AR000214A1 - Catalizador para la deshidrogenación de las c3-c15-parafinas procedimiento para prepararlo y el procedimiento para deshidrogenar parafinas c3-15 que utiliza dicho catalizador - Google Patents
Catalizador para la deshidrogenación de las c3-c15-parafinas procedimiento para prepararlo y el procedimiento para deshidrogenar parafinas c3-15 que utiliza dicho catalizadorInfo
- Publication number
- AR000214A1 AR000214A1 AR33440795A AR33440795A AR000214A1 AR 000214 A1 AR000214 A1 AR 000214A1 AR 33440795 A AR33440795 A AR 33440795A AR 33440795 A AR33440795 A AR 33440795A AR 000214 A1 AR000214 A1 AR 000214A1
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst
- paraffins
- procedure
- dehydrogenating
- dehydrogenation
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/628—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/324—Catalytic processes with metals
- C07C5/325—Catalytic processes with metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/60—Platinum group metals with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un catalizador para la deshidrogenación de las parafinas de 6 a 15 átomos de carbono. El catalizador contiene sobre un soporte, por lo menosun componente del grupo del platino, por lo menos un componente promotor de entre el grupo del estano, germanio y plomo, como también por lo menos unmodificador adicional. El modificador adicional contiene por lo menos un metal alcalino-térreo. La estabilidad del catalizador de acuerdo con la invención, esesencialmente superior con respecto a la utilización habitual de un metal alcalino. Se describe además el procedimiento para preparar dicho catalizadory el procedimiento para deshidrogenar parafinas C6-15 que utiliza dicho catalizador.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4442327 | 1994-11-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR000214A1 true AR000214A1 (es) | 1997-05-21 |
Family
ID=6534359
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AR33440795A AR000214A1 (es) | 1994-11-29 | 1995-11-21 | Catalizador para la deshidrogenación de las c3-c15-parafinas procedimiento para prepararlo y el procedimiento para deshidrogenar parafinas c3-15 que utiliza dicho catalizador |
Country Status (9)
Country | Link |
---|---|
US (2) | US5849657A (es) |
EP (1) | EP0714872B1 (es) |
JP (1) | JPH08224475A (es) |
KR (1) | KR960016959A (es) |
CN (1) | CN1081081C (es) |
AR (1) | AR000214A1 (es) |
BR (1) | BR9505527A (es) |
DE (1) | DE59508645D1 (es) |
ES (1) | ES2151015T3 (es) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2169803T3 (es) * | 1995-06-16 | 2002-07-16 | Inst Francais Du Petrole | Catalizadores utilizables en las reacciones de transformacion de hidrocarburos, que contienen un metal dopante. |
CN1099907C (zh) * | 1998-06-18 | 2003-01-29 | 中国科学院大连化学物理研究所 | 一种饱和烃脱氢用催化剂及其制备 |
FR2792550B1 (fr) * | 1999-04-26 | 2001-06-01 | Inst Francais Du Petrole | Catalyseur comprenant un element des groupes 8,9 et 10 presentant une bonne accessibilite et son utilisation dans un procede de deshydrogenation des paraffines |
US7147947B2 (en) * | 2002-02-25 | 2006-12-12 | Delphi Technologies, Inc. | Selective carbon monoxide oxidation catalyst, method of making the same and systems using the same |
US20060102520A1 (en) * | 2004-11-12 | 2006-05-18 | Lapinski Mark P | Reforming process using high density catalyst |
US7989173B2 (en) * | 2006-12-27 | 2011-08-02 | The Johns Hopkins University | Detection and diagnosis of inflammatory disorders |
US8546622B2 (en) | 2008-07-31 | 2013-10-01 | Celanese International Corporation | Process for making ethanol from acetic acid using acidic catalysts |
US8309773B2 (en) | 2010-02-02 | 2012-11-13 | Calanese International Corporation | Process for recovering ethanol |
US8338650B2 (en) | 2008-07-31 | 2012-12-25 | Celanese International Corporation | Palladium catalysts for making ethanol from acetic acid |
US8309772B2 (en) | 2008-07-31 | 2012-11-13 | Celanese International Corporation | Tunable catalyst gas phase hydrogenation of carboxylic acids |
US8471075B2 (en) | 2008-07-31 | 2013-06-25 | Celanese International Corporation | Processes for making ethanol from acetic acid |
US8304586B2 (en) | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
US8501652B2 (en) * | 2008-07-31 | 2013-08-06 | Celanese International Corporation | Catalysts for making ethanol from acetic acid |
US8680317B2 (en) | 2008-07-31 | 2014-03-25 | Celanese International Corporation | Processes for making ethyl acetate from acetic acid |
US8637714B2 (en) | 2008-07-31 | 2014-01-28 | Celanese International Corporation | Process for producing ethanol over catalysts containing platinum and palladium |
US8450535B2 (en) | 2009-07-20 | 2013-05-28 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
US8710277B2 (en) | 2009-10-26 | 2014-04-29 | Celanese International Corporation | Process for making diethyl ether from acetic acid |
US8680321B2 (en) | 2009-10-26 | 2014-03-25 | Celanese International Corporation | Processes for making ethanol from acetic acid using bimetallic catalysts |
US8211821B2 (en) | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
US8747492B2 (en) | 2010-02-02 | 2014-06-10 | Celanese International Corporation | Ethanol/fuel blends for use as motor fuels |
US8344186B2 (en) | 2010-02-02 | 2013-01-01 | Celanese International Corporation | Processes for producing ethanol from acetaldehyde |
US8541633B2 (en) | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
US8460405B2 (en) | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
US8569549B2 (en) | 2010-02-02 | 2013-10-29 | Celanese International Corporation | Catalyst supports having crystalline support modifiers |
US8668750B2 (en) | 2010-02-02 | 2014-03-11 | Celanese International Corporation | Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels |
US8858659B2 (en) | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
US8314272B2 (en) | 2010-02-02 | 2012-11-20 | Celanese International Corporation | Process for recovering ethanol with vapor separation |
US8728179B2 (en) | 2010-02-02 | 2014-05-20 | Celanese International Corporation | Ethanol compositions |
US8680343B2 (en) | 2010-02-02 | 2014-03-25 | Celanese International Corporation | Process for purifying ethanol |
US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
US8754267B2 (en) | 2010-05-07 | 2014-06-17 | Celanese International Corporation | Process for separating acetaldehyde from ethanol-containing mixtures |
US9486786B2 (en) * | 2010-07-02 | 2016-11-08 | Savannah River Nuclear Solutions, Llc | Highly dispersed metal catalyst |
US8350098B2 (en) | 2011-04-04 | 2013-01-08 | Celanese International Corporation | Ethanol production from acetic acid utilizing a molybdenum carbide catalyst |
CN102909101B (zh) * | 2011-08-01 | 2015-04-15 | 中国石油化工股份有限公司 | 一种采用低浓度氢气低温还原活化脱氢催化剂的方法 |
CN102909092B (zh) * | 2011-08-01 | 2015-04-01 | 中国石油化工股份有限公司 | 低浓度氢气高温还原结合低温还原的脱氢催化剂活化方法 |
US8536382B2 (en) | 2011-10-06 | 2013-09-17 | Celanese International Corporation | Processes for hydrogenating alkanoic acids using catalyst comprising tungsten |
US8658843B2 (en) | 2011-10-06 | 2014-02-25 | Celanese International Corporation | Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation |
US8703868B2 (en) | 2011-11-28 | 2014-04-22 | Celanese International Corporation | Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol |
US9233899B2 (en) | 2011-12-22 | 2016-01-12 | Celanese International Corporation | Hydrogenation catalysts having an amorphous support |
US9000234B2 (en) | 2011-12-22 | 2015-04-07 | Celanese International Corporation | Calcination of modified support to prepare hydrogenation catalysts |
US9024086B2 (en) | 2012-01-06 | 2015-05-05 | Celanese International Corporation | Hydrogenation catalysts with acidic sites |
MX2014008253A (es) | 2012-01-06 | 2014-08-08 | Celanese Int Corp | Catalizadores de hidrogenacion con soportes modificados con cobalto. |
US8981164B2 (en) | 2012-01-06 | 2015-03-17 | Celanese International Corporation | Cobalt and tin hydrogenation catalysts |
US9050585B2 (en) | 2012-02-10 | 2015-06-09 | Celanese International Corporation | Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol |
US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
WO2019089906A1 (en) * | 2017-11-02 | 2019-05-09 | Uop Llc | Processes for regenerating a catalyst for the selective conversion of hydrocarbons |
KR102464144B1 (ko) * | 2020-12-04 | 2022-11-04 | 희성촉매 주식회사 | 링 타입 금속분포를 가지는 탈수소화 촉매 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE753072A (en) * | 1970-07-06 | 1970-12-16 | Chevron Res | Dehydrogenation catalyst |
US3745112A (en) * | 1971-11-23 | 1973-07-10 | Universal Oil Prod Co | Platinum-tin uniformly dispersed hydro-carbon conversion catalyst and process |
US3892657A (en) * | 1972-07-17 | 1975-07-01 | Universal Oil Prod Co | Hydrocarbon conversion with a multimetallic catalytic composite |
US3998900A (en) * | 1973-03-05 | 1976-12-21 | Universal Oil Products Company | Dehydrogenation of hydrocarbons with a multimetallic catalytic composite |
JPS5163261U (es) * | 1974-11-13 | 1976-05-18 | ||
US4486547A (en) | 1981-11-05 | 1984-12-04 | Uop Inc. | Indium-containing dehydrogenation catalyst |
CN1013361B (zh) * | 1987-03-13 | 1991-07-31 | 中国科学院大连化学物理研究所 | 饱和烃类脱氢用铂、锡、锂、硫催化剂 |
IT1228545B (it) * | 1987-07-31 | 1991-06-20 | Eniricerche Spa | Catalizzatore di deidrogenazione e procedimento per la sua preparazione. |
US4886928A (en) * | 1988-09-26 | 1989-12-12 | Uop | Hydrocarbon dehydrogenation process |
US4964975A (en) * | 1989-06-30 | 1990-10-23 | Uop | Reforming catalyst with homogeneous metals dispersion |
-
1995
- 1995-11-04 DE DE59508645T patent/DE59508645D1/de not_active Expired - Fee Related
- 1995-11-04 EP EP95117393A patent/EP0714872B1/de not_active Expired - Lifetime
- 1995-11-04 ES ES95117393T patent/ES2151015T3/es not_active Expired - Lifetime
- 1995-11-17 US US08/560,096 patent/US5849657A/en not_active Expired - Fee Related
- 1995-11-21 AR AR33440795A patent/AR000214A1/es unknown
- 1995-11-27 BR BR9505527A patent/BR9505527A/pt not_active Application Discontinuation
- 1995-11-27 CN CN95120276A patent/CN1081081C/zh not_active Expired - Fee Related
- 1995-11-28 KR KR1019950044072A patent/KR960016959A/ko active IP Right Grant
- 1995-11-29 JP JP7310684A patent/JPH08224475A/ja active Pending
-
1998
- 1998-10-09 US US09/169,011 patent/US5912394A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1130101A (zh) | 1996-09-04 |
BR9505527A (pt) | 1997-10-28 |
CN1081081C (zh) | 2002-03-20 |
JPH08224475A (ja) | 1996-09-03 |
ES2151015T3 (es) | 2000-12-16 |
KR960016959A (ko) | 1996-06-17 |
DE59508645D1 (de) | 2000-09-21 |
US5912394A (en) | 1999-06-15 |
US5849657A (en) | 1998-12-15 |
EP0714872A2 (de) | 1996-06-05 |
EP0714872B1 (de) | 2000-08-16 |
EP0714872A3 (de) | 1996-11-20 |
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