KR960010660A - 실란 폴리설파이드의 제조방법 - Google Patents

실란 폴리설파이드의 제조방법 Download PDF

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Publication number
KR960010660A
KR960010660A KR1019950032286A KR19950032286A KR960010660A KR 960010660 A KR960010660 A KR 960010660A KR 1019950032286 A KR1019950032286 A KR 1019950032286A KR 19950032286 A KR19950032286 A KR 19950032286A KR 960010660 A KR960010660 A KR 960010660A
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carbon atoms
solution
group
product
process according
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KR1019950032286A
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KR100374897B1 (ko
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엣지워드 칠드레스 토마스
스티븐 릿스처 제임스
쥬니어 커티스 루이스 스컬링
쥬니어 오케이 글렌 터커
진 베도우 도날드
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제임스 에이치. 코넬
오시 스페셜티스, 인코포레이티드
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Priority claimed from US08/314,204 external-priority patent/US5466848A/en
Application filed by 제임스 에이치. 코넬, 오시 스페셜티스, 인코포레이티드 filed Critical 제임스 에이치. 코넬
Publication of KR960010660A publication Critical patent/KR960010660A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1872—Preparation; Treatments not provided for in C07F7/20
    • C07F7/1892—Preparation; Treatments not provided for in C07F7/20 by reactions not provided for in C07F7/1876 - C07F7/1888

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)

Abstract

본 발명에 따라. 경화가능한 고무에 유용한 커플링 기약으로, 자동차 타이어에 대한 저회전 저항성을 포함하여 다양한 큭성을 강화한 황함유 유기 실리콘 화합물이 제조된다. 바람직한 화합물에는,

Description

실란 폴리설파이드의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 일반식 Q-R-Sn-R-Q의 화합물을 제조하기 위하여, (a)황화수소 가스를 활성 금속 알콕시드 용액과 접촉시키는 단계,(b)단계(a)의 생성물을 황원소와 반응시키는 단계, 및 (c)단계 (b)생성물을 일반식 Q-R-X의 활로히드로카르빌알콕시실란과 반응시키는 단계를 포함하는 실란 폴리설파이드의 제조방법.
    [상기에서 Q는 하기 구조식과 같다.
    상기 구조식에서, R1은 탄소수가 1 내지 4인 알킬기 또는 페닐이고, R2는 탄소수가 1 내지 8, 바람직하게는1 내지 4인 알콕시기, 탄소수가 5 내지 8인 시클로알콕시기 또는 탄소수가 1 내지 8인 직선 또는 곁가지 사슬 알킬 메르캅토기이고, 다양한 R1및 R2기는 동일하거나 다를 수 있고, R은 탄소수가 1내지 18인 2가의 히드로 카르빌기이고, X는 할로겐이다, 또한 n은 2 내지 9의 정수이다]
  2. 일반식 Q-R-Sn-R-Q화합물을 제조하기 위하여, (a)황화수소 가스를 활성 금속 알콕시드 용액과 접촉시키는 단계, (b)단계 (a)의 생성물을 황원소 및 Q-R-X식의 할로히드로카르빌알콕시실란과 반응시키는 단계를 포함하는 길란 폴리설파이드의 제조방법.
    [상기에서 Q는 하기 구조식과 같다.
    상기 구조식에서, R1은 탄소수가 1 내지 4인 알킬기 또는 페닐이고, R2는 탄소수가 1 내지 8, 바람직하게는1 내지 4인 알콕시기, 탄소수가 5내지 8인 시클로알콕시기 또는 탄소수가 5 내지 8인 시클로알콕시기 또는 탄소수가 1 내지 8인 직선 또는 곁가지 사슬 알킬 메프캅토기이고, 다양한 R1및 R2기는 동일하거나 다를 수 있고, R은 탄소수가 1 내지 18인 2가의 히드로카르빌기이고, X는 할로겐이다. 또한, n은 2 내지 9의 정수이다.]
  3. 제1항 또는 제2항에 있어서, n은 범위가 3 내지 5인 것을 특징으로 하는 방법.
  4. 제1항 또는 제2항에 있어서, Q는 하기의 구조식을 갖는 것을 특징으로 하는 방법.
  5. 제1항 또는 제2항에 있어서, R2가 에톡시인 것을 특징으로 하는 방법.
  6. 제1항 또는 제2항에 있어서, 활성 금속 알콕시드가 에톡시화나트륨인 것을 특징으로 하는 방법.
  7. 제1항 또는 제2항에 있어서, 할로겐이 염소인 것을 특징으로 하는 방법.
  8. 제1항 또는 제2항에 있어서, R이 1,3-프로필렌인 것을 특징으로 하는 방법.
  9. 제1항과 제2항에 있어서, 최종 반응단계의 생성물이 메톡시 유도체이고, 메톡시실란 유도체가 고급 알콕 시기를 포함하는 실란 유도체로 전환되는 것을 특징으로 하는 방법.
  10. 하기 단계로 이루어진 그룹으로 부터 선택된 (C2H5O)3Si(CH2)3-S4-(CH2)3Si(OC2H5)3의 제조 방법;(a) 나트륨 에톡실레이트의 에탄올 용액을 황화수소 가스와 접촉시켜 Na2S용액을 생산하고, Na2S용액에 황원소를 충분한 향 첨가해 톨리설파이드를 형성하고, Cl(CH2)3Si(C2H5O)3를 생성되는 방응 혼합물에 첨가해 반응을 완결시키는 단계 및 (b)나트륨 에톡실레이트의 에탄올 용액을 황화수고 가스와 접촉시켜 Na2S용액을 생산사고, Na2S용액에 황원소 및 Cl(CH2)3Si(C2H5O)3에 첨가해 반응을 완결시키는 단계.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950032286A 1994-09-28 1995-09-28 실란폴리설파이드의제조방법 KR100374897B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US08/314204 1994-09-28
US08/314,204 US5466848A (en) 1994-09-28 1994-09-28 Process for the preparation of silane polysulfides
US08/314,204 1994-09-28
US08/383480 1995-02-02
US08/383,480 1995-02-02
US08/383,480 US5489701A (en) 1994-09-28 1995-02-02 Process for the preparation of silane polysulfides

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KR960010660A true KR960010660A (ko) 1996-04-20
KR100374897B1 KR100374897B1 (ko) 2003-06-11

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US (1) US5489701A (ko)
EP (1) EP0705838B1 (ko)
JP (1) JPH08198883A (ko)
KR (1) KR100374897B1 (ko)
BR (1) BR9504173A (ko)
DE (1) DE69521001T2 (ko)

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KR100374897B1 (ko) 2003-06-11
BR9504173A (pt) 1996-08-06
EP0705838A2 (en) 1996-04-10
US5489701A (en) 1996-02-06
JPH08198883A (ja) 1996-08-06
DE69521001T2 (de) 2001-09-06
DE69521001D1 (de) 2001-06-28
EP0705838B1 (en) 2001-05-23
EP0705838A3 (en) 1998-03-18

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