KR950032485A - 신규반응성 염료, 그의 제조 방법 및 그의 용도 - Google Patents
신규반응성 염료, 그의 제조 방법 및 그의 용도 Download PDFInfo
- Publication number
- KR950032485A KR950032485A KR1019950013804A KR19950013804A KR950032485A KR 950032485 A KR950032485 A KR 950032485A KR 1019950013804 A KR1019950013804 A KR 1019950013804A KR 19950013804 A KR19950013804 A KR 19950013804A KR 950032485 A KR950032485 A KR 950032485A
- Authority
- KR
- South Korea
- Prior art keywords
- radical
- formula
- reactive
- reactive dye
- group
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
- C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
- C09B62/4411—Azo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
- D06P1/382—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group directly attached to heterocyclic group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/10—Material containing basic nitrogen containing amide groups using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
Abstract
본 발명은 개선된 적용 특성을 나타내는 하기 일반식의 신규 반응성 염료에 관한 것이다.
식 중에서, A는 CH=CH2또는 CH2-CH2Z(여기서, Z는 염색 조건하에서 분리될 수 있는 치환체를 나타냄)를 나타내고, 다른 기들은 상세한 설명에 주어진 정의와 같다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 하기 일반식(Ⅰ)의 반응성 염료.(Ⅰ)상기 식에서, K1및 K2는 동일 또는 상이하고 서로 독립적으로 커플링 성분의 라디칼을 나타내고, D는 디아조 성분.과는 상이한 디아조 성분의 라디칼을 나타내며, A는 CH=CH2또는 CH2-CH2Z(여기서, Z는 염색 조건하에서 분리될 수 있는 치환체를 나타냄)를 나타내고, Y는 불소, 염소와 같은 할로겐, 또는 임의로 치환된 피리디늄 라디칼을 나타내며, S02-A기는 4- 또는 5- 위치에 결합된다.
- 제1항에 있어서, 디아조 성분 H2N-D (2)가 하기 일반식 (3),(4) 및 (5) 중의 하나에 해당하는 반응성 염료.H2N-D1(3)H2N-D2-B1-SO2A (4)H2N-D3-B2-X (5)상기 식에서, D1는 반응성 기가 없고 임의로 치환된 페닐 또는 나프틸 라디칼을 나타내고, D2및 D3는 임의로 치환된 페닐렌 또는 나프틸렌 라디칼을 나타내며, B1은 직접 결합 또는 2가 다리결합 구성원을 나타내고, B2는 2가 다리결합 구성원을 나타내며, X는 섬유-반응성 라디칼이다.
- 제2항에 있어서, B1이,-CH2-, 또는(여기서, R은 수소, 메틸 또는 에틸이고, *로 표시한 결합은 라디칼 D2에 연결됨)이고 B2가,또는(여기서, R은 수소, 메틸 또는 에틸이고, *로 표시한 결합은 라디칼 D3에 연결됨)인 반응성 염료.
- 제1항에 있어서, Z가 -OSO3H, -OPO3H2,-OCOCH3-, CI,-OSO2CH3또는 -S2O3H인 반응성 염료.
- 제1항에 있어서, K1및 K2가 서로 독립적으로 아미노히드록시나프탈렌 술폰산 라디칼인 반응성 염료.
- 제1항에 있어서, K1및 K2가 서로 독립적으로 하기 식(6)의 라디칼을 나타내는 반응성 염료.(6)식 중에서, n은 0 또는 1이다.
- 제1항에 있어서, 라디칼 D인 D1이 하기 구조식을 나타내고; 라디칼 D인 -D2-B1-SO2A가 히기의 라디칼을 나타내며; 라디칼 D인 -D3-B2-X가 하기의 라디칼 [여기서,X′는 하기의 섬유-반응성 라디칼(여기서, 술포기는 NH기에 대하여 o,m또는 p의 위치에 있음), 및이다]을 나타내는 반응성 염료.
- 제1항에 있어서, 라디칼 SO2-A가 아조 다리결합에 대해 p위치에 있고, A가 CH2CH2OSO3H 또는 CH=CH2를 나타내며, K1및 K|2가를 나타내고, Y가염소를 나타내는 반응성 염료.
- 하기식(7)의 아민(여기서; 라디칼 So2A는 아미노그룹에대해 4- 또는 5-위치에 있다)을 수성무기산 매질중에서 디아조화시킨 다음, 디아조화 생성물을 pH 3 내지 7에서 하기식(8)의 나프탈렌트리아진 유도체(여기서, Y1은 염소 또는 불소이고 n은 0 또는 1이다)와 커플링시키고, 생성된 하기식(9)의 중간 생성물을 pH 3 내지 6 및 0 내지 40℃의 온도에서 하기 식(6)(6)의 아미노나프탈렌술폰산(여기서, n은 0 또는 1이다)과 반응시켜 하기식의 생성물을 얻은 다음, 생성물(10)을 식 H2N-D(2)의 디아조 성분과 커플링시켜 하기 식(11)의 염료를 얻거나 또는 역순으로 일반식(1)의 염료를 합성하는 것으로 이루어진 , 제1항에 따른 화합물의 제조 방법.
- 반응성 염료로서 제1항에 따른 염료를 사용하는 것으로 이루어진 것을 특징으로 하는, 히드록실 또는 아미드기를 함유하는 물질을 반응성 염료로 염색 또는 날염하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4418992.3 | 1994-05-31 | ||
DE4418992A DE4418992A1 (de) | 1994-05-31 | 1994-05-31 | Neue Reaktivfarbstoffe, deren Herstellung und Verwendung |
Publications (1)
Publication Number | Publication Date |
---|---|
KR950032485A true KR950032485A (ko) | 1995-12-20 |
Family
ID=6519434
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950013804A KR950032485A (ko) | 1994-05-31 | 1995-05-30 | 신규반응성 염료, 그의 제조 방법 및 그의 용도 |
Country Status (6)
Country | Link |
---|---|
US (1) | US5625042A (ko) |
EP (1) | EP0685532A1 (ko) |
JP (1) | JPH07331100A (ko) |
KR (1) | KR950032485A (ko) |
CA (1) | CA2150303A1 (ko) |
DE (1) | DE4418992A1 (ko) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG73449A1 (en) * | 1996-04-24 | 2000-06-20 | Ciba Sc Holding Ag | Fibre-reactive dyes their preparation and their use |
US5886159A (en) * | 1996-08-23 | 1999-03-23 | Sumitomo Chemical Company, Limited | Bisazo compound and method for dyeing or printing fibrous materials using the same |
ES2202029T3 (es) * | 1999-11-05 | 2004-04-01 | Ciba Specialty Chemicals Holding Inc. | Colorantes reactivos, procedimiento de obtencion y utilizacion de los mismos. |
AU2003250950A1 (en) * | 2002-07-24 | 2004-02-23 | Ciba Specialty Chemicals Holding, Inc. | Fibre-reactive azo dyes, their preparation and their use |
CN105504872A (zh) * | 2015-12-23 | 2016-04-20 | 湖北华丽染料工业有限公司 | 一种亮橙色活性染料及其制备方法和应用 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2748966C3 (de) * | 1977-11-02 | 1980-08-21 | Hoechst Ag, 6000 Frankfurt | Wasserlösliche Farbstoffe, Verfahren zu deren Herstellung, ihre Verwendung als faserreaktive Farbstoffe zum Färben und Bedrucken von Cellulose- und Polyamid-Fasermaterialien |
DE2748965C3 (de) * | 1977-11-02 | 1981-10-01 | Hoechst Ag, 6000 Frankfurt | Wasserlösliche Farbstoffe, Verfahren zu deren Herstellung, ihre Verwendung als faserreaktive Farbstoffe zum Färben und Bedrucken von Fasermaterialien |
DE2748929A1 (de) * | 1977-11-02 | 1979-05-10 | Hoechst Ag | Wasserloesliche farbstoffe, verfahren zu ihrer herstellung, deren verwendung als faserreaktive farbstoffe zum faerben und bedrucken von fasermaterialien und fasermaterialien, die mit ihnen gefaerbt wurden |
DE3629574A1 (de) * | 1986-08-30 | 1988-03-03 | Hoechst Ag | Wasserloesliche disazoverbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe |
DE4021067A1 (de) * | 1990-07-03 | 1992-01-09 | Hoechst Ag | Disazoverbindungen, verfahren zu deren herstellung und ihre verwendung als farbstoffe |
DE4113838A1 (de) * | 1991-04-27 | 1992-10-29 | Basf Ag | Azofarbstoffe mit mehreren reaktiven ankergruppen |
-
1994
- 1994-05-31 DE DE4418992A patent/DE4418992A1/de not_active Withdrawn
-
1995
- 1995-05-18 EP EP95107602A patent/EP0685532A1/de not_active Withdrawn
- 1995-05-24 US US08/449,194 patent/US5625042A/en not_active Expired - Fee Related
- 1995-05-25 JP JP7149736A patent/JPH07331100A/ja active Pending
- 1995-05-26 CA CA002150303A patent/CA2150303A1/en not_active Abandoned
- 1995-05-30 KR KR1019950013804A patent/KR950032485A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP0685532A1 (de) | 1995-12-06 |
DE4418992A1 (de) | 1995-12-07 |
CA2150303A1 (en) | 1995-12-01 |
JPH07331100A (ja) | 1995-12-19 |
US5625042A (en) | 1997-04-29 |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |