JP3470976B2 - 銅錯体殺菌／殺カビ剤およびそれの製造方法 - Google Patents
銅錯体殺菌／殺カビ剤およびそれの製造方法Info
- Publication number
- JP3470976B2 JP3470976B2 JP09489293A JP9489293A JP3470976B2 JP 3470976 B2 JP3470976 B2 JP 3470976B2 JP 09489293 A JP09489293 A JP 09489293A JP 9489293 A JP9489293 A JP 9489293A JP 3470976 B2 JP3470976 B2 JP 3470976B2
- Authority
- JP
- Japan
- Prior art keywords
- copper
- aqueous solution
- composition
- polycarboxylic acid
- plant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000417 fungicide Substances 0.000 title claims abstract description 133
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 112
- 150000004699 copper complex Chemical class 0.000 title claims abstract description 54
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 239000000645 desinfectant Substances 0.000 title description 2
- 239000010949 copper Substances 0.000 claims abstract description 246
- 229910052802 copper Inorganic materials 0.000 claims abstract description 204
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 202
- 239000002253 acid Substances 0.000 claims abstract description 113
- 239000007864 aqueous solution Substances 0.000 claims abstract description 99
- 150000001875 compounds Chemical class 0.000 claims abstract description 38
- 230000001580 bacterial effect Effects 0.000 claims abstract description 35
- 208000035143 Bacterial infection Diseases 0.000 claims abstract description 19
- 208000031888 Mycoses Diseases 0.000 claims abstract description 19
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 18
- 208000022362 bacterial infectious disease Diseases 0.000 claims abstract description 17
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims description 102
- 238000000034 method Methods 0.000 claims description 68
- 239000000243 solution Substances 0.000 claims description 65
- 241000196324 Embryophyta Species 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 58
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 231100000674 Phytotoxicity Toxicity 0.000 claims description 26
- 239000005752 Copper oxychloride Substances 0.000 claims description 18
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 claims description 18
- 229940116318 copper carbonate Drugs 0.000 claims description 15
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims description 15
- 201000010099 disease Diseases 0.000 claims description 13
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 13
- 239000005750 Copper hydroxide Substances 0.000 claims description 12
- 229910001956 copper hydroxide Inorganic materials 0.000 claims description 12
- 239000005848 Tribasic copper sulfate Substances 0.000 claims description 11
- -1 polyoxyethylene Polymers 0.000 claims description 11
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 10
- 238000003306 harvesting Methods 0.000 claims description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 239000005749 Copper compound Substances 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 150000001880 copper compounds Chemical class 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229960004643 cupric oxide Drugs 0.000 claims description 2
- 231100000208 phytotoxic Toxicity 0.000 claims description 2
- 230000000885 phytotoxic effect Effects 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 24
- 229910021529 ammonia Inorganic materials 0.000 claims 12
- 230000000249 desinfective effect Effects 0.000 claims 2
- 231100000331 toxic Toxicity 0.000 claims 1
- 230000002588 toxic effect Effects 0.000 claims 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract description 10
- 239000003899 bactericide agent Substances 0.000 abstract description 7
- 229920002125 Sokalan® Polymers 0.000 description 51
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 48
- 239000004584 polyacrylic acid Substances 0.000 description 42
- 229920001577 copolymer Polymers 0.000 description 38
- 229920000642 polymer Polymers 0.000 description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 30
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 28
- 239000007787 solid Substances 0.000 description 22
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 18
- 241000894006 Bacteria Species 0.000 description 15
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 14
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 14
- 239000011976 maleic acid Substances 0.000 description 14
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 14
- 239000007788 liquid Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 150000007513 acids Chemical class 0.000 description 12
- 229910000365 copper sulfate Inorganic materials 0.000 description 12
- 239000006185 dispersion Substances 0.000 description 12
- 235000013399 edible fruits Nutrition 0.000 description 12
- 239000008272 agar Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 229920001817 Agar Polymers 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 238000009472 formulation Methods 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 8
- 230000000536 complexating effect Effects 0.000 description 8
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 8
- 239000010452 phosphate Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 7
- 241000233866 Fungi Species 0.000 description 7
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 240000008067 Cucumis sativus Species 0.000 description 6
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 6
- 241000589636 Xanthomonas campestris Species 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 230000004071 biological effect Effects 0.000 description 6
- LTYZGLKKXZXSEC-UHFFFAOYSA-N copper dihydride Chemical compound [CuH2] LTYZGLKKXZXSEC-UHFFFAOYSA-N 0.000 description 6
- 229910000050 copper hydride Inorganic materials 0.000 description 6
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 229910020366 ClO 4 Inorganic materials 0.000 description 5
- 241000589634 Xanthomonas Species 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 5
- 150000001879 copper Chemical class 0.000 description 5
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 241000213004 Alternaria solani Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- 238000004108 freeze drying Methods 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 3
- 241000223600 Alternaria Species 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 241000207199 Citrus Species 0.000 description 3
- 244000070406 Malus silvestris Species 0.000 description 3
- 241001480007 Phomopsis Species 0.000 description 3
- 241001533598 Septoria Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 244000098338 Triticum aestivum Species 0.000 description 3
- 235000021016 apples Nutrition 0.000 description 3
- 150000007514 bases Chemical class 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 229910001431 copper ion Inorganic materials 0.000 description 3
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 3
- 229960003280 cupric chloride Drugs 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 3
- 231100001184 nonphytotoxic Toxicity 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 235000000832 Ayote Nutrition 0.000 description 2
- 108010077805 Bacterial Proteins Proteins 0.000 description 2
- 239000004135 Bone phosphate Substances 0.000 description 2
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 2
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 2
- 235000007516 Chrysanthemum Nutrition 0.000 description 2
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 2
- 235000001543 Corylus americana Nutrition 0.000 description 2
- 235000007466 Corylus avellana Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 244000241257 Cucumis melo Species 0.000 description 2
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- 235000009854 Cucurbita moschata Nutrition 0.000 description 2
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 240000007049 Juglans regia Species 0.000 description 2
- 235000009496 Juglans regia Nutrition 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 241000233614 Phytophthora Species 0.000 description 2
- 241001149949 Phytophthora cactorum Species 0.000 description 2
- 240000003889 Piper guineense Species 0.000 description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 description 2
- 241000589516 Pseudomonas Species 0.000 description 2
- 241000589615 Pseudomonas syringae Species 0.000 description 2
- 241000220324 Pyrus Species 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000010668 complexation reaction Methods 0.000 description 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 2
- 229940112669 cuprous oxide Drugs 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 230000035784 germination Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 235000020232 peanut Nutrition 0.000 description 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003141 primary amines Chemical class 0.000 description 2
- 235000015136 pumpkin Nutrition 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- IEDVJHCEMCRBQM-UHFFFAOYSA-N trimethoprim Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(N)=NC=2)N)=C1 IEDVJHCEMCRBQM-UHFFFAOYSA-N 0.000 description 2
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 2
- 235000020234 walnut Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XXZCIYUJYUESMD-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-(morpholin-4-ylmethyl)pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)CN1CCOCC1 XXZCIYUJYUESMD-UHFFFAOYSA-N 0.000 description 1
- 241000208140 Acer Species 0.000 description 1
- 206010000598 Acrodynia Diseases 0.000 description 1
- 235000009434 Actinidia chinensis Nutrition 0.000 description 1
- 235000009436 Actinidia deliciosa Nutrition 0.000 description 1
- 241000199898 Alaria <Phaeophyceae> Species 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 241000946391 Alternaria citri Species 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 240000007087 Apium graveolens Species 0.000 description 1
- 235000015849 Apium graveolens Dulce Group Nutrition 0.000 description 1
- 235000010591 Appio Nutrition 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 241000218993 Begonia Species 0.000 description 1
- 235000011889 Bermuda lily Nutrition 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 241001465180 Botrytis Species 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000004221 Brassica oleracea var gemmifera Nutrition 0.000 description 1
- 235000017647 Brassica oleracea var italica Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 235000012905 Brassica oleracea var viridis Nutrition 0.000 description 1
- 244000064816 Brassica oleracea var. acephala Species 0.000 description 1
- 244000308368 Brassica oleracea var. gemmifera Species 0.000 description 1
- 235000005039 Brassica rapa var. dichotoma Nutrition 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 235000009025 Carya illinoensis Nutrition 0.000 description 1
- 244000068645 Carya illinoensis Species 0.000 description 1
- 241001157813 Cercospora Species 0.000 description 1
- 208000032544 Cicatrix Diseases 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 241000222199 Colletotrichum Species 0.000 description 1
- 241001529387 Colletotrichum gloeosporioides Species 0.000 description 1
- 241000222235 Colletotrichum orbiculare Species 0.000 description 1
- 241001529717 Corticium <basidiomycota> Species 0.000 description 1
- 240000009226 Corylus americana Species 0.000 description 1
- 240000007582 Corylus avellana Species 0.000 description 1
- 241000652564 Coryneum Species 0.000 description 1
- 235000009917 Crataegus X brevipes Nutrition 0.000 description 1
- 235000013204 Crataegus X haemacarpa Nutrition 0.000 description 1
- 235000009685 Crataegus X maligna Nutrition 0.000 description 1
- 235000009444 Crataegus X rubrocarnea Nutrition 0.000 description 1
- 235000009486 Crataegus bullatus Nutrition 0.000 description 1
- 235000017181 Crataegus chrysocarpa Nutrition 0.000 description 1
- 235000009682 Crataegus limnophila Nutrition 0.000 description 1
- 240000000171 Crataegus monogyna Species 0.000 description 1
- 235000004423 Crataegus monogyna Nutrition 0.000 description 1
- 235000002313 Crataegus paludosa Nutrition 0.000 description 1
- 235000009840 Crataegus x incaedua Nutrition 0.000 description 1
- 235000015001 Cucumis melo var inodorus Nutrition 0.000 description 1
- 240000002495 Cucumis melo var. inodorus Species 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- 241000219122 Cucurbita Species 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 241000371644 Curvularia ravenelii Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 235000009355 Dianthus caryophyllus Nutrition 0.000 description 1
- 240000006497 Dianthus caryophyllus Species 0.000 description 1
- 101100117236 Drosophila melanogaster speck gene Proteins 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000208367 Euonymus Species 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 241001284615 Frangula californica Species 0.000 description 1
- 241000208152 Geranium Species 0.000 description 1
- 241000245654 Gladiolus Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241001091440 Grossulariaceae Species 0.000 description 1
- 241000532524 Grovesinia pyramidalis Species 0.000 description 1
- 240000008669 Hedera helix Species 0.000 description 1
- 241001181537 Hemileia Species 0.000 description 1
- 241000679711 Homona Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 235000008694 Humulus lupulus Nutrition 0.000 description 1
- 244000025221 Humulus lupulus Species 0.000 description 1
- 241000692870 Inachis io Species 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 241000555723 Leptosphaerulina Species 0.000 description 1
- 235000002156 Lilium lancifolium Nutrition 0.000 description 1
- 241000784732 Lycaena phlaeas Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 240000004658 Medicago sativa Species 0.000 description 1
- 235000017587 Medicago sativa ssp. sativa Nutrition 0.000 description 1
- 206010027146 Melanoderma Diseases 0.000 description 1
- 208000003351 Melanosis Diseases 0.000 description 1
- 235000016462 Mimosa pudica Nutrition 0.000 description 1
- 240000001140 Mimosa pudica Species 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 241000285727 Mycosphaerella coffeicola Species 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241001279833 Pachysandra Species 0.000 description 1
- 240000004371 Panax ginseng Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 241000588912 Pantoea agglomerans Species 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000008673 Persea americana Nutrition 0.000 description 1
- 244000025272 Persea americana Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 240000005809 Prunus persica Species 0.000 description 1
- 235000006029 Prunus persica var nucipersica Nutrition 0.000 description 1
- 244000017714 Prunus persica var. nucipersica Species 0.000 description 1
- 241000589540 Pseudomonas fluorescens Species 0.000 description 1
- 244000128206 Pyracantha coccinea Species 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 241000593917 Quercus virginiana Species 0.000 description 1
- 241000208422 Rhododendron Species 0.000 description 1
- 235000002357 Ribes grossularia Nutrition 0.000 description 1
- 241000109329 Rosa xanthina Species 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 240000007651 Rubus glaucus Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 235000004433 Simmondsia californica Nutrition 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- 241000271567 Struthioniformes Species 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- 240000006909 Tilia x europaea Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 241001661987 Tillandsia recurvata Species 0.000 description 1
- 241000722921 Tulipa gesneriana Species 0.000 description 1
- 240000001717 Vaccinium macrocarpon Species 0.000 description 1
- 244000078534 Vaccinium myrtillus Species 0.000 description 1
- 241000863480 Vinca Species 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 241001306237 Volutella Species 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 235000004519 Yucca filamentosa Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 240000002706 Zephyranthes atamasco Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 244000000005 bacterial plant pathogen Species 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 235000021029 blackberry Nutrition 0.000 description 1
- 210000000081 body of the sternum Anatomy 0.000 description 1
- 244000130745 brown sarson Species 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000021019 cranberries Nutrition 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- ZMMDPCMYTCRWFF-UHFFFAOYSA-J dicopper;carbonate;dihydroxide Chemical group [OH-].[OH-].[Cu+2].[Cu+2].[O-]C([O-])=O ZMMDPCMYTCRWFF-UHFFFAOYSA-J 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- UPBDXRPQPOWRKR-UHFFFAOYSA-N furan-2,5-dione;methoxyethene Chemical compound COC=C.O=C1OC(=O)C=C1 UPBDXRPQPOWRKR-UHFFFAOYSA-N 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 208000023469 infantile mercury poisoning Diseases 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Chemical compound CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000008654 plant damage Effects 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 235000021013 raspberries Nutrition 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 230000037387 scars Effects 0.000 description 1
- 230000007226 seed germination Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000009528 severe injury Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010981 turquoise Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
- A01N37/04—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof polybasic
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86321792A | 1992-04-03 | 1992-04-03 | |
| US863217 | 1992-04-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0624912A JPH0624912A (ja) | 1994-02-01 |
| JP3470976B2 true JP3470976B2 (ja) | 2003-11-25 |
Family
ID=25340590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP09489293A Expired - Lifetime JP3470976B2 (ja) | 1992-04-03 | 1993-03-31 | 銅錯体殺菌／殺カビ剤およびそれの製造方法 |
Country Status (25)
| Country | Link |
|---|---|
| EP (1) | EP0565266B1 (enExample) |
| JP (1) | JP3470976B2 (enExample) |
| KR (1) | KR930021064A (enExample) |
| CN (1) | CN1060616C (enExample) |
| AT (1) | ATE176128T1 (enExample) |
| AU (1) | AU658275B2 (enExample) |
| BR (1) | BR9301186A (enExample) |
| CA (1) | CA2091136C (enExample) |
| CO (1) | CO4180383A1 (enExample) |
| DE (1) | DE69323229T2 (enExample) |
| DK (1) | DK0565266T3 (enExample) |
| ES (1) | ES2125947T3 (enExample) |
| GE (1) | GEP20002223B (enExample) |
| GR (1) | GR3030066T3 (enExample) |
| HU (1) | HU216092B (enExample) |
| IL (1) | IL105197A0 (enExample) |
| LT (1) | LT3225B (enExample) |
| LV (1) | LV10364B (enExample) |
| MX (1) | MX9301833A (enExample) |
| NZ (1) | NZ247274A (enExample) |
| OA (1) | OA09872A (enExample) |
| PT (1) | PT101248B (enExample) |
| RU (1) | RU2094988C1 (enExample) |
| TW (1) | TW272116B (enExample) |
| ZA (1) | ZA931681B (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0891708A1 (en) * | 1997-07-17 | 1999-01-20 | The Procter & Gamble Company | Anti-microbic agent |
| FR2792501B1 (fr) * | 1999-04-26 | 2004-02-06 | Elf Atochem Agri Sa | Traitement phytosanitaire des plantes par un chelate de cuivre soluble libere graduellement in situ a partir d'une source de cuivre non chelate et d'un chelate et compositions utilisables a cet effet |
| US6918715B2 (en) | 1999-06-11 | 2005-07-19 | Anchor Wall Systems, Inc. | Block splitting assembly and method |
| EG22120A (en) * | 1999-11-02 | 2002-08-30 | Delta Agro Chemical | Fungicide formulations contain copper and their method for preparation |
| CN1195534C (zh) * | 2000-01-31 | 2005-04-06 | 五井野正 | 担子菌亚门和五加科提取物的生理活性组合物 |
| US6891079B2 (en) | 2001-12-20 | 2005-05-10 | Kimberly-Clark Worldwide, Inc. | Wipe |
| US7485110B2 (en) | 2001-12-20 | 2009-02-03 | Kimberly Clark Worldwide, Inc. | Wipe comprising a pathogen selective antimicrobial |
| US7154018B2 (en) | 2001-12-20 | 2006-12-26 | Kimberly-Clark Worldwide, Inc. | Absorbent article |
| JP2003238316A (ja) * | 2002-02-20 | 2003-08-27 | Dainichiseika Color & Chem Mfg Co Ltd | 有用植物の胴枯性病菌の生育抑制剤及び胴枯性病防除方法 |
| US6874494B2 (en) | 2002-03-20 | 2005-04-05 | Anchor Wall Systems, Inc. | Block splitting assembly and method |
| US7390774B2 (en) * | 2004-04-08 | 2008-06-24 | Rohm And Haas Company | Antibacterial composition and methods of making and using the same |
| CN101010008B (zh) * | 2004-09-02 | 2012-08-22 | 杜邦公司 | 稳定氢氧化铜的方法 |
| US7497901B2 (en) | 2005-12-30 | 2009-03-03 | E. I. Dupont De Nemours And Company | Tungstate and molybate wood preservatives |
| US7427316B2 (en) | 2005-12-30 | 2008-09-23 | E.I. Du Pont De Nemours And Company | Tropolone complexes as wood preservatives |
| US7462227B2 (en) | 2005-12-30 | 2008-12-09 | E.I. Du Pont De Nemours And Company | Ibuprofen complexes as wood preservatives |
| US7540906B2 (en) * | 2005-12-30 | 2009-06-02 | E.I. Du Pont De Nemours & Company | Metal salts of hydrolyzed olefin/maleic anhydride copolymers and their use as wood preservatives |
| US20110105333A1 (en) * | 2007-08-16 | 2011-05-05 | Rafel Israels | Seed Treatment Compositions and Methods |
| RU2371920C1 (ru) * | 2008-07-15 | 2009-11-10 | Николай Николаевич Леонов | Способ защиты персика от курчавости листьев |
| RU2415568C2 (ru) * | 2009-03-27 | 2011-04-10 | Игорь Павлович Ефимов | Способ борьбы с болезнями пчел с использованием биоцидных свойств наночастиц металлов |
| DE102009032895B4 (de) | 2009-07-10 | 2016-06-23 | Chevita Tierarzneimittel-Gesellschaft M.B.H. | Zusammensetzung und Verfahren zur Prävention und Behandlung von Feuerbrand |
| CL2013003667A1 (es) * | 2013-12-20 | 2014-08-08 | Sebastian Herreros | Composición acuosa, que comprende complejo de cobre polimérico y aloe vera barbadensis, bactericida y fungicida, donde la concentración de cobre expresado como cobre metálico puede variar entre 2000 y 3000 ppm; uso de dicha composición en el tratamiento de heridas, de humanos y en animales, tales como mastitis en vacas, inmersión post-ordeño y prevención de la mastitis en vacas. |
| CN105123765A (zh) * | 2015-10-08 | 2015-12-09 | 苏州科大微龙农业科技有限公司 | 一种甲壳素乳酸铜灰霉病防治剂的制备方法 |
| JP6757181B2 (ja) * | 2016-05-31 | 2020-09-16 | 株式会社日本触媒 | 抗菌剤 |
| CN106222718B (zh) * | 2016-08-30 | 2018-06-26 | 武汉理工大学 | 一种羧甲基纤维素的电沉积方法 |
| RU2667300C1 (ru) * | 2017-06-26 | 2018-09-18 | Федеральное государственное бюджетное образовательное учреждение высшего образования "ОРЛОВСКИЙ ГОСУДАРСТВЕННЫЙ УНИВЕРСИТЕТ имени И.С. ТУРГЕНЕВА" (ОГУ им. И.С. Тургенева) | Антиадгезионное покрытие фунгицидного действия |
| CA3134232A1 (en) | 2019-04-03 | 2020-10-08 | Clearleaf Inc | Colloidal silver-based compositions and methods of use thereof for preventing and controlling plant diseases |
| CN111138582B (zh) * | 2020-01-10 | 2021-01-08 | 中国科学院大学温州研究院(温州生物材料与工程研究所) | 一种含铜离子的阴离子聚合物水凝胶及制备方法与应用 |
| TW202234998A (zh) * | 2020-12-02 | 2022-09-16 | 以色列商亞達瑪馬克天辛有限公司 | 銅基殺菌劑組成物 |
| IT202300001038A1 (it) * | 2023-01-25 | 2024-07-25 | Gowan Crop Prot Limited | Formulazioni sinergiche a base di composti contenenti rame, polivinilpirrolidone e un componente costituito da un polimero derivato della cellulosa o da una miscela di polimeri derivati della cellulosa |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US24324A (en) | 1859-06-07 | Improvement in sewing-machines | ||
| US3428731A (en) | 1965-10-19 | 1969-02-18 | Mary A Furness | Stable dispersions of finely divided phosphate-process cupric hydroxide |
| JPS5312572B2 (enExample) * | 1973-12-22 | 1978-05-02 | ||
| JPS5948804B2 (ja) * | 1977-08-08 | 1984-11-29 | 三菱化学株式会社 | 植物ウイルス病防除薬剤 |
| DE2807293A1 (de) * | 1978-02-21 | 1979-08-23 | Bp Chem Int Ltd | Homogenes, fluessiges, einen cuprammonium-komplex umfassendes praeparat |
| US4227911A (en) * | 1978-10-10 | 1980-10-14 | Conklin Company, Inc. | Wetting agent and use thereof in agriculture |
| GR75196B (enExample) * | 1980-05-03 | 1984-07-13 | Basf Ag | |
| DE3017123A1 (de) * | 1980-05-03 | 1981-11-05 | Basf Ag, 6700 Ludwigshafen | Fungizid |
| US5242685A (en) * | 1986-03-15 | 1993-09-07 | Basf Aktiengesellschaft | Copper-containing agent for controlling fungi and bacteria |
| DE3608681A1 (de) * | 1986-03-15 | 1987-09-17 | Basf Ag | Kupferhaltiges mittel zur bekaempfung von pilzen und bakterien |
| JPH0317160A (ja) * | 1989-06-14 | 1991-01-25 | Asahi Chem Ind Co Ltd | 消臭・殺菌性合成樹脂成形物 |
| JPH03179063A (ja) * | 1989-09-27 | 1991-08-05 | Saiden Kagaku Kk | 水性防藻，防黴，防汚塗料組成物 |
| CA2051716C (en) * | 1990-10-01 | 2002-05-14 | James H. Lefiles | Copper hydroxide dry flowable bactericide/fungicide and method of making and using same |
| FR2668031B1 (fr) * | 1990-10-19 | 1997-01-31 | Nippon Oils & Fats Co Ltd | Bouillies bordelaises et leur procede de preparation. |
-
1993
- 1993-03-09 ZA ZA931681A patent/ZA931681B/xx unknown
- 1993-03-10 CA CA002091136A patent/CA2091136C/en not_active Expired - Lifetime
- 1993-03-16 BR BR9301186-5A patent/BR9301186A/pt not_active IP Right Cessation
- 1993-03-19 LT LTIP447A patent/LT3225B/lt not_active IP Right Cessation
- 1993-03-23 EP EP93302191A patent/EP0565266B1/en not_active Expired - Lifetime
- 1993-03-23 AT AT93302191T patent/ATE176128T1/de active
- 1993-03-23 ES ES93302191T patent/ES2125947T3/es not_active Expired - Lifetime
- 1993-03-23 DK DK93302191T patent/DK0565266T3/da active
- 1993-03-23 DE DE69323229T patent/DE69323229T2/de not_active Expired - Lifetime
- 1993-03-25 AU AU35478/93A patent/AU658275B2/en not_active Expired
- 1993-03-29 IL IL105197A patent/IL105197A0/xx unknown
- 1993-03-29 NZ NZ247274A patent/NZ247274A/en not_active IP Right Cessation
- 1993-03-31 TW TW082102396A patent/TW272116B/zh not_active IP Right Cessation
- 1993-03-31 OA OA60358A patent/OA09872A/en unknown
- 1993-03-31 MX MX9301833A patent/MX9301833A/es unknown
- 1993-03-31 JP JP09489293A patent/JP3470976B2/ja not_active Expired - Lifetime
- 1993-04-02 CN CN93103563A patent/CN1060616C/zh not_active Expired - Lifetime
- 1993-04-02 HU HUP9300973A patent/HU216092B/hu unknown
- 1993-04-02 CO CO93381156A patent/CO4180383A1/es unknown
- 1993-04-02 RU RU9393004715A patent/RU2094988C1/ru active
- 1993-04-02 PT PT101248A patent/PT101248B/pt not_active IP Right Cessation
- 1993-04-02 LV LVP-93-223A patent/LV10364B/en unknown
- 1993-04-02 KR KR1019930005609A patent/KR930021064A/ko not_active Abandoned
- 1993-06-08 GE GEAP1993849A patent/GEP20002223B/en unknown
-
1999
- 1999-04-26 GR GR990401151T patent/GR3030066T3/el unknown
Non-Patent Citations (1)
| Title |
|---|
| カナダ国特許出願公開第２０５１７１６号明細書 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0565266A1 (en) | 1993-10-13 |
| DK0565266T3 (da) | 1999-09-13 |
| BR9301186A (pt) | 1993-10-13 |
| IL105197A0 (en) | 1993-07-08 |
| MX9301833A (es) | 1994-02-28 |
| ATE176128T1 (de) | 1999-02-15 |
| TW272116B (enExample) | 1996-03-11 |
| EP0565266B1 (en) | 1999-01-27 |
| HUT64182A (en) | 1993-12-28 |
| KR930021064A (ko) | 1993-11-22 |
| CO4180383A1 (es) | 1995-06-07 |
| HU216092B (hu) | 1999-04-28 |
| PT101248B (pt) | 1999-10-29 |
| GR3030066T3 (en) | 1999-07-30 |
| LV10364B (en) | 1996-02-20 |
| LT3225B (en) | 1995-04-25 |
| DE69323229T2 (de) | 1999-08-19 |
| CA2091136C (en) | 2001-01-02 |
| CN1060616C (zh) | 2001-01-17 |
| CA2091136A1 (en) | 1993-10-04 |
| AU658275B2 (en) | 1995-04-06 |
| DE69323229D1 (de) | 1999-03-11 |
| NZ247274A (en) | 1994-06-27 |
| RU2094988C1 (ru) | 1997-11-10 |
| OA09872A (en) | 1994-08-15 |
| AU3547893A (en) | 1993-10-07 |
| LTIP447A (en) | 1994-09-25 |
| CN1076829A (zh) | 1993-10-06 |
| GEP20002223B (en) | 2000-09-25 |
| ES2125947T3 (es) | 1999-03-16 |
| HU9300973D0 (en) | 1993-07-28 |
| PT101248A (pt) | 1994-06-30 |
| ZA931681B (en) | 1993-12-07 |
| LV10364A (lv) | 1995-02-20 |
| JPH0624912A (ja) | 1994-02-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3470976B2 (ja) | 銅錯体殺菌／殺カビ剤およびそれの製造方法 | |
| US6471976B1 (en) | Copper complex bactericide/fungicide and method of making same | |
| EP0480614B1 (en) | Copper hydroxide dry flowable bactercide/fungicide and method of making and using same | |
| US8221796B2 (en) | Copper-based fungicide/bactericide | |
| US20100129466A1 (en) | Compositions and methods for treating plants | |
| MXPA03006755A (es) | Metodos y composiciones para controlar patogenos en plantas. | |
| US8192766B2 (en) | Copper-based fungicide/bactericide | |
| US20120219638A1 (en) | Method and Compositions for Treating Plant Infections | |
| WO2007123531A1 (en) | Copper-based fungicide/bactericide | |
| US3620773A (en) | Method for treating harvested nonchlorophylleous produce | |
| US5116825A (en) | Phytosanitary composition, its process for preparation and its use for treating cryptogamic diseases | |
| US20050079227A1 (en) | Compositions for the treatment and prevention of plant pathogens | |
| EP0713645B1 (en) | Agrohorticultural bactericide | |
| AU2002331462B2 (en) | Compositions for the treatment and prevention of plant pathogens | |
| AU2011250685A1 (en) | Methods and compositions for treating biofilms |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20070912 Year of fee payment: 4 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080912 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080912 Year of fee payment: 5 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090912 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090912 Year of fee payment: 6 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100912 Year of fee payment: 7 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110912 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110912 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120912 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130912 Year of fee payment: 10 |