LT3225B - Copper complex bactericide/fungicide and method of making same - Google Patents
Copper complex bactericide/fungicide and method of making same Download PDFInfo
- Publication number
- LT3225B LT3225B LTIP447A LTIP447A LT3225B LT 3225 B LT3225 B LT 3225B LT IP447 A LTIP447 A LT IP447A LT IP447 A LTIP447 A LT IP447A LT 3225 B LT3225 B LT 3225B
- Authority
- LT
- Lithuania
- Prior art keywords
- copper
- acid
- aqueous solution
- polycarboxylic acid
- partially neutralized
- Prior art date
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 77
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 62
- 150000004699 copper complex Chemical class 0.000 title claims abstract description 34
- 239000000417 fungicide Substances 0.000 title abstract description 70
- 239000003899 bactericide agent Substances 0.000 title abstract description 66
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 239000010949 copper Substances 0.000 claims abstract description 187
- 229910052802 copper Inorganic materials 0.000 claims abstract description 154
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 152
- 239000002253 acid Substances 0.000 claims abstract description 98
- 239000007864 aqueous solution Substances 0.000 claims abstract description 55
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- 230000001580 bacterial effect Effects 0.000 claims abstract description 21
- 208000035143 Bacterial infection Diseases 0.000 claims abstract description 9
- 208000031888 Mycoses Diseases 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 59
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims description 56
- 239000005750 Copper hydroxide Substances 0.000 claims description 55
- 229910001956 copper hydroxide Inorganic materials 0.000 claims description 55
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- 238000000034 method Methods 0.000 claims description 29
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 14
- 239000005752 Copper oxychloride Substances 0.000 claims description 12
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 12
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 10
- 239000011976 maleic acid Substances 0.000 claims description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 10
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- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims description 9
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 9
- 239000005848 Tribasic copper sulfate Substances 0.000 claims description 7
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 claims description 7
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 5
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 5
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- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims description 4
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- 150000002148 esters Chemical class 0.000 claims description 3
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- 239000005749 Copper compound Substances 0.000 claims 4
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- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract description 8
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- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 31
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- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229940041514 candida albicans extract Drugs 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 108010079058 casein hydrolysate Proteins 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000021019 cranberries Nutrition 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- UPBDXRPQPOWRKR-UHFFFAOYSA-N furan-2,5-dione;methoxyethene Chemical compound COC=C.O=C1OC(=O)C=C1 UPBDXRPQPOWRKR-UHFFFAOYSA-N 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 235000019223 lemon-lime Nutrition 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 230000017074 necrotic cell death Effects 0.000 description 1
- 230000001338 necrotic effect Effects 0.000 description 1
- 235000014571 nuts Nutrition 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000008654 plant damage Effects 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 235000021013 raspberries Nutrition 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000020637 scallop Nutrition 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 230000037387 scars Effects 0.000 description 1
- 230000009528 severe injury Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000012138 yeast extract Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
- A01N37/04—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof polybasic
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86321792A | 1992-04-03 | 1992-04-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| LTIP447A LTIP447A (en) | 1994-09-25 |
| LT3225B true LT3225B (en) | 1995-04-25 |
Family
ID=25340590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LTIP447A LT3225B (en) | 1992-04-03 | 1993-03-19 | Copper complex bactericide/fungicide and method of making same |
Country Status (25)
| Country | Link |
|---|---|
| EP (1) | EP0565266B1 (enExample) |
| JP (1) | JP3470976B2 (enExample) |
| KR (1) | KR930021064A (enExample) |
| CN (1) | CN1060616C (enExample) |
| AT (1) | ATE176128T1 (enExample) |
| AU (1) | AU658275B2 (enExample) |
| BR (1) | BR9301186A (enExample) |
| CA (1) | CA2091136C (enExample) |
| CO (1) | CO4180383A1 (enExample) |
| DE (1) | DE69323229T2 (enExample) |
| DK (1) | DK0565266T3 (enExample) |
| ES (1) | ES2125947T3 (enExample) |
| GE (1) | GEP20002223B (enExample) |
| GR (1) | GR3030066T3 (enExample) |
| HU (1) | HU216092B (enExample) |
| IL (1) | IL105197A0 (enExample) |
| LT (1) | LT3225B (enExample) |
| LV (1) | LV10364B (enExample) |
| MX (1) | MX9301833A (enExample) |
| NZ (1) | NZ247274A (enExample) |
| OA (1) | OA09872A (enExample) |
| PT (1) | PT101248B (enExample) |
| RU (1) | RU2094988C1 (enExample) |
| TW (1) | TW272116B (enExample) |
| ZA (1) | ZA931681B (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0891708A1 (en) * | 1997-07-17 | 1999-01-20 | The Procter & Gamble Company | Anti-microbic agent |
| FR2792501B1 (fr) * | 1999-04-26 | 2004-02-06 | Elf Atochem Agri Sa | Traitement phytosanitaire des plantes par un chelate de cuivre soluble libere graduellement in situ a partir d'une source de cuivre non chelate et d'un chelate et compositions utilisables a cet effet |
| US6918715B2 (en) | 1999-06-11 | 2005-07-19 | Anchor Wall Systems, Inc. | Block splitting assembly and method |
| EG22120A (en) * | 1999-11-02 | 2002-08-30 | Delta Agro Chemical | Fungicide formulations contain copper and their method for preparation |
| CN1195534C (zh) * | 2000-01-31 | 2005-04-06 | 五井野正 | 担子菌亚门和五加科提取物的生理活性组合物 |
| US6891079B2 (en) | 2001-12-20 | 2005-05-10 | Kimberly-Clark Worldwide, Inc. | Wipe |
| US7485110B2 (en) | 2001-12-20 | 2009-02-03 | Kimberly Clark Worldwide, Inc. | Wipe comprising a pathogen selective antimicrobial |
| US7154018B2 (en) | 2001-12-20 | 2006-12-26 | Kimberly-Clark Worldwide, Inc. | Absorbent article |
| JP2003238316A (ja) * | 2002-02-20 | 2003-08-27 | Dainichiseika Color & Chem Mfg Co Ltd | 有用植物の胴枯性病菌の生育抑制剤及び胴枯性病防除方法 |
| US6874494B2 (en) | 2002-03-20 | 2005-04-05 | Anchor Wall Systems, Inc. | Block splitting assembly and method |
| US7390774B2 (en) * | 2004-04-08 | 2008-06-24 | Rohm And Haas Company | Antibacterial composition and methods of making and using the same |
| CN101010008B (zh) * | 2004-09-02 | 2012-08-22 | 杜邦公司 | 稳定氢氧化铜的方法 |
| US7497901B2 (en) | 2005-12-30 | 2009-03-03 | E. I. Dupont De Nemours And Company | Tungstate and molybate wood preservatives |
| US7427316B2 (en) | 2005-12-30 | 2008-09-23 | E.I. Du Pont De Nemours And Company | Tropolone complexes as wood preservatives |
| US7462227B2 (en) | 2005-12-30 | 2008-12-09 | E.I. Du Pont De Nemours And Company | Ibuprofen complexes as wood preservatives |
| US7540906B2 (en) * | 2005-12-30 | 2009-06-02 | E.I. Du Pont De Nemours & Company | Metal salts of hydrolyzed olefin/maleic anhydride copolymers and their use as wood preservatives |
| US20110105333A1 (en) * | 2007-08-16 | 2011-05-05 | Rafel Israels | Seed Treatment Compositions and Methods |
| RU2371920C1 (ru) * | 2008-07-15 | 2009-11-10 | Николай Николаевич Леонов | Способ защиты персика от курчавости листьев |
| RU2415568C2 (ru) * | 2009-03-27 | 2011-04-10 | Игорь Павлович Ефимов | Способ борьбы с болезнями пчел с использованием биоцидных свойств наночастиц металлов |
| DE102009032895B4 (de) | 2009-07-10 | 2016-06-23 | Chevita Tierarzneimittel-Gesellschaft M.B.H. | Zusammensetzung und Verfahren zur Prävention und Behandlung von Feuerbrand |
| CL2013003667A1 (es) * | 2013-12-20 | 2014-08-08 | Sebastian Herreros | Composición acuosa, que comprende complejo de cobre polimérico y aloe vera barbadensis, bactericida y fungicida, donde la concentración de cobre expresado como cobre metálico puede variar entre 2000 y 3000 ppm; uso de dicha composición en el tratamiento de heridas, de humanos y en animales, tales como mastitis en vacas, inmersión post-ordeño y prevención de la mastitis en vacas. |
| CN105123765A (zh) * | 2015-10-08 | 2015-12-09 | 苏州科大微龙农业科技有限公司 | 一种甲壳素乳酸铜灰霉病防治剂的制备方法 |
| JP6757181B2 (ja) * | 2016-05-31 | 2020-09-16 | 株式会社日本触媒 | 抗菌剤 |
| CN106222718B (zh) * | 2016-08-30 | 2018-06-26 | 武汉理工大学 | 一种羧甲基纤维素的电沉积方法 |
| RU2667300C1 (ru) * | 2017-06-26 | 2018-09-18 | Федеральное государственное бюджетное образовательное учреждение высшего образования "ОРЛОВСКИЙ ГОСУДАРСТВЕННЫЙ УНИВЕРСИТЕТ имени И.С. ТУРГЕНЕВА" (ОГУ им. И.С. Тургенева) | Антиадгезионное покрытие фунгицидного действия |
| CA3134232A1 (en) | 2019-04-03 | 2020-10-08 | Clearleaf Inc | Colloidal silver-based compositions and methods of use thereof for preventing and controlling plant diseases |
| CN111138582B (zh) * | 2020-01-10 | 2021-01-08 | 中国科学院大学温州研究院(温州生物材料与工程研究所) | 一种含铜离子的阴离子聚合物水凝胶及制备方法与应用 |
| TW202234998A (zh) * | 2020-12-02 | 2022-09-16 | 以色列商亞達瑪馬克天辛有限公司 | 銅基殺菌劑組成物 |
| IT202300001038A1 (it) * | 2023-01-25 | 2024-07-25 | Gowan Crop Prot Limited | Formulazioni sinergiche a base di composti contenenti rame, polivinilpirrolidone e un componente costituito da un polimero derivato della cellulosa o da una miscela di polimeri derivati della cellulosa |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US24324A (en) | 1859-06-07 | Improvement in sewing-machines | ||
| US3428731A (en) | 1965-10-19 | 1969-02-18 | Mary A Furness | Stable dispersions of finely divided phosphate-process cupric hydroxide |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5312572B2 (enExample) * | 1973-12-22 | 1978-05-02 | ||
| JPS5948804B2 (ja) * | 1977-08-08 | 1984-11-29 | 三菱化学株式会社 | 植物ウイルス病防除薬剤 |
| DE2807293A1 (de) * | 1978-02-21 | 1979-08-23 | Bp Chem Int Ltd | Homogenes, fluessiges, einen cuprammonium-komplex umfassendes praeparat |
| US4227911A (en) * | 1978-10-10 | 1980-10-14 | Conklin Company, Inc. | Wetting agent and use thereof in agriculture |
| GR75196B (enExample) * | 1980-05-03 | 1984-07-13 | Basf Ag | |
| DE3017123A1 (de) * | 1980-05-03 | 1981-11-05 | Basf Ag, 6700 Ludwigshafen | Fungizid |
| US5242685A (en) * | 1986-03-15 | 1993-09-07 | Basf Aktiengesellschaft | Copper-containing agent for controlling fungi and bacteria |
| DE3608681A1 (de) * | 1986-03-15 | 1987-09-17 | Basf Ag | Kupferhaltiges mittel zur bekaempfung von pilzen und bakterien |
| JPH0317160A (ja) * | 1989-06-14 | 1991-01-25 | Asahi Chem Ind Co Ltd | 消臭・殺菌性合成樹脂成形物 |
| JPH03179063A (ja) * | 1989-09-27 | 1991-08-05 | Saiden Kagaku Kk | 水性防藻，防黴，防汚塗料組成物 |
| CA2051716C (en) * | 1990-10-01 | 2002-05-14 | James H. Lefiles | Copper hydroxide dry flowable bactericide/fungicide and method of making and using same |
| FR2668031B1 (fr) * | 1990-10-19 | 1997-01-31 | Nippon Oils & Fats Co Ltd | Bouillies bordelaises et leur procede de preparation. |
-
1993
- 1993-03-09 ZA ZA931681A patent/ZA931681B/xx unknown
- 1993-03-10 CA CA002091136A patent/CA2091136C/en not_active Expired - Lifetime
- 1993-03-16 BR BR9301186-5A patent/BR9301186A/pt not_active IP Right Cessation
- 1993-03-19 LT LTIP447A patent/LT3225B/lt not_active IP Right Cessation
- 1993-03-23 EP EP93302191A patent/EP0565266B1/en not_active Expired - Lifetime
- 1993-03-23 AT AT93302191T patent/ATE176128T1/de active
- 1993-03-23 ES ES93302191T patent/ES2125947T3/es not_active Expired - Lifetime
- 1993-03-23 DK DK93302191T patent/DK0565266T3/da active
- 1993-03-23 DE DE69323229T patent/DE69323229T2/de not_active Expired - Lifetime
- 1993-03-25 AU AU35478/93A patent/AU658275B2/en not_active Expired
- 1993-03-29 IL IL105197A patent/IL105197A0/xx unknown
- 1993-03-29 NZ NZ247274A patent/NZ247274A/en not_active IP Right Cessation
- 1993-03-31 TW TW082102396A patent/TW272116B/zh not_active IP Right Cessation
- 1993-03-31 OA OA60358A patent/OA09872A/en unknown
- 1993-03-31 MX MX9301833A patent/MX9301833A/es unknown
- 1993-03-31 JP JP09489293A patent/JP3470976B2/ja not_active Expired - Lifetime
- 1993-04-02 CN CN93103563A patent/CN1060616C/zh not_active Expired - Lifetime
- 1993-04-02 HU HUP9300973A patent/HU216092B/hu unknown
- 1993-04-02 CO CO93381156A patent/CO4180383A1/es unknown
- 1993-04-02 RU RU9393004715A patent/RU2094988C1/ru active
- 1993-04-02 PT PT101248A patent/PT101248B/pt not_active IP Right Cessation
- 1993-04-02 LV LVP-93-223A patent/LV10364B/en unknown
- 1993-04-02 KR KR1019930005609A patent/KR930021064A/ko not_active Abandoned
- 1993-06-08 GE GEAP1993849A patent/GEP20002223B/en unknown
-
1999
- 1999-04-26 GR GR990401151T patent/GR3030066T3/el unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US24324A (en) | 1859-06-07 | Improvement in sewing-machines | ||
| US3428731A (en) | 1965-10-19 | 1969-02-18 | Mary A Furness | Stable dispersions of finely divided phosphate-process cupric hydroxide |
Non-Patent Citations (1)
| Title |
|---|
| F. WALL S. GILL: "Interaction of cupric ions with poliacrylic acid", J. AMERICAN CHEM. COC., 77, pages 3692 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0565266A1 (en) | 1993-10-13 |
| DK0565266T3 (da) | 1999-09-13 |
| BR9301186A (pt) | 1993-10-13 |
| IL105197A0 (en) | 1993-07-08 |
| MX9301833A (es) | 1994-02-28 |
| ATE176128T1 (de) | 1999-02-15 |
| TW272116B (enExample) | 1996-03-11 |
| EP0565266B1 (en) | 1999-01-27 |
| HUT64182A (en) | 1993-12-28 |
| KR930021064A (ko) | 1993-11-22 |
| CO4180383A1 (es) | 1995-06-07 |
| HU216092B (hu) | 1999-04-28 |
| PT101248B (pt) | 1999-10-29 |
| GR3030066T3 (en) | 1999-07-30 |
| JP3470976B2 (ja) | 2003-11-25 |
| LV10364B (en) | 1996-02-20 |
| DE69323229T2 (de) | 1999-08-19 |
| CA2091136C (en) | 2001-01-02 |
| CN1060616C (zh) | 2001-01-17 |
| CA2091136A1 (en) | 1993-10-04 |
| AU658275B2 (en) | 1995-04-06 |
| DE69323229D1 (de) | 1999-03-11 |
| NZ247274A (en) | 1994-06-27 |
| RU2094988C1 (ru) | 1997-11-10 |
| OA09872A (en) | 1994-08-15 |
| AU3547893A (en) | 1993-10-07 |
| LTIP447A (en) | 1994-09-25 |
| CN1076829A (zh) | 1993-10-06 |
| GEP20002223B (en) | 2000-09-25 |
| ES2125947T3 (es) | 1999-03-16 |
| HU9300973D0 (en) | 1993-07-28 |
| PT101248A (pt) | 1994-06-30 |
| ZA931681B (en) | 1993-12-07 |
| LV10364A (lv) | 1995-02-20 |
| JPH0624912A (ja) | 1994-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM9A | Lapsed patents |
Effective date: 20010319 |