c τθμ, htočh coxpaHHTB odisļee. jias-jīcKiie, parHoe 3 kt/cij^ Γ, u ocymecTBji&Jin nojaiMepiJ3sn:nK) b to-ηθηηθ 2 racoB, saīeM nocjie OKOimamm peaiaiun npoB3BOjmn pa3-jiosenao κοκποϋβΗΤΟΒ KaTaiffl3aT0pa c πομοπικο MeTaHOJia κ BacyuiH-Eajoj odpasoBaBaL'iicH nojmnponiuiGH, hto ho3£OJīkjio πο^^βτβ B30Tai?Tii^ecKEfi nojiiinponBJieH /2,5 r/. Akthbhoctb KaTana3aTopa cocia-EJULm 27 kl’/γ ^.nac. Ero tmei^JLapsiS βθο ρ&εηλ,ίοη 7600. ΓΓΡΗΜ6Ρ 14 jlByxjiopBCTūii iņKjioseTpaMeTaneHciūiiiJj/ipKJioiieHTaj(jieHaa/ /aeTMBjJKJioneHTaABeHBji/TOKOHEii
Bce ρβΒΚΓζΒΒ ocymecTBMJiH b aTMocgepe unepTiioro ra3a. ΚροΜθ •τογο pac TBopBτθλβ peaKiiEB npe^BapBTejiBHO βηο^ιιιββθλβ no ero npHLieHeHiia b btom npoiiecce. B CTeiūcsHHOM peaKEpiOEHOM cocyne eMKocTLio 200 mji pacTBop&JHi iņaiuioTeTpaMeTajieH/ipaKJioneHTaflBOHnV /MeTiJJiiĻaiūioneKTaflueHiKr/cajiaH /3,4 r, 15 mosieft/ b neHTSHe /50 m/9 nocjie nero no κειυυη.ι μθλπθηηο ^odaBJisjra pacTEpp /22 lui/ H-dyTUJUiUTm /1,6 M/ b reKcaue, nepeueīnzBaJiH otj ctaecB npn KoisaTHoū Ternepar^pe b τθηθηκθ 3 ^acoB, οτγοη&ίη pa CTBopETejiB c 0dpa30EaHneM de,ioro τβθρλρ.γο Eeme.c,TBa ļL / 2/7CH^^Sr/C^H^/. /ijeCgH^/// ^ κ Be^ecTBy ^ocJaESjum Teiparimpor^paii /50 iaji/, *£TO n03B0JnUl0 ĪIOJI^TB IIp03paHHyiO %.ejlTyiO KEAKOCTB. B ΟΤΘΚΛΗΗΗΟΜ ρΘ0HliOM COC^G eMKOCTLK) 500 Ml OKJlSJEiflajIlI ^θΤΒίρβχχΛορΕοτκϋ ιρίρκοΗκΰ /3,5 r, 15 amnefi/ λο -78°C, ^odaE- - 29 - aHātUM/.# /: /ne/nfia.zu£/tcq9yr/uLK. /SfCu-v/, /u> 'ΐρο&β*?·*#'
JifljnivnoJii'^eHHyio Eunie npo3pa^Hyio sejiijB ebakoctb npn TeMnepa-
Type -78°C, nepeuecmBaim 3Ty cmgcb npn κομηετηοη TeiinepaType b τβηθΗΒθ 48 nacoB,. oTromum pacTBOpuTejiL U3 sejiToro pacTBopa, coAepsamero dejmft ocsaok, Aodaaram ΜβτιυιβΗΧΛορΗΑ /200 ϊμ/, OTpJEbTpOBHBajin odpasoBaHiieecB τβθραοθ BeniecTBo, koh-
UeHTpnpoEajBa πο^ηβΗΗκϋ κθατηζι čmīBTpaT, AOdaEjiHJui neHTan n oxjiaBAajiH civiecB ao -30°C, hto no3B0Aiwo πολ^ηβτβ sejiTOBaTO- -dejrae KpBCTSJuiij /0,39 r/. 3ηβηθηηβ ^ηβιήθοκηχ cboEctb 3τογο ΟΟβΑΗΗΘΗΒΛ ΠρίίΒβΑΘΗΙί ΗΒΕΘ. ΚρΟΜΘ ΤΟΓΟ, ΠρΟΒΒΒΟΑΒΛΒ ΟΙΐρθΑβΛΘΗΒΘ BH^paiipaCHKX ΟΠΘΚΤρΟΒ C BCI10JIB30ΒΒΗΚβΜ ΙίβΤΟΑδ, ΟΟΗΟΒδΗΗΟΓΟ na ΠρΚΜΘΚΘΗΒΒ ΚΒ/*'', Η Olipe^eJUIJin ΟΠΘΚΤρΗ %-ΗΜΡ C ΗΟΠΟΛΒβΟΒΘΗΒΘΜ CDCIg β Ka^ecTEe pacTBopBTejin. 3ELa^eHHiT θΛθΜθϋτερΗΟΓο anajinsa: /CjgHjgc*2 U2/^f BHCHHTaKHoe 3Ηβ^θηβθ /%/: C 46,37 H 4,67 Ecm^eHHoe 3Ha^eHiiG /%!: C 47,03 H‘ 4,82 MHgpaKpacHHe οπθκτρκ: noKa3aim na pnc.13.
CneKTpu HMP: noKa3aHH Ha pac. 14. Πρζμθρ 15 Πθ·7ΙΕΜβΡΒ33ΙΙΚΗ B aBTOKJias θι.ιεοοτβκ) 1,5 λ, xopomo προ^τιώ ra30odpa3-hhm a30T0M, nocjieAOK.TejiLHo AodaEHazasd onauieHHtai mizoji /500 m/.t mTiuiajiκγ/ώηοκcaH, Β3γοτοεα6κκη2 gijjasofi "Tofto CTaygep κβωζκθΛ komishu, aut." /MOAeKyjiBpHHS Bec : 770/ /4.0 mmojih/ n A3yXAOOpECTHŪ IĻUKAOTeTpaiviGΤΕΛ6Η01ΡΊΙΜ/ΐρΚΛΟΠΘΠΤΘΑΕβΗΐυΐ//ΜΘ~
Tiijn^K^oneHTaAneHiiVīPipKOHL'ii /0,005 mkojm/, nocjie nero ποεκ-majns TeKaiepaīypy ao 30°C npn HenpepuEHoii noA^ne npomweHa c τθμ, HTodn coxpaHi5TL e$nee ΑδΕΛθΗΕβ, paEHoe 3 kt/ci,? Γ, II ocymecTB^njm nojiEMepassiņiio β τοεβηβθ 2-x ^bcob, 3aTew nocjie - 30 - LV 10213 ΟΚΟΗΗΕΗΒΒ peaKIļHM HpOU3BOAMJIH pa3JI0&eHB8 ΚΟΜΠΟΗΘΗΤΟΒ KaTatfU-
Topa h BHcyuiuBajijj 0dpa30BaEmjīScH nojumponiuieH, ^το πο3βολμλο πο,^εκτβ H30TaKTH^ecKKū ποΛκπροπιυΐθΗ:·: /3,6 r/. Aktkbhoctb Ka-TajM3aTopa cocTaBJLHJiK 3,9 Kr/r^.^ac. Ero MOJieKjJiapHim Bec paBHBJiCH 4200. fļpUNtp 16. JĪByX^OpHCTHii ^ΜΘΤΙϋΙΟΗΛΗΛ/ΜΘΤΗΛΙ^ϊΚΛΟΠβΚΤβΛΗβΗΙϋτ/ /ΛΙίΓνΙΘ T2JDD;HKJI0neK ΤΘΛΚβΗΜ/ίΡφΚΟΗΐώ Bce peaiaņaB ocymecTBJLfio b am>c$epe EHepraoro ra3a. Kpo-m τογο paoTBopKTejiL peaKiļiiH npeABapuτθλββο BHcyiimBaji2 ro ero ΠρϋΜΘΗΘΗΒΗ B 3TOM ΠρΟΙφΟΟβ. B ΟΤβΚΛΗΗΗΟΜ peaKIļHOHHOM CO-cyAe eMicocTBio 200 mji pacTBopHJin ΑΚΜβΤΜ/ΜβΤΗΛηκιαοπθΕΤδΛΐίβΗ^ΐϋΐ/ /ΛΒΚΘΤΗΛίρϊΙϋΙΟΙΙΘΗΤβΛΗβΗΙϋΐ/ΟΒΛδΗ /3,5 Γ, 15 MMOJiefl/ B ΠΘΗΤβΙΙΘ /50 μη/, nocjie ^ero μθ&ηθηηο no Kanonu AodaEuiffin! pacTBop /22 mh/ H-dy τΒΛίίΗΤΜΛΓ /1,6 14/ b renoaHe npa οχλθβήθηεβ jibaom, πβρθΜβπΐΗΕΒΛΗ 9Ty civiecB πρπ κομηβτηο2 TeMffepaType Β ΤΘ^ΘΗΗΘ 5 hscob, OTroEsjiu pacTBopaTejiB c 0<5pa30BaHB8M čejioro TBeņzoro BecļecTBa /lj/ 2 AOdanjinjui κ 9TOMy BeiiļecTBy TeTparuflpo^ypaH /50 m/f ktq πο3Βολβλβ πολ^ηπτβ se^~ toΒδτο-κορκπηθBybd npo3panHyd sbako^ctb. Β οτθκκηηηομ peaKnuoHHOM cocy^e θμκοοτβιο 500 wi ojcjias&aHn ^ompexxjiop0CTHH ιχκρκοΗκϋ /3,5 r, 15 MMOjiefi/ λο -78°C, nocjie ηθγό AodaBjiajm TeTparnflpo£ypaH /250 mti/, Mejpiemio no KaiuiaM Aoda'EumjiH noayneHHyio βηιιιθ sēji to Baro-κορπ πη e sy k> npo3paHHyjQ se£-koctl npu TeMneparype ~78°c, nepeMeniBBajiH 3Ty civiecB npH kom-aaTHofi. TeMneparype b re^eiHie-18· nācos-, HarpeBS3ia"ee c odpammA , XOJIO^HJIBHHKOM Β ΤΘΠΘΗΚΘ 6 HaCOB, OTTOEHJIH paCTBOpBT&HB ΟΤ ΠΟ-' ' ηβΗΗΟΓυ κ&πτοττο pacrEopa, «BodaEJuum ΜβτΒηβΗΧΛορίϊΑ /300 m/t ΟΤφΗΛΒΤρΟBELBSJIB 0(5pa30EaBLūecCH ΤΒθρΛΟβ ΕΘΙϋθΟΤΕΟ, KOHIļeHTpHpO*-BajiB nojiyneHHHŪ ae/iTtdi ^idJīBTpaT , jmdaBanjm naHTaa, <ļiui£- - 31 - ΤρΟΕΘΛΗ 0dpa30BaHUeeCH ΤΒΘΡΑΟΘ BeiI»eCTBO Η peKp0CTaJIJIH3OBIiB8JlH TBepRoe BemecTBo 23 γορβηθγο renīaHa /200 μη/, ητο iio3bojih:io eoj^^ktb »attTOBaTO-<3ejiH0 KpBCTajum /1,08 r/. $232-
HeCKIDC CBOŪCTB 3Τ0Γ0 COeAūpeHIiū ΠρίΙΒΘΛβΗΗ Η35ΗΘ. ΚρΟΜΘ ΤΟΓΟ, ΠρθΕ3ΒΟβΒ£ΟΟΒ ΟΠρβΛΘΛβΗΒβ EH$paXpaCHHX ΟΠΘΚίρΟΒ B ΟΟΟΤΕΘΤΟΓ-BBE C ΜβΤΟΛΟΜ, OCHOBBHHHM Ha ΠρΗΜβΗΘΗΒΒ KB 2 OUpeAGJIBJIBCB cneKTpH %-HMP c BcnojiB3OBaH0eM CDCIg b KanecTĒe pacTBop2Tejuj. 3η3ηθκβε 3JieweHTapHoro aiiejmsa.: /¾¾}¾ BKC^uraHHoe 3HaqeHiie: C 46,13 H 5,16 IIoji^eHKoe 3Ha^eHEe: C 46,22 H 5,16.
IlH^paKpaciise οπβκτρϋ: noKasaHH Ha pnc.15 ΟπβκτρΗ HLiP: noKasann Ha pac.16. Πρημθρι. 17 . < . HoJiKMepH3aiiEfl B aBTOKJias θμκοοτβιο 1,5 ji, χοροωο προγκώ ra3oo<5-pa3HHL! a30Tou, nocjie^oBaTejiBHo AodacjīBjm οηβηιθηηηη To;iyoji /500 mji/, KeTHJiajiKīiHHOKcaH, b3rotobjighhhž $υρ&5οκ "īb&o Cīay$ep
KeiJKKSJi KOKnaHH. λμτ." /mjieKSJisspmā seo : 770/ /4,0 mbd&i/ h flEyxj:op2CTHŪ ΑΚΜβτhjiclumji/mgthjhīhk jioiibHTajudehe λ//ηβμ8tbji— iļHKJioneHTajmeHiur/uBpKOHiiS /0,005 μμολ*/, ποολθ ηθγο noBHinajm
TewnepaTypy #o 30°C npu HenpepHBHOM ββθλθημβ npoimjieHa c τθμ, HTodu cojcpaHHTB odinee ΛΟΜθΗΕβ, paBKoe 3 κγ/cm^ Γ, 2 ocyņecTBjw- JIB Π0ΛΗΜβρΗ38ΙίΒΕ) B ΤΘ^ΘΗΒΟ 2-Χ qaCOB, 3aTeM HOCyie ΟΧΟΗΊΒΗϋΛ peaioņjH npon3BOABJiu paaaoaeHMe κομποηθητοβ KaTaaa3BTopa c no- ► ūoiiļBD MeraHojia n BbicyiiiHBaji2 nojiyHeHHKii πολβπροςπιλθη c cdpaao-BaHBeM HSOTaKTBHecKoro nojinnponujieHa /45 r/. Aktbehoctb KaTa-jm3aTopa cocTaB&EJia 49 Kr/r^.nac. Ero M0JieKyjwpHH8 Bec paB-HJLZICH 5600. LV 10213 - 32 ~ HPHMep 18
toxjiopnc thū αβγ.·:θ tbjicwmji6uc/m til^hkjioπθηtotθ m^i/ra^HuS
Bce peaKiļuu ocymecTEJuwi! b aTM0C$epe ηηθρτηογο ra3a. Kpo-m τογο pacTBopuTejiL· peaKUEB npeflEapuTejiBHo BHcyimaBajrH nepe# erO ΠρΗΜβΗΘΗΒβΜ B 3T0M ΠρΟΙξβΟΟβ. B ΟΤθΚΠΗΗΗΟΜ psaKlļBOHHOM cocy#e eī.iKOCTLD 200 īm pacTBop/ifln flBMeTBJidiic/AieTiūmHKJiOEeHTa-ABeHBJi/cBJiaH /3,3 r, 15 i^iojieū/ b TeTparn;apoaypaHe /50 ī.ui/, nocuie ^ero no Kamīni μθ&χθηηο AodaBJiHJiB pacTBop /21 wi/ Hnjy-m/uiHTna /1,6 W b reKcaHG npa οχλ8Ελθηββ jibaom b neņeuemBajm 3Ty CMecs npH KOMHeTHoft TeMnepaiype b Tenenne 2~x escob c od— pa30BaHnew npo3paqHoii εθλτοη sb^ksctk 11} 2/ί1β^ί/'ihB0tŅ.rJ^/. B CTeKJLHHHOM peaKiņsoHKOM cocyAe θμκοοτβκ) 500 m oxjia5wa*ra ίΡΤίφθχχΛορζοτΗβ ra£wiž flo -78°C, nocjie nero &Q6amsum TeTpa-rijflpo^ypaH /200 ι\υι/, μθλζγθηηο no KanjiHM ;aodaBjmjiB no^y^eHHyio Bmiie iipo3paHHyK)-S8JiTyiD «MflKocTL npn TeMnepaType -78°C, nepe-MeumBajni 3Ty cMecL'npa κομηβτηο8 Tervraepaiype b Te^eHne 17,5 ^acoBr Harpesara ee c odpaTHHM xojioabjibhekom b τθεθηβθ ο&ηογο ^aca, ocTanjūiziH ηο^^θΗΗίώ προ,π^κτ jum fflCJiaafleHna, ottoh&eb paoTBopBTejiL B3 pacTBopa sejiTO-opaBzeBoro ΐζΒβτα, coaepsamero dejiuž ocsaok, ^oc5aE3uyiB μθτβλθηχλορηλ /200 wi/t a 32τθμ pa3~ daBJieHHJ'E) X^OpBCTOBOnopOAHya KHCJIOT? /100 iVJl/, ΟΤΛβΛΛΛΒ 2ΒΛ- KOCTt, BHcyiuBBajiB cjioti MeTPUieHxnopn^a Ha^ (5θ3βο^ηημ cyjiB<laTOM HaipBB, OTIOHHJIB ΜβΤΚΛΘΗΧΛΟρΕΑ, AOdaBJIHJIE ΠΟΗΤ£Η, OTpJIBTpO- BHBajin HepacTBopHMoe TBopjļoe EeaļecTfio, oxjrasy;a^B εθλτηζ £bjib-TpaT c 0(5pa30BaHneM &ejrTOBaTO-dejmx KpECTanjioB /2,02 r/. 3na- ΗβΗΒΒ $Μ3ΒΗΘ0Κ1ΪΧ CBOHCTB 3Τ0Γ0 ΟΟβ/ζΠΗΘΚΕΕ ΠρΒΒΘββΗΗ HESS. ΚρΟ-m τογο, npoasBOjuum onpenejienne EH$paKpacHnx οπβκτροΒ b coot-B8TCTEHB C MeTOflOM, OCHOBaHHIiM Ha ΠρΗΜβΗβΚΗΒ KB^, 13 ΟΠρβΛΘΛ^ΟΙΕ - 33 - cneKTpH %-HMP ripu εοπολβ3οβ8ηηβ CDGI3 b na^ecTBe pacTBopn- rejig. KHipaKpacHne οπβκτρυ: noKasaHH na pac. 17
CneKTpu HJ.IP: noKasami Ha pnc. 18. Πώεμθρ 19 ļlOJIUMSPB 33ΙΙΗ£Γ B aBTOKJias $>1TS θιλκοοτβιο 1,5 ji, χοροπιο προίΰ/τΗϋ ra3oodpa3-Ebdi a30T0M, ποοζτθλοβετ&κβηο Rotiamsūna οηηιιιοηηκΕ TOJiyoji /500 m/, iJeTHJiaCKL'iffiHOKCaH, Μ3ΓΟΤΟΜβΗΗΚ2: <ρρ&θ2: "Tofio CT§^C|ep ΚΘΪ&3Κ3Λ ηομπηηε, jimt" AiojieK7JLf3pHHā eso: 770° /4,0 mmojih/ e ab^juio-pECT£$ ^MQTIWCIiJIE^EC/MeTEJIIiEKJIOneHTazy3eEIiJl/ra^HE2 /0,005 mmojih /, nocjie ^ero nosuniajiE TeMneTapyiy λο 30°C npH HenpepnB-eoū no^a^e npomizresa c τθμ, ητοόη coxpaHETL odmee AaBJienne, paBHoe 3 κγ/ομ^Γ, e ocymecTBJXHJiE nojiHMepBsaiUīiD b Te^eHEe 2-x ^acsB, saieM nocjie okohesihih peaKUBB προιΐ3ΒθΛΐυΐ0 paajioseEue ΚΟΓνίΠΟΗβΗΤΟΒ KaTajIE3a_T0pa H BHCJlUBBaJIE ΠΟΛ^ΗΘΗΗΐώ HOJIEIiponEJieH c odpaaoBaHBeM K30TaxTEHecKoro nojiEnpomuieHa /16 r/. Aktebhoctb KaTajiE3aTopa οοοτεβλλτιη 8,9 κγ/γ Hf .gac, a ero μολθκ^ληρηκΜ sec paBHBJiCH 66800. Πρεμθρ 20
JlByxjiopEcm2 ^MeTiuīcnjiEji/i^K^oneHTaAEeHiiV/HeTEJiipjKjio-. neHTamieHEJi/reaHEH
Bce peaKiiīra ocyņecTBjyuna b aTMoegepe ΗΚθρτΗΟΓο ra3a. Kpoue Toro, pacTBopETejiB peaicuEB npeflBapHT&JiLHO BECj^oniBa.’iE nepe^- ero..
I npuMeKeiuieM b npouecce. B ct8Kjmhhom peaKUBOHHOM cocy,ne β&κσ-ctm) 200 kji pacTBOpattH ΑΜΐβτηπ/ιφΐ}νιθΕβιιτ8Μ&ιχχ/ΑΛΒΤΐνπιρΐϋΐο~ neETajļHeHMji/cEjiaH /3,0, 15 mmojigS/ b neHTane /50 rji/, ποολθ Hero no KaiuiHM μθμθηηο nodanajum pacTBop /20 m/ h—<5ytejltehthh - 34 - LV 10213 /1,6 11/ b reKcaae npn oxJi£2Qiezkh jibaou, nepei/ieumBajua 3Ty cmscl npH Kor.iHaTHoS TerniepaTjpe b Tenemie 2 ^scob .2 οτγοηπλιη pa-
Tpar2ApoaypaH /50 m/t ητο ποββο,π^λο nojryHUTi> προ spārei aejiTyio etokoctb.
B CTewinHROM peaKmioiiHOM cocy%e θμκοοτβκ) 500 ma ojaas^ajm ^θΤΗρβχχΛορποτωί ra|HUM /4,8 r, 15 MMDaeii/ flo -78°C, noejie Mēro ^odaBJiHJin TeTparn^po^[ypaH /200 μτγ/ no ksiijihm ΜβΛΕβΗβο ^odaEJinJin nojiyneHHyD βηπιθ npo3paqHyK> KejiTyK) 2οιλκοοτβ πρπ τβκ-nepaType -78°C, nepeMeiiMBajm 3Ty cmscs npn κομηβτηο& TeMnepa-iype b TeneHiic 14 nacoB, ottohbjtu pactbopbτβjib H3 sejrroro pa-CTBopa, coflepaaūļero feoe TBep;noe boiijoctbo , ^odaEJiHJiB μθτηλθη-xjiopiw /200 m/9 a saseM pa30aBJieHHyio kjiopbctoboaopootk) kh~ c^otj /100 m/ πριι οχλοβήθηηη jeb^om οτλ&ελιη sh^kactb, BHcy— UIBBajin CJIOfi MeTBJI6H3UIOpHfla ΗΘΛ ($Θ3Β0ΛΗΗΜ CyjIL$aTOM ΗΕΤρΒη, OTTOHBJm ΜβΤΒΛΘΗΧΛΟρΒΛ, R06aBJWJl2 ΠβΗΤ2Η, OTgiUIBTpOBHBSJīH nojiyneHHoe τεβρ^οβ βθιαθοτβο o odpa30BamīeM dJieAHo-sejieHoro ΤΒβρΛΟΓο BenļecsBa /2,22 r/ 0 peKpucTajuii330BHBaji2 KpucTajLEH B3 ropnnero renTana /20BHjt/, hto no3BOjmjio nojiynnTL άιο£ΗΗθ sejiTOBaTO-<5ejiHe kpbctsjijih /0,94 r/. SHa^emia p3B^ecKHx cboSctb 3Τ0Γ0 ΟΟβΛΒΗΘΗΚη ΠρΗΒβΛΘΗΗ HHSe* KpOMe ΤΟΓΟ, HpOJ33BOflIdJII2 ΟΙΐρο,ΠΘΛβΗΒΘ 2HipaKpaCHHX ΟΠΘΚΤρΟΒ 0 C00TB6TCTBBH C ΜβΤΟΛΟΒ Ha OCHOB0 ΠρΗΜΘΗβΗΒΗ ΚΒΓ7, H ΟΠρθΛ&ΕΗΛΗ ΟΠΘΚΤρΗ %~HMP C HC-n0vži'L30BaH.neM CDCIg B-KanecTBe pacTBopHTejiir; I'lH(|paKpacHHe οπθκτρη: ποκβ3βηη Ha pnc. 19. Οπθκτρη KMP: ποκβ3&εη Ha pnc. 29. - 35 - Πρίπ.;ερ 21 IIojinr.:eOH3aiiKfl ι Β &βτοκλ3.β STļ βί,ζκοστΒία 1,5 λ, χοροιιιο nponyTHii ra3oo<5-pa3EKM 33οτομ, nocyie.noaaTejiBHO nodaEjiBzn oninneHHtai TOJiyoJi i. /500 LBl/, L5CTBJISJIEP/iliHOKCaK, BSrOTOBJieHHHŪ pJŪiOK "Toifo CTay-cčep KeMMKaji κομποηβ, jimt." ApjieKyjinpHKM Bec: 770/ /4,0 mojix/ η AByxJiopKCTuii nm.:eτkjiclunL^i/n^κηοπ gh TanueH hji A:eτjumukjio ne ii ?a-flHeHMJi/ražHHfi /0,005 mmojih/, nocjiennero noBHmajm maiepaTypy no 30°C npM KenpepHEHOH nonāks nponujiena c τθμ, ^rrodn coxpa-ebtb odnee nannenue, paanoe 3 kt/cj,? Γ. 0 ocymecT£jinjnj nonu-
* I
Mep03aipjE) b τθηθκηθ 2 nacoB, 3aTew nocjie οκοηηβηβη peaKmra npou 3Εοηιΐ/Ίϋ paaEozeKBe κομποηοητοε KaTaji23aiopa c imx>inEK) MeTanojia n BycyaiiESjm πο^ηθηκη# nojiEnponnjieH c odpasoBanneM ΐ53θτεκτΐΉ8θκοΓθ nojumponnneHa /0,6 r/· Aktbbhoctb KaTann3airo-pa cocTaE/iHJia 0,34 κγ/γ fiilnao, a ero iJOjieKyjiHpHHS Bec paB-KfLTCH 52800.
Ifonuep 22
Jfeyxjiopi3CthIī nHr^BTBjiciūiujidsc/ipeT-d^ mutHioioneHTaniJeHiui/- rapu2
Bce peaKujra ocymecTBJUM b aTMoegepe HHeprHoro ra3a. KpoMe τογο pacTBOpSTejiL peaioniii npenEapBTejīBHO EKcyniiiB&sa nepe# ero πρΕΜβΗθΚΒθΜ b nponecce. B CTeKJiHHHOM peanpJOHEOM cocyne ew-koctbej 200 m. pacTBopajni n0^eTiwd2c/Ti)ST^yTHJiiņ:KJioneHTan0eHiiJi/ CHnaH /4,8 r, 16 MMOjiēii/ β πθητθεθ /50 mji/, 'nocjie Mēro no Kamīna MenjienHo nodaB/ia^n pacTBop /22 m/ H“dyTZJumTL'n /1,6 W b reKcane npn oxnaaneHiiu ηΒΛΟΜ, nepeMemuBajm 3¾7 ομθοβ npn KOMHaTHoii TeMnepaType b TeneHiie 4 nacoB, ottohhjih pacTEopn- - 36 - LV 10213
Tejii, c odpaaoBaHKeu (5e;ioro -TBepaoro BemecTBa / Atņlue^ii/ I ·ζ?-Β iz-CgH^/» a ποτογ.; ^odaam/TB κ 3Tot:y BemecT£y τβτρβΓκ- . ,^po(£ypaH /60 wi/t ητο πο3εο.ίιβιο πολ^ήηγε npo3pā^Hy}o KejiTjno 2fCH£K0CTB. B CTeKJiHHHOM peaiapjoiiHOM cocyae θμκοοτβιο 500 i.vi oxaaswa- jm qerapexxJiopBCTHft ra^rnai /5,1 rf , 16 kmiieS/ #o -78°C, nocjie ·« ^ero .nodaE.’LHJrn TeTpari5;npo$ypaH /250 m/t no Kamuai KejvieHHO AodaBJuittB npo3pawK) ūe;iTyio hbakoctb npu Tei>inepaType -78°C, OCTaEJULlB OTy CMGCB JUDT ΒΗΟΤΟΕΒΒΗΗΗ C H0JIBIO flOCTKKeHKH KDElHaT- ho3 Ter.mepaT^pH, Harpesanu c odpaTHHM χολολ&πβηηκομ b τηίθκκθ 84 ^acoB, οοτΒΕΕίϋΐη noji^eHHKii ^aTepuaji oxJia££emiH, ot~
rOHBUIB paOTBOpKTeJIL B3 np03pa^H0P0 paCTBOpa SeJITO-OpSBSeEOrO
HseTa, ^odaBJBum ΐ,'βτιυίθΗχτιορηΛ /300 m/, o 3aTeM pa3(5aBjieHHya xjiopL'CTOEO^opoAKyio KBCJioay /100 m/ πρη οκεββ^θηκη jib^om, ot- fiozsvus sn^KocTB, BHcyaHB3Jin Cviofl i5ieTi3JieHXJiopiiĀa Ha& de3B0#- / hhm cy^B(TaTOM HaTpna, ottohhjiu MeTiuieHXJiopn#, ftodaBMU πθη-TaH, $MhT]X>B3JIJ2t KOKDieHTpiipOEaJIB B OX^a2WaJIB IIOJ^eHHKŽ aeJiTHS ^BJīBTpaT c odpasoBanueM dJie£HO-£ejiTHx KpncTanjioB /1,41 r/. SHa^eHKH 523BnecKBx cbobctb θτογο οοθλιιηθηεη πρηΒβ-fleHH IIHEG. ΚξΟΜΘ ΤΟΓΟ, npoH3BOJūUm ΟΠρθΛΘΛβΗΕΘ BH$paKpaCHHX οπβκιτροΒ b cooTBeTCTBuu c μθτολομ Ha ocHose npnMepeHBB KB Γ, h onpejieiLfEHs cneKTpū c βοπολββοββηβθμ CDCIg b itanecTBe pac T BO pil T ©JIH · 3aa^eHBH 3JieM3BTapHoro aHajiE3a: /¾¾)¾^ ^ / ΒΗΟΏίΐδϋΗοβ 3HaH8HBe../^/f· · C· 43,84 - H-5,52-IIojiy^eKHoe 3Η&ίθηηο /%ļ\ C 44,05 H 5,62 UH^paKpacHHe cneKipH: H0Ka3aHH na pnc.2I CneKipu HLS: noKa3aiai Ha puc. 22. - 37 - ' Πρημθρ 23 Πθ.ΠΚΜβΡΕ351ΠΡΐ B aBTOKJias $ΊΓ£ θμκοοτβιο 1,5 λ, χοροιιιο προ^τιώ ra3oo<5-pa3HKL··! a3QT0U, nocjie&oBaTejiBKo AOO'aBJiHJiH o^iineHHHfi toji^oji' /500 isji/t. MenuiajuūMHHOKcaH, Β30Τ0Μθηηη2 gapMofi "Τοίίο Csay$ep KeLiEKSJi Kor.caHU, joit" /?āO ji e kjjlhphhh Bec: 370/ /4,0 hmojw/ h jpayxjiopHCTHJt Āi5i3eTiuicHJiEJi0i3c/TpeT-<3y TMiļEKJioneHTa^HeE/nji/rai-Γΐώ /0,005 rasojis/, nocjie nero noMiara TeranepaTypy ao 30°C irpn HenpepHBKofi no^ane nponajieaa c τβΜ, hto(5h coxpaHBT£ odmee Λ ΛΟΒΛΘΗΒΘ, paBHOe 3 ΚΓ/6νΐ r, H. OCpiiļeOJTBJIttJIH IIOJIBMepB3δφ!Ι0 B ΤβΗβΗΒΘ 2 ^aCOB, 33ΤΘΜ nocjie OKOHRaHEH peaKtpia προE3BOLĪTU paajioseHEe κομποηθητοβ kατευιυ3aTopa c noMomEio L-eraHojia π ehcj-uniBajni nojipneHHKiS: nojEsnpomsjieH c odpa30Banner.i H30TaKTBnecKoro nojuraponaneHa /0,3 r/, Akthbhootb KaT8-TH3aTopa cocraBJUKa 0.17 κγ/γ H-f ,^ac, Ero MOJieKyjwpHBift Bec pasHasca 17200. COaBHETGJimjii ΠΌΗΜΘΡ' 4 B aBTOKJiajB SVJeLrīKOCTBK) 1,5 ji, χοροιηο προ^τιώ ra30odpa3-HHM aŠOTOM. Π0CJIBROB3.T8JILH0 ROCaBAAJIīI O^MļeHHHŽ TOJiyo;i /500 m/, mTEJiajnaanHokcan, Ε3Γοτοεπθηηηη φιρκοΑ "Tofio Crapgep κθμεκθλ Koi/Hisnu, jimt". AiojieKpjīBpHHŪ Bec: 770/ /4,0 mičojis/ z &Eyxjio-pncTKfi jiEMeTHJiCEJiidJi<jBc/ip3KJioneHTa^EeHHjr/ra5iin2 /0,005 MvJojib/, nocjie nero noBumajis reijnepaTypy peaHUHH ro 30°C πρκ HenpepnB-hoS no^a^e nporauiena c τθμ, hto6u coxpaHET£ odmee ;iaBJieHJie, paBHoe 3 κγ/cm2 Γ, % ocymecTBJWJD3 nojoiMep03Simio a Te seni; e -2 -na~ cob, 3&Teu nocjie OKoiraaBEH peaKitiia προη3Βολμλη pasjroaemie kom-ποηθητοβ KaTajic3aTopa c πομο^βιο MeTaHOJia u BHcponBajiii uojjyqeHr-hhū ποΛκπροπΗΛθΗ c odpaBOBamieM aTaKTHHOCKoro nojronponHJieHa /3,5 r/. Aktmbhoctl KaTajD33aTopa paBHHJiacL 2,0 κγ/γ H*f.Rac. - 38 - LV 10213 - 38 - LV 10213 *Λ'
«MRMIA HS0SPBT3HM)!
Ij. Οοολεηθημθ πβρθΧΟΗΗΟΓο tieTajma gopr^jni /1/
3 κοτοροζ M npeflCTaBJweT.impKOHnfi hjih rapnž; VnpeflCTaa^ī- Λ βτ κρβΜΗίΐϋ ji® repMaimS; κε&Ακ£ U3 sjīeMeHTSB R·^-CgH^ yja -CgH^ ^ npejļCTaEjiiieT He3aMemeEiiyio ejih · 32iiemeHEyio ιϊηκεοπθκ-Ta^iieHUJi£Hyio rpymry; γ\ u \jf npe^cTaBJineT ijejioe hhojio ot 0 #o 4, ho cjry*īafi, Koraa n = (^-0 u īl~(j/=4, βοκλβηββτοα; οοοτεθτ-CTE^KUļBe 3JIGMeH.TH R? MOryT Ι3Ι*ίβΤΕ O^BHSKOEie BJIH pG3JI2HHKe 3KaH0HUH u npe^c τε&Ί/ποτ a?ou so^opo^a, cmmurj® rpyniīy hot yrjreBo;ioporaiS paanKaji; cooTBeTCTEyionae θλθμθητη R? iioryT ημοτβ OAEHaKOBHe mjie paara^EHe 3Ha^emia h npeflCTaEjunoT ετοΜ Eo^opo^a iunj yrjresoflopoflKHS pa^UKSJi; 2 cooTB9TCTBysipe ajieiseKTu X ivioryT uivieTB oABHSKOBue ejie paaEB^HKe sHa^eima 2 npe^cTaBJunor stom no^opo^a, ετο’νΐ rsjioreHa imi yrjieBO£opo£HHii pa^EKaji; u 2. KaTa^msaTop mx nojņvemvī CTepeoperyjiapHoro nojnmepa ojiegHKa,. OTJiE^aEiuiiScB Tewf ^to oh b Ka^eoTse ©^.θκτηεεεχ kom- ΠΟΗΘΗΤΟΒ BKjiio^iaeT: /Aj coejmiieHue nepexoAHoro ueTajura čopMyjm - 39 -
Β κοτορο2 Μ npeflCTSBJiHeT coe^KeHiie ιιθρθεοληογο MGTajL»ra iņap- KOH13H 2JI2 lTaČHBH; Υ ΠρΘ£ΟΤ£ΕΕ£βΤ ΚρβΙ,'ΊΚΗΗ I5JH3 ΓθρΜΒΗϋΜ \
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η i\s^.4= 4, BCKJiio'iaeTCH; οοοτβθγοτβ^πι^κο βλομθητη' Εγ r-.:-oryT ΒΙν'ΘΤΒ ΟΛΒΗδΚΟΒΗΘ 2JI2 ga3JDĪHHHe 3ΗΒΗβΗ2Η 2 ΠρΘβΟT£BJIBDT aTOM
Bo^opo^a, chjimjilh^io rpynuy mm yrjieBOflopoflHH3 pewnKajx, ho no-λοκθηηθ 3JieweHTa R? β ηηκλοπθητθλβθηιμιβηομ zojiiņe 2 τηπ ajre- τ
MeHTa R ΛΟΛΚΗΗ COOTESTCTBOBaTB KOHfHrypaiiUHf rtpa κοτοροϋ OT-cyTCTByeT Kaitaa-juido iuiockoctb cmavieipim, EKjnoHSEmsH M; čoot- _9 ...
EeTCTB^Etpe ajieMeHTH Rp MoryT ημθτβ οβΠΗεκοΕΗθ hjiīj pasjiHmme '3Ha^em3H 2 npejic Ta^ara aioM Bo^opo^a ara yr^eBOflopojiHHŪ pa~ Λ2Κδϋΐ; 2 cooTBeTCTEyiaii2e θλθμθητη X woryr βμθτβ o^naKOEne ara pa.a7i2HHHe 3HaHeHEH 2 npe^cTaBJiaioT stoli Bo^opo^a, btom ra-jioreHa 2Jm yr^eBo^opo^Hidi pa^Ka^, 2
/5/ ajncfvmiiOKcaH popipyjiH /Π/ mm gopMyjiy /W - 40 - LV 10213
L ί°*|Ί^Ρ - 0") b κοτορίίχ M npe^oraEJiBer iļejioo ojotio ot 4 ,no 30, a I^3 npe^cTaB-jineT yrjieBo,nopo^HKii pa^naji. - 41 - LV 10213 ΡΒΦΕΡΑΤ Ηοβοθ cosflimeHHe nepexo£Horo MeTSjuia, coaepzainee <5EC3a-
i^Y lueiIļGHHHH ΙζΙίΙϋΙΟΠΘΗΤδΛΙΙβΚΕΛΒΗΗΚ JfflTaim C l^OCTHKOBOŽ CTpyKTypoft /1/, H HOBaS CMeCB ΟΟΘΛΗΗΘΗΙΙΗ /1/ C amiHBOKCaHOM /B/t κοτορπβ BB7IHI0TCB nOJieSKHTiU B ΚΕΗΟΟΤΕΘ ΚΟΜΒΟΗ6ΗΤΟΞ KaTcUIU 3ST0pa flJUĪ CTepeoperyjwpHofi nojimiepH3aixKH ojiepHa, npireeM coe®3HeHiie /1/ εμοθτ c|opMy;iy
ληθτ HesaMemeHHjD'iuīH 3aiviemeHHyio βρκλοπθητοληθιμ^ίο rpynny; η i 0/ πρθΛοτεΒΛΗΐοτ i^ejioe ^iecjio ot 0 jxo 4, ho cj^^an, Kor^a
ΟΛϋΗδΚΟΒΗΘ J3JI2 pa3JIIIHHHe 3Ha^eHHū H ΠρβΑΟΤβΒΛίϊΙΟΤ H, CBJffiJI HHB
hjib paattHEHHe ana^eHHn η npeitCTaBJunor H ejih yrjie Bo^opo ahhž pajtEKaji; η θλθμθητη X MoryT εμθτβ ojuiHaKOBKe bjib pa3jraEHHe SHa^eHBH η itpe^c tslbjuūdt H, rajioreH BJm yrjieBo;iopo(rtfiH& pa&n-jsaji; a amaiHOKcaH maeeT gopMyjiy /Π/ mm $opwy;iy /Ui/ - 42 -
ο β κοτορΗΧ Μ npe^CT2BJweT iļejioe ^kcjio οτ 4 £0 30, a £ npe^ CTaBjineT ^γλθεολοροληηϊϊ pa^Kajr.
Claims (3)
- LV 10213 Izgudrojuma formula 1. Pārejas metāla savienojums ar formulu (I):kurā: M ir cirkonija vai hafnija atoms; Y ir silīcija vai germānija atoms; katra no grupām RVCsbVn un R1 -C5H4^ ir neobligāti aizvietota ciklopentadienilgrupa; n un q ir vesels skaitlis no 0 līdz 4, izņemot gadījumus, kad n=q=0 un n=q=4; R1, kas var būt vienādi vai dažādi, ir ūdeņraža atoms, sililgrupa, vai ogļūdeņraža palieka; 1 R2, kas var būt vienādi vai dažādi, ir ūdeņraža atoms vai ogļūdeņraža palieka; X , kas var būt vienādi vai dažādi, ir ūdeņraža atoms, halogēna atoms vai ogļūdeņraža palieka.
- 2. Katalizators stereoregulāru olefīnu grupas polimēru iegūšanai, kas a t š ķ i r a s ar to, ka tas satur kā aktīvos komponentus: (A) pārejas metāla savienojumu ar formulu (I):(I) kurā: M ir pārejas metāla cirkonija vai hafnija atoms; Y ir silīcija vai germānija atoms; katra no grupām RVc5H4_n un R1 -CSH4^ ir neobligāti aizvietota ciklopentadienilgrupa; n un q ir vesels skaitlis no 0 līdz 4, izņemot gadījumus, kad n=q=0 un n=q=4; R1, kas var būt vienādi vai dažādi, ir ūdeņraža atoms, sililgrupa, vai ogļūdeņraža palieka; pie kam R1 vietai ciklopentadienilgrupā un tās tipam jātbilst konfigurācijai, kas nesatur nekādu M iekļaujošu simetrijas plakni; R2 , kas var būt vienādi vai dažādi, ir ūdeņraža atoms vai ogļūdeņraža palieka; X , kas var būt vienādi vai dažādi, ir ūdeņraža atoms, halogēna atoms vai ogļūdeņraža palieka; unR
- 3 (B) aluminoksānu ar formulu (II) vai (lll_ RgAI 2 3 LV 10213 - (OA0 — (III) R3 kurās m ir vesels skaitlis no 4 līdz 30, bet R3 ir ogļūdeņraža palieka. 3
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62282538A JP2587251B2 (ja) | 1987-11-09 | 1987-11-09 | 立体規則性オレフィン重合体製造用触媒 |
| JP63151666A JPH0720973B2 (ja) | 1988-06-20 | 1988-06-20 | 橋架け構造のビス置換シクロペンタジエニル配位子を有するハフニウム化合物 |
| JP63151665A JPH0713075B2 (ja) | 1988-06-20 | 1988-06-20 | 橋架け構造のビス置換シクロペンタジエニル配位子を有するジルコニウム化合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| LV10213A LV10213A (lv) | 1994-10-20 |
| LV10213B true LV10213B (en) | 1995-08-20 |
Family
ID=27320148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LVP-92-216A LV10213B (en) | 1987-11-09 | 1992-11-25 | The compound of transition metal and catalist for producing of stereoregular polymer |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4931417A (lv) |
| EP (1) | EP0316155B1 (lv) |
| KR (1) | KR0137477B1 (lv) |
| AT (1) | ATE133966T1 (lv) |
| AU (1) | AU603268B2 (lv) |
| CA (1) | CA1326676C (lv) |
| CS (1) | CS277432B6 (lv) |
| DE (1) | DE3854987T2 (lv) |
| LV (1) | LV10213B (lv) |
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Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| CA1268754A (en) * | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
| US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| EP0260999A1 (en) * | 1986-09-19 | 1988-03-23 | Exxon Chemical Patents Inc. | High pressure, high temperature polymerization of ethylene |
| ATE133690T1 (de) * | 1987-04-03 | 1996-02-15 | Fina Technology | Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke. |
| IL89525A0 (en) * | 1988-03-21 | 1989-09-10 | Exxon Chemical Patents Inc | Silicon-bridged transition metal compounds |
| US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
-
1988
- 1988-11-02 US US07/266,065 patent/US4931417A/en not_active Expired - Lifetime
- 1988-11-04 CS CS887281A patent/CS277432B6/cs not_active IP Right Cessation
- 1988-11-04 AU AU24765/88A patent/AU603268B2/en not_active Ceased
- 1988-11-08 KR KR1019880014639A patent/KR0137477B1/ko not_active IP Right Cessation
- 1988-11-08 CA CA000582530A patent/CA1326676C/en not_active Expired - Fee Related
- 1988-11-09 AT AT88310549T patent/ATE133966T1/de not_active IP Right Cessation
- 1988-11-09 EP EP88310549A patent/EP0316155B1/en not_active Expired - Lifetime
- 1988-11-09 DE DE3854987T patent/DE3854987T2/de not_active Expired - Fee Related
-
1992
- 1992-11-25 LV LVP-92-216A patent/LV10213B/lv unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0316155A2 (en) | 1989-05-17 |
| KR890008153A (ko) | 1989-07-10 |
| LV10213A (lv) | 1994-10-20 |
| EP0316155B1 (en) | 1996-02-07 |
| AU603268B2 (en) | 1990-11-08 |
| DE3854987D1 (de) | 1996-03-21 |
| CS277432B6 (en) | 1993-03-17 |
| DE3854987T2 (de) | 1996-09-12 |
| ATE133966T1 (de) | 1996-02-15 |
| CA1326676C (en) | 1994-02-01 |
| KR0137477B1 (ko) | 1998-05-01 |
| AU2476588A (en) | 1989-05-11 |
| US4931417A (en) | 1990-06-05 |
| CS728188A3 (en) | 1992-08-12 |
| EP0316155A3 (en) | 1991-07-24 |
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