LU81073A1 - Procede de fabrication de monoethylphosphite d'aluminium - Google Patents
Procede de fabrication de monoethylphosphite d'aluminium Download PDFInfo
- Publication number
- LU81073A1 LU81073A1 LU81073A LU81073A LU81073A1 LU 81073 A1 LU81073 A1 LU 81073A1 LU 81073 A LU81073 A LU 81073A LU 81073 A LU81073 A LU 81073A LU 81073 A1 LU81073 A1 LU 81073A1
- Authority
- LU
- Luxembourg
- Prior art keywords
- mixture
- aluminum
- reaction
- temperature
- monoethylphosphite
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 42
- -1 ALUMINUM MONOETHYLPHOSPHITE Chemical compound 0.000 title claims description 11
- 239000000203 mixture Substances 0.000 claims description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 33
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 23
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 15
- ZUNGGJHBMLMRFJ-UHFFFAOYSA-O ethoxy-hydroxy-oxophosphanium Chemical compound CCO[P+](O)=O ZUNGGJHBMLMRFJ-UHFFFAOYSA-O 0.000 claims description 14
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 238000000354 decomposition reaction Methods 0.000 claims description 9
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 238000007127 saponification reaction Methods 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 8
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 8
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 235000010755 mineral Nutrition 0.000 claims description 6
- 238000006386 neutralization reaction Methods 0.000 claims description 6
- 239000012429 reaction media Substances 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 235000019441 ethanol Nutrition 0.000 description 14
- XRBGEQKKQIRUOE-UHFFFAOYSA-N dialuminum ethyl phosphite Chemical compound [Al+3].[Al+3].CCOP([O-])[O-].CCOP([O-])[O-].CCOP([O-])[O-] XRBGEQKKQIRUOE-UHFFFAOYSA-N 0.000 description 11
- IYYIUOWKEMQYNV-UHFFFAOYSA-N sodium;ethoxy-oxido-oxophosphanium Chemical compound [Na+].CCO[P+]([O-])=O IYYIUOWKEMQYNV-UHFFFAOYSA-N 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000010924 continuous production Methods 0.000 description 5
- RPGRUARWZPXHAG-UHFFFAOYSA-N CCOP(O)O.N.N Chemical compound CCOP(O)O.N.N RPGRUARWZPXHAG-UHFFFAOYSA-N 0.000 description 4
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- HJJOHHHEKFECQI-UHFFFAOYSA-N aluminum;phosphite Chemical compound [Al+3].[O-]P([O-])[O-] HJJOHHHEKFECQI-UHFFFAOYSA-N 0.000 description 3
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 3
- 229960003750 ethyl chloride Drugs 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- ZHLKXBJTJHRTTE-UHFFFAOYSA-N Chlorobenside Chemical compound C1=CC(Cl)=CC=C1CSC1=CC=C(Cl)C=C1 ZHLKXBJTJHRTTE-UHFFFAOYSA-N 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001944 continuous distillation Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- FIJLRUHPLOIGRX-UHFFFAOYSA-N dipotassium;ethyl phosphite Chemical compound [K+].[K+].CCOP([O-])[O-] FIJLRUHPLOIGRX-UHFFFAOYSA-N 0.000 description 1
- PVBGTKPJXULQCH-UHFFFAOYSA-N disodium;ethyl phosphite Chemical compound [Na+].[Na+].CCOP([O-])[O-] PVBGTKPJXULQCH-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 150000003109 potassium Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010850 salt effect Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/142—Esters of phosphorous acids with hydroxyalkyl compounds without further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7809965 | 1978-03-24 | ||
FR7809965A FR2420540A1 (fr) | 1978-03-24 | 1978-03-24 | Procede de fabrication de monoethylphosphite d'aluminium |
Publications (1)
Publication Number | Publication Date |
---|---|
LU81073A1 true LU81073A1 (fr) | 1980-10-08 |
Family
ID=9206658
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
LU81073A LU81073A1 (fr) | 1978-03-24 | 1979-03-23 | Procede de fabrication de monoethylphosphite d'aluminium |
Country Status (25)
Country | Link |
---|---|
US (1) | US4272448A (de) |
JP (1) | JPS54132526A (de) |
AT (1) | AT376223B (de) |
BE (1) | BE875081A (de) |
BR (1) | BR7901800A (de) |
CA (1) | CA1117967A (de) |
CH (1) | CH636624A5 (de) |
DD (1) | DD142535A5 (de) |
DE (1) | DE2911516A1 (de) |
DK (1) | DK146628C (de) |
ES (1) | ES478893A0 (de) |
FR (1) | FR2420540A1 (de) |
GB (1) | GB2017706B (de) |
IE (1) | IE47939B1 (de) |
IL (1) | IL56936A (de) |
IT (1) | IT1114217B (de) |
LU (1) | LU81073A1 (de) |
NL (1) | NL188698C (de) |
PL (1) | PL126412B1 (de) |
PT (1) | PT69389A (de) |
RO (1) | RO77719A (de) |
SE (1) | SE447655B (de) |
SU (1) | SU971102A3 (de) |
YU (1) | YU41150B (de) |
ZA (1) | ZA791379B (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1005265B (zh) * | 1985-04-12 | 1989-09-27 | 福建师范大学 | 新型铝体系偶联剂 |
JP2747586B2 (ja) * | 1988-01-29 | 1998-05-06 | 花王株式会社 | ジアルキルリン酸ポリアルミニウム塩の製造方法,該塩からなる油ゲル化剤及び該塩を含有する外用剤組成物 |
DE19639657C2 (de) * | 1996-09-27 | 2000-03-09 | Hoechst Ag | Verfahren zur Herstellung von Aluminium-dialkylphosphinaten |
CN101525302B (zh) * | 2009-04-30 | 2012-02-08 | 山东德浩化学有限公司 | 在乙草胺生产中联产杀菌剂三乙膦酸铝的方法 |
CN102268033A (zh) * | 2011-06-16 | 2011-12-07 | 浙江嘉华化工有限公司 | 0-乙基磷酸钠生产方法 |
CN102766157B (zh) * | 2012-09-05 | 2015-11-11 | 利民化工股份有限公司 | 一种生产三乙膦酸铝原药的方法 |
CN113121595A (zh) * | 2019-12-30 | 2021-07-16 | 江苏剑牌农化股份有限公司 | 一种α-R烷氧基对氯苄基膦酸单酯 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2456627C2 (de) * | 1973-12-14 | 1984-05-10 | PEPRO - Société pour le Développement et la Vente de Spécialités Chimiques, Lyon | Fungizide Mittel auf der Basis von Phosphonsäureestern |
FR2254276B1 (de) * | 1973-12-14 | 1977-03-04 | Philagro Sa | |
DE2513965C3 (de) * | 1975-03-29 | 1979-05-31 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Herstellung von MetaUphosphorigsäuremonoesterverbindungen |
GB1589670A (en) * | 1976-11-16 | 1981-05-20 | Philagro Sa | Process for the manufacture of aluminium ethylphosphite |
-
1978
- 1978-03-24 FR FR7809965A patent/FR2420540A1/fr active Granted
-
1979
- 1979-03-22 ZA ZA791379A patent/ZA791379B/xx unknown
- 1979-03-22 IL IL56936A patent/IL56936A/xx unknown
- 1979-03-22 YU YU690/79A patent/YU41150B/xx unknown
- 1979-03-22 DD DD79211746A patent/DD142535A5/de not_active IP Right Cessation
- 1979-03-22 CA CA000323962A patent/CA1117967A/en not_active Expired
- 1979-03-22 GB GB7910175A patent/GB2017706B/en not_active Expired
- 1979-03-23 BE BE0/194208A patent/BE875081A/xx not_active IP Right Cessation
- 1979-03-23 AT AT0218779A patent/AT376223B/de not_active IP Right Cessation
- 1979-03-23 RO RO7997025A patent/RO77719A/ro unknown
- 1979-03-23 DK DK120079A patent/DK146628C/da not_active IP Right Cessation
- 1979-03-23 LU LU81073A patent/LU81073A1/fr unknown
- 1979-03-23 PT PT69389A patent/PT69389A/pt unknown
- 1979-03-23 IT IT21266/79A patent/IT1114217B/it active
- 1979-03-23 BR BR7901800A patent/BR7901800A/pt unknown
- 1979-03-23 DE DE19792911516 patent/DE2911516A1/de active Granted
- 1979-03-23 PL PL1979214335A patent/PL126412B1/pl unknown
- 1979-03-23 JP JP3417379A patent/JPS54132526A/ja active Granted
- 1979-03-23 SE SE7902656A patent/SE447655B/sv not_active IP Right Cessation
- 1979-03-23 NL NLAANVRAGE7902320,A patent/NL188698C/xx not_active IP Right Cessation
- 1979-03-23 CH CH274379A patent/CH636624A5/fr not_active IP Right Cessation
- 1979-03-23 ES ES478893A patent/ES478893A0/es active Granted
- 1979-03-24 SU SU792739698A patent/SU971102A3/ru active
- 1979-06-25 US US06/051,753 patent/US4272448A/en not_active Expired - Lifetime
- 1979-08-08 IE IE636/79A patent/IE47939B1/en not_active IP Right Cessation
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0403351B2 (de) | Verfahren zur Herstellung von Ascorbinsäure | |
EP2147089B1 (de) | Verfahren zur herstellung alkoholischer ester aus triglyceriden und alkoholen unter verwendung heterogener katalysatoren mit einem phosphat oder einer organophosphorierten verbindung von zirconium | |
JPS6336760B2 (de) | ||
FR2700767A1 (fr) | Procédé perfectionné de fabrication de (méthacrylates d'alkyle par estérification directe. | |
LU81073A1 (fr) | Procede de fabrication de monoethylphosphite d'aluminium | |
CA2383104C (en) | Non-corrosive catalytic hydrolysis of fatty acid esters to fatty acids | |
FR2791673A1 (fr) | Procede de preparation des esters de l'acide hydroxymethylthiobutyrique | |
KR100814597B1 (ko) | 메틸 4-포밀벤조에이트와 디메틸테레프탈레이트의 분리방법 | |
CN103145796A (zh) | 一种纽甜合成工艺 | |
CN102633640A (zh) | 乙酰柠檬酸三丁酯的一体化生产工艺 | |
CN101967081B (zh) | 一种生产抗氧剂1010产生的含水甲醇溶液的回收工艺 | |
CN112375007B (zh) | 一种制备甘氨酸乙酯盐酸盐过程中产生的脚料的处理工艺 | |
CN102964252A (zh) | 利用混合催化剂制备没食子酸丙酯的工艺 | |
US3259662A (en) | Purification of trimethylolpropane | |
JPH02117640A (ja) | エーテルカルボキシレートの製造方法 | |
JPH02117638A (ja) | エーテルカルボキシレートの製造方法 | |
KR100228736B1 (ko) | 말론산에스터 폐액으로부터 말론산디알킬에스터의 제조방법 | |
US3948985A (en) | Method of producing carboxymethyloxysuccinic acid | |
JPS6174588A (ja) | 乳酸エステルの製法 | |
FR2601674A1 (fr) | Procede de preparation d'une solution aqueuse du sel de sodium de la methionine | |
BE840903R (fr) | Procede de preparation d'une composition tensio-active obtenue par transesterification du saccharose avec un ou plusieurs triglycerides | |
CH625532A5 (de) | ||
JP4505936B2 (ja) | プロピオール酸エステルの製造方法 | |
JP4240565B2 (ja) | アクリル酸エステルの製造法 | |
KR20050105769A (ko) | 폐 초산 에틸로부터 고 순도의 초산 에틸을 제조하는 방법 |