KR950701967A - 안정된 포스페이트 에스테르-기초 기능성 유체 조성물 - Google Patents

안정된 포스페이트 에스테르-기초 기능성 유체 조성물

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Publication number
KR950701967A
KR950701967A KR1019940704510A KR19940704510A KR950701967A KR 950701967 A KR950701967 A KR 950701967A KR 1019940704510 A KR1019940704510 A KR 1019940704510A KR 19940704510 A KR19940704510 A KR 19940704510A KR 950701967 A KR950701967 A KR 950701967A
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South Korea
Prior art keywords
phosphate
composition
alkyl
butyl
base stock
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KR1019940704510A
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English (en)
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KR0161554B1 (ko
Inventor
절브랜드 디트먼
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원본미기재
몬산토 캄파니
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Abstract

트리알킬 포스페이트를 50∼70중량% 포함하고, 여기에서 알킬치환들은 C3∼C8이고, 제1탄소원자를 통해서 포스페이트 성분에 결합되며, 디알킬아릴포스페이트를 18∼35중량%포함하며, 여기에서 일킬치환체들은 C3∼C8이고 제1탄소원자를 통해 포스페이트 성분에 결합되며, 알킬디아릴 포스페이트를 0∼-5중량%포함하는 신규의 베이스 스톡을 포함하는 가능성 유체.
바람직하게는 알킬치환체들은 이소부틸 또는 이소펜틸이다. 그 유체는 산 스케빈저, 부식방지 첨가제, 점도 지수 개선제와 산화방지제를 더 포함한다. 신규의 첨가제 컴비네이션을 고분자량의 부틸/헥실 메타크릴레이트 점도지수 개선제, 퍼플루오로알킬설포내이트 부식방지 텀가제, 3, 4-에폭시 시클로헥산 카르복실레이트 또는 디에톡사이드 산 스캔 빈저 디(알킬페닐)아민, 과 2, 4, 6-트리알킬 페놀과 비스(3, 5-디알킬-4-히드록시아릴)메탄, 1, 3, 5-트리메틸-2, 4, 6-트리스(3, 5-디-t-부틸-4-히드록시아릴)벤젠과 이들의 혼합물로 이루어진 군으로 부터 선택된 힌더드 폴리페놀 조성물로 된 혼합물을 포함하는 페놀성 산화방지 제를 포함한다.
바람직하게는, 조성물은 가능성 유체의 안정성을 증진시키기 위하여, 4, 5-디 히드로이미다졸 유도체를 더 포함한다.

Description

안정된 포스페이트 에스테르-기초 기능성 유체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 온도 수분함량 및 다른 파리미터를 달리하는 여러가지의 다른 조건하에서 테스트한 수압용 유체소정물에 대한 에폭사이드 소모 대 시간의 도표이다.

Claims (45)

  1. 다음의 내용을 포함하는 것을 특징으로 하는 항공기 수압용 유체로 사용하기에 적합한 유체 조성물 : 베이스 스톡이 트리알길 포스페이트를 50∼72 중량%로 포함하고, 여기에서 알킬 치환체들은 3∼8개의 탄소원자를 포함하며, 제1탄소원자를 통해 포스페이트 부분에 결합되고, 디알킬 아릴포스페이트를 18∼35중량 %로 포함하고, 여기에서 일킬 치환체들은 3∼8개 사이의 탄소원자를 포함하고, 제1탄소원자를 통해 포스페이트 부분에 결합되고, 알킬디아릴 포스페이트를 0∼5중량 %포함하는 내화성이 있는 포스페이트 에스테르 베이스 스톡; 상기 베이스 스톡의 어떤 포스페이트 에스테르의 가수분해에 의하여 원상태에서 생성된 인산부분 에스테를 증화시키는데 효과적인 양의 산 스캐빈저; 수압용 시스템에서 수압용 서어브밸브의 유량계 가장자리의 유동을 유도하는 전기화학적 부식 또는 제타부식을 억제시키기에 효과적인 양의 부식방지용 첨가제, 약 210℉에서 적어도 3.0센티스트고, 100℉에서는 최소한 9.0센티스톡, -65℉에서는 4200센티스톡 이하의 점도지도를 나타내는 유체 조성물을 만들기에 효과적인 양의 전도지수 개선제; 및 산화제 존재하에서 유체 조성물 성분의 산화를 억제시키기에 효과적인 양의 산화방지제.
  2. 다음의 내용을 포함하는 것을 특징으로 하는 항공기 수압용 유체로서 사용하기에 적합한 유체 조성물 : 베이스 스톡이 트리알킬 포스페이트를 50∼72 중량%로 포함하고, 여기에서 알킬 치환체들은 실질적으로 C4또는 C5이고, 디알킬아릴 포스페이트를 18∼35중량 %포함하고, 여기에서 알킬 치환제는 실질적으로 C4또는 C5이고, 알킬디아릴 포스페이트 0∼5중량 %를 포함하는 내화성이 있는 포스페이트 에스테르 베이스 스톡; 상기 베이스 스톡의 어떤 포스페이스 에스테르의 가수분해에 의하여 원상태에서 생성된 인산부분 에스테르를 중화시키기에 효과적인 양의 산 스캐빈저, 수압용 시스템에서 수압용 서어브밸브의 유량계 가장자리의 유동을 유도하는 전기화학적 또는 제타 부식을 억제시키기에 효과적인 양의 부식방지용 첨가제; 약 210℉에서 적어도 3.0센티스톡, 100℉에서는 최소한 9.0센티스톡, -65℉에서 4200센티스톡 이하의 점도지수를 나타내는 유체 조성물을 만들기에 효과적인 양의 점도지수 개선제; 및 산화제 존재하에서 유체 조성물 성분의 산화를 억제시키기에 효과적인 양의 산화 방지제.
  3. 제2항에 있어서, 상기 더알킬아릴 포스페이트는 디알킬페닐 포스페이트인 것을 특징으로 하는 유체 조성물.
  4. 제2항에 있어서, 상기 점도지수 개선제는 약 210℉dp서 약 3∼5센티스톡의 점도지수를 100f74서는 9∼15센티스톡의 점도지수를 나타내는 유체 조성물을 야기하기에 효과적인 양으로 존재함을 특징으로 하는 조성물.
  5. 제2항에 있어서, 상술한 조성물증의 점도지수 개선제를 약 3%∼10%사이의 비율로 포함하고, 상술한 점도지수 개선제는 메타크릴레이트 에스테르 중합체를 포함하며, 이들의 반부유니트는 실질적으로 부틸과 헥실메타크릴레이트를 포함하며, 50,000∼1,500,000사이의 분자량을 갖는 상술한 중합체를 최소한 95%포함하는 것을 특징으로 하는 조성물.
  6. 제2항에 있어서, 상기 조성물에 2, 4, 6-트리알킬페놀을 약 0.1%∼1.0%사이의 비율로 포함하고, 디(알킬페닐)아민을 0.3∼1%사이의 비율로 포함하고, 비스(3,5-디알킬-4-히드록시아릴)메탄과 1, 3, 5-트리알킬-2,4, 6는-트리스(3, 5-7-t-부틸-4-히드록시아릴)벤젠과 이들의 혼합물로 이루어진 군으로 부터 선택된 힌더드 폴리페놀 조성물을 약 0.3∼1%사이의 비율로 포함하는 것을 특징으로 하는 화함물.
  7. 제2항에 있어서, 아릴치환체를 포함하는 에스테르들은 상술한 베이스 스톡을 약 25%이상을 함유하지 않는 것을 특징으로 하는 조성물.
  8. 제1항에 있어서, 상술한 알킬 치환제들은 실질적으로 이소부틸 또는 이소펜틸 인것.
  9. 다음의 내용을 포함하는 것을 특징으로 하는, 항공기 수압용 유체로 사용하기에 적합한 유체 조성물; 트리알킬 포스페이트를 약 10%∼90%사이로 포함하고, 여기에서 알킬 치환체들은 3∼8개 사이의 탄소원자를 포함하며, 일차 탄소를 통해 포스페이트 성분에 결합되고, 디알킬 아릴포스페이트를 0∼70%사이로 포함하고, 여기에서 알킬 치환체들은 3∼8%사이의 탄소원자를 포함하며, 일차탄소를 통해 포스페이트성분에 결합되고, 알킬디아릴포스페이트를 0∼5%사이로 포함하는 내화성이 있는 포스페이트 에스테르 베이스 스톡; 상술한 조성물에서 약 3∼10%사이의 비율로 포함된 점도지수 개선제를; 상술한 점도 지수 개선제는 메타크릴레이트 에스테르 중합체를 포함하고, 이의 반복유니트는 실질적으로 부틸과 헥실메타크릴레이트를 포함하고, 약 50,000∼1,500,000사이의 분자량을 갖는 상술한 중합체를 최소한 95%를 포함하는 점도지수 개선제; 상술한 조성물에 0.02-0.08%사이의 비울인 부식방지제, 상술한 부식방지제는 퍼플루오로 알킬설폰산의 알카리금속염을 포함하고, 이들의 알킬 치환제는, 헥실, 헵틸, 옥틸, 노닐 또는 데씰 또는 이들의 혼합물인 부식방지제; 상술한 조성물에서 1.5∼10%사이의 비율인 산 포착제 에폭사이드 화합물을 포함하는 산 포착제, 상술한 조성물에서 0.1∼1.0%사이의 비율인 2, ,4 6-트리알킬페놀; 상술한 조성물에서 약 0.3∼1%사이의 비율인 디 (알킬페닐)아민; 과 비스(3, 5-디알킬-4-히드록시아릴)메탄, 1, 3, 5-트릴메틸-2, 4, 6-트리스(3, 5,-디-t-부틸 -4-히드록시아릴)벤젠과 이들의 혼합물로 이루어진 군으로 부터 선택되고, 상술한 조성물의 약 0.3∼1%사이의 비율인 힌더드 폴리페놀조성물.
  10. 다음의 내용을 포함하는 것을 특징으로 하는, 항고기 수압용 유도체로서 사용하기에 적합한 유체 조성물 : 트리알킬 포스게이트를 약 10∼90%사이로 포함하고, 여기에서 알킬 치환체는 실절적으로 부틸 또는 펜틸이고, 디알킬아릴포스페이트를 0∼70%사이로 포함하며, 여기에서 알킬 치환제는 실질적으로 부틸 또는 펜틸이고, 알킬 디아릴포스페이트를 0∼25%사이로 포함하는 내화성이 있는 포스페이트 에스테르 베이스 스톡; 상술한 조성 물에서 3∼10%사이의 비율인 점도지수 개선제, 상술한 점도지수 개선제는 메타크릴레이트 에스테르 폴리머를 포함하며, 이의 반복 유니트는 실질적으로 부틸과 헥실 메타크릴레이트를 포함하며, 약 50,000과 1,500,000사이의 분자량을 갖는 상술한 폴리머를 최소한 95%포함하는 점도지수 개선제; 상술한 조성물의 약 0.02-0.08%사이의 비율인 부식방지제, 상술한 부식방지제는 퍼풀루오로 알킬 설폰산의 알카리 금속염을 포함하고, 이들의 알킬 치환체는 헥실, 헵틸, 옥틸, 노닐 또는 데씰 또는 이들의 혼합물인 부식억제제; 상기 조성물의 약 1.5∼10%사이의 비율인 산 포착제, 상술한 산 포착제는 3, 4-에폭시시클로 헥산 카르복실레이트의 유도체와 당의 구조식에 상응하는 디에폭사이드 화합물로 이루어진 군으로 부터 선택되며;
    여기에서 R3는 탄소원자 1∼10개를 포함하며, 산소원자 0∼6개를, 질소원자를 0∼6개를 포함하는 유기기이며, R4∼R9는 수소와 탄소원자 1∼5개를 포함하는 지방족기와 상술한 3, 4∼에폭시시클로헥산 카르복실레이트와 상술한 디에폭사이드 화합물 가운데서 각각 선택된것; 상술한 조성물의 약 0.1∼1.0%사이의 사이의 비율인 2, 4, 6-트리알킬 페놀; 상술한 조성물의 약 0.3%와 약 1%사이의 비율인 디(알킬 페닐)아민; 과 비스(3, 5-디알킬-4-히드록시아릴)메탄, 1, 3, 5-트리메틸-2, 4, 6-트리스(3, 5-디-t-부틸-히드록시아릴)벤젠과 이들의 혼합물로 이루어진 군으로 부터 선택되고, 상술한 조성물의 약 0.3-1%사이의 비율인 힌더드 폴리페놀 조성물.
  11. 제10항에 있어서, 구리부식억제제로서, 벤조트리아졸 또는 벤조트리아졸 유도체를 약 0.005%와 0.09ppm사이의 비율로 더 포함하는 것을 특징으로 하는 조성물.
  12. 제10항에 있어서, 알카리금속 아릴레이트를 0.0035∼0.10%사이로 더 포함하는 겻을 특징으로 하는 조성물.
  13. 제10항에 있어서, 상술한 베이스 스톡은 트리알킬포스페이트를 약 35∼90중량 % 포함하고, 여기에서 알킬 치환체는 실질적으로 부틸 또는 펜틸이고, 디알킬 아릴 포스 페이트를 0∼35중량%포함하고, 여기에서, 알킬 치환체는 실질적으로 부틸 또는 펜틸이고, 트리아릴 포스페이트를 0∼20중량%포함하는 것을 특징으로 하는 유체 조성물.
  14. 제13항에 있어서, 상술한 베이스 스톡은, 트리알킬 포스페이트를 80∼90%사이로 포함하고, 여기에서 알킬 치환체는 실질적으로 부틸 또는 펜틸이고, 트리(알킬아릴)포스페이트를 약 10∼20중량%사이로 포함하는 것을 특징으로 하는 유체 조성물.
  15. 제14항에 있어서, 상술한 트리(알킬아릴)포스페이트는 트리(이소프로필페닐) 포스페이트를 포함하는 것을 특징으로 하는 유체 조성물.
  16. 제10항에 있어서, 상술한 베이스 스톡은 트리알킬 포스페이트를 10∼72%사이로 포함하며, 여기에서 알킬 치환체들은 실질적으로 부틸 또는 펜틸이고 디알킬 아릴포스페이트를 18∼70%사이로 포함하며, 여기에서 알킬 치환체는 실절적으로 부틸 또는 펜틸이고, 알킬디아릴 포스페이트를 0∼25%사이를 포함하는 유체 조성물.
  17. 제16항에 있어서, 상술한 베이스 스톡은 트리알킬 포스페이트를 10∼25%사이로 포함하고, 여기에서 알킬 치환체는 실질적으로 부틸 또는 펜틸이고, 디알킬 아릴 포스페이트를 45∼70%사이로 포함하고, 여기에서 알질 치환체들은 실질적으로 부틸 또는 펜틸이고, 알킬디아킬 포스페이트를 5∼25%사이로 포함하며, 여기에서 알길 치환체는 실질적으로 부틸 또는 펜틸인 유체 조성물.
  18. 제16항에 있어서, 상술한 베이스 스톡은 트리알킬 포스페이트를 50∼72%사이로 포함하고, 여기에서 알킬 치환체들은 실질적으로 부틸 또는 펜틸이구 디알킬 아릴포스페이트를 18∼35중량%사이로 포함하고, 여기에서 알킬 치환체는 실절적으로 부틸 또는 펜틸이며, 알킬 디아릴 포스페이트를 0∼10중량%사이로 포함하는 유체 조성물.
  19. 제10항에 있어서, 상술한 베이스 스톡은 알킬 디아릴 포스페이트를 0∼5중량%사이로 포함하는 것을 특징으로 하는 유체 조성물.
  20. 제10항에 있어서, 상술한 알길 치환체들은 실질적으로 이소부틸 또는 이소펜틸인 조성물.
  21. 다음의 내용을 포함하는 것을 특징으로 하는 항공기 수압용 유체로 사용하기에 적합한 유체 조성물; 트리알킬 포스페이트를 10∼90중량%사이로 포함하며, 여기에서 알킬 치환체는 실질적으로 이소부틸 또는 이소펜틸이며, 디알킬 아릴 포스페이트를 0∼70중량%사이로 포함하며, 여기에서 알킬치환체는 실질적으로 이소부틸 또는 이소펜틸이며, 알킬 디아릴 포스페이트를 0∼25중량%사이로 포함하는 내화성 포스페이트 에스테르 베이스 스톡; 상술한 베이스 스톡의 어떤 포스페이트 에스테르의 가수분해에 의하여 원상태에서 생성된 인산 부분 에스테르를 중화시키는데 효과적인 양의 산 포착제; 수압용 시스템에서 수압용 보조밸브의 유동제량 미터링 가장자리의 유동을 유도하는 전기화학적 부식을 억제시키기에 효과적인 양의 부식방지용 첨가제; 210℉에서 적어도 3.0센티스톡, 100℉에서 최소한 9.0센티스톡, -65℉에선 4200센티스톡 이하의 점포지수를 나타내는 유체 조성물 만들기에 효과적인 양의 점도지수 개선제와; 산화제의 존재하에서, 유체 조성물 성분의 산화를 억제시키기에 효과적인 양의 산화 방지제.
  22. 제21항에 있어서, 상술한 트리알킬포스페이트는 트리이소부틸 포스페이트이고, 상술한 디알킬 아릴 포스페이트는 디오소부틸 페닐 포스페이트인 조성물.
  23. 제23항에 있어서, 구리부식억제제로서 벤조트리아졸 또는 벤조트리아졸 유도체틀 약 0.005∼0.09중량%사이로 포함하는 것을 특징으로 하는 조성물.
  24. 제21항에 있어서, 다음 구조식에 상응하는 4, 5-디히드로 이미다졸 화합물을 포함하는 조성물.
    여기에서 R1은 수소, 알킬, 알케닐, 히드록시알킬, 히드록시알케닐, 알콕시알킬과 알록시 알케닐으로 이루어진 군으로 부터 선택되며, R2은 알킬, 알케닐과 지방족 카르복실레이트로 이루어진 군으로 부터 선택된 것.
  25. 제24항에 있어서, 상술한 4, 5-디히드로이미다졸은 2-(8-헵타데세닐)4, 5-디히드로-1H-이미다졸-1-에탄올과 C14∼C18지방산과 4, 5∼디히드로-1H-이미다졸의 축합생성물로 이루어진 군으로 부터 선택된 조성물.
  26. 제25항에 있어서, 상술한 4, 5-디히드로이미다졸 화합물은 C16∼C18지방산과 4, 5-디히드로-1H-이미다졸의 축합 생성물인 조성물.
  27. 제24항에 있어서, 상술한 산화방지제는 힌더드 페놀을 포함하는 것을 특징으로 하는 조성물.
  28. 제27항에 있어서, 상술한 힌더드 페놀은 비스(3, 5-디알킬-4-히드록시아릴)메탄, 1, 3, 5-트리알킬-2, 4, 6-트리스(3, 5-디터시어리 부틸-4-히드록시 아릴)벤젠과 이들의 혼합물을 포함하는 것을 특징으로 하는 조성물.
  29. 제27항에 있어서, 상술한 산화방지 제는 아민화합물을 더 포함하는 것을 특징으로 하는 조성물.
  30. 제29항에 있어서, 디아릴아민 산화방지제를 더 포함하는 것을 특징으로 하는 조성물.
  31. 제30항에 있어서, 상술한 디아릴아민은 디(P-옥틸페닐)아민을 포함하는것을 특징으로 하는 조성물.
  32. 제30항에 있어서, 2, 6-디-t-부틸-P-크레졸 0.7중량 %를 포함하는 것을 특징으로 하는 조성물.
  33. 다음 내용을 포함하는 것을 특징으로 하는 항공기 수압용 유체로서 사용하기에 적합한 유체 조성물; 트리알킬 포스페이트를 10∼90중랑% 사이의 양으로 포함하고, 여기에서 알킬치환체는 실질적으로 부틸 또는 펜틸이며, 또 디알킬 아릴 포스페이트를 0∼70중량%사이로 포함하며, 여기에서 알킬치환테는 실질적으로 부틸 또는 펜틸이고, 알킬 디아릴 포스페이트를 0∼25중량% 사이로 포함하는 내화성이 있는 포스페이트 에스테르 베이스 스톡; 상술한 베이스 스톡의 어떤 포스페이트 에스테르의 가수분해에 의하여 원상태에서 생성된 인산부분 에스테르를 중화시키는데 효과적인 양의 산 포착제; 수압용 시스템에서 수압용 보조밸브의 유동제량 미터링 가장자리의 유동을 유도하는 전기화학적 또는 제타 부식작웅을 억제시키기에 효과적인 양으로 된 부식방지 첨가제; 약 210℉에서 최소한 3.0센티스톡의 점도지수를 나타내고, 100℉에서 최소한 9.0센티스톡, -65℉에서 약 4200센티스톡 이하의 점도지수를 나타내도록, 유체조성물에 효과적인 양으로 된 점도지수 개선제; 산화제의 존재하에서, 유체 조성물 성분의 산화를 억제시키기에 효과적인 양으로 된 산화 방지제;와 에폭사이드 소모에 의하여 측정한바로 300℉에서 최소한 25% 정도로 조성물의 안정성을 증가시키기에 효과적인 양으로 된 4, 5-디히드로 이미다졸 화합물, 상술한 4, 5-디히드로 이미다졸 화합물은 다음 구조식에서 상응하며;
    여기에서 R1은 수소, 알킬, 알케닐, 히드록시 알킬, 히드록시 알케닐, 알콕시 알킬과 알콕시 알케닐으로 이루어진 군으로 부터 선택되며, R2은 알킬, 알케닐과 지방족 카르복실레이트로 이루어진 군으로 부터 선택된 것.
  34. 제33항에 있어서, R1은 수소 또는 저급알킬이고, R2은 지방산 잔기인 것을 특징으로 하는 조성물.
  35. 제33항에 있어서, R1은 히드록시알킬이고, R2는 알케닐인 것을 특징으로 하는 조성물.
  36. 제33항에 있어서, 상술한 4, 5-디히드로이미다졸은 2-(8-헵타데세닐)-4, 5-디히드로-1H-이미다졸-1-에탄올과 C14-C18지방산과 4, 5-디히드로-1H-이미다졸의 축합생성물로 이루어진 군으로 부터 선택된 조성물.
  37. 제36항에 있어서, 상술한 4, 5-디히드로이미다졸 화합물은 C16∼C18지방산과 4, 5-디히드로-1H-이미다졸의 축합생성물인 것을 특징으로 하는 조성물.
  38. 제37항에 있어서, 상술한 트리알킬 포스페이트와 상술한 디알킬아릴 포스페이트의 알킬치환제들은 실질적으로 이소부틸 또는 이소펜틸인 조성물.
  39. 제33항에 있어서, 상술한 산화방지제는 힌더드 페놀을 포함하는 것을 특징으로 하는 조성물.
  40. 제39항에 있어서, 상술한 힌더드 페놀은 비스(3, 5-디알킬-4-히드록시 아릴) 메탄, 1, 3, 5-트릴알킬-2, 4, 6-트리스(3, 5-디-t-부틸-4-히드록시 아릴)벤젠과 이들의 혼합물로 이루어진 군으로 부터 선택된 힌더드 폴리페놀성 화합물을 포함하는 것을 특징으로 하는 조성물.
  41. 제39항에 있어서, 상술한 산화방지제는 아민 화합물을 더 포함하는 것을 특징으로 하는 조성물.
  42. 제41항에 있어서, 디아릴아민 산화방지제를 더 포함하는 것을 특징으로 하는 조성물.
  43. 제42항에 설명된 조성물에 있어서, 상술한 디아릴아민은 디(p-옥틸페닐)아민을 포함하는 것을 특징으로 하는 조성물.
  44. 제42항에 있어서, 2, 6-디-t-부틸-p-크레졸을 약 1.0중량%포함하는 것을 것을 특징으로 하는 조성물.
  45. 제33항에 있어서, 상술한 트리알킬 포스페이트와 상술한 디알킬 아릴 포스페이트의 알킬치환제들은 실질적으로 이소부틸 또는 이소펜틸인 제33항에 설명된 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940704510A 1992-06-11 1993-06-01 안정된 포스페이트 에스테르-기초 기능성 유체 조성물 KR0161554B1 (ko)

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