KR950032358A - 친수성 폴리우레탄-폴리우레아 및 합성 수지용 분산제로서의 이의 용도 - Google Patents

친수성 폴리우레탄-폴리우레아 및 합성 수지용 분산제로서의 이의 용도 Download PDF

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KR950032358A
KR950032358A KR1019950011105A KR19950011105A KR950032358A KR 950032358 A KR950032358 A KR 950032358A KR 1019950011105 A KR1019950011105 A KR 1019950011105A KR 19950011105 A KR19950011105 A KR 19950011105A KR 950032358 A KR950032358 A KR 950032358A
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polyurea
hydrophilic polyurethane
mol
isocyanate
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메르텐 게르하르트
조엘러 요아힘
우르바노 에드문트
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카를-헤르만 마이어-돌호이어, 베른하르트 엠. 백크
훽스트 아크티엔게젤샤프트
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Publication of KR950032358A publication Critical patent/KR950032358A/ko

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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
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    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/2815Monohydroxy compounds
    • C08G18/282Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • C08G18/2825Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
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    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
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    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

본 발명은 (A) 하나 이상의 유기 폴리이소아네이트를 포함하는 폴리이소시네이트 성분, (B) 하나 이상의 이소시아네이트-반응성 지방산 유도체. (C)필요에 따라, 하이드록실 및 카복실 그롭에서 선택된 두개 이상의 작용성 그룹을 함유하는 화합물, (D) 500 내지 10,000g/mol의 분자량 범위를 갖는 폴리알킬렌 글리콜 성분, 및 (E) 물보다 NCO 그룹과 더 빨리 반응하는 하나 이상의 활성 수소 원자를 갖는 화합물을, 이들 출발 성분(A) 내지 (E)모두를 기준으로 하여 이소시아네이트 그룹 대 이소시아네이트-반응성 그룹의 수소 원자 총합의 몰비를 0.5:1 내지 2:1 로 유지하면서 반응시킴으로써 의해 수득가능한 친수성 폴리우페탄-폴리우레아를 제공한다.

Description

친수성 폴리우레탄-폴리우레아 및 합성 수지용 분산제로서의 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. (A)하나 이상의 유기 폴리이소시아네이트를 포함하는 폴리이소시아네이트 성분, (B) 하나 이상의 이소시아네이트-반응성 지방산 유도체. (C)필요에 따라, 하이드록실 및 카복실 그룹에서 선택된 두개 이상의 작용성 그룹을 함유하는 화합물, (D)500 내지 10,000/mol의 분자량 범위를 갖는 폴리알킬렌 글리콜 성분, 및 (E)몰보다 NCO 그룹과 더 빨리 반응하는 하나 이상의 활성 수소 원자를 갖는 화합물을, 이들 출발성분(A) 내지 (E)모두를 기준으로 하여 이소시아네이트 그룹 디이소시아네이트-반응성 그룹의 수소 원자 총합의 몰비를 0.5:1 내지 2:1로 유지하면서 반응킴으로써 수득가능한 친수성 폴리우레탄-폴리우레아.
  2. 제1항에 있어서, 모든 출발성분(A) 내지 (E)를 기준으로하여, 이소시아네이트 그룹 대 하이드록실 및 아미노 그룹의 총수소 원자의 몰비가 0.7:1 내지 1.5:1인 친수성 폴리우레탄-폴리우레아.
  3. 제1항에 있어서, 성분(A)1mol당 0.1 내지 1mol의 성분(B), 0 내지 0.8mol의 성분(C), 0.1 내지 0.8mol의 성분(D) 및 0.01 내지 0.3mol의 성분(E)를 사용하는 친수성 폴리우레탄-폴리우레아.
  4. 제1항에 있어서, 성분(B)가 불포화된 친수성 폴리우레탄-폴리우레아.
  5. 제1항에 있어서, 성분(B)가 지방 알콜, 지방 아민 및 1 내지 30개의 에틸렌 옥사이드 단위를 갖는 에톡시화된 지방 알콜 및 지방 아민에서 선택되는 친수성 폴리우레탄-폴리우레아.
  6. 제1항에, 성분(B)가 1 내지 20개의 에틸렌 옥사이드 단위를 갖는 에톡시화된 지방 알콜인 친수성 폴리우레탄-폴리우레아.
  7. 제1하에 있어서, 성분(B)가 폴리올을 갖는 지방산의 반응 생성물이면서도 아미노 그룹을 함유할 수 있는 친수성 폴리우레탄-폴리우레아.
  8. 제1항에 있어서, 성분(B)가 지방산과 모노에폭사이드의 반응 생성물인 친수성 폴리우레탄-폴리우레아.
  9. 제1항에있어서, 성분(C)가 비스하이드록시알칸 카복실산인 친수성 폴리우레탄-폴리우레아.
  10. 제1항에 있어서,성분(C)가 디메틸올프로피온산인 친수성 폴리우레탄-폴리우레아.
  11. 추가의 유화제를 사용하거나 사용하지 않고, 수성 합성-수지 분산액의 제조시 물에 분산될 수 없는 합성 수지용 유화제로서 제1항에 따른 친수성 폴리우레탄-폴리우레아를 사용하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950011105A 1994-05-09 1995-05-08 친수성 폴리우레탄-폴리우레아 및 합성 수지용 분산제로서의 이의 용도 KR950032358A (ko)

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DE4416336A DE4416336A1 (de) 1994-05-09 1994-05-09 Hydrophile Polyurethan-Polyharnstoffe und deren Verwendung als Dispergiermittel für Kunstharze
DEP4416336.3 1994-05-09

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JP (1) JPH0848743A (ko)
KR (1) KR950032358A (ko)
AU (1) AU1792295A (ko)
BR (1) BR9501946A (ko)
CA (1) CA2148550A1 (ko)
CZ (1) CZ118595A3 (ko)
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BR9608714A (pt) * 1995-06-07 1999-06-29 Sherwin Williams Co Tintas penetrantes e selantes de dispersões de poliuretano
US6191213B1 (en) 1996-06-06 2001-02-20 The Sherwin-Williams Company Penetrating stains and sealants from polyurethane dispersions
US6087444A (en) * 1996-09-20 2000-07-11 Ppg Industries Ohio, Inc. Humidity resistant aqueous urethane resins based on hydrophobic polyhydroxy compounds and coatings
DE19822603A1 (de) 1998-05-20 1999-11-25 Goldschmidt Ag Th Pigmentpasten enthaltend hydrophob modifizierte Polyasparaginsäurederivate
DE19852621A1 (de) * 1998-11-14 2000-05-18 Hansa Textilchemie Gmbh Permanentes Mittel zum Ausrüsten von Fasern oder aus Faser bestehenden Produkten
DE19930961A1 (de) 1999-07-05 2001-01-11 Bayer Ag Polyurethan-Dispersionen
DE10215053A1 (de) 2002-04-05 2003-10-23 Bayer Ag Polyurethan-Dispersionen auf Basis von Fettsäuredialkanolamiden
DE10232908A1 (de) 2002-07-19 2004-01-29 Goldschmidt Ag Verwendung organfunktionell modifizierter, Phenylderivate enthaltender Polysiloxane als Dispergier- und Netzmittel für Füllstoffe und Pigmente in wässrigen Pigmentpasten und Farb- oder Lackformulierungen
DE10334753A1 (de) * 2003-07-30 2005-03-10 Constr Res & Tech Gmbh Selbstvernetzende hochmolekulare Polyurethan-Dispersion
EP1566413B1 (de) 2004-02-20 2006-04-19 Goldschmidt GmbH Verfahren zur Herstellung von homogenen, lagerstabilen Pasten, Farben, Lacken unter Mitverwendung ionischer Flüssigkeiten als Dispergierhilfsmittel
US7968197B2 (en) * 2005-08-25 2011-06-28 Ppg Industries Ohio, Inc. Polyurea coating comprising an amine/(meth)acrylate oligomeric reaction product
EP2765147A1 (en) * 2013-02-06 2014-08-13 Momentive Specialty Chemicals Research Belgium S.A. Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters
PL2895522T3 (pl) * 2012-09-13 2021-08-16 Hexion Research Belgium Sa Wodna dyspersja poliuretanowa pochodząca z estrów tert-alkilo-glicydylowych
ES2706826T3 (es) 2015-12-10 2019-04-01 Covestro Deutschland Ag Dispersiones de poliuretano de secado oxidativo con una resistencia a productos químicos especialmente alta
CN107602782B (zh) * 2017-08-22 2022-08-09 山西省建筑科学研究院 含聚脲结构的聚羧酸减水剂的制备方法
CN112778498B (zh) * 2019-11-05 2023-05-26 万华化学集团股份有限公司 一种水性改性聚氨酯分散体及其用途与其制备的头发调理剂

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CA1131376A (en) * 1976-10-04 1982-09-07 David G. Hangauer, Jr. Aqueous urea-urethane dispersions
DE4022539A1 (de) * 1990-07-16 1992-01-23 Henkel Kgaa Polyurethane fuer die ledergrundierug
US5198508A (en) * 1990-09-18 1993-03-30 Mitsui Toatsu Chemicals, Inc. Resin compositions and molded articles
DE4306946A1 (de) * 1993-03-05 1994-09-08 Hoechst Ag Ungesättigte Polyurethane und deren Verwendung als Dispergiermittel für Alkydharze

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JPH0848743A (ja) 1996-02-20
BR9501946A (pt) 1995-12-12
CZ118595A3 (en) 1995-11-15
EP0682049A1 (de) 1995-11-15
AU1792295A (en) 1995-11-16
DE4416336A1 (de) 1995-11-16
CA2148550A1 (en) 1995-11-10
ZA953669B (en) 1996-11-08

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