KR950005866A - 폴리우레탄 중점제 및 수성계의 중점을 위한 그의 용도 - Google Patents
폴리우레탄 중점제 및 수성계의 중점을 위한 그의 용도 Download PDFInfo
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- KR950005866A KR950005866A KR1019940020013A KR19940020013A KR950005866A KR 950005866 A KR950005866 A KR 950005866A KR 1019940020013 A KR1019940020013 A KR 1019940020013A KR 19940020013 A KR19940020013 A KR 19940020013A KR 950005866 A KR950005866 A KR 950005866A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
본 발명은 알콜의 친수성/소수성 혼합물 기재의 선택된 알콜 성분 a) 및 이 소시아네이트 성분 b)로부터 제조되는 수성계의 중점제로서 적합한 수용성 또는 수분산성 폴리우레탄, 및 수성계를 중점시키기 위한 그의 용도에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- a) a1)1종 이상의 일반식 R2-O-AyH의 화합물 25 내지 80몰%, a2)1종 이상의 HO-Az-(BO)z′-Az″-H의 화합물 10 내지 60몰%, 및 a3)1종 이상의 HO-R3-OH의 화합물 5 내지 60몰%를 함유한 알콜 성분과, b) 평균 NCO관능도가 1.5 내지 2.5이고, 일반식 R1(NCO)x의 유기 이소시아네이트를 적어도 하나 함유한 이소시아네이트 성분을 0.8:1 내지 1.4:1의 NCO/OH당량비로 반응시킴으로써 제조되고, 여기서, R1은 탄소수 6 내지 28의 지방족, 지환족, 방향족 또는 방향지방족 탄화수소 라디칼 및 임의로 불활성 치환체를 나타내고, R2는 탄소수 12 내지 24의 지방족 탄화수소 라디칼을 나타내고, R3은 탄소수 4 내지 36이 지방족 또는 방향지방족 탄화수소 라디칼 및 임의로 에테르 산소 원자를 나타내고, 단 적어도 3개의 탄소 원자가 두 개 히드록실기 사이에 배열되고, 임의로 존재하는 에테르 산소 원자에 대한 탄소 원자의 수치비가 적어도 2.5:1이고, A)는 탄소수 2 내지 3의 알킬렌옥사이드 라디칼을 나타내고, 이때 탄소수 3의 라디칼의 비는 40몰%를 초과하지 않고, 다른 알킬렌옥사이드 라디칼은 임의의 분포로 존재할 수 있고, B)는 탄소수 2 내지 18의 지방족 탄화수소 라디칼, 탄소수 4 내지 13의 지환족 탄화수소 라디칼 또는 탄소수 6 내지 15의 방향족 탄화수소 라디칼을 나타내고, x는 정수 또는 평균적으로 1.5 내지 2.5의 분수를 나타내고, y는 5 내지 200의 수를 나타내고, z 및 z″는 각각 0 내지 400의 수를 나타내고, 단 z 및 z″의 합은 10 내지 400이고, Z′는 0 또는 1이고, a1), a2) 및 a3)의 합은 총 100%이며, 라디칼 R2와 R3의 중량은 성분 a)의 총 중량을 기준으로 15중량% 미만인, 수성계의 증점제로서 적합한 수용성 또는 수분산성 폴리우레탄.
- 제1항에 있어서, 상기 NCO/OH 단량비가 0.9:1 내지 1.2:1인 폴리우레탄.
- 제1항에 있어서, R2가 탄소수 16 내지 18의 지방족 탄화수소 라디칼을 나타내는 것인 폴리우레탄.
- 제2항에 있어서, R2가 탄소수 16 내지 18의 지방족 탄화수소 라디칼을 나타내는 것인 폴리우레탄.
- 제1항에 있어서, A가 필수적으로 에틸렌 옥사이드 라디칼을 함유하고, y가 30 내지 150의 수를 나타내고, z 및 z″이 각각 0 내지 300의 수를 나타내고, 단 z와 z″의 합은 100 내지 300이고, z′은 0을 나타내는 것인 폴리우레탄.
- 제2항에 있어서, A가 필수적으로 에틸렌 옥사이드 라디칼을 함유하고, y가 30 내지 150의 수를 나타내고, z 및 z″이 각각 0 내지 300의 수를 나타내고, 단 z와 z″의 합은 100 내지 300이고, z′은 0을 나타내는 것인 폴리우레탄.
- 제3항에 있어서, A가 필수적으로 에틸렌 옥사이드 라디칼을 함유하고, y가 30 내지 150의 수를 나타내고, z 및 z″이 각각 0 내지 300의 수를 나타내고, 단 z와 z″의 합은 100 내지 300이고, z′은 0을 나타내는 것인 폴리우레탄.
- 제4항에 있어서, A가 필수적으로 에틸렌 옥사이드 라디칼을 함유하고, y가 30 내지 150의 수를 나타내고, z 및 z″이 각각 0 내지 300의 수를 나타내고, 단 z와 z″의 합은 100 내지 300이고, z′은 0을 나타내는 것인 폴리우레탄.
- 제1항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
- 제2항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
- 제3항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
- 제4항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
- 제5항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
- 제6항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
- 제7항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
- 제8항에 있어서, 성분 a3)가 필수적으로 탄소수 6 내지 18의 ω,ω′-디히드록시알칸을 함유하는 것인 폴리우레탄.
- 수성 폴리머 분산액 및 제1항의 수용성 또는 수분산성 폴리우레탄을 함유하는 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4327481.1 | 1993-08-16 | ||
DE4327481A DE4327481A1 (de) | 1993-08-16 | 1993-08-16 | Als Verdickungsmittel geeignete Polyurethane und ihre Verwendung zur Verdickung wäßriger Systeme |
Publications (2)
Publication Number | Publication Date |
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KR950005866A true KR950005866A (ko) | 1995-03-20 |
KR100297345B1 KR100297345B1 (ko) | 2001-10-24 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019940020013A KR100297345B1 (ko) | 1993-08-16 | 1994-08-13 | 폴리우레탄증점제및수성계의증점을위한그의용도 |
Country Status (10)
Country | Link |
---|---|
US (1) | US5594087A (ko) |
EP (1) | EP0639595B1 (ko) |
JP (1) | JP3364014B2 (ko) |
KR (1) | KR100297345B1 (ko) |
AT (1) | ATE151789T1 (ko) |
CA (1) | CA2129932C (ko) |
DE (2) | DE4327481A1 (ko) |
DK (1) | DK0639595T3 (ko) |
ES (1) | ES2102742T3 (ko) |
TW (1) | TW338048B (ko) |
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US7074850B2 (en) * | 2001-09-26 | 2006-07-11 | Basf Aktiengesellschaft | Cross-linkable polyurethane block copolymers and their use in dispersion binding agent systems |
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DE102004031786A1 (de) * | 2004-07-01 | 2006-01-26 | Cognis Deutschland Gmbh & Co. Kg | Verdickungsmittel auf Polyurethanbasis |
FR2894980B1 (fr) * | 2005-12-20 | 2012-05-04 | Coatex Sas | Compositions aqueuses epaissantes et limpides, leur utilisation dans des formulations aqueuses acides, formulations obtenues. |
GB2453473B (en) * | 2006-08-31 | 2011-04-20 | Kansai Paint Co Ltd | Aqueous coating resin composition and aqueous coating composition |
EP2184304A1 (de) * | 2008-05-06 | 2010-05-12 | Basf Se | Polyurethanverdicker |
WO2009135857A2 (de) * | 2008-05-06 | 2009-11-12 | Basf Se | Polyurethane als rheologiemodifizierende mittel für kosmetische zubereitungen |
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DE3630319A1 (de) * | 1986-09-05 | 1988-03-10 | Akzo Gmbh | Verdickungsmittel |
US5023309A (en) * | 1987-09-18 | 1991-06-11 | Rheox, Inc. | Water dispersible, modified polyurethane thickener with improved high shear viscosity in aqueous systems |
DE4101239C1 (ko) * | 1991-01-17 | 1992-04-02 | Th. Goldschmidt Ag, 4300 Essen, De | |
FI920502A (fi) * | 1991-02-08 | 1992-08-09 | Sherwin Williams Co | Foertjockningsmedel foer belaeggningar. |
-
1993
- 1993-08-16 DE DE4327481A patent/DE4327481A1/de not_active Withdrawn
-
1994
- 1994-07-01 TW TW083105989A patent/TW338048B/zh not_active IP Right Cessation
- 1994-08-03 DE DE59402429T patent/DE59402429D1/de not_active Expired - Lifetime
- 1994-08-03 AT AT94112114T patent/ATE151789T1/de active
- 1994-08-03 DK DK94112114.7T patent/DK0639595T3/da active
- 1994-08-03 EP EP94112114A patent/EP0639595B1/de not_active Expired - Lifetime
- 1994-08-03 ES ES94112114T patent/ES2102742T3/es not_active Expired - Lifetime
- 1994-08-04 US US08/286,040 patent/US5594087A/en not_active Expired - Lifetime
- 1994-08-11 CA CA002129932A patent/CA2129932C/en not_active Expired - Fee Related
- 1994-08-12 JP JP21075094A patent/JP3364014B2/ja not_active Expired - Fee Related
- 1994-08-13 KR KR1019940020013A patent/KR100297345B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
TW338048B (en) | 1998-08-11 |
CA2129932A1 (en) | 1995-02-17 |
JP3364014B2 (ja) | 2003-01-08 |
CA2129932C (en) | 2006-10-10 |
JPH0776614A (ja) | 1995-03-20 |
ES2102742T3 (es) | 1997-08-01 |
US5594087A (en) | 1997-01-14 |
DK0639595T3 (da) | 1997-10-06 |
EP0639595A1 (de) | 1995-02-22 |
EP0639595B1 (de) | 1997-04-16 |
KR100297345B1 (ko) | 2001-10-24 |
ATE151789T1 (de) | 1997-05-15 |
DE4327481A1 (de) | 1995-02-23 |
DE59402429D1 (de) | 1997-05-22 |
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