KR960041268A - 폴리프로필렌계 수지 조성물 - Google Patents

폴리프로필렌계 수지 조성물 Download PDF

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KR960041268A
KR960041268A KR1019960017720A KR19960017720A KR960041268A KR 960041268 A KR960041268 A KR 960041268A KR 1019960017720 A KR1019960017720 A KR 1019960017720A KR 19960017720 A KR19960017720 A KR 19960017720A KR 960041268 A KR960041268 A KR 960041268A
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acid
resin composition
polypropylene resin
weight
composition according
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KR1019960017720A
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KR100405448B1 (ko
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유타카 아즈마
사토시 다무라
츠네노스케 하라마츠
게이고 우메모토
도시오 가노
마사미치 곤도
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가와노 에이지로
이데미쓰 세키유 가가쿠 가부시키가이샤
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Priority claimed from JP14074395A external-priority patent/JPH08333492A/ja
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Publication of KR960041268A publication Critical patent/KR960041268A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C08K5/57—Organo-tin compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1. 청구범위에 기재된 발명이 속한 기술분야
본 발명은 폴리프로필렌계 수지조성물에 관한 것이다.
2. 발명이 해결하려고 하는 기술적 과제본 발명이 두께변화가 작고, 외관 및 내열성이 양호하고, 또한 가소화폴리염화비닐성형체와 같은 유연성을 가지며, 토목건재나 자동차용 내장표피재 등으로서 유용한 필름이나 시이트를 카렌다성형기로 성형성 좋게 만들 수 있는 폴리프로필렌계 수지조성물을 제공하는 것을 목적으로 하는 것이다.
3. 발명의 해결방법의 요지
본 발명의 (A) (a) (i) 동위체탄소 핵자기공명스펙트럼(13C-NMR)에 의한 펜타드분율에 있어서, rrrr/(1-mmmm)×100이 20∼60%, (ii) 시차주사열량분석계(DSC)로 측정한 융해피크온도(Tm)가 150℃ 이상 및 (iii) DSC로 측정한 융해엔탈피( H)가 100J/ 이하인 프로필렌의 단독중합체 및/또는 4중량% 이하의 다른 올레핀 단위를 함유하는 공중합체 100∼20중량%%와 (b) 프로필렌계 이외의 올레핀단위 10∼80중량%를 함유하는 프로필렌계 공중합계 0∼80중량%로 된 폴리프로필렌계 수지 100중량부에 대하고, (B) 옥틸석지방산염, 알킬렌비스지방산아미드, 다가알콜의 지방산에스테르 및 지방족 모노카르복시산 금속염 중에서 선택된 적어도 1종의 지방산 유도체 0.01∼5중량부를 배합하여 된 폴리프로필렌계 수지조성물을 제공하는 것이다.
4. 발명의 중요한 용도
본 발명의 수지 조성물을 이용하면, 두께변화가 작고, 외관 및 내열성이 양호하고, 또 가소화폴리염화비닐성형체에 의한 유연성을 갖는 필름이나 시이트를 카렌다성형기로 성형성을 좋게 만들 수 있다.

Description

폴리프로필렌계 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. (A) (a) (i) 동위체탄소 핵자기공명스펙트럼(13C-NMR)에 의한 펜타드분율에 있어서, rrrr/(1-mmmm)×100가 20∼60%, (ii) 시차주사열량분석계(DSC)로 측정한 융해피크온도(Tm)가 150℃ 이상 및 (iii) DSC로 측정한 융해엔탈피( H)가 100J/ 이하인 프로필렌의 단독중합체 및/또는 4중량% 이하의 다른 올레핀 단위를 함유하는 공중합체 100∼20중량%%와, (b) 프로필렌계이외이 올레핀단위 10∼80중량%를 함유하는 프로필렌계 공중합체 0∼80중량%로 된 폴리프로필렌계 수지 100중량부에 대하고, (B) 옥틸석지방산염, 알킬렌비스지방산아미드, 다가알콜의 지방산에스테르 및 지방산모노카르복시산금속염 중에서 선택된 적어도 1종의 지방산 유도체 0.01∼5중량부를 배합해서 된 폴리 프로필렌계 수지조성물.
  2. 제1항에 있어서, (B) 성분의 옥틸석지방산염이, 일반식(Ⅰ)
    (C8H17)KSn(OOC-R)4-K(Ⅰ)
    〔식중, R은 탄소수 9∼21의 알킬기 또는 알케닐기, k는 1 또는 2를 나타내고, 복수의 R-COO기는 각각 동일해도 달라도 된다.〕로 표시되는 화합물인 폴리프로필렌계 수지조성물.
  3. 제1항에 있어서, (B) 성분분인 알킬렌비스지방산 아미드가, 에틸렌비스스테아린산 아미드 또는 메틸렌비스스테아린산 아미드인 폴리프로필렌계 수지조성물.
  4. 제1항에 있어서, (B) 성분인 다가알콜의 지방산에스테르가, 펜타에리스리톨의 지방산 전부아니면 부분 에스테르 또는 디펜타에리스리톨의 지방산 전부 아니면 분 에스테르인 폴리프로필렌계 수지조성물.
  5. 제1항에 있어서, (B) 성분인 지방족모노카르복시산 금속염의 1종 또는 2종 이상을 배합해서 된 폴리프로필렌계 수지조성물.
  6. 제5항에 있어서, (B) 성분인 지방족모노카르복시산 금속염을 구성하는 금속이, 주기율표 1, 2 및 8∼14족의 어느 하나에 속하는 금속인 폴리프로필렌계 수지조성물.
  7. 제5항에 있어서, (B) 성분인 지방족모노카르복시산 금속염을 구성하는 지방족모노카르복시산이, 관능기를 함유하고 있어도 되는 탄소수 8∼32의 포화 또는 불포화의 모노카르복시산인 폴리프로필렌계 수지조성물.
  8. 제6항 또는 제7항에 있어서, (B) 성분인 지방족모노카르복시산 금속염을 구성하는 금속이 Li, Na, K, Cu, Mg, Ca, Ba, Sr, Zn, Cd, Al, Pb, Sn, Fe, Co 또는 Ni이고, 또 그 지방족 모노카르복시산 금속염을 구성하는 지방족모노카르복시산이, 라우린산, 미리스틴산, 팔미틴산, 아라긴산, 헵타데실산, 베헨산, 올레인산, 에라이딘산, 에루크산, 리놀산, 리놀레인산, 리시놀산, 히드록시스테아린산, 몬탄산, 이소스테아린산 또는 에폭시스테아린산인 폴리프로필렌계 수지조성물.
  9. 제1항에 기재된 수지조성물로 이루어진 카렌다성형용 수지조성물.
  10. 제1항에 기재된 폴리프로필렌계 수지조성물로 이루어진 필름 또는 시이트.
  11. 제1항에 기재된 폴리프로필렌계 수지조성물을 카렌다성형하는 필름 또는 시이트의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019960017720A 1995-05-25 1996-05-23 폴리프로필렌계수지조성물 KR100405448B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP95-126118 1995-05-25
JP12611895A JP3367585B2 (ja) 1995-05-25 1995-05-25 ポリプロピレン系樹脂組成物
JP14074395A JPH08333492A (ja) 1995-06-07 1995-06-07 ポリプロピレン系樹脂組成物
JP95-140743 1995-06-07

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KR960041268A true KR960041268A (ko) 1996-12-19
KR100405448B1 KR100405448B1 (ko) 2004-03-26

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US (2) US5955524A (ko)
EP (1) EP0744439B1 (ko)
KR (1) KR100405448B1 (ko)
DE (1) DE69601105T2 (ko)

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KR100544398B1 (ko) * 2000-08-01 2006-01-23 한화종합화학 주식회사 캘린더가 가능한 데코시트용 폴리프로필렌계 조성물 및이를 이용한 폴리프로필렌 필름 및 시이트의 제조방법

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KR100405448B1 (ko) 2004-03-26
EP0744439B1 (en) 1998-12-09
US6159614A (en) 2000-12-12
DE69601105T2 (de) 1999-06-02
DE69601105D1 (de) 1999-01-21
EP0744439A1 (en) 1996-11-27

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