KR960700333A - 고형의 세정, 헹굼 및 세척제(solid washing rinsing and cleaning agents) - Google Patents
고형의 세정, 헹굼 및 세척제(solid washing rinsing and cleaning agents)Info
- Publication number
- KR960700333A KR960700333A KR1019950703105A KR19950703105A KR960700333A KR 960700333 A KR960700333 A KR 960700333A KR 1019950703105 A KR1019950703105 A KR 1019950703105A KR 19950703105 A KR19950703105 A KR 19950703105A KR 960700333 A KR960700333 A KR 960700333A
- Authority
- KR
- South Korea
- Prior art keywords
- ether
- average molecular
- molecular weight
- process according
- sulfates
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/126—Acylisethionates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
Abstract
하기 성분을 함유하는 고형의 세척, 헹굼 및 청결제는 점진적인 비이온성 텐시드(tensides)의 회피에 내성이 있다: a) 9:1 내지 1:9의 중량비의 음이온성 및 비이온성 계면성활성제와 혼합물, 및 b) 비이온성 계면활성제에 대하여 1 내지 50중량%의 선택된 중합성 고형화제.
그것을 함유하는 판지를 통한 지방 침투는 방지될 수 있다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- a) 9:1 내지 1:9의 중량비의 음이온성 및 비이온성 계면성활성제, 및 b) 비이온성 계면활성제를 기준으로, b1) 12,000 내지 500,000의 평균 분자량을 갖는 폴리에틸렌 글리콘 에테르, b2) 400 내지 20,000의 평균 분자량을 가지는 디카르복실산의 에스테르, b3) 400 내지 20,000의 평균 분자량을 가지는 폴리에틸렌 글리콜 에테르와 디알킬 카보네이트와의 에스테르 교환 반응 산물, 및 b4) 5 내지 1,000의 축합도를 가지는 올리고- 또는 폴리사카리드로 이루어지는 군으로부터 선택되는 1 내지 50중량%의 중합성고형화제의 혼합물을 함유하는 고형의 세탁 세정제, 식기 세정제 및 세척제.
- 비이온성 계면활성제를 기준으로 b1) 12,000 내지 500,000의 평균 분자량을 갖는 폴리에틸렌 글리콘 에테르, b2) 400 내지 20,000의 평균 분자량을 가지는 디카르복실산의 에스테르, b3) 400 내지 20,000의 평균 분자량을 가지는 폴리에틸렌 글리콜 에테르와 디알킬 카보네이트와의 에스테르 교환 반응 산물, 및 b4) 5 내지 1,000의 축합도를 가지는 올리고- 또는 폴리사카리드로 이루어지는 군으로부터 선택되는 1 내지 50중량%의 중합성고형화제를 9:1 내지 1:9중량비의 음이온 및 비이온성 계면활성제의 혼합물에 첨가하여 고형의 세탁세정제, 식기 세정제 및 세척제를 제조하는 방법.
- 제2항에 있어서, 사용되는 음이온 계면활성제가 알킬 벤젠술포네이트, 알칸 술포네이트, 올레핀 술포네이트, 알킬 에테르 술포네이트, 글리세롤 에테르 술포네이트,-메틸 에스테르 술포네이트, 술포 지방산, 지방 알콜 술페이트, 집아 알콜 에세틀 술페이트, 글리세롤 에테르 술페이트, 히드록시 혼합 에테르 술페이트, 모노글리세리드(에테르)술페이트, 지방산아미드(에테르)술페이트, 술포숙시네이트, 술포숙시나메이트, 술포트리글리세리드, 아미드 숲(soap), 에테르 카르복실산, 이세티오네이트, 사코시네이트, 타우리드, 알킬 올리고글루코시드 술페이트 및 알킬(에테르)포스페이트로 이루어지는 군으로부터 선택됨을 특징으로 하는 방법.
- 제3항에 있어서, 사용되는 음이온성 계면활성제가 식(Ⅰ)에 해당되는 지방 알콜 술페이트임을 특징으로하는 방법:R1OSO3X (Ⅰ)〔상기 식 중, R1은 12 내지 22개의 탄소원자를 함유하는 직쇄 또는 분지쇄 알킬 및/또는 알케닐 라디칼이고, X는 알카리 금속 및/또는 알카리토 금속, 암모늄, 알칼암모늄, 알카놀암모늄 또는 글루카암모늄이다.〕
- 제3항 및 4항에 있어서, R1이 16 내지 18개의 탄소원자를 함유하는 알킬 라디칼이고, X는 나트륨인 일반식(Ⅰ)에 해당하는 지방 알콜 술페이트가 사용됨을 특징으로 하는 방법.
- 제2항 내지 5항중 어느 한 항에 있어서, 사용되는 비이온성 계면활성제가 식(Ⅱ)에 해당되는 지방 알콜 폴리글리콜 에테르임을 특징으로 하는 방법:〔상기 식 중, R2는 6 내지 18개의 탄소원자를 가지며, 0,1,2 또는 3개의 이중 결합을 가지는 선상 또는 가지난 지방족 탄화수소 라디칼이며, n은 0 또는 1 내지 3이 수이고, m은 1 내지 10의 수 이다.〕
- 제2항 내지 5항 중 어느 한 항에 있어서, 사용되는 비이온성 계면활성제가 식(Ⅲ)에 해당하는 알킬 올리고 글리코시드임을 특징으로 하는 방법.R3-O-〔G〕p(Ⅲ)〔상기 식 중, R3은 6 내지 22개의 탄소원자를 함유하는 알칼 라디칼이고, G는 5또는 6개의 탄소원자를 함유하는 당 단위이며, p는 1 내지 10의 수 이다.〕
- 제2항 내지 7항중 어느 한 항에 있어서, 중합성 고형화제로 12,000 내지 500,000의 평균 분자량을 가지는 폴리에틸렌 글리콜 에테르가 사용됨을 특징으로 하는 방법.
- 제2항 내지 7항 중 어느 한 항에 있어서, 중합성 고형화제로 400 내지 20,000의 평균 분자량을 가지는 폴리에틸렌 글리콜 에테르와 하기 식(Ⅳ)에 해당하는 디카르복실산과의 에스테르가 사용됨을 특징으로하는 방법.HOOC-(CH2)y-COOH (Ⅳ)〔상기 식 중, y는 0 또는 1 내지 12의 수이다.〕
- 제2항 내지 7항 중 어느 한 항에 있어서, 중합성 고형화제로, 400 내지 20,000의 평균 분자량을 가지는 폴리에틸렌 글리콜 에테르와 디알킬 카보네이트와의 에스테르 교환 반응 산물이 사용됨을 특징으로 하는 방법.
- 제2항 내지 7항 중 어느 한 항에 있어서, 중합성 고형화제로, 5 내지 1,000의 축합도를 가지는 올리고-또는 폴리사카리드가 사용됨을 특징으로 하는 방법.
- 고형의 세탁 세정제, 식기 세정제 및 세척제의 제조용 원료로 상용되는 제1항 내지 제11항에 따른 방법으로 수득될 수 있는 혼합물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4303176A DE4303176C2 (de) | 1993-02-04 | 1993-02-04 | Feste Wasch-, Spül- und Reinigungsmittel |
DEP4303176.5 | 1993-02-04 | ||
PCT/EP1994/000208 WO1994018293A1 (de) | 1993-02-04 | 1994-01-26 | Feste wasch-, spül- und reinigungsmittel |
Publications (1)
Publication Number | Publication Date |
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KR960700333A true KR960700333A (ko) | 1996-01-19 |
Family
ID=6479622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950703105A KR960700333A (ko) | 1993-02-04 | 1994-01-26 | 고형의 세정, 헹굼 및 세척제(solid washing rinsing and cleaning agents) |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0682691B2 (ko) |
JP (1) | JPH08506367A (ko) |
KR (1) | KR960700333A (ko) |
DE (2) | DE4303176C2 (ko) |
ES (1) | ES2100697T3 (ko) |
WO (1) | WO1994018293A1 (ko) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USH1514H (en) * | 1994-06-01 | 1996-01-02 | The Procter & Gamble Company | Detergent compositions with oleoyl sarcosinate and polymeric dispersing agent |
TW326472B (en) * | 1994-08-12 | 1998-02-11 | Kao Corp | Method for producing nonionic detergent granules |
US5866530A (en) * | 1995-11-25 | 1999-02-02 | Henkel Kommanditgesellschaft Auf Aktien | Non-aqueous liquid mixtures of alkyl polyglycoside and alkyl polyalkylene glycol ether useful in various detergent applications |
GB2314563B (en) * | 1996-06-28 | 2000-03-29 | Laporte Esd Ltd | Surfactant compositions |
DE19635555C2 (de) * | 1996-09-02 | 2000-06-08 | Cognis Deutschland Gmbh | Wäßrige Handgeschirrspülmittel |
DE19719606C2 (de) * | 1997-05-09 | 1999-02-18 | Henkel Kgaa | Feststoffzubereitungen |
DE19858886C2 (de) | 1998-12-19 | 2002-10-31 | Cognis Deutschland Gmbh | Tensidgranulate |
DE19911040A1 (de) | 1999-03-12 | 2000-09-21 | Cognis Deutschland Gmbh | Tensidgranulate |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU60943A1 (ko) * | 1970-05-20 | 1972-02-23 | ||
US3803285A (en) * | 1971-01-20 | 1974-04-09 | Cpc International Inc | Extrusion of detergent compositions |
PH14451A (en) † | 1972-10-31 | 1981-07-23 | Procter & Gamble | Detergent compositions |
JPS5241612A (en) * | 1975-09-30 | 1977-03-31 | Kao Corp | Granular or powdered detergent compositions |
GB8302980D0 (en) † | 1983-02-03 | 1983-03-09 | Procter & Gamble Ltd | Laundry additive compositions |
DE3424317A1 (de) * | 1984-07-02 | 1986-01-23 | Henkel KGaA, 4000 Düsseldorf | Mittel zur toilettenreinigung |
CA1293421C (en) * | 1985-07-09 | 1991-12-24 | Mark Edward Cushman | Spray-dried granular detergent compositions containing nonionicsurfactant, polyethylene glycol, and polyacrylate |
CA2017922C (en) † | 1989-06-09 | 1995-07-11 | Frank Joseph Mueller | Formation of discrete, high active detergent granules using a continuous neutralization system |
DE4124701A1 (de) * | 1991-07-25 | 1993-01-28 | Henkel Kgaa | Verfahren zur herstellung fester wasch- und reinigungsmittel mit hohem schuettgewicht und verbesserter loesegeschwindigkeit |
-
1993
- 1993-02-04 DE DE4303176A patent/DE4303176C2/de not_active Expired - Fee Related
-
1994
- 1994-01-26 KR KR1019950703105A patent/KR960700333A/ko not_active Application Discontinuation
- 1994-01-26 DE DE59402383T patent/DE59402383D1/de not_active Expired - Fee Related
- 1994-01-26 ES ES94906151T patent/ES2100697T3/es not_active Expired - Lifetime
- 1994-01-26 EP EP94906151A patent/EP0682691B2/de not_active Expired - Lifetime
- 1994-01-26 JP JP6517588A patent/JPH08506367A/ja active Pending
- 1994-01-26 WO PCT/EP1994/000208 patent/WO1994018293A1/de active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
JPH08506367A (ja) | 1996-07-09 |
EP0682691B2 (de) | 2004-01-14 |
EP0682691A1 (de) | 1995-11-22 |
WO1994018293A1 (de) | 1994-08-18 |
DE4303176C2 (de) | 1997-07-31 |
EP0682691B1 (de) | 1997-04-09 |
DE4303176A1 (de) | 1994-08-11 |
DE59402383D1 (de) | 1997-05-15 |
ES2100697T3 (es) | 1997-06-16 |
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