KR950005866A - 폴리우레탄 중점제 및 수성계의 중점을 위한 그의 용도 - Google Patents

폴리우레탄 중점제 및 수성계의 중점을 위한 그의 용도 Download PDF

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KR950005866A
KR950005866A KR1019940020013A KR19940020013A KR950005866A KR 950005866 A KR950005866 A KR 950005866A KR 1019940020013 A KR1019940020013 A KR 1019940020013A KR 19940020013 A KR19940020013 A KR 19940020013A KR 950005866 A KR950005866 A KR 950005866A
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carbon atoms
essentially contains
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polyurethane according
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쾨니흐 클라우스
마자네크 얀
슈빈트 위르겐
디트리히 만프레트
클라인 게르하르트
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게르하르트 뮬러
바이 악티엔게젤샤프트
게르하르트 베버
바이 엘악티엔게젤샤프트
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/2815Monohydroxy compounds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
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    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
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    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
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  • Wood Science & Technology (AREA)
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Abstract

본 발명은 알콜의 친수성/소수성 혼합물 기재의 선택된 알콜 성분 a) 및 이 소시아네이트 성분 b)로부터 제조되는 수성계의 중점제로서 적합한 수용성 또는 수분산성 폴리우레탄, 및 수성계를 중점시키기 위한 그의 용도에 관한 것이다.

Description

폴리우레탄 중점제 및 수성계의 중점을 위한 그의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. a) a1)1종 이상의 일반식 R2-O-AyH의 화합물 25 내지 80몰%, a2)1종 이상의 HO-Az-(BO)z′-Az″-H의 화합물 10 내지 60몰%, 및 a3)1종 이상의 HO-R3-OH의 화합물 5 내지 60몰%를 함유한 알콜 성분과, b) 평균 NCO관능도가 1.5 내지 2.5이고, 일반식 R1(NCO)x의 유기 이소시아네이트를 적어도 하나 함유한 이소시아네이트 성분을 0.8:1 내지 1.4:1의 NCO/OH당량비로 반응시킴으로써 제조되고, 여기서, R1은 탄소수 6 내지 28의 지방족, 지환족, 방향족 또는 방향지방족 탄화수소 라디칼 및 임의로 불활성 치환체를 나타내고, R2는 탄소수 12 내지 24의 지방족 탄화수소 라디칼을 나타내고, R3은 탄소수 4 내지 36이 지방족 또는 방향지방족 탄화수소 라디칼 및 임의로 에테르 산소 원자를 나타내고, 단 적어도 3개의 탄소 원자가 두 개 히드록실기 사이에 배열되고, 임의로 존재하는 에테르 산소 원자에 대한 탄소 원자의 수치비가 적어도 2.5:1이고, A)는 탄소수 2 내지 3의 알킬렌옥사이드 라디칼을 나타내고, 이때 탄소수 3의 라디칼의 비는 40몰%를 초과하지 않고, 다른 알킬렌옥사이드 라디칼은 임의의 분포로 존재할 수 있고, B)는 탄소수 2 내지 18의 지방족 탄화수소 라디칼, 탄소수 4 내지 13의 지환족 탄화수소 라디칼 또는 탄소수 6 내지 15의 방향족 탄화수소 라디칼을 나타내고, x는 정수 또는 평균적으로 1.5 내지 2.5의 분수를 나타내고, y는 5 내지 200의 수를 나타내고, z 및 z″는 각각 0 내지 400의 수를 나타내고, 단 z 및 z″의 합은 10 내지 400이고, Z′는 0 또는 1이고, a1), a2) 및 a3)의 합은 총 100%이며, 라디칼 R2와 R3의 중량은 성분 a)의 총 중량을 기준으로 15중량% 미만인, 수성계의 증점제로서 적합한 수용성 또는 수분산성 폴리우레탄.
  2. 제1항에 있어서, 상기 NCO/OH 단량비가 0.9:1 내지 1.2:1인 폴리우레탄.
  3. 제1항에 있어서, R2가 탄소수 16 내지 18의 지방족 탄화수소 라디칼을 나타내는 것인 폴리우레탄.
  4. 제2항에 있어서, R2가 탄소수 16 내지 18의 지방족 탄화수소 라디칼을 나타내는 것인 폴리우레탄.
  5. 제1항에 있어서, A가 필수적으로 에틸렌 옥사이드 라디칼을 함유하고, y가 30 내지 150의 수를 나타내고, z 및 z″이 각각 0 내지 300의 수를 나타내고, 단 z와 z″의 합은 100 내지 300이고, z′은 0을 나타내는 것인 폴리우레탄.
  6. 제2항에 있어서, A가 필수적으로 에틸렌 옥사이드 라디칼을 함유하고, y가 30 내지 150의 수를 나타내고, z 및 z″이 각각 0 내지 300의 수를 나타내고, 단 z와 z″의 합은 100 내지 300이고, z′은 0을 나타내는 것인 폴리우레탄.
  7. 제3항에 있어서, A가 필수적으로 에틸렌 옥사이드 라디칼을 함유하고, y가 30 내지 150의 수를 나타내고, z 및 z″이 각각 0 내지 300의 수를 나타내고, 단 z와 z″의 합은 100 내지 300이고, z′은 0을 나타내는 것인 폴리우레탄.
  8. 제4항에 있어서, A가 필수적으로 에틸렌 옥사이드 라디칼을 함유하고, y가 30 내지 150의 수를 나타내고, z 및 z″이 각각 0 내지 300의 수를 나타내고, 단 z와 z″의 합은 100 내지 300이고, z′은 0을 나타내는 것인 폴리우레탄.
  9. 제1항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
  10. 제2항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
  11. 제3항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
  12. 제4항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
  13. 제5항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
  14. 제6항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
  15. 제7항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
  16. 제8항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
  17. 수성 폴리머 분산액 및 제1항의 수용성 또는 수분산성 폴리우레탄을 함유하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940020013A 1993-08-16 1994-08-13 폴리우레탄증점제및수성계의증점을위한그의용도 KR100297345B1 (ko)

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DEP4327481.1 1993-08-16
DE4327481A DE4327481A1 (de) 1993-08-16 1993-08-16 Als Verdickungsmittel geeignete Polyurethane und ihre Verwendung zur Verdickung wäßriger Systeme

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AT (1) ATE151789T1 (ko)
CA (1) CA2129932C (ko)
DE (2) DE4327481A1 (ko)
DK (1) DK0639595T3 (ko)
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TW338048B (en) 1998-08-11
CA2129932A1 (en) 1995-02-17
JP3364014B2 (ja) 2003-01-08
CA2129932C (en) 2006-10-10
JPH0776614A (ja) 1995-03-20
ES2102742T3 (es) 1997-08-01
US5594087A (en) 1997-01-14
DK0639595T3 (da) 1997-10-06
EP0639595A1 (de) 1995-02-22
EP0639595B1 (de) 1997-04-16
KR100297345B1 (ko) 2001-10-24
ATE151789T1 (de) 1997-05-15
DE4327481A1 (de) 1995-02-23
DE59402429D1 (de) 1997-05-22

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