KR970000337A - 할로겐화 알루미나를 주성분으로 하는 촉매, 이의 제조 방법 및 노말 c_4- c_6 파라핀의 이성화에 사용하는 방법 - Google Patents

할로겐화 알루미나를 주성분으로 하는 촉매, 이의 제조 방법 및 노말 c_4- c_6 파라핀의 이성화에 사용하는 방법 Download PDF

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KR970000337A
KR970000337A KR1019960024906A KR19960024906A KR970000337A KR 970000337 A KR970000337 A KR 970000337A KR 1019960024906 A KR1019960024906 A KR 1019960024906A KR 19960024906 A KR19960024906 A KR 19960024906A KR 970000337 A KR970000337 A KR 970000337A
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catalyst
support
alumina
catalyst according
isomerization
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KR1019960024906A
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English (en)
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베 꼬쁘리에쯔 에르
뜨라베르 크리스틴
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알프레드 엘마레
앵스띠뛰 프랑세 뒤 뻬뜨롤
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Publication of KR970000337A publication Critical patent/KR970000337A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/24—Chlorinating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/226—Catalytic processes not covered by C07C5/23 - C07C5/31 with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2791—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 1종 이상의 할로겐, 1종 이상의 Ⅷ족 금속 및 감마 알루미나와 임의로 에타 알루미나를 포함하는 지지체를 포함하는 촉매에 관한 것인 바, 상기 촉매는 상기 지지체의 최소 평균 직경이 0.8mm 내지 2mm이고, 염소 함량은 4.5 내지 15 중량%인 것을 특징으로 한다. 또한, 본 발명은 상기 촉매의 제조 방법, 바람직하게는 CCl4또는 CHCl3의 존재하에서 염소화(이때, 할로겐은 염소임)시키는 것에 관한 것이다. 또한 본 발명은 상기 촉매를 노말 C4-C6파라핀의 이성화에 사용하는 방법에 관한 것이다.

Description

할로겐화 알루미나를 주성분으로 하는 촉매, 이의 제조 방법 및 노말 C4-C6파라핀의 이성화에 사용하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

1종 이상의 할로겐, 1종 이상의 Ⅷ족 금속 및 감마 알루미나를 함유하는 지지체를 포함하는 촉매로서, 상기 촉매는 상기 지지체의 최소 평균 직경이 0.8mm 내지 2mm이고, 염소 함량은 4.5 내지 15 중량%인 것을 특징으로 하는 촉매.
제1항에 있어서, 지지체가 에타 알루미나를 추가로 포함하는 촉매.
제1항 또는 제2항에 있어서, 지지체가 압출물을 주성분으로 하는 촉매.
제1항 또는 제2항에 있어서, 지지체는 평균 직경이 0.8mm 내지 2mm인 소구체를 주성분으로 하는 촉매.
제1항 내지 제4항중 어느 한 항에 있어서, 감마 알루미나의 비표면적은 150 내지 300㎡/g이고, 공극 부피는 0.4 내지 0.8㎠/g이며; 촉매의 지지체에 에타 알루미나가 존재하는 경우에, 에타 알루미나의 비표면적은 400 내지 600㎡/g이고, 공극 부피는 0.3 내지 0.5㎡/g인 촉매.
제1항 내지 제5항중 어느 한 항에 있어서, Ⅷ족 금속은 백금, 팔라듐 및 니켈로 형성된 군에서 선택되는 촉매.
제1항 내지 제6항중 어느 한 항에 있어서, 할로겐은 염소인 촉매.
사염화탄소 또는 클로로포름을 사용하여 염소화를 수행하여 제7항의 촉매를 제조하는 방법.
제1항 내지 제7항중 어느 한 항의 촉매 또는 제8항에서 제조한 촉매를 분자당 탄소수 4 내지 6개를 함유한 노말 파라핀을 주로 포함하는 공급물을 이성화시키는 데 사용하는 방법.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960024906A 1995-06-28 1996-06-28 할로겐화 알루미나를 주성분으로 하는 촉매, 이의 제조 방법 및 노말 c_4- c_6 파라핀의 이성화에 사용하는 방법 KR970000337A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9507887A FR2735993B1 (fr) 1995-06-28 1995-06-28 Catalyseur a base d'alumine halogenee, sa preparation et son utilisation en isomerisation des normales paraffines c4-c6
FR9507887 1995-06-28

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KR970000337A true KR970000337A (ko) 1997-01-21

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KR1019960024906A KR970000337A (ko) 1995-06-28 1996-06-28 할로겐화 알루미나를 주성분으로 하는 촉매, 이의 제조 방법 및 노말 c_4- c_6 파라핀의 이성화에 사용하는 방법

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EP (1) EP0750941B1 (ko)
JP (1) JPH0910590A (ko)
KR (1) KR970000337A (ko)
CA (1) CA2179925A1 (ko)
DE (1) DE69630632T2 (ko)
FR (1) FR2735993B1 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2744441B1 (fr) 1996-02-05 1998-03-27 Inst Francais Du Petrole Procede d'isomerisation de paraffines
FR2744458B1 (fr) 1996-02-05 1998-03-27 Inst Francais Du Petrole Procede d'isomerisation de paraffines par distillation reactive
JP3306070B2 (ja) * 1996-02-27 2002-07-24 日本ペイント株式会社 ブース循環水の泡抑制方法
FR2771307B1 (fr) * 1997-11-25 1999-12-31 Inst Francais Du Petrole Preparation et utilisation en isomerisation des normales paraffines c4-c8 d'un catalyseur halogene a base d'alumine traitee a la vapeur d'eau

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3963643A (en) * 1974-04-22 1976-06-15 Universal Oil Products Company Method of catalyst manufacture
US4003849A (en) * 1974-11-25 1977-01-18 Phillips Petroleum Company Lead/chloride/alumina isomerization catalyst for gasoline
US4039604A (en) * 1975-08-18 1977-08-02 Phillips Petroleum Company Hydrocarbon isomerization with increased temperature and lowered hydrogen/hydrocarbon ratio
CA2082430A1 (en) * 1990-05-21 1991-11-22 Gyanesh P. Khare Catalytic compositions

Also Published As

Publication number Publication date
JPH0910590A (ja) 1997-01-14
DE69630632T2 (de) 2004-05-13
EP0750941A1 (fr) 1997-01-02
EP0750941B1 (fr) 2003-11-12
CA2179925A1 (fr) 1996-12-29
DE69630632D1 (de) 2003-12-18
FR2735993B1 (fr) 1997-08-14
FR2735993A1 (fr) 1997-01-03

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