KR950005914A - 열가소성 수지조성물 - Google Patents

열가소성 수지조성물 Download PDF

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KR950005914A
KR950005914A KR1019940020458A KR19940020458A KR950005914A KR 950005914 A KR950005914 A KR 950005914A KR 1019940020458 A KR1019940020458 A KR 1019940020458A KR 19940020458 A KR19940020458 A KR 19940020458A KR 950005914 A KR950005914 A KR 950005914A
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meth
thermoplastic resin
parts
resin composition
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KR0152571B1 (ko
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유타카 나카야마
히데유키 스미
히로시 오타
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스기야먀 토모오
다이이치 고교 세이야쿠 가부시키가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/286—Chlorinated polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K5/00—Use of organic ingredients
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    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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    • C—CHEMISTRY; METALLURGY
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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    • C—CHEMISTRY; METALLURGY
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    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06

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  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 열가소성 수지조성물에 관한 것으로 열가소성수지 (A) 100중량부, 함불소계유기계 난연제 (B) 2.0~40중량부 및 하기 구조단위 (Ⅰ)~(Ⅲ)가 선상으로 배열하고, 중량평균분자량이 1,000~50,000인 (메트) 아크릴아미드계 공중합체 및/또는 (메트) 아크릴산 에스테르계 공중합체⒞ 1.0~30중량부를 함유하여 이루어지며, 이때 올레핀 구조 단위(Ⅰ) 65~95몰%(메트) 아크릴레이트 구조단위(Ⅱ) 0~15몰% 및 (메트) 아크릴레이트(Ⅲ) 구조단위 또는 (메트) 아크릴산 에스테르 구조단위 1~35몰%을 함유하여 종래부터 업계에서 불가능하게 여겨왔던 우수한 난연성과 영구대전방지성의 두가지 물리적 특성을 겸비한 열가소성수지 조성물을 제공하는 것을 특징으로 한다.

Description

열가소성 수지조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. (A) 열가소성수지 100중량부, (B) 함불소계유기계 난연제 2.0~40중량부 (C) 하기 구조단위 (Ⅰ)~(Ⅲ)가 선상으로 배열하여 이루어지는 중량평균분자량이 1,000~50,000인 (메트) 아크릴아미드계 공중합체 및/또는 (메트) 아크릴산 에스테르계 공중합체 1.0~30중량부를 함유하여 이루어지는 열가소성수지 조성물,
    (식중 R1은 수소원자 또는 메틸기)로 나타내어지는 폴리올레핀 구조단위(Ⅰ) 65~99몰% 일반식 :
    (식중 R2는 수소원자 또는 메틸기, R3는 수소원자, 탄소수 1~12의 알킬기를 나타낸다)으로 나타내어지는 (메트) 아크릴레이트 구조단위(Ⅱ) 0~15몰% 일반식 :
    (식중 Y는 산소원자 또는 NH, R4는 수소원자 또는 메틸기, R5는 탄소수 2~8의알킬렌기, R6및 R7은 각각 탄소수 1~4의 알킬기, R8은 탄소수 1~12의 알킬기, 탄소수 6~12의 아릴알킬기 또는 탄소수 6~12의 지방족고리알킬기, X는 할로겐원자, ClO3, CH3OSO3, 또는 C2H5OSO3를 나타낸다)에서 나타내어지는 (메트) 아크릴아미드 구조단위 또는 (메트) 아크릴산 에스테르 구조단위(Ⅲ) 1~35몰%.
  2. 제1항에 있어서, 상기 (B)성분이 방향족 불소치환체 또는 지방족 불소치환체인 것을 특징으로 하는 열가소성 수지조성물.
  3. 제1항 또는 제2항에 있어서, (D) 무기계 난연조제가 15중량부 이하 배합되어 있는 것을 특징으로 하는 열가소성 수지조성물.
  4. 제1항 또는 제2항에 있어서, (D) 무기계 난연조제가 2~15중량부 배합되어 있는 것을 특징으로 하는 열가소성 수지조성물.
  5. 제3항 또는 제4항에 있어서, (D) 무기계 난연조제가 안티몬화합물인 것을 특징으로 하는 열가소성 수지조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940020458A 1993-08-19 1994-08-19 대전방지성, 내구성 및 난연성을 구비한 열가소성 수지조성물 KR0152571B1 (ko)

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Application Number Priority Date Filing Date Title
JP93-204976 1993-08-19
JP5204976A JPH0753878A (ja) 1993-08-19 1993-08-19 熱可塑性樹脂組成物

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KR950005914A true KR950005914A (ko) 1995-03-20
KR0152571B1 KR0152571B1 (ko) 1998-10-15

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KR1019940020458A KR0152571B1 (ko) 1993-08-19 1994-08-19 대전방지성, 내구성 및 난연성을 구비한 열가소성 수지조성물

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US (1) US5541242A (ko)
EP (1) EP0639623B1 (ko)
JP (1) JPH0753878A (ko)
KR (1) KR0152571B1 (ko)
DE (1) DE69418791T2 (ko)
TW (1) TW257778B (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5654369A (en) * 1995-07-25 1997-08-05 Dai-Ichi Kogyo Seiyaku Co., Ltd. Antistatic thermoplastic resin composition
US20040072929A1 (en) * 2002-06-27 2004-04-15 De Schryver Daniel A. Flame retardant compositions
WO2004085524A1 (ja) * 2003-03-25 2004-10-07 Teijin Dupont Films Japan Limited 帯電防止性積層ポリエステルフィルム
KR101234458B1 (ko) * 2009-11-18 2013-02-18 주식회사 엘지화학 열가소성 난연 수지 조성물

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3666692A (en) * 1970-02-24 1972-05-30 Dow Chemical Co Flame retardant polypropylene and polyurethane
US3950306A (en) * 1972-06-09 1976-04-13 The Dow Chemical Company Tris-(polyhalophenoxy)-s-triazine flame retardants
US3846469A (en) * 1972-06-12 1974-11-05 Dow Chemical Co Isopropylidene bis(2,6-dihalo-p-phenylene) bis(poly-halophenyl) carbonates
JPS5776042A (en) * 1980-10-29 1982-05-12 Kanegafuchi Chem Ind Co Ltd Flame-retardant thermoplastic resin composition
JPS60170667A (ja) * 1984-02-16 1985-09-04 Kanegafuchi Chem Ind Co Ltd 耐熱着色性に優れた難燃性樹脂組成物
US4565889A (en) * 1984-03-12 1986-01-21 Texaco Inc. Process for the production of N-(3-dimethylaminopropyl)methacrylamide
JPH066673B2 (ja) * 1986-06-13 1994-01-26 日東化成株式会社 安定化された難燃性熱可塑性樹脂組成物
US5306739A (en) * 1987-12-16 1994-04-26 Mlt/Micro-Lite Technology Corporation Highly filled polymeric compositions
JP2837162B2 (ja) * 1988-01-14 1998-12-14 出光興産株式会社 難燃性樹脂組成物
JPH02185553A (ja) * 1989-01-12 1990-07-19 Sumitomo Chem Co Ltd 熱可塑性樹脂組成物
US5064699A (en) * 1989-05-19 1991-11-12 W. R. Grace & Co.-Conn. Semi-rigid heat-sealable laminates with permanent antistatic characteristics
US5202193A (en) * 1990-11-28 1993-04-13 Kai-Ichi Kogyo Seiyaku Co., Ltd. N-substituted acrylamide copolymer
JPH04299109A (ja) * 1991-03-28 1992-10-22 Fujimori Kogyo Kk 光学用積層体
SG49029A1 (en) * 1992-04-14 1998-05-18 Sumitomo Electric Industries Flame-retardant resin composition electric wire using same and tube made of same

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EP0639623A2 (en) 1995-02-22
EP0639623B1 (en) 1999-06-02
DE69418791T2 (de) 2000-01-27
DE69418791D1 (de) 1999-07-08
KR0152571B1 (ko) 1998-10-15
EP0639623A3 (en) 1995-08-30
TW257778B (ko) 1995-09-21
US5541242A (en) 1996-07-30
JPH0753878A (ja) 1995-02-28

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