KR950704396A - 무수물 수지를 함유하는 경화성 조성물(Curable composition containing anhydride resins) - Google Patents

무수물 수지를 함유하는 경화성 조성물(Curable composition containing anhydride resins)

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Publication number
KR950704396A
KR950704396A KR1019950701890A KR19950701890A KR950704396A KR 950704396 A KR950704396 A KR 950704396A KR 1019950701890 A KR1019950701890 A KR 1019950701890A KR 19950701890 A KR19950701890 A KR 19950701890A KR 950704396 A KR950704396 A KR 950704396A
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anhydride
curable composition
moiety
resin
polymer
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KR1019950701890A
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English (en)
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엘. 고울드 마이클
에이. 그릴리 데이비드
엘. 테트로프 마빈
에이. 히크너 리차드
에이. 라본 제임스
Original Assignee
스티븐 에스. 그레이스
더 다우 케미칼 캄파니
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Publication of KR950704396A publication Critical patent/KR950704396A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
    • C08G67/04—Polyanhydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L73/00—Compositions of macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C08L59/00 - C08L71/00; Compositions of derivatives of such polymers
    • C08L73/02—Polyanhydrides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D173/00—Coating compositions based on macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C09D159/00 - C09D171/00; Coating compositions based on derivatives of such polymers
    • C09D173/02—Polyanhydrides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03—Powdery paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31515—As intermediate layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31515—As intermediate layer
    • Y10T428/31522—Next to metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31529—Next to metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

중심 잔기 및 하나 이상의 비환식 무수물 잔기를 함유하는 공빈응물 수지 및 무수물 중합체의 조성물을 경화시켜 외부 내구성이 양호한 피복물을 제공한다. 바람직한 고분자량의 무수물 중합체는 불포화 지방족 탄화수소 단량체로부터 유도된 25중량% 이하의 반복 단위를 갖는 중심 중합체 잔기를 함유한다. 다른 바람직한 무수물 중합체에 있어서, 무수물 잔기는 에스테르 잔기에 의해 중심 잔기에 결합된다.

Description

[발명위 명칭]
무수물 수지를 함유하는 경화성 조성물(Curable composition containing anhydride resins)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 무수물 중합체 수지가 중심 잔기(1) 및 중심 잔기 각각에 결합되는 평균 하나 이상의 측쇄의 비환식 무수물 잔기(2)를 함유함을 특징으로 하는, (a)무수물 중합체 수지, 및 (b)경화조건하의 무수물 중합체 수지와 반응하는 하나 이상의 공반응물 수지를 포함하는 경화성 조성물.
  2. 무수물 중합체 수지가 중시 잔기(1) 및 중심 잔기 각각에 결합되는 평균 하나 이상의 측쇄의 비환식 무수물 잔기(2)를 함유함을 특징으로 하여, (a)무수물 중합체 및 하나 이상의 공반응물 수지를 함유하는 경화성 조성물을 기판에 적용시키고, (b)단계(a)에서 적용시킨 조성물을 가열하여 조성물을 경화시키는 단계를 포함하여 제품을 피복시키는 방법.
  3. 제1항 또는 제2항에 있어서, 경화성 조성물이 분말 형태인 경화성 조성물 또는 방법.
  4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 경화성 조성물이 추가로 용매를 포함하고 조성물의 고체 함량이 55중량% 이상인 경화성 조성물 또는 방법.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, 공반응물 수지가 에폭시 수지를 함유하는 평화성 조성물 또는 방법.
  6. 제5항에 있어서, 공반응물 수지가 추가로 폴리올 수지 또는 폴리아민 수지를 함유하는 경화성 조성물 또는 방법.
  7. 제1항 내지 제6항 중의 어느 한 항에 있어서, 무수물 중합체 수지가 분자당 평균 2개 이상의 무수물 잔기를 함유하는 경화성 조성물 또는 방법.
  8. 제1항 내지 제7항 중의 어느 한 항에 있어서, 중합체 무수물 수지가 하기 일반식의 잔기를 포함하는 경화성 조성물 또는 방법.
    상기식에서, A는 다가의 유기 잔기이고, Q는 2가의 유기 잔기이고, R은 수소원자 또는 유기 잔기이고, n은 2 이상인 측쇄 그룹의 수이다.
  9. 제1항 내지 제8항 중의 어느 한 항에 있어서, 무수물 중합체 수지가 하기 일반식(1(a))의 잔기를 함유하는 경화성 조성물 또는 방법.
    상기식에서, CM은 수평균 분자량이 1000이상인 중합체를 함유하고, R1은 수소원자 는 유기 잔기이고 n은 무수물 잔기의 수이다.
  10. 착색층 또는 투명 피복층, 또는 이들 두 층 모두 제1항 또는 제3항 내지 제9항 중의 어느 한 항에 따른 조성물의 경화 생성물을 함유함을 특징으로 하여, (a)기판, (b)임의로는 기판에 부착된 프라이머(primer)층 또는 표면 처리층, (c)기판, 또는 프라이머층 또는 표면 처리층에 부착시킨 착색층, 및 (d)프라이머층에 부착시킨 투명 피복층을 포함하는 피복제품.
  11. (a)다가의 유기 잔기, (b)다가의 유기 잔기에 결합된 다수의 에스테르 결합, (c)에스테르 결합에 결합되는 2가의 유기 잔기 및 (d)2가의 유기 잔기에 결합된 비환식 무수물 잔기를 포함하는 무수물 중합체.
  12. 무수물 중합체가 하기 일반식(4)의 화합물인 제11항에 따른 무수물 중합체, 제1항 내지 제8항 중의 어느 한 항에 따른 경화성 조성물 또는 방법 또는 제10항에 따른 피복 제품.
    상기식에서, A는 알킬 그룹이고, R은 각각 수소원자 또는 저급 알킬 그룹이고, n은 평균 1개 이상의 치환체 그룹의 수이다.
  13. 중심 잔기가 분자량이 1000이상이고 불포화 지방족 탄화수소 단량체로부터 유도된 25중량% 이하의 단량체 단위를 포함하는 중합체를 함유함을 특징으로 하는, (a)중심 잔기, 및 (b)중심 잔기에 결합되는 평균 2개 이상의 측쇄의 비환식 무수물 잔기를 포함하는 무수물 중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950701890A 1992-11-12 1993-10-14 무수물 수지를 함유하는 경화성 조성물(Curable composition containing anhydride resins) KR950704396A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US97456992A 1992-11-12 1992-11-12
US07/974569 1992-11-12
PCT/US1993/009880 WO1994011415A1 (en) 1992-11-12 1993-10-14 Curable composition containing anhydride resins

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KR950704396A true KR950704396A (ko) 1995-11-20

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US (6) US5428082A (ko)
EP (1) EP0668883A1 (ko)
JP (1) JPH08503502A (ko)
KR (1) KR950704396A (ko)
CN (2) CN1036270C (ko)
AU (1) AU5361194A (ko)
BR (1) BR9307564A (ko)
CA (1) CA2147361A1 (ko)
MX (1) MX9307059A (ko)
WO (1) WO1994011415A1 (ko)

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CN1167130A (zh) 1997-12-10
CA2147361A1 (en) 1994-05-26
BR9307564A (pt) 1999-06-01
US5698641A (en) 1997-12-16
AU5361194A (en) 1994-06-08
CN1087652A (zh) 1994-06-08
JPH08503502A (ja) 1996-04-16
WO1994011415A1 (en) 1994-05-26
MX9307059A (es) 1994-05-31
US5633020A (en) 1997-05-27
EP0668883A1 (en) 1995-08-30
US5602274A (en) 1997-02-11
US5633330A (en) 1997-05-27
US5698332A (en) 1997-12-16
US5428082A (en) 1995-06-27
CN1036270C (zh) 1997-10-29

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