CN1329108A - 层状矿物及其组合物 - Google Patents
层状矿物及其组合物 Download PDFInfo
- Publication number
- CN1329108A CN1329108A CN01119236A CN01119236A CN1329108A CN 1329108 A CN1329108 A CN 1329108A CN 01119236 A CN01119236 A CN 01119236A CN 01119236 A CN01119236 A CN 01119236A CN 1329108 A CN1329108 A CN 1329108A
- Authority
- CN
- China
- Prior art keywords
- composition
- layer mineral
- positively charged
- charged ion
- polycarbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims description 51
- 239000011707 mineral Substances 0.000 title claims description 51
- -1 heteroaromatic cation Chemical class 0.000 claims abstract description 14
- 125000003118 aryl group Chemical group 0.000 claims abstract description 12
- 150000002500 ions Chemical class 0.000 claims description 46
- 125000002091 cationic group Chemical group 0.000 claims description 19
- 229920001955 polyphenylene ether Polymers 0.000 claims description 19
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 17
- 229920002601 oligoester Polymers 0.000 claims description 17
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 229920000515 polycarbonate Polymers 0.000 claims description 11
- 239000004417 polycarbonate Substances 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 125000004429 atom Chemical group 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 230000000379 polymerizing effect Effects 0.000 claims description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004697 Polyetherimide Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 229920001601 polyetherimide Polymers 0.000 claims description 4
- 239000004642 Polyimide Substances 0.000 claims description 3
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 3
- 229910000271 hectorite Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 229910052902 vermiculite Inorganic materials 0.000 claims description 3
- 239000010455 vermiculite Substances 0.000 claims description 3
- 235000019354 vermiculite Nutrition 0.000 claims description 3
- GVLZQVREHWQBJN-UHFFFAOYSA-N 3,5-dimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical group CC1=C(O2)C(C)=CC2=C1 GVLZQVREHWQBJN-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 claims description 2
- 229910001594 brammallite Inorganic materials 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- 229910001649 dickite Inorganic materials 0.000 claims description 2
- 229910052621 halloysite Inorganic materials 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 229910052622 kaolinite Inorganic materials 0.000 claims description 2
- 239000008239 natural water Substances 0.000 claims description 2
- 229910000273 nontronite Inorganic materials 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 229910000276 sauconite Inorganic materials 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical class O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 3
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical class [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims 2
- 229920000265 Polyparaphenylene Polymers 0.000 claims 1
- 241000242583 Scyphozoa Species 0.000 claims 1
- 150000001733 carboxylic acid esters Chemical class 0.000 claims 1
- 125000005842 heteroatom Chemical class 0.000 abstract description 27
- 229910052604 silicate mineral Inorganic materials 0.000 abstract description 3
- 238000005341 cation exchange Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 12
- 229920013636 polyphenyl ether polymer Polymers 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 125000001072 heteroaryl group Chemical group 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- PCVVBHUFWPHCAL-UHFFFAOYSA-N butane-1,4-diol;terephthalic acid Chemical compound OCCCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 PCVVBHUFWPHCAL-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 150000002390 heteroarenes Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002114 nanocomposite Substances 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- JRBPAEWTRLWTQC-UHFFFAOYSA-O dodecylazanium Chemical group CCCCCCCCCCCC[NH3+] JRBPAEWTRLWTQC-UHFFFAOYSA-O 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
- CYPPCCJJKNISFK-UHFFFAOYSA-J kaolinite Chemical class [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[O-][Si](=O)O[Si]([O-])=O CYPPCCJJKNISFK-UHFFFAOYSA-J 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- FFYRIXSGFSWFAQ-UHFFFAOYSA-N 1-dodecylpyridin-1-ium Chemical compound CCCCCCCCCCCC[N+]1=CC=CC=C1 FFYRIXSGFSWFAQ-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- GAMYYCRTACQSBR-UHFFFAOYSA-N 4-azabenzimidazole Chemical compound C1=CC=C2NC=NC2=N1 GAMYYCRTACQSBR-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 1
- 239000002262 Schiff base Substances 0.000 description 1
- 150000004753 Schiff bases Chemical class 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229960004830 cetylpyridinium Drugs 0.000 description 1
- 150000001793 charged compounds Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical class C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 229920003247 engineering thermoplastic Polymers 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZDPRGVZJAFZMPE-UHFFFAOYSA-N n,n,1-tributylpyridin-1-ium-4-amine Chemical compound CCCCN(CCCC)C1=CC=[N+](CCCC)C=C1 ZDPRGVZJAFZMPE-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002905 orthoesters Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical class CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical class CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/20—Mica; Vermiculite
- C04B14/206—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/20—Mica; Vermiculite
- C04B14/206—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate
- C04B14/208—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate delaminated mica or vermiculite platelets
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0087—Ion-exchanging agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
本发明描述的是一种与至少一种杂芳族阳离子进行阳离子交换的新的硅酸盐矿物及其组合物,该阳离子是含一个带正电荷的有机取代的杂原子和/或至少一个带正电荷的杂原子,该杂原子不在芳族环上,该环具有至少一个键序大于1的键。
Description
本申请是申请号为96106007.7、申请日为1996年4月3日、发明名称为“层状矿物及其组合物”的发明专利申请的分案申请。
本发明涉及新的硅酸盐矿物及其包含它们的组合物。特别是本发明涉及与至少一种杂芳族阳离子进行阳离子交换的层状矿物，该阳离子是由一带正电荷的有机取代的杂原子和/或至少一种带正电荷的杂原子组成，该杂原子不在芳族环上，该环具有至少一个键序大子1的键。
由聚碳酸酯、聚酯和聚亚苯基醚组成的组合物可制成例如价值很高的工程热塑塑料。它们的特征在于化学、物理、电学的独特结合。例如，它们具有化学稳定性并且通常又具有高的冲击强度。
人们逐渐关心制备一种聚合物组合物，这种组合物在保持它们的特性的同时，又具有高的热偏差温度。特别是需要具有增加热偏差温度的聚碳酸酯、聚酯和聚亚苯基醚的组合物，这是因为它们通常被用于暴露在高温下的工业应用中。此外，为了改性，例如把填料加到聚合物组合物中。
因此，本发明发现了一种可以被用作为组合物的组份的新的层状矿物和可由低粘度大环低聚物制备的新组合物。
人们已经公开了制备聚合纳米级复合材料的成果。在国际专利申请WO94/11430中，描述了有两种必要组份的纳米级复合材料和这两种必要组份是γ相聚酰胺和层状纤丝状的无机材料，该材料是经季铵阳离子处理的。
制备含层状硅酸盐的复合材料也取得了其它成果。在美国专利4889885中，描述了具有高机械强度和耐热性的复合材料，该材料适用于汽车部件、飞机部件和建筑材料。
本发明与上述的成果具有专利区别，这是因为连同其它原因在内，本发明涉及的新的层状矿物是与至少一种杂芳族阳离子进行阳离子交换的层状矿物，该阳离子是由一带正电荷的有机取代杂原子和/或至少一种带正电荷的杂原子组成，该杂原子不在芳族环上，该环具有至少一个键序大于1的键，以及由它们制成的组合物。另外，本发明涉及由低粘度大环低聚物制备的新的组合物。
第一方面，本发明涉及与选自下述组的至少一种阳离子进行离子交换的新的层状矿物：
(a)含至少一个带正电荷的有机取代杂的原子的杂芳族阳离子，
(b)含至少一个带正电荷的有机杂原子阳离子，该杂原子不在芳族环上，该环具有至少一个键序大于1的键。
第二方面，本发明涉及含至少一种有机体系的组合物，该有机体系是大环聚合物和/或直链聚合物和/或支链聚合物以及前面提到的与(a)和(b)中所述的至少一种阳离子进行阳离子交换的层状矿物。
第三方面，本发明涉及含大环低聚物和层状矿物的组合物，该层状矿物与鎓类化合物进行阳离子交换。
第四方面，本发明涉及在层状矿物的存在下通过聚合大环低聚物制备聚合物的方法。
第五方面，本发明涉及大环低聚物组成的聚合产品。
这里所述的组合物优选的常常包含与在(a)和(b)中所述的阳离子进行阳离子交换的层状矿物，因为这类组合物明显地提高了刚度，它是通过弹性模量的增加来表示的，和/或明显地提高了稳定性，它是通过分子量来表示的。此外，把聚合物和层状矿物混合之后，可将组合物称之为纳米级复合材料，本文中纳米级复合材料被定义为有机体系和分散在其中的层状矿物(粘土)组份的组合物，且层状矿物至少有一维是纳米级大小。
就本发明中所使用的层状矿物而言，除了它们能与上述的阳离子和/或鎓类化合物进行阳离子交换外，对其没有限制。本发明中可使用的这类层状矿物的实例包括例如高岭石类和蒙脱石类。前者可包括高岭石、多水高岭石、地开石和珍珠陶土等。后者包括蒙脱石、囊脱石、贝得石、水辉石和滑石粉等。
使用伊利石的矿物也在本发明的范围之内，它们包括水云母、多硅白云母、钠伊利石、海绿石和绿鳞石等。此外层状矿物包括水羟硅钠石、天然水玻璃、白云母、锌蒙脱石、蛭石、铬岭石以及在本发明中也可以使用的phyrophyllics类、云母类或绿土类；条件是它们能与上述提及的阳离子进行阳离子交换。
此外，分类为层状双氢氧化物的层状矿物以及在层上带有少量或不带电荷的层状矿物也包括在本发明的范围之内，只要该层状矿物与上述的阳离子和鎓类化合物接触时能够膨胀。
但是，优选的层状矿物常常包括那些称之为2∶1的层状硅酸盐矿物，象白云母、蛭石、贝得石、滑石粉、水辉石和蒙脱石，其中，常常优选蒙脱石。
除了上述粘土外，也能使用由它们制成的混合物以及副矿物，例如石英、黑云母、褐铁矿、水云母和长石等。
上述矿物可以人工合成制造。但大多数是天然存在的和从市场上买到的。一般通过许多方法制备，包括硅酸盐的水解和水合、页岩风蚀以及酸性粘土、腐殖土和无机酸对原生硅酸盐的作用。
这里所使用的阳离子定义为例如从杂芳族化合物、杂脂环族化合物、或被取代的或未被取代的杂芳族化合物衍生的带正电荷的化合物，包括单环、双环、三环和多环化合物。
在本发明中对含至少一种带正电荷的有机取代的杂原子的杂芳族化合物阳离子，或含至少一个带正电荷的杂原子的阳离子没有限制，该杂原子不在芳族环上，该环具有至少一个键序大于1的键。本文中大于1的键序被称之为大于单键的任何键，包括部分双键和双键。条件是只要能够与本发明所使用的层状矿物进行阳离子交换。
除了有机取代的杂原子外，本发明中所使用的杂芳族阳离子，也可以在原子上是被取代或未被取代的，并且它们能包含多于1个的杂原子。因此，从C3-14芳族衍生的阳离子包括在本发明的范围之内，包括苯、萘、蒽或菲等，通篇所用“从……衍生”词意指用至少一个杂原子代替至少一个骨架碳原子。
含至少一个带正电荷的原子(该原子具有至少一个键序大于1的键)的阳离子包括例如：亚胺(席夫碱类)和由其衍生的inium阳离子，例如包含阳离子的吖、噻、磷杂和噁。因此，含至少一个带正电荷的有机取代的杂原子，和含至少一个带正电荷的杂原子的阳离子的(该杂原子不在芳族环上，该环具有至少一个键序大于1的键)杂芳族阳离子，在本文中称之为inium型阳离子，这是因为它们的性质是三角平面形，与性质是四面体的鎓型阳离子有区别。
对本发明中所使用的杂原子没有限制，它们常常选自N、P、O和S，特别是N。
本发明所使用的含至少一种带正电荷的有机取代的杂原子的通常优选的杂芳族阳离子包括例如吡咯、咪唑、噻唑、噁唑、吡啶、嘧啶、喹啉、异喹啉、吲哚、嘌呤、苯并咪唑、苯并三唑、苯并噁唑、吡嗪、喹喔啉、吖啶、吩嗪、咪唑并吡啶和联吡啶等的N-有机取代的盐。
在有机取代的杂原子上的有机取代基常常是C1-25脂肪族基、脂环族基或芳族基，优选C1-18基团，通常优选的阳离子是N-C10-18吡啶鎓阳离子。举例说明包括例如N-十二烷基吡啶鎓阳离子、N、N＇-双十四烷基苯并咪唑鎓盐阳离子和4-(二烷基氨基)-N-烷基吡啶鎓阳离子如4-(二丁基氨基)-N-丁基吡啶鎓阳离子等。
含至少一个杂原子(该原子具有一个键序大于1的键)，组成的离子常常包括例如具有下式的离子其中R1、R2、R3和R4分别独立地表示氢、C1-20烷基、芳香基、取代的杂原子或
和R5是氢或C1-10烷基，或至少R1和R2、R3和R4、R1和R3以及R2和R4之一与连接它们的原子一起能形成4-10节的单环或双环。本发明常常使用的优选阳离子包括胍盐和脒盐；因此，胍盐型和脒盐型离子，举例说明包括六烷基胍盐如N，N，N＇，N＇，N″，N″-六丁基胍盐离子以及在美国专利5132423中所述的胍盐离子，这里引入本文作为参考。
含至少一个杂原子(该原子具有一个键序大于1的键)的其它阳离子包括例如从C1-14杂脂环族链烯衍生的阳离子例如二环十二碳烯、二环壬烯、二环十一碳烯、三环十四碳烯等以及由二环和螺二环化合物衍生的阳离子。
当用大环低聚物制备组合物时，可以使用与鎓类化合物进行阳离子交换的层状矿物。这种鎓类化合物包括铵、磷鎓和锍型盐例如有下式的盐其中每个R6独立地表示氢、C1-20烷基或取代或非取代的芳香基或两个R6与连接它们的原子一起能形成4-12节的单环或双环和X代表N、P或S以及Y代表阴离子常常是Cl或Br。至少一种R6包含反应的官能团也属于本发明的范围之内，例如不饱和烃基、包含羧基的羧酸衍生物，包含氮的衍生物例如胺等以及环氧基和原酸酯基等。
可以使用的其它鎓类阳离子包括例如吡咯烷、哌啶、哌嗪和吗啉的盐以及从二环十二烷、二环壬烷、二环十一烷和三环十四烷等衍生的杂阳离子。
包含与至少一种杂芳族阳离子进行阳离子交换的层状矿物(该阳离子含一个带正电荷的有机取代的杂原子和/或至少一个带正电荷的杂原子，该杂原子不在芳族环上，该环具有至少一个键序大于1的键)的本发明组合物也包含有机体系，该有机体系被定义为能够与层状矿物结合的任何聚合物或低聚物。这种有机体系常常包括大环低聚物以及直链和支链的聚合物。对本发明使用的有机体系是没有限制的，它们是在工业上已知和按传统法生产。它们常常包括由聚碳酸酯、聚酯、聚亚苯基醚、聚酰亚胺、烯烃、聚醚酰亚胺、酰胺、聚亚芳基硫化物、聚砜、聚醚酮、丙烯腈丁二烯苯乙烯共聚物、聚苯乙烯组成的直链和支链的聚合物和由它们制成的混合物组合物或共聚物。
另外，本发明使用的有机体系常常可包括大环低聚物，它们选自大环聚碳酸酯、聚酯、聚酰亚胺、聚醚酰亚胺、聚亚苯基醚聚碳酸酯共低聚物、聚醚酰亚胺聚碳酸酯共低聚物和由它们制备的混合物，组合物和共低聚物。此外，常常优选包括聚酯、聚碳酸酯或聚亚苯基醚的有机体系。这类有机体系典型地包括例如聚酯如聚(1，2-对苯二酸-乙二醇)、聚(1，4-对苯二酸-丁二醇)、聚(1，2-亚乙基2，6-萘二羧酸酯)等和它们的共聚物，聚碳酸酯如双酚A聚碳酸酯等和聚亚苯基醚，包括含2，6-二甲基-1，4-亚苯基醚单元或2，3，6-三甲基-1，4-亚苯基醚单元的高聚物以及它们的共聚物。这里应注意的是所有的有机体系通过本领域已知的方法，包括本领域通用的酸、酐和原酸酯型官能化作用可以使其具有官能化的或非官能化的作用。
本发明的层状矿物一般具有带负电荷层，该层中嵌有无机碱和/或碱土阳离子。结果在带电层和阳离子之间有强静电作用，致使层状矿物常常难以分散在非极性的有机体系中。在本发明中，层状矿物的制备例如是通过把它们置于阳离子作用下，该阳离子是由带正电荷的有机取代的杂原子和/或至少一个带正电荷的杂原子组成的，该杂原子不在芳族环上，该环具有至少一个键序大于1的键，通常分散在由水和包括醇类和酮类水溶的有机溶剂的均匀分散体中。
包含层状矿物的组合物例如是通过在聚合作用之前，将层状矿物与聚合物熔融混合/挤压或在低粘度大环低聚物混合层状矿物制备的，其中低粘度定义为小于2000厘泊。当层状矿物在低粘度大环低聚物中混合时，通常通过加入适当的催化剂如包含聚合催化剂的锌、钛或锡后形成聚合物。此外，本发明中包含层状矿物的组合物常常含不超过约70％(重量)，优选不超过约40％(重量)，更优选不超过20％(重量)的层状矿物(基于组合物的总重量)。
下面的实施例进一步说明和便于理解本发明。所得到的产品可以通过常规技术例如质子和碳13核磁共振分光镜和GPC分析得到证实。
实施例1：
把500毫升水、200毫升甲醇和11克钠蒙脱石(10％水119meq/100克)加入混合机中，加入部分钠蒙脱石是为了产生均匀的分散液。强力搅拌均匀的分散液，并同时向分散液中加入由4.85克(26.2毫摩尔)胺、2.64克37％盐酸溶液、25毫升水和25毫升甲醇组成的十二烷基氯化铵溶液。产生白色沉淀并通过过滤回收，接着用水冲洗。将所产生的经冲洗的沉淀物重新分散在700毫升水中。通过过滤和真空冷冻干燥重新回收得到的经冲洗的沉淀物(具有与铵阳离子进行阳离子交换的蒙脱石)。
实施例2：
在实施例2中，除了使用N-十六烷基吡啶鎓氯化物代替十二烷基氯化铵外用与实施例1中所述的相同方法制备层状矿物。回收与含带正电荷的有机取代杂的原子的阳离子进行阳离子交换的蒙脱石。
实施例3和4：
通过下列步骤制备大环低聚物组合物，将两个混合烧瓶都装入4.8克大环低聚物(乙二醇和丁二醇5∶95混合的环对苯二酸酯共低聚物，基于共低聚物的总重量)，一个(实施例3)具有实施例1中所述经过阳离子交换的蒙脱石(0.2克)，另一个(实施例4)具有实施例2中所述经过阳离子交换的蒙脱石(0.2克)。所得到的混合物用氮气冲洗，然后在0.05毫米汞柱的真空中在110℃干燥0.5小时。然后把烧瓶放在油浴中在真空下保持在190℃下熔化混合物。生成的低粘度半透明的液体在190℃下搅拌15分钟生成大环低聚物熔融组合物。接着冷却，将层状矿物的固态组合物物均匀地分散在其中。
实施例5：
将聚合催化剂二辛基锡dioctoxide(62μl，0.109毫摩尔)在190℃下加入到在实施例4中制备的大环低聚物熔融组合物中，聚合低聚物。在大约15秒钟内熔融体变为粘稠体，在大约2分钟内形成含具有进行阳离子交换的蒙脱石的固体聚合物组合物。通过凝胶渗透色谱法测定得到的聚合组合物的重均分子量(Mw)为103000。
实施例6：
除了使用环状对苯二酸丁二醇均低聚物代替由乙二醇和丁二醇的5∶95混合物组成的环对苯二酸酯共低聚物，使用2，2-二乙基-1，3-丙烯二氧钛酸二辛酯作为聚合催化剂代替二辛基锡dioctoxide外，按照与实施例5中所述的相同方法制备组合物。得到的聚合组合物的重均分子量为145000。
实施例7：
在本实施例中，除了使用实施例2中制备的蒙脱石代替实施例1中制备的蒙脱石和使用钛酸四辛酯聚合催化剂代替2，2-二乙基-1，3-丙烯二氧钛酸二辛酯外，按照与实施例6中所述的相同方法制备组合物。重均分子量为139000。
实施例8：
将聚亚苯基醚(包含2，6-二甲基-1，4-亚苯基醚单元的均聚物)(20份)和实施例2中制备的蒙脱石(1份)完全混合的干混合物，用双螺旋挤压机，在295℃下、喂料速度约为40克/分钟、400转/分钟的操作条件下挤压。使挤出物成粒，在真空烘箱里在90℃下干燥，在310℃下，用15吨注射模型成形机将测试样品注射模制。组合物在室温下具有的剪切模量为13.9×109达因/厘米2，比使用未改性的蒙脱石生产的组合物的模量增加29％。使用鎓盐改性蒙脱石生产的组合物的模量只提高15％。
实施例9：
在本实施例中，除了使用聚(1，4-对苯二酸丁二醇)粉代替聚亚苯基醚和挤压机温度为约260℃外，按照与实施例8中所述的相同方法制备组合物。将所得到的挤压物成粒、在空气循环烘箱中在120℃下干燥4小时，并在30吨注射模成形机上模制。组合物的重均分子量为97.2×103，而使用十二烷基铵阳离子改性的层状矿物制备的组合物的重均分子量为84.6×103。
下表中提供的数据表明：本发明具有意想不到的和优良的特性。所有数值是按照与实施例中所述的相同方法作出的。
表I序号 有机体系a 层状矿物b 阳离子c T℃ 剪切模量d
1 PBT 无 无 60 4.59
150 0.86
200 0.51
2 PBT M Na+ 60 5.74
1.50 1.13
200 0.666
3 PBT m Na+ 60 7.88
200 0.87
4 c-PBT M＇ DDA 60 6.80
150 1.79
200 0.82
5 PBT M DDA 60 9.04
6 PBT m DDA 60 15.6
7 PBT M DDA 200 0.88
8 PBT m DDA 200 1.38
9 PBT M HDA 80 9.8
200 0.97
10 PBT M HDP 60 8.27
200 0.85
11 PPE 无 无 25 10.2
12 PPE M Na+ 25 10.8
13 PPE M HDA 25 12.4
14 PPE M HDP 25 13.9aPBT＝聚(1，4-对苯二酸丁二醇)；c—PBT＝这里是大环对苯二酸丁二醇低聚物的开环聚合形成的聚合物；PPE＝聚亚苯基醚。bM＝蒙脱石，有机体系总重的5％。m＝蒙脱石，有机体系总重的15％；M＇＝有机体系总重的4％。cNa+＝对照物；DDA＝十二烷基铵阳离子；HDA＝十六烷基铵阳离子；HDP＝N-十六烷基吡啶鎓阳离子。d(109达因/厘米2)。
表II序号 有机体系e 层状矿物 阳离子g MWb1 PPE 无 无 74.02 PPE M Na+ 72.93 PPE M DDA 61.94 PPE M TDA 67.65 PPE M HDA 62.26 PPE M TDP 65.27 PPE M HDP 67.08 PBT 无 无 104.09 PBT M Na+ 94.910 PBT m Na+ 92.911 PBT M DDA 84.612 PBT n DDA 74.313 PBT M HDP 97.2e定义同表1。f定义同表1。g定义同表1和TDP＝N-十四烷基吡啶鎓；Na+＝对照物。h重均分子量×10-3。
Claims (12)
1.一种组合物包括：
(a)大环低聚物，
(b)与具有下式的阳离子进行阳离子交换的层状矿物，
其中每个R6独立地是氢、C1-20烷基或取代或未取代的芳香基或两个R6与连接它们的原子一起能形成4-12节的单环或双环和X代表N、P或S以及Y代表阴离子。
2.按照权利要求1的组合物，其中所说的阴离子是Cl或Br。
3.按照权利要求1的组合物，其中所说的大环低聚物是选自大环聚碳酸酯、聚酯、聚酰亚胺、聚醚酰亚胺、聚亚苯基醚-聚碳酸酯低聚物和由它们制备的混合物，组合物和共低聚物。
4.按照权利要求3的组合物，其中所说的聚酯是聚(1，2-对苯二酸乙二醇)、聚(1，4-对苯二酸丁二醇)、聚(1，2-亚乙基2，6-萘联羧酸酯)和其共聚物。
5.按照权利要求3的组合物，其中所说的聚亚苯基醚包括2，6-二甲基-1，4-亚苯基醚单元、2，3，6-三甲基-1，4-亚苯基醚单元的均聚物和它们的共聚物。
6.按照权利要求3的组合物，其中所说的聚碳酸酯是双酚A聚碳酸酯。
7.按照权利要求1的组合物，其中所说的层状矿物是高岭石类、蒙脱石类或伊利石类。
8.按照权利要求7的组合物，其中所说高岭石类包括高岭石、多水高岭土、地开石或珍珠陶土。
9.按照权利要求7的组合物，其中所说的的蒙脱石类包括蒙脱石、囊脱石、贝得石、水辉石或滑石粉。
10.按照权利要求7的组合物，其中所说的伊利石类包括水母、多硅白云母、钠伊利石、海绿石或绿鳞石。
11.按照权利要求1的组合物，其中所说的层状矿物为水羟硅钠石、天然水玻璃、白云母、锌蒙脱石、蛭石、铬岭石、phrophyllics、云母或绿土。
12.一种制造含层状矿物和聚合的有机体系的组合物的方法，包括把聚合催化剂加入下面混合物中的步骤：
(a)大环低聚物；
(b)层状矿物。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US416112 | 1995-04-03 | ||
| US416,112 | 1995-04-03 | ||
| US08/416,112 US5530052A (en) | 1995-04-03 | 1995-04-03 | Layered minerals and compositions comprising the same |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96106007A Division CN1125115C (zh) | 1995-04-03 | 1996-04-03 | 层状矿物及其组合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1329108A true CN1329108A (zh) | 2002-01-02 |
| CN1161420C CN1161420C (zh) | 2004-08-11 |
Family
ID=23648583
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96106007A Expired - Fee Related CN1125115C (zh) | 1995-04-03 | 1996-04-03 | 层状矿物及其组合物 |
| CNB011192364A Expired - Fee Related CN1161420C (zh) | 1995-04-03 | 1996-04-03 | 层状矿物及其组合物 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96106007A Expired - Fee Related CN1125115C (zh) | 1995-04-03 | 1996-04-03 | 层状矿物及其组合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US5530052A (zh) |
| EP (1) | EP0736490B1 (zh) |
| JP (1) | JP4100726B2 (zh) |
| KR (1) | KR100354308B1 (zh) |
| CN (2) | CN1125115C (zh) |
| DE (1) | DE69628496T2 (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1980990B (zh) * | 2004-03-29 | 2011-03-02 | 株式会社普利司通 | 纳米复合材料及其生产方法 |
| CN115073049A (zh) * | 2022-05-23 | 2022-09-20 | 唐山冀东水泥外加剂有限责任公司 | 一种聚羧酸减水剂及其制备方法及使用方法 |
Families Citing this family (144)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5932634A (en) * | 1995-09-26 | 1999-08-03 | Showa Denko K.K. | Method of producing resin composition containing inorganic filler |
| US6162857A (en) | 1997-07-21 | 2000-12-19 | Eastman Chemical Company | Process for making polyester/platelet particle compositions displaying improved dispersion |
| US5773502A (en) * | 1997-10-14 | 1998-06-30 | General Electric Company | Fire retardant blends |
| US6486252B1 (en) | 1997-12-22 | 2002-11-26 | Eastman Chemical Company | Nanocomposites for high barrier applications |
| WO1999043747A1 (en) * | 1998-02-27 | 1999-09-02 | General Electric Company | Flame retardant polymer blends |
| EP1155079B1 (en) * | 1998-12-07 | 2003-08-20 | University of South Carolina Research Foundation | Polymer/clay nanocomposite and process for making same |
| AU1836600A (en) * | 1998-12-07 | 2000-06-26 | Eastman Chemical Company | A polymer/clay nanocomposite having improved gas barrier comprising a clay material with a mixture of two or more organic cations and a process for preparing same |
| AU758538B2 (en) | 1998-12-07 | 2003-03-27 | University Of South Carolina Research Foundation | A colorant composition, a polymer nanocomposite comprising the colorant composition and articles produced therefrom |
| JP2002531666A (ja) * | 1998-12-07 | 2002-09-24 | イーストマン ケミカル カンパニー | オリゴマー樹脂前駆体を用いて展開された高ｉ．ｖ．ポリマーナノ複合体を製造する方法並びにそれから製造された物品 |
| US6552114B2 (en) | 1998-12-07 | 2003-04-22 | University Of South Carolina Research Foundation | Process for preparing a high barrier amorphous polyamide-clay nanocomposite |
| WO2000034375A1 (en) | 1998-12-07 | 2000-06-15 | Eastman Chemical Company | A polymer/clay nanocomposite comprising a clay mixture and a process for making same |
| JP2002531640A (ja) * | 1998-12-07 | 2002-09-24 | イーストマン ケミカル カンパニー | ２種又はそれ以上の有機カチオンの混合物を有するクレイ物質を含む、ガス遮断性の改良されたポリマー／クレイナノ複合材料及びその製造方法 |
| US6548587B1 (en) | 1998-12-07 | 2003-04-15 | University Of South Carolina Research Foundation | Polyamide composition comprising a layered clay material modified with an alkoxylated onium compound |
| US6417262B1 (en) | 1998-12-07 | 2002-07-09 | Eastman Chemical Company | High barrier amorphous polyamide-clay nanocomposite and a process for preparing same |
| KR20010101734A (ko) * | 1999-01-28 | 2001-11-14 | 베르너 훽스트, 지크프리트 포트호프 | 멜라민-개질 필로실리케이트 |
| US6350804B2 (en) | 1999-04-14 | 2002-02-26 | General Electric Co. | Compositions with enhanced ductility |
| EP1200254A1 (en) * | 1999-06-17 | 2002-05-02 | Triton Systems Inc. | High performance nanocomposites |
| US6777479B1 (en) | 1999-08-10 | 2004-08-17 | Eastman Chemical Company | Polyamide nanocomposites with oxygen scavenging capability |
| US6610772B1 (en) | 1999-08-10 | 2003-08-26 | Eastman Chemical Company | Platelet particle polymer composite with oxygen scavenging organic cations |
| US6423768B1 (en) | 1999-09-07 | 2002-07-23 | General Electric Company | Polymer-organoclay composite compositions, method for making and articles therefrom |
| US20040192822A1 (en) * | 1999-11-11 | 2004-09-30 | Junji Shirai | Thin injection molded articles |
| US6579926B2 (en) | 1999-11-15 | 2003-06-17 | General Electric Company | Fire retardant polyphenylene ether-organoclay composition and method of making same |
| US6831123B1 (en) * | 1999-11-16 | 2004-12-14 | General Electric Company | Ionomeric polyester compositions containing organoclays, and method |
| US6486253B1 (en) | 1999-12-01 | 2002-11-26 | University Of South Carolina Research Foundation | Polymer/clay nanocomposite having improved gas barrier comprising a clay material with a mixture of two or more organic cations and a process for preparing same |
| US6552113B2 (en) | 1999-12-01 | 2003-04-22 | University Of South Carolina Research Foundation | Polymer-clay nanocomposite comprising an amorphous oligomer |
| US7084199B1 (en) * | 1999-12-29 | 2006-08-01 | The Dow Chemical Company | Thermoplastic olefin nanocomposite |
| US6960626B2 (en) * | 2000-01-21 | 2005-11-01 | Cyclics Corporation | Intimate physical mixtures containing macrocyclic polyester oligomer and filler |
| US6906147B2 (en) * | 2002-03-20 | 2005-06-14 | Cyclics Corporation | Catalytic systems |
| US7256241B2 (en) * | 2000-01-21 | 2007-08-14 | Cyclics Corporation | Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters |
| US20050282952A1 (en) * | 2000-01-21 | 2005-12-22 | Cyclics Corporation | Graphite-polyester composites made from macrocyclic polyester oligomers |
| US7151143B2 (en) * | 2000-01-21 | 2006-12-19 | Cyclics Corporation | Blends containing macrocyclic polyester oligomer and high molecular weight polymer |
| US6369157B1 (en) | 2000-01-21 | 2002-04-09 | Cyclics Corporation | Blend material including macrocyclic polyester oligomers and processes for polymerizing the same |
| US6420047B2 (en) * | 2000-01-21 | 2002-07-16 | Cyclics Corporation | Macrocyclic polyester oligomers and processes for polymerizing the same |
| CA2401052A1 (en) * | 2000-03-23 | 2001-09-27 | Anant Singh | High-temperature polymer/inorganic nanocomposites |
| EP1307506A2 (en) | 2000-05-30 | 2003-05-07 | University of South Carolina Research Foundation | A polymer nanocomposite comprising a matrix polymer and a layered clay material having an improved level of extractable material |
| US6737464B1 (en) | 2000-05-30 | 2004-05-18 | University Of South Carolina Research Foundation | Polymer nanocomposite comprising a matrix polymer and a layered clay material having a low quartz content |
| WO2002018476A2 (en) | 2000-09-01 | 2002-03-07 | Cyclics Corporation | Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters |
| US7750109B2 (en) | 2000-09-01 | 2010-07-06 | Cyclics Corporation | Use of a residual oligomer recyclate in the production of macrocyclic polyester oligomer |
| US7767781B2 (en) | 2000-09-01 | 2010-08-03 | Cyclics Corporation | Preparation of low-acid polyalkylene terephthalate and preparation of macrocyclic polyester oligomer therefrom |
| US6436548B1 (en) | 2000-09-12 | 2002-08-20 | Cyclics Corporation | Species modification in macrocyclic polyester oligomers, and compositions prepared thereby |
| US6815491B2 (en) | 2000-12-28 | 2004-11-09 | General Electric | Reinforced thermoplastic composition and articles derived therefrom |
| US6420048B1 (en) | 2001-06-05 | 2002-07-16 | Cyclics Corporation | High molecular weight copolyesters from macrocyclic oligoesters and cyclic esters |
| ES2250687T3 (es) | 2001-06-27 | 2006-04-16 | Cyclics Corporation | Aislamiento, formulacion, y moldeo de oligoesteres macrociclicos. |
| US7304123B2 (en) * | 2001-06-27 | 2007-12-04 | Cyclics Corporation | Processes for shaping macrocyclic oligoesters |
| US6436549B1 (en) | 2001-07-16 | 2002-08-20 | Cyclics Corporation | Block copolymers from macrocyclic oligoesters and dihydroxyl-functionalized polymers |
| US6956084B2 (en) * | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
| US6787632B2 (en) | 2001-10-09 | 2004-09-07 | Cyclics Corporation | Organo-titanate catalysts for preparing pure macrocyclic oligoesters |
| US6831138B2 (en) | 2002-01-07 | 2004-12-14 | Cyclics Corporation | Polymer-containing organo-metal catalysts |
| EP1359202A1 (de) * | 2002-05-03 | 2003-11-05 | Sika Schweiz AG | Hitze-härtbare Epoxydharzzusammensetzung |
| KR100981899B1 (ko) | 2002-09-11 | 2010-09-13 | 데이진 가부시키가이샤 | 열가소성 필름, 열가소성 수지 조성물 및 층상 규산염 |
| CN100441636C (zh) * | 2002-09-20 | 2008-12-10 | 通用电气公司 | 引擎盖下组件 |
| US20040106713A1 (en) * | 2002-12-03 | 2004-06-03 | Avakian Roger W. | Use of additives in compounds containing macrocyclic poly(alkylene dicarboxylate) oligomers |
| EP1431325A1 (de) * | 2002-12-17 | 2004-06-23 | Sika Technology AG | Hitze-härtbare Epoxidharzzusammensetzung mit verbesserter Tieftemperatur-Schlagzähigkeit |
| AU2003301053A1 (en) * | 2002-12-18 | 2004-07-22 | Bridgestone Corporation | Method for clay exfoliation, compositions therefore, and modified rubber contaiing same |
| WO2004058854A1 (en) * | 2002-12-20 | 2004-07-15 | Cyclics Corporation | Purification of macrocyclic oligoesters |
| AU2003300010A1 (en) * | 2002-12-20 | 2004-07-22 | Dow Global Technologies Inc. | Polymerized macrocyclic oligomer nanocomposite compositions |
| US7106924B2 (en) * | 2002-12-24 | 2006-09-12 | Sumitomo Electric Industries, Ltd. | Optical switching device and optical transmission system |
| US20060102871A1 (en) * | 2003-04-08 | 2006-05-18 | Xingwu Wang | Novel composition |
| KR100543217B1 (ko) * | 2003-06-20 | 2006-01-20 | 한국과학기술연구원 | 폴리에스터/클레이 나노 복합 재료 및 그 제조방법 |
| EP1498441A1 (de) * | 2003-07-16 | 2005-01-19 | Sika Technology AG | Hitzehärtende Zusammensetzungen mit Tieftemperatur-Schlagzähigkeitsmodifikatoren |
| US20050029194A1 (en) * | 2003-08-07 | 2005-02-10 | Hall David Bruce | Method for removal of guanidine compound from aqueous media |
| WO2005030850A1 (en) * | 2003-10-01 | 2005-04-07 | Universidade Estadual De Campinas - Unicamp | Process to obtain an intercalated or exfoliated polyester with clay hybrid nanocomposite material |
| EP1694771B1 (en) * | 2003-12-19 | 2010-03-10 | Cyclics Corporation | Processes for dispersing an impact modifier in a macrocyclic polyester oligomer |
| US7148282B2 (en) * | 2003-12-19 | 2006-12-12 | Cornell Research Foundations, Inc. | Composite of high melting polymer and nanoclay with enhanced properties |
| US7022765B2 (en) * | 2004-01-09 | 2006-04-04 | General Electric | Method for the preparation of a poly(arylene ether)-polyolefin composition, and composition prepared thereby |
| US7205370B2 (en) | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
| US20050159526A1 (en) * | 2004-01-15 | 2005-07-21 | Bernard Linda G. | Polymamide nanocomposites with oxygen scavenging capability |
| US8063142B2 (en) | 2004-03-02 | 2011-11-22 | Bridgestone Corporation | Method of making nano-particles of selected size distribution |
| US7718737B2 (en) | 2004-03-02 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing functionalized polymer nanoparticles |
| US20050228074A1 (en) * | 2004-04-05 | 2005-10-13 | Bridgestone Corporation | Amphiphilic polymer micelles and use thereof |
| US7491263B2 (en) * | 2004-04-05 | 2009-02-17 | Technology Innovation, Llc | Storage assembly |
| US20050288420A1 (en) * | 2004-06-18 | 2005-12-29 | Paquette Michael S | Method for preparing reactive formulations of macrocyclic oligomers |
| EP1763558A1 (en) * | 2004-06-18 | 2007-03-21 | Dow Gloval Technologies Inc. | Method for preparing nanocomposites from fillers and macrocyclic oligomers |
| JP2008503614A (ja) * | 2004-06-18 | 2008-02-07 | ダウ グローバル テクノロジーズ インコーポレイティド | 大環状オリゴマーのポリマー中の複合体のための触媒含有クレイ材料 |
| EP1773927A1 (en) * | 2004-06-18 | 2007-04-18 | Dow Gloval Technologies Inc. | Polymerizable macrocyclic oligomer masterbatches containing dispersed fillers |
| US20050282956A1 (en) * | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
| US7998554B2 (en) * | 2004-07-06 | 2011-08-16 | Bridgestone Corporation | Hydrophobic surfaces with nanoparticles |
| CN101014666A (zh) * | 2004-08-30 | 2007-08-08 | 普立万公司 | 具有提高的加工性能的强化热塑性组合物 |
| EP1819498A1 (en) * | 2004-10-27 | 2007-08-22 | Arkema France | Process for the production of (co) polyamide nanocomposite materials |
| EP1679341A1 (de) * | 2005-01-11 | 2006-07-12 | Sika Technology AG | Schlagzähe Zusammensetzung |
| US7572855B2 (en) * | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
| US7579398B2 (en) | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
| US7659342B2 (en) * | 2005-02-03 | 2010-02-09 | Bridgestone Corporation | Polymer nano-particle with polar core and method for manufacturing same |
| WO2006098909A1 (en) * | 2005-03-10 | 2006-09-21 | Cyclics Corporation | Methods for preparing polyester-based nanocomposites |
| DE102005025720A1 (de) * | 2005-06-04 | 2006-12-07 | Solvay Infra Bad Hönningen GmbH | Nanopartikelhaltige makrocyclische Oligoester |
| EP1741734A1 (de) * | 2005-07-05 | 2007-01-10 | Sika Technology AG | Tieftemperaturschlagzähe hitze-härtbare Epoxidharzzusammensetzung mit Epoxidfestharzen |
| DE102005048769A1 (de) * | 2005-10-10 | 2007-05-03 | Epc Anlagenbau Rudisleben Gmbh | Verfahren zur Herstellung von Polyester mit verbesserten Herstellungs- und Gebrauchseigenschaften zur Anwendung in der Verpackungsmittelindustrie |
| US7538159B2 (en) * | 2005-12-16 | 2009-05-26 | Bridgestone Corporation | Nanoparticles with controlled architecture and method thereof |
| US9061900B2 (en) | 2005-12-16 | 2015-06-23 | Bridgestone Corporation | Combined use of liquid polymer and polymeric nanoparticles for rubber applications |
| US7884160B2 (en) | 2005-12-19 | 2011-02-08 | Bridgestone Corporation | Non-spherical nanoparticles made from living triblock polymer chains |
| US8288473B2 (en) | 2005-12-19 | 2012-10-16 | Bridgestone Corporation | Disk-like nanoparticles |
| US7560510B2 (en) | 2005-12-20 | 2009-07-14 | Bridgestone Corporation | Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties |
| US8697775B2 (en) | 2005-12-20 | 2014-04-15 | Bridgestone Corporation | Vulcanizable nanoparticles having a core with a high glass transition temperature |
| US8877250B2 (en) | 2005-12-20 | 2014-11-04 | Bridgestone Corporation | Hollow nano-particles and method thereof |
| US7601772B2 (en) * | 2005-12-20 | 2009-10-13 | Bridgestone Corporation | Nano-composite and method thereof |
| JP5129448B2 (ja) * | 2005-12-28 | 2013-01-30 | 富士フイルム株式会社 | 有機化層状ケイ酸塩及びその製造方法、並びに樹脂組成物 |
| ES2332474T3 (es) * | 2006-02-13 | 2010-02-05 | Council Of Scientific And Industrial Research | Composiciones de nanocompuesto polimerico de filosilicato exfoliado y un proceso para la preparacion de las mismas. |
| EP1818336A1 (en) * | 2006-02-13 | 2007-08-15 | Council of Scientific and Industrial Research | 2,2-bis-(4-hydroxyphenyl)-alkyl onium salt and a process for the preparation thereof |
| US7935184B2 (en) * | 2006-06-19 | 2011-05-03 | Bridgestone Corporation | Method of preparing imidazolium surfactants |
| US9161440B2 (en) * | 2006-06-26 | 2015-10-13 | Sabic Global Technologies B.V. | Articles comprising a polyimide solvent cast film having a low coefficient of thermal expansion and method of manufacture thereof |
| US7915332B2 (en) * | 2006-06-26 | 2011-03-29 | Sabic Innovative Plastics Ip B.V. | Compositions and methods for polymer composites |
| US7928154B2 (en) | 2006-06-26 | 2011-04-19 | Sabic Innovative Plastics Ip B.V. | Methods of preparing polymer-organoclay composites and articles derived therefrom |
| US8568867B2 (en) * | 2006-06-26 | 2013-10-29 | Sabic Innovative Plastics Ip B.V. | Polyimide solvent cast films having a low coefficient of thermal expansion and method of manufacture thereof |
| US7928155B2 (en) | 2006-06-26 | 2011-04-19 | Sabic Innovative Plastics Ip B.V. | Compositions and methods for polymer composites |
| US8545975B2 (en) * | 2006-06-26 | 2013-10-01 | Sabic Innovative Plastics Ip B.V. | Articles comprising a polyimide solvent cast film having a low coefficient of thermal expansion and method of manufacture thereof |
| EP1876194A1 (de) * | 2006-06-30 | 2008-01-09 | Sika Technology AG | Hitzehärtende Zusammensetzung geeignet zum Verkleben von beschichteten Substraten |
| EP3495322A1 (en) | 2006-07-28 | 2019-06-12 | Bridgestone Corporation | Polymeric core-shell nanoparticles with interphase region |
| WO2008021035A1 (en) * | 2006-08-10 | 2008-02-21 | Dow Global Technologies, Inc. | Polymers of macrocyclic oligomers containing highly expanded graphite |
| CN101528828A (zh) * | 2006-08-10 | 2009-09-09 | 陶氏环球技术公司 | 填充有高倍膨胀石墨的聚合物 |
| EP1916285A1 (de) * | 2006-10-24 | 2008-04-30 | Sika Technology AG | Derivatisiertes Epoxid-Festharz und dessen Verwendungen |
| EP1916272A1 (de) | 2006-10-24 | 2008-04-30 | Sika Technology AG | Hitzehärtende Epoxidharzzusammensetzung enthaltend ein blockiertes und ein epoxidterminiertes Polyurethanprepolymer |
| EP1916269A1 (de) * | 2006-10-24 | 2008-04-30 | Sika Technology AG | Blockierte Polyurethanprepolymere und hitzehärtende Epoxidharzzusammensetzungen |
| EP1916270A1 (de) | 2006-10-24 | 2008-04-30 | Sika Technology AG | Hitzehärtende Epoxidharzzusammensetzung mit blockiertem Polyurethanprepolymer |
| US7597959B2 (en) * | 2006-12-19 | 2009-10-06 | Bridgestone Corporation | Core-shell fluorescent nanoparticles |
| US7649049B2 (en) * | 2006-12-20 | 2010-01-19 | Bridgestone Corporation | Rubber composition containing a polymer nanoparticle |
| EP1935955A1 (de) | 2006-12-21 | 2008-06-25 | Sika Technology AG | Bördelfalzverklebung |
| EP1972646A1 (de) * | 2007-03-20 | 2008-09-24 | Sika Technology AG | Epoxidgruppen terminierte Polymer, deren Zusammensetzungen und deren Verwendung als Schlagzähigkeitsmodifikatoren |
| US7829624B2 (en) | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
| US20090018264A1 (en) * | 2007-07-12 | 2009-01-15 | Canon Kabushiki Kaisha | Resin composition |
| EP2017294A1 (de) | 2007-07-16 | 2009-01-21 | Sika Technology AG | Hitzehärtender Schaum |
| EP2060592B1 (de) * | 2007-11-14 | 2010-01-27 | Sika Technology AG | Hitzehärtende Epoxidharzzusammensetzung enthaltend nichtaromatische Harnstoffe als Beschleuniger |
| ATE484547T1 (de) * | 2008-01-30 | 2010-10-15 | Sika Technology Ag | Auswaschbeständige hitzehärtende epoxidharzklebstoffe |
| EP2110397A1 (de) | 2008-04-16 | 2009-10-21 | Sika Technology AG | Auf amphiphilen Block-Copolymer basierendes Polyurethan-Polymer und dessen Verwendung als Schlagzähigkeitsmodifikator |
| JP5687187B2 (ja) | 2008-04-30 | 2015-03-18 | シーカ・テクノロジー・アーゲー | エポキシ樹脂組成物のための活性剤 |
| EP2113525A1 (de) | 2008-04-30 | 2009-11-04 | Sika Technology AG | Aktivator für Epoxidharzzusammensetzungen |
| EP2128182A1 (de) * | 2008-05-28 | 2009-12-02 | Sika Technology AG | Hitzehärtende Epoxidharzzusammensetzung enthaltend einen Beschleuniger mit Heteroatomen |
| DE502008000478D1 (de) | 2008-07-17 | 2010-05-06 | Sika Technology Ag | Haftvermittlerverbindungen für beölten Stahl |
| EP2145924A1 (de) * | 2008-07-18 | 2010-01-20 | Sika Technology AG | Auf amphiphilen Block-Copolymer basierende Reaktionsprodukte und deren Verwendung als Schlagzähigkeitsmodifikator |
| EP2161274B1 (de) | 2008-08-27 | 2010-05-19 | Sika Technology AG | Silan-/Harnstoff-Verbindung als hitzeaktivierbarer Härter für Epoxidharzzusammensetzungen |
| US20100056693A1 (en) * | 2008-09-03 | 2010-03-04 | Sreepadaraj Karanam | Process for Synthesis of Imidazolium and Benzimidazolium Surfactants and their use in Clays and Nanocomposites |
| RU2560722C2 (ru) | 2008-12-31 | 2015-08-20 | Бриджстоун Корпорейшн | Наночастицы типа "ядро-оболочка", способ их синтеза и их применение |
| US9062144B2 (en) | 2009-04-03 | 2015-06-23 | Bridgestone Corporation | Hairy polymeric nanoparticles with first and second shell block polymer arms |
| US20110172364A1 (en) * | 2009-12-29 | 2011-07-14 | Chen Yaohong | Charged Nanoparticles And Method Of Controlling Charge |
| US9115222B2 (en) | 2009-12-29 | 2015-08-25 | Bridgestone Corporation | Well defined, highly crosslinked nanoparticles and method for making same |
| EP2436712A1 (de) | 2010-10-01 | 2012-04-04 | Sika Technology AG | Schlagzähigkeitsmodifikatoren für Epoxidharzzusammensetzungen |
| EP2730594A1 (de) | 2012-11-12 | 2014-05-14 | Sika Technology AG | Reaktive Flüssigkautschuke aus blockierten Isocyanat-terminierten Präpolymeren mit Glycolfänger |
| CN104768991B (zh) | 2012-11-12 | 2018-01-19 | Sika技术股份公司 | 用于环氧基粘合剂的新型抗冲改性剂 |
| EP3064518A1 (de) | 2015-03-04 | 2016-09-07 | Sika Technology AG | Verbesserte tieftemperaturschlagzähigkeit in ptmeg basierenden polyurethan-schlagzähigkeitsmodifikatoren |
| EP3402835B1 (de) | 2016-01-13 | 2019-10-30 | Sika Technology AG | Einkomponentiger hitzehärtender epoxidklebstoff mit verbesserter haftung |
| EP3281982A1 (de) | 2016-08-11 | 2018-02-14 | Sika Technology AG | Blockierte polyurethan-schlagzähigkeitsmodifikatoren zur verbesserung der schlagzähigkeit einkomponentiger tieftemperaturhärtender epoxidklebstoffe |
| CN110072687A (zh) | 2016-12-14 | 2019-07-30 | Sika技术股份公司 | 借助化学螺钉即时预固定优选由塑料制成的胶粘剂粘合嵌件 |
| US11643580B2 (en) | 2018-07-18 | 2023-05-09 | Sika Technology Ag | Method for strengthening of metal structures using toughened 2C-epoxy adhesives |
| EP4442726A1 (en) | 2023-04-05 | 2024-10-09 | Sika Technology AG | Multi-component epoxy resin composition with accelerated curing |
| CN116874058B (zh) * | 2023-09-07 | 2023-12-15 | 杭州尚善若水环保科技有限公司 | 一种混合药剂及其制备方法与用途 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4077938A (en) * | 1976-02-13 | 1978-03-07 | Motoyuki Imai | Sol of ultra-fine particles of layered structure material |
| US4558075A (en) * | 1984-03-30 | 1985-12-10 | Ppg Industries, Inc. | High-solids coating composition for improved rheology control containing organo-modified clay |
| ES535316A0 (es) * | 1984-08-21 | 1985-06-16 | Tolsa Sa | Procedimiento de fabricacion de arcillas fibrosas organofilicas |
| DE3434709A1 (de) * | 1984-09-21 | 1986-04-03 | Hoechst Ag, 6230 Frankfurt | Adsorbentien auf basis organophil modifizierter schichtkieselsaeuren |
| DE3434983C2 (de) * | 1984-09-24 | 1993-10-14 | Hoechst Ag | Gelbildendes organophiles Schichtsilikat, Verfahren zu seiner Herstellung und Verwendung |
| CA1241506A (en) * | 1984-10-18 | 1988-09-06 | Thomas M. Tymon | Flocced mineral materials and water-resistant articles made therefrom |
| US4695402A (en) * | 1985-08-20 | 1987-09-22 | Nl Chemicals, Inc. | Organophilic clay gellants and process for preparation |
| US4739007A (en) * | 1985-09-30 | 1988-04-19 | Kabushiki Kaisha Toyota Chou Kenkyusho | Composite material and process for manufacturing same |
| DE3806548C2 (de) * | 1987-03-04 | 1996-10-02 | Toyoda Chuo Kenkyusho Kk | Verbundmaterial und Verfahren zu dessen Herstellung |
| JPH0778089B2 (ja) * | 1987-03-26 | 1995-08-23 | 株式会社豊田中央研究所 | 複合材料の製造方法 |
| US5075033A (en) * | 1987-10-19 | 1991-12-24 | Rheox, Inc. | Processes for preparing organophilic clay gellants |
| US5248720A (en) * | 1988-09-06 | 1993-09-28 | Ube Industries, Ltd. | Process for preparing a polyamide composite material |
| US5137568A (en) * | 1989-05-02 | 1992-08-11 | J.M. Huber Corporation | Organokaolin pigments in ink formulations |
| JPH0747644B2 (ja) * | 1989-05-19 | 1995-05-24 | 宇部興産株式会社 | ポリアミド複合材料及びその製造方法 |
| JPH0621027B2 (ja) * | 1989-09-28 | 1994-03-23 | 忠蔵 加藤 | 固体間反応による有機スメクタイトの製造方法 |
| US5106421A (en) * | 1989-10-27 | 1992-04-21 | J. M. Huber Corporation | Mineral dye pigments |
| IT1236972B (it) * | 1989-11-03 | 1993-05-07 | Eniricerche Spa | Argilla organofila e procedimento per la sua preparazione. |
| JP2872756B2 (ja) * | 1990-05-30 | 1999-03-24 | 株式会社豊田中央研究所 | ポリイミド複合材料およびその製造方法 |
| US5298064A (en) * | 1990-12-06 | 1994-03-29 | Hoechst Aktiengesellschaft | Water-containing organophilic phylloisilicates |
| WO1993004118A1 (en) * | 1991-08-12 | 1993-03-04 | Allied-Signal Inc. | Melt process formation of polymer nanocomposite of exfoliated layered material |
| DE4137091C2 (de) * | 1991-11-12 | 1995-06-01 | Hoechst Ag | Wäßrige Feindispersion eines organophilen Schichtsilikates |
| US5385776A (en) * | 1992-11-16 | 1995-01-31 | Alliedsignal Inc. | Nanocomposites of gamma phase polymers containing inorganic particulate material |
-
1995
- 1995-04-03 US US08/416,112 patent/US5530052A/en not_active Expired - Lifetime
- 1995-12-18 US US08/574,012 patent/US5707439A/en not_active Expired - Lifetime
-
1996
- 1996-03-25 EP EP96302022A patent/EP0736490B1/en not_active Expired - Lifetime
- 1996-03-25 DE DE69628496T patent/DE69628496T2/de not_active Expired - Fee Related
- 1996-04-01 JP JP07860596A patent/JP4100726B2/ja not_active Expired - Fee Related
- 1996-04-02 KR KR1019960009851A patent/KR100354308B1/ko not_active IP Right Cessation
- 1996-04-03 CN CN96106007A patent/CN1125115C/zh not_active Expired - Fee Related
- 1996-04-03 CN CNB011192364A patent/CN1161420C/zh not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1980990B (zh) * | 2004-03-29 | 2011-03-02 | 株式会社普利司通 | 纳米复合材料及其生产方法 |
| CN115073049A (zh) * | 2022-05-23 | 2022-09-20 | 唐山冀东水泥外加剂有限责任公司 | 一种聚羧酸减水剂及其制备方法及使用方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0736490A1 (en) | 1996-10-09 |
| US5707439A (en) | 1998-01-13 |
| DE69628496D1 (de) | 2003-07-10 |
| KR960037595A (ko) | 1996-11-19 |
| EP0736490B1 (en) | 2003-06-04 |
| KR100354308B1 (ko) | 2002-12-28 |
| CN1148060A (zh) | 1997-04-23 |
| CN1161420C (zh) | 2004-08-11 |
| DE69628496T2 (de) | 2004-04-15 |
| JPH08337414A (ja) | 1996-12-24 |
| JP4100726B2 (ja) | 2008-06-11 |
| CN1125115C (zh) | 2003-10-22 |
| US5530052A (en) | 1996-06-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1125115C (zh) | 层状矿物及其组合物 | |
| Shibata et al. | Thermal and mechanical properties of plasticized poly (l‐lactide) nanocomposites with organo‐modified montmorillonites | |
| Giannelis | Polymer layered silicate nanocomposites | |
| Someya et al. | Nanocomposites based on poly (butylene adipate‐co‐terephthalate) and montmorillonite | |
| EP1040081B1 (en) | Polymer nanocomposites for high gas barrier applications | |
| DE69717020T2 (de) | Blättrige Schichtmaterialien und Nanozusammensetzungen, die derartige Materialien enthalten mit daran anhaftenden, wasserunlöslichen Oligomeren oder Polymeren | |
| Chen et al. | Preparation, characterization, and nanostructural evolution of epoxy nanocomposites | |
| CN106432297A (zh) | 一种三元稀土配合物及其在制备高强度杂化发光水凝胶中的应用 | |
| CN105504749A (zh) | 一种3d打印用聚碳酸酯复合材料及其制备方法 | |
| CN103509357A (zh) | 环保型沥青混合料改性剂及其制备方法 | |
| CN103282419A (zh) | 含有机改性的层状硅酸盐的聚合物材料 | |
| CN106220895A (zh) | 一种纳米增强的纸塑材料及其制造方法 | |
| Gusain et al. | 3D‐Printed Hydrogels and Aerogels for Water Treatment and Energy Storage Applications | |
| KR20070009608A (ko) | 폴리에스테르 수지 조성물 | |
| Abdelaal et al. | An overview on polysulphone/clay nanocomposites | |
| Shibata et al. | Nanocomposites based on poly (ϵ‐caprolactone) and the montmorillonite treated with dibutylamine‐terminated ϵ‐caprolactone oligomer | |
| Krithika et al. | Introduction of Nanohybrid Materials | |
| CN101434745B (zh) | 一种聚合物合金及其制备方法 | |
| CN101899199A (zh) | 一种剥离型pet/黏土纳米复合材料及制备方法 | |
| Li et al. | Direct melt extrusion processing of nylon 6/clay nanocomposites based on pristine montmorillonite | |
| KR20060069860A (ko) | 층상 규산염, 및 그것을 함유하는 열가소성 수지 조성물 | |
| KR102082274B1 (ko) | 유기 아연 담지 촉매, 이의 제조 방법, 및 상기 촉매를 이용한 폴리알킬렌 카보네이트 수지의 제조 방법 | |
| JP2006328210A (ja) | ポリエステル樹脂組成物および成形体 | |
| Yamaguchi et al. | Preparation and mechanical properties of clay/polystyrene‐block‐polybutadiene‐block‐polystyrene triblock copolymer (SBS) intercalated nanocomposites using organoclay containing stearic acid | |
| JP3430334B2 (ja) | ヘテロ凝集体 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: SAUDI ARABIA BASE CREATION PLASTICS IP PRIVATE CO Free format text: FORMER OWNER: GENERAL ELECTRIC CO. Effective date: 20080822 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20080822 Address after: Holland city Aupu zoom Bergen Patentee after: Sabic Innovative Plastics IP Address before: American New York Patentee before: General Electric Company |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20040811 Termination date: 20150403 |
|
| EXPY | Termination of patent right or utility model |