KR960037595A - 층상 광물 및 이를 포함하는 조성물 - Google Patents
층상 광물 및 이를 포함하는 조성물 Download PDFInfo
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- KR960037595A KR960037595A KR1019960009851A KR19960009851A KR960037595A KR 960037595 A KR960037595 A KR 960037595A KR 1019960009851 A KR1019960009851 A KR 1019960009851A KR 19960009851 A KR19960009851 A KR 19960009851A KR 960037595 A KR960037595 A KR 960037595A
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- 239000000203 mixture Substances 0.000 title claims abstract 34
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims 17
- 239000011707 mineral Substances 0.000 title claims 17
- 150000001768 cations Chemical class 0.000 claims abstract 16
- 125000005842 heteroatom Chemical class 0.000 claims abstract 16
- -1 heteroaromatic cations Chemical class 0.000 claims abstract 15
- 238000000034 method Methods 0.000 claims abstract 11
- 125000003118 aryl group Chemical group 0.000 claims abstract 8
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims 10
- 229910052901 montmorillonite Inorganic materials 0.000 claims 9
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims 7
- 229910052622 kaolinite Inorganic materials 0.000 claims 7
- CYPPCCJJKNISFK-UHFFFAOYSA-J kaolinite Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[O-][Si](=O)O[Si]([O-])=O CYPPCCJJKNISFK-UHFFFAOYSA-J 0.000 claims 7
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 6
- 239000010445 mica Substances 0.000 claims 6
- 229910052618 mica group Inorganic materials 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- 229920000515 polycarbonate Polymers 0.000 claims 5
- 239000004417 polycarbonate Substances 0.000 claims 5
- 150000003839 salts Chemical class 0.000 claims 5
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims 4
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims 4
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 claims 4
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 claims 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 4
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 claims 4
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 claims 4
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims 4
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 claims 4
- 229920000728 polyester Polymers 0.000 claims 4
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000004429 atom Chemical group 0.000 claims 3
- 125000002619 bicyclic group Chemical group 0.000 claims 3
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 claims 3
- 125000004122 cyclic group Chemical group 0.000 claims 3
- 229910001649 dickite Inorganic materials 0.000 claims 3
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 claims 3
- 229910000271 hectorite Inorganic materials 0.000 claims 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 claims 3
- 229910052627 muscovite Inorganic materials 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- 229910000273 nontronite Inorganic materials 0.000 claims 3
- 229910052698 phosphorus Inorganic materials 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- 229920001955 polyphenylene ether Polymers 0.000 claims 3
- 229910000275 saponite Inorganic materials 0.000 claims 3
- 229910021647 smectite Inorganic materials 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 229910052902 vermiculite Inorganic materials 0.000 claims 3
- 239000010455 vermiculite Substances 0.000 claims 3
- 235000019354 vermiculite Nutrition 0.000 claims 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 2
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 claims 2
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims 2
- KPTMGJRRIXXKKW-UHFFFAOYSA-N 2,3,5-trimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical group O1C2=C(C)C(C)=C1C=C2C KPTMGJRRIXXKKW-UHFFFAOYSA-N 0.000 claims 2
- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 claims 2
- GVLZQVREHWQBJN-UHFFFAOYSA-N 3,5-dimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical group CC1=C(O2)C(C)=CC2=C1 GVLZQVREHWQBJN-UHFFFAOYSA-N 0.000 claims 2
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical compound O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 claims 2
- GAMYYCRTACQSBR-UHFFFAOYSA-N 4-azabenzimidazole Chemical compound C1=CC=C2NC=NC2=N1 GAMYYCRTACQSBR-UHFFFAOYSA-N 0.000 claims 2
- PCXMISPZSFODLD-UHFFFAOYSA-N 6,9-dioxatricyclo[9.3.1.14,14]hexadeca-1(14),2,4(16),11(15),12-pentaene-5,10-dione Chemical compound C1=C(C=C2)C(=O)OCCOC(=O)C3=CC=C1C2=C3 PCXMISPZSFODLD-UHFFFAOYSA-N 0.000 claims 2
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 claims 2
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 claims 2
- 239000004642 Polyimide Substances 0.000 claims 2
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims 2
- 150000001409 amidines Chemical class 0.000 claims 2
- 150000001450 anions Chemical class 0.000 claims 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 125000001072 heteroaryl group Chemical group 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims 2
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 229920001601 polyetherimide Polymers 0.000 claims 2
- 229920001721 polyimide Polymers 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 2
- JWVCLYRUEFBMGU-UHFFFAOYSA-N quinazoline Chemical compound N1=CN=CC2=CC=CC=C21 JWVCLYRUEFBMGU-UHFFFAOYSA-N 0.000 claims 2
- 229910000276 sauconite Inorganic materials 0.000 claims 2
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 claims 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004697 Polyetherimide Substances 0.000 claims 1
- 229920000265 Polyparaphenylene Polymers 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims 1
- 229910001594 brammallite Inorganic materials 0.000 claims 1
- 229910001596 celadonite Inorganic materials 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 239000010433 feldspar Substances 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 229910052621 halloysite Inorganic materials 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 229910052900 illite Inorganic materials 0.000 claims 1
- 150000002462 imidazolines Chemical class 0.000 claims 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229920001643 poly(ether ketone) Polymers 0.000 claims 1
- 229920002492 poly(sulfone) Polymers 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000412 polyarylene Polymers 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims 1
- 239000010453 quartz Substances 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/20—Mica; Vermiculite
- C04B14/206—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/20—Mica; Vermiculite
- C04B14/206—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate
- C04B14/208—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate delaminated mica or vermiculite platelets
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0087—Ion-exchanging agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
본 발명은 양전하의 오가노-치환된 헤테로원자를 포함하는 헤테로방향족 양이온 하나 이상 및/또는 1 보다 큰 결합차수의 결합을 하나 이상 갖는 방향족 고리의 일부가 아닌 양전하의 헤테로원자 하나 이상을 포함하는 양이온으로 양이온 교환된 신규한 실리케이트 광물 및 이를 포함하는 조성물에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (46)
- (a) 양전하의 오가노-치환된 헤테로원자를 하나 이상 포함하는 헤테로방향족 양이노; 및 (b) 1 보다 큰 결합차수의 결합을 하나 이상 갖는 방향족 고리의 일부가 아닌 양전하의 헤테로원자를 하나 이상 포함하는 양이온으로 구성된 그룹에서 선택되는 하나 이상의 양이온으로 양이온 교환된 층상 광물.
- 제1항에 있어서, 카올리나이트(kaolinite)류, 몬모릴로나이트(montmorillonite)류, 일라이트(illite)류 또는 이들의 혼합물에서 선택되는 층상 광물.
- 제2항에 있어서, 상기 카올리나이트류가 카올리나이트, 할로이사이트(halloysite), 딕카이트(dickite) 또는 네이크라이트(nacrite)를 포함하는 층상 광물.
- 제2항에 있어서, 상기 몬모릴로나이트류가 몬모릴로나이트, 논트로나이트(nontronite), 베이덜라이트(beidellite), 헥토라이트(hectorite) 또는 사포나이트(saponite)를 포함하는 층상 광물.
- 제2항에 있어서, 상기 일라이트류가 함수 운모, 펭가이트(phengite), 브람말라이트(brammallite), 글라우코마이트(glaucomite) 또는 셀라도나이트(celadonite)를 포함하는 층상 광물.
- 제1항에 있어서, 케냐이트(kenyaite), 매가다이트(magadite), 무스코바이트(muscovite), 사우코나이트(sauconite), 베르미큘라이트(vermiculite), 볼콘스코이트(volkonskoite), 피로필릭(phyrophylic), 운모 또는 스멕타이트(smectite)인 층상 광물.
- 제1항에 있어서, (a)의 상기 양이온 및 (b)의 상기 양이온이 N, P, O 및 S로 구성된 그룹에서 선택되는 헤테로원자를 포함하는 층상 괴물.
- 제7항에 있어서, 양전하의 오가노-치환된 헤테로원자를 하나 이상 포함하는 상기 헤테로방향족 양이온이피롤, 이미다졸, 티아졸, 옥사졸, 피리딘, 피리미딘, 퀴놀린, 이소퀴놀린, 인돌, 퓨린, 벤즈이미다졸, 벤조티아졸, 벤족사졸, 피라진, 퀴녹살린, 퀴나졸린, 아크리딘, 페나진, 이미다조피리딘 또는 디피리딜의 오가노-치환된 염인 층상 광물.
- 제8항에 있어서, 상기 오가노-치환된 헤테로원자가 C1내지 C25의 지방족, 치환족 또는 방향족 기로 치환되는 층상 광물.
- 제9항에 있어서, 상기 헤테로방향족 양이온이 N-C1내지18피리디늄 양이온인 층상 광물.
- 제1항에 있어서, 1보다 큰 결합치수의 결합을 하나 이상 갖는 방향족 고리의 일부가 아닌 양전하의 헤테로원자를 하나 이상 포함하는 상기 양이온이 하기 일반식을 갖는 층상 광물:상기 식에서, R1, R2, R3및 R4는 각각 독립적으로 수소, C1내지 C20의 알킬기, 방향족 라디칼, 치환된 헤테로원자 또는(이때, R5는 수소 또는 C1내지 C10의 알킬 기임)이거나 또는 R1과 R2, R3과 R4, R1과 R3및 R2와 R4중 하나 이상은 이들을 연결하는 원자와 함께 4 내지 10원의 환상 또는 이환상 고리를 형성한다.
- 제11항에 있어서. 방향족 고리의 일부가 아닌 양전하의 헤테로원자를 하나 이상 포함하는 상기 양이온이구아니딘 또는 아미딘의 염인 층상 광물.
- 제12항에 있어서, 상기 구아니딘의 염이 헥사알킬구아니디늄 염인 층상 광물.
- (a) (i) 양전하의 오가노-치환된 헤테로원자를 하나 이상 포함하는 헤테로방향족 양이온, 및 (ii) 1 보다 큰 결합차수의 결합을 하나 이상 갖는 방향족 고리의 일부가 아닌 양전하의 헤테로원자를 하나 이상 포함하는 양이온으로 구성된 그룹에서 선택되는 하나 아상의 양이온으로 양이온 교환시킨 층상 광물; 및 (b) 유리 시스템을 포함하는 조성물.
- 제14항에 있어서, 상기 층상 광물이 카올리나이트류, 몬모릴로나이트류 또는 일라이트류에서 선택되는 조성물.
- 제15항에 있어서, 상기 카올리나이트류가 카올리나이트, 할로이사이트, 딕카이트 또는 네이크라이트를 포함하는 조성물.
- 제15항에 있어서, 상기 몬모릴로나이트류가 몬모릴로나이트, 논트로나이트, 베이델라이트, 헥토라이트 또는 사포나이트를 포함하는 조성물.
- 제15항에 있어서, 상기 일라이트류가 함수 운모, 펭가이트, 브람말라이트, 글라우코마이트 또는 셀라도나이트를 포함하는 조성물.
- 제14항에 있어서, 상기 층상 광물이 케냐이트, 매가다이트, 무스코바이트, 사우코나이트, 베르미큘라이트, 볼콘스코이트, 피로필릭, 운모 또는 스멕타이트인 조성물.
- 제14항에 있어서, (a)의 상기 양이온 및 (b)의 상기 양이온이 N, P, O 및 S로 구성된 그룹에서 선택되는 헤테로원자를 포함하는 조성물.
- 제20항에 있어서, 양전하의 오가노-치환된 헤테로원자를 하나 이상 포함하는 상기 헤테로방향족 양이온 이 피롤, 이미다졸, 티아졸, 옥사졸, 피리딘, 피리미딘, 퀴놀린, 이소퀴놀린, 인돌, 퓨린, 벤즈이미다졸, 벤조티아졸, 벤족사졸, 피라진, 퀴녹살린, 퀴나졸린, 아크리딘, 페나진, 이미다조피리딘 또는 디피리딜의 오가노-치환된 염인 조성물.
- 21항에 있어서, 상기 오가노-치환된 헤테로원자가 C1내지 C25의 지방산, 치환족 또는 방향족 기로 치환되는 조성물.
- 제22항에 있어서, 상기 헤테로방향족 양이온이 N-C1내지18피리디늄 양이온인 조성물.
- 제14항에 있어서, 1 보다 큰 결합차수의 결합을 하나 이상 갖는 방향족 고리의 일부가 아닌 양전하의 헤테로원자를 하나 이상 포함하는 상기 양이온이 하기 일반식을 갖는 조성물:상기식에서, R1, R2, R3및 R4는 각각 독립적으로 수소, C1내지 C20의 알킬기, 방향족 라디칼, 치환된 헤테로원자는 또는(이때, R5는 수소 또는 C1내지 C10의 알킬 기임)이거나 R1과 R2, R3과 R4, R1과 R3및 R2와 R4중 하나 이상은 이들을 연결하는 원자와 함께 4 내지 10원의 환상 또는 이환상 고리를 형성한다.
- 제24항에 있어서, 방향족 고리의 일부가 아닌 양전하의 헤테로원자를 하나 이상 포함하는 상기 양이온이구아니딘 또는 아미딘의 염인 조성물.
- 제25항에 있어서, 상기 구아니딘의 염이 헥사알킬구아니디늄 염인 조성물.
- 제14항에 있어서, 상기 유기 시스템이 거대환상 올리고머, 선형 중합체 또는 분지된 중합체를 포함하는 조성물.
- 제27항에 있어서, 상기 유기 시스템이 거대환상 올리고머이며, 거대환상 폴리카보네이트, 폴리에스테르, 폴리이미드, 폴리에테르이미드, 폴리페닐렌 에테르-폴리카보네이트 올리고머, 및 이들로부터 제조된 블렌드, 조성물 또는 코올리고머로 구성된 그룹에서 선택되는 조성물.
- 제28항에 있어서, 상기 유기 시스템이 선형 또는 분지된 중합체이며, 폴리카보네이트, 폴리에스테르, 폴리페닐렌 에테르, 폴리이미드, 올레핀, 폴리에테르이미드, 폴리아미드, 폴리아릴렌 설파이드, 폴리설폰, 폴리에테르케톤, 아크릴로니트릴 부타디엔 스티렌 공중합체, 폴리스티렌, 및 이들로부터 제조된 블렌드, 조성물 및 공중합체로 구성된 그룹에서 선택되는 조성물.
- 제29항에 있어서, 상기 폴리에스테르가 폴리(1,2-에틸렌 테레프탈레이트), 폴리(1,4-부틸렌 테레프탈레이트), 폴리(1,2-에틸렌 2,6-나프탈렌디카복실레이트) 또는 이들로부터 제조된 공중합체인 조성물.
- 제29항에 있어서, 상기 폴리페닐렌 에테르가 2,6-디메틸 1,4-페닐렌 에테르 단위 또는 2,3,6-트리메틸-1,4-페닐렌 에테르 단위의 단독중합체 또는 이들로부터 제조된 공중합체를 포함하는 조성물.
- 제29항에 있어서, 상기 폴리카보네이트가 비스페놀 A 폴리카보네이트인 조성물.
- 제14항에 있어서, 석영, 브로타이트(brotite), 리모나이트(limonite), 함수 운모 또는 장석을 포함하는 조성물.
- 제28항에 따른 조성물의 중합 생성물인 조성물.
- (a) 거대환상 올리고머; 및 (b) 하기 일반식의 양이온으로 양이온 교환된 층상 광물을 포함하는 조성물:상기식에서, R6은 각각 독립적으로 수소, C1내지 C20의 알킬 기, 또는 치환되거나 또는 치환되지 않은 방향족 라디칼이거나, 또는 두 R6은 이들을 연결하는 원자와 함께 4 내지 12원의 환상 또는 이환상 고리를 형성 할 수 있고, X는 N, P 또는 S이며, y는 음이온이다.
- 제35항에 있어서, 상기 음이온이 C1 또는 Br인 조성물.
- 제37항에 있어서, 상기 폴리에스테르가 폴리(1,2-에틸렌 테레프탈레이트), 폴리(1,4-부틸렌 테레프탈레이트), 폴리(1,2-에틸렌 2,6-나프탈렌디카복실레이트) 및 이들의 공중합체인 조성물.
- 제37항에 있어서, 상기 폴리페닐렌 에테르가 2,6-디메틸-1,4-페닐렌 에테르 단위 또는 2,3,6-트리메틸-1,4-페닐렌 에테르 단위의 단독중합체 및 이들의 공중합체를 포함하는 조성물.
- 제37항에 있어서, 상기 폴리카보네이트가 비스페놀 A 폴리카보네이트인 조성물.
- 제35항에 있어서, 상기 층상 광물이 카올리나이트류, 몬모릴로나이트류 또는 일라이트류에서 선택되는 조성물.
- 제41항에 있어서, 상기 카올리나이트류가 카올리나이트, 할로이사이트, 딕카이트 또는 네이크라이트를 포함하는 조성물.
- 제41항에 있어서, 상기 몬모릴로나이트류가 몬모릴로나이트, 논트로나이트, 베이델라이트, 헥토라이트 또는 사포나이트를 포함하는 조성물.
- 제41항에 있어서, 상기 일라이트류가 함수 운모, 펭가이트, 브람말라이트, 글라우코마이트 또는 셀라도나이트를 포함하는 조성물.
- 제35항에 있어서, 상기 층상 광물이 케냐이트, 매가다이트, 무스코바이트, 사우코나이트, 베르미큘라이트, 불콘스코이드, 피로필릭, 운모 또는 스멕타이트인 조성물.
- (a) 거대환상 올리고머; 및 (b) 층상 광물의 혼합물에 중합 촉매를 첨가하는 단계를 포함하는, 층상광물 및 중합된 유기 시스템을 포함하는 조성물을 제조하는 방법.
- 제35항에 따른 조성물의 중합 생성물인 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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| Application Number | Priority Date | Filing Date | Title |
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| US08/416,112 | 1995-04-03 | ||
| US08/416,112 US5530052A (en) | 1995-04-03 | 1995-04-03 | Layered minerals and compositions comprising the same |
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| KR960037595A true KR960037595A (ko) | 1996-11-19 |
| KR100354308B1 KR100354308B1 (ko) | 2002-12-28 |
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| US (2) | US5530052A (ko) |
| EP (1) | EP0736490B1 (ko) |
| JP (1) | JP4100726B2 (ko) |
| KR (1) | KR100354308B1 (ko) |
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-
1995
- 1995-04-03 US US08/416,112 patent/US5530052A/en not_active Expired - Lifetime
- 1995-12-18 US US08/574,012 patent/US5707439A/en not_active Expired - Lifetime
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1996
- 1996-03-25 EP EP96302022A patent/EP0736490B1/en not_active Expired - Lifetime
- 1996-03-25 DE DE69628496T patent/DE69628496T2/de not_active Expired - Fee Related
- 1996-04-01 JP JP07860596A patent/JP4100726B2/ja not_active Expired - Fee Related
- 1996-04-02 KR KR1019960009851A patent/KR100354308B1/ko not_active IP Right Cessation
- 1996-04-03 CN CNB011192364A patent/CN1161420C/zh not_active Expired - Fee Related
- 1996-04-03 CN CN96106007A patent/CN1125115C/zh not_active Expired - Fee Related
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|---|---|
| KR100354308B1 (ko) | 2002-12-28 |
| CN1161420C (zh) | 2004-08-11 |
| US5707439A (en) | 1998-01-13 |
| CN1329108A (zh) | 2002-01-02 |
| CN1148060A (zh) | 1997-04-23 |
| JPH08337414A (ja) | 1996-12-24 |
| EP0736490B1 (en) | 2003-06-04 |
| JP4100726B2 (ja) | 2008-06-11 |
| DE69628496T2 (de) | 2004-04-15 |
| EP0736490A1 (en) | 1996-10-09 |
| CN1125115C (zh) | 2003-10-22 |
| DE69628496D1 (de) | 2003-07-10 |
| US5530052A (en) | 1996-06-25 |
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