KR970707064A - 카르복실산 에스테르의 직접 수소화 방법 및 촉매(process and catalyst for the direct hydrogenation of carboxylic esters) - Google Patents

카르복실산 에스테르의 직접 수소화 방법 및 촉매(process and catalyst for the direct hydrogenation of carboxylic esters)

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Publication number
KR970707064A
KR970707064A KR1019970703051A KR19970703051A KR970707064A KR 970707064 A KR970707064 A KR 970707064A KR 1019970703051 A KR1019970703051 A KR 1019970703051A KR 19970703051 A KR19970703051 A KR 19970703051A KR 970707064 A KR970707064 A KR 970707064A
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South Korea
Prior art keywords
catalyst
range
compounds
ester
compound
Prior art date
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KR1019970703051A
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English (en)
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KR100403190B1 (ko
Inventor
브렌단 더어모트 머레이
데이비드 마이클 싱글리톤
Original Assignee
지스트라텐 알베르터스 빌헬머스 요안느
쉘 인터내셔널 리써치 마챠피즈 비. 브이.
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Priority claimed from US08/335,018 external-priority patent/US5475159A/en
Priority claimed from US08/335,021 external-priority patent/US5475160A/en
Priority claimed from US08/335,024 external-priority patent/US5463143A/en
Application filed by 지스트라텐 알베르터스 빌헬머스 요안느, 쉘 인터내셔널 리써치 마챠피즈 비. 브이. filed Critical 지스트라텐 알베르터스 빌헬머스 요안느
Publication of KR970707064A publication Critical patent/KR970707064A/ko
Application granted granted Critical
Publication of KR100403190B1 publication Critical patent/KR100403190B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

200 내지 400℃ 미만의 온도에서 화합물을 하소하여 제조된, 구리 화합물, 아연 화합물 및 알루미늄, 지르코늄, 마그네슘, 회토류 및 그의 혼합물로 이루어진 군에서 선택된 하나 이상의 화합물을 함유하는 촉매의 존재하에 주 액상 수소화 조건에서 하나 이상의 에스테르르 수소화 접촉 및 반응시키는 것을 포함하는 카르복실산 에스테르의 직접 수소화 방법 및 촉매.

Description

카르복실산 에스테르의 직접 수소화 방법 및 촉매(PROCESS AND CATALYST FOR THE DIRECT HYDROGENATION OF CARBOXYLIC ESTERS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 구리 화합물, 아연 화합물 및 알루미늄, 지르코늄, 마그네슘, 회토류 및 그의 혼합물로 이루어진 군에서 선택된 하나 이상의 화합물을 함유하며 200 내지 400℃ 미만의 온도에서 이러한 화합물을 하소하여 제조된 수소화 촉매.
  2. 제1항에 있어서, 하소 전에, 20 내지 100℃ 범위의 온도 및 5.5 내지 7.5의 pH에서 이들 화합물이 침전되는 촉매.
  3. 제1항 또는 2항에 있어서, 상기 촉매가 250 내지 350℃ 범위의 온도에서 이들 화합물을 하소하여 제조되는 촉매.
  4. 제1항 내지 3항 중 어느 한 항에 있어서, 상기 촉매는 촉매의 총중량을 기준으로, 산화물로 계산하여, 10 내지 80중량% 범위의 구리를 함유하는 촉매.
  5. 제1항 내지 4항 중 어느 한 항에 있어서, 상기 촉매는 촉매의 총중량을 기준으로, 산화물로 계산하여, 10 내지 80중량% 범위의 아연을 함유하는 촉매.
  6. 제1항 내지 5항 중 어느 한 항에 있어서, 상기 촉매가 하나 이상의 회토류 화합물을 함유하는 촉매.
  7. 제6항에 있어서, 상기 촉매는 촉매의 총중량을 기준으로, 산화물로 계산하여, 0.1 내지 20중량% 범위의 회토류를 함유하는 촉매.
  8. 하나 이상의 에스테르를 제1항 내지 7항 중의 어느 한 항에서 청구된 촉매의 존재하에 주 액상 수소화 조건하에 수소와 접촉 및 반응시키는 것을 포함하는 카르복실산 에스테르의 직접 수소화 방법.
  9. 제8항에 있어서, 상기 에스테르가 세제 범위의 메틸 에스테르, 트리글리세리드, 또는 왁스 에스테르인 방법.
  10. 제8항 또는 9항에 있어서, 상기 방법이 170 내지 250℃ 범위의 온도에서 및 20.7 내지 138바 게이지 범위의 압력에서 수행되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970703051A 1994-11-07 1995-11-06 카르복실산에스테르의직접수소화방법및촉매 KR100403190B1 (ko)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US08/335,018 US5475159A (en) 1994-11-07 1994-11-07 Process for the direct hydrogenation of methyl esters
US08/335,021 US5475160A (en) 1994-11-07 1994-11-07 Process for the direct hydrogenation of triglycerides
US08/335,024 US5463143A (en) 1994-11-07 1994-11-07 Process for the direct hydrogenation of wax esters
US08/335021 1994-11-07
US08/335,024 1994-11-07
US08/335024 1994-11-07
US08/335018 1994-11-07
US08/335,018 1994-11-07
US08/335,021 1994-11-07

Publications (2)

Publication Number Publication Date
KR970707064A true KR970707064A (ko) 1997-12-01
KR100403190B1 KR100403190B1 (ko) 2004-03-20

Family

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KR1019970703051A KR100403190B1 (ko) 1994-11-07 1995-11-06 카르복실산에스테르의직접수소화방법및촉매

Country Status (10)

Country Link
EP (1) EP0804396B1 (ko)
JP (1) JP3859231B2 (ko)
KR (1) KR100403190B1 (ko)
CN (1) CN1075048C (ko)
AU (1) AU3982495A (ko)
BR (1) BR9509625A (ko)
DE (1) DE69507906T2 (ko)
MX (1) MX9703182A (ko)
MY (1) MY129140A (ko)
WO (1) WO1996014280A1 (ko)

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DE10241529A1 (de) * 2002-09-05 2004-03-11 Basf Ag Adsorptionsmasse und Verfahren zur Entfernung von Kohlenmonoxid aus Stoffströmen
DE10313702A1 (de) † 2003-03-27 2004-10-07 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
DE102004033556A1 (de) 2004-07-09 2006-02-16 Basf Ag Katalysatorformkörper und Verfahren zur Hydrierung von Carbonylverbindungen
JP5073170B2 (ja) * 2005-03-08 2012-11-14 花王株式会社 アルコールの製造方法
US20090098036A1 (en) * 2006-02-14 2009-04-16 Basf Se Adsorption composition and method of removing co from streams
RU2008136689A (ru) 2006-02-14 2010-03-20 Басф Се (De) Адсорбционная масса и способ для удаления со из потоков веществ
JP5198441B2 (ja) 2006-06-21 2013-05-15 ビーエーエスエフ ソシエタス・ヨーロピア 液体プロピレン流からｃｏを除去するための方法
BRPI0714401A2 (pt) 2006-07-17 2013-02-26 Basf Se processo para hidrogenar hidrocarbonetos insaturados sobre catalisadores contendo cobre e zinco
US8236264B2 (en) 2006-12-01 2012-08-07 Basf Se Adsorption composition and process for removing CO from material streams
GB0719251D0 (en) 2007-10-03 2007-11-14 Davy Process Techn Ltd Process
GB0906031D0 (en) 2009-04-07 2009-05-20 Davy Process Techn Ltd Process
JP5771192B2 (ja) * 2009-05-20 2015-08-26 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 銅含有不均一触媒上で、脂肪酸トリグリセリドの水素化を行うことによって脂肪アルコールを製造する方法
CN103261134B (zh) * 2010-12-08 2015-09-02 花王株式会社 高级醇的制造方法
CN102093162B (zh) * 2010-12-13 2012-04-18 西南化工研究设计院 一种用醋酸酯加氢制备乙醇的方法
CN105646142B (zh) * 2014-12-02 2017-12-26 中国科学院大连化学物理研究所 一种催化酯加氢制醇的方法

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JPS55106543A (en) * 1979-02-10 1980-08-15 Mitsubishi Gas Chem Co Inc Preparation of catalyst for synthesizing methanol
JPS5910256B2 (ja) * 1979-11-12 1984-03-07 三菱瓦斯化学株式会社 メタノ−ル合成触媒の製造法
FR2558738B1 (fr) * 1984-01-27 1987-11-13 Inst Francais Du Petrole Procede de fabrication de catalyseurs contenant du cuivre, du zinc et de l'aluminium, utilisables pour la production de methanol a partir de gaz de synthese
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US5334779A (en) * 1993-06-01 1994-08-02 Eastman Kodak Company Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters

Also Published As

Publication number Publication date
MY129140A (en) 2007-03-30
EP0804396A1 (en) 1997-11-05
CN1075048C (zh) 2001-11-21
JP3859231B2 (ja) 2006-12-20
AU3982495A (en) 1996-05-31
CN1162951A (zh) 1997-10-22
KR100403190B1 (ko) 2004-03-20
MX9703182A (es) 1997-07-31
DE69507906T2 (de) 1999-08-05
BR9509625A (pt) 1998-01-06
EP0804396B1 (en) 1999-02-17
JPH10508531A (ja) 1998-08-25
WO1996014280A1 (en) 1996-05-17
DE69507906D1 (de) 1999-03-25

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