KR950005859A - 하이드록실 그룹을 함유하는 공중합체, 이의 제조방법 및 하이 솔리드 도료 조성물에서의 이의 용도 - Google Patents

하이드록실 그룹을 함유하는 공중합체, 이의 제조방법 및 하이 솔리드 도료 조성물에서의 이의 용도 Download PDF

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KR950005859A
KR950005859A KR1019940019552A KR19940019552A KR950005859A KR 950005859 A KR950005859 A KR 950005859A KR 1019940019552 A KR1019940019552 A KR 1019940019552A KR 19940019552 A KR19940019552 A KR 19940019552A KR 950005859 A KR950005859 A KR 950005859A
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copolymer
olefinically unsaturated
steric hindrance
component
monomer
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KR1019940019552A
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에플레 울리히
쿠빌루스 우베
슈미트 홀거
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칼-헤르만 마이어-둘호이어
훽스트 아크티엔게젤샤프트
베른하르트 엠. 벡크
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Application filed by 칼-헤르만 마이어-둘호이어, 훽스트 아크티엔게젤샤프트, 베른하르트 엠. 벡크 filed Critical 칼-헤르만 마이어-둘호이어
Publication of KR950005859A publication Critical patent/KR950005859A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/02—Polymerisation in bulk
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

본 발명은 벌크 중합에 의해 제조될 수 있는, 점도가 특히 낮은 공중합체에 관한 것으로서, 한 성분(A)가 주입되고 후속의 중합과정에서 올레핀계 불포화 공중합성 단량체(B) 2개 이상(이들 중의 하나 이상은 하나 이상의 COOH 그룹을 함유하고 입체 장해된다)이 첨가된다.

Description

하이드록실 그룹을 함유하는 공중합체, 이의 제조방법 및 하이 솔리드 도료 조성물에서의 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 벌크 중합에 의해 제조될 수 있는, 용액 점도가 특히 낮은 공중합체로서, 한 성분(A)가 주입되고 후속의 중합과정에서 올레핀계 불포화 공중합성 단량체(B) 2개 이상(이들 중의 하나 이상은 하나 이상의 COOH 그룹을 함유하고 입체 장해된다)이 첨가된 공중합체.
  2. 제1항에 있어서, 3차 또는 4차 α 탄소원자를 함유하는 지방족 포화 모노카복실산의 하나 이상의 글리시딜 에스테르 A) 5 내지 50중량%의 2개 이상의 올레핀계 불포화 공중합성 단량체(이들 중의 하나 이상은 하나 이상의 COOH 그룹을 함유하고 입체 장해된다) B) 95 내지 50중량%를 포함하는 공중합체.
  3. 제1항에 있어서, 입체 장해 단량체가 탄소 측쇄 및/또는 환상 구조를 갖는 올레핀계 불포화 화합물인 공중합체.
  4. 제2항에 있어서, B에 따른 올레핀계 불포화 단량체가 하나 이상의 -COOH 그룹을 함유하는 하나 이상의 올레핀계 불포화 단량체 B1), 하나 이상의 올레핀계 불포화 입체 장해 단량체 B2)와, 경우에 따라, 하나 이상의 성분 B3) 내지 B5), 즉 하나 이상의 α,β-불포화 카복실산의 하이드록시알킬 에스테르 B3), 탄소수 1 내지 20의 1가 지방족 알콜과 α,β-불포화 카르복실산과의 하나 이상의 에스테르 B4), 및 B1), B2), B3) 또는 B4)에 포함되어 있지 않은 하나 이상의 올레핀계 불포화 화합물 B5) 중에서 선택되는 공중합체.
  5. 제1항 내지 제4항 중의 어느 한 항에 있어서, 입체 장해 단량체가 측쇄 또는 지환족 알콜과 아크릴산 또는 메타크릴산과의 에스테르 공중합체.
  6. 제1항 내지 제5항 중의 어느 한 항에 있어서, OH가 40 내지 250㎎ KOH/g이고, 수평분자량(<Mn>)이 500g/㏖ 이하이며, 용액 점도가 10 내지 2000mPa S(23℃에서 50% 농도 용액으로 측정)인 공중합체.
  7. 제 1항 내지 제 6항 중의 어느 한 항에 있어서, 유리전이온도가 승온률 10K/min에서 실온(20℃)이상인 공중합체.
  8. 반응에 있어서, 성분(A)를 초기에 주입한 다음, 성분(B)와 하나 이상의 자유 라디칼 개시제를 벌크 상태로 동시에 또는 각각 가하여 배취를 공동 중합시킴을 포함하는, 제1항 내지 제7항에서 청구한 공중합체의 제조방법.
  9. 제1항 내지 제7항에서 청구한 공중합체를 사용하여 도료를 제조하는 방법.
  10. 제1항 내지 제7항에서 청구한 공중합체를 사용하여 중간 도막 또는 착색되거나 착색되지 않은 표면처리 도막을 제조하는 방법.
  11. 제1항 내지 제7항에서 청구한 공중합체를 도료, 특히 하이 솔리드 도료용 결합제로서 사용하는 방법.
  12. 제1항 내지 제7항에서 청구한 하나 이상이 공중합체를 결합제 성분(들)으로서 포함하고, 중은 또는 실온에서 폴리이소시아네이트를 사용하여 가교결합시킴으로써 경화하는 도료.
  13. 제1항 내지 제7항에서 청구한 공중합체를 사용하여 분체 도료를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940019552A 1993-08-09 1994-08-09 하이드록실 그룹을 함유하는 공중합체, 이의 제조방법 및 하이 솔리드 도료 조성물에서의 이의 용도 KR950005859A (ko)

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DEP4326656.8 1993-08-09
DE4326656A DE4326656A1 (de) 1993-08-09 1993-08-09 Hydroxylgruppen enthaltende Copolymerisate, ihre Herstellung und ihre Verwendung in festkörperreichen Beschichtungsmitteln

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US (2) US5608012A (ko)
EP (1) EP0638591B1 (ko)
JP (1) JPH07196741A (ko)
KR (1) KR950005859A (ko)
CN (1) CN1106417A (ko)
AT (1) ATE162806T1 (ko)
AU (1) AU683066B2 (ko)
BR (1) BR9403185A (ko)
CA (1) CA2128657A1 (ko)
CZ (1) CZ192994A3 (ko)
DE (2) DE4326656A1 (ko)
DK (1) DK0638591T3 (ko)
ES (1) ES2114637T3 (ko)
TW (1) TW264506B (ko)

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KR100518793B1 (ko) * 2002-10-01 2005-10-04 주식회사 케이씨씨 하이솔리드 폴리에스테르 수지 및 이의 제조방법

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EP0638591A2 (de) 1995-02-15
AU6895294A (en) 1995-02-16
JPH07196741A (ja) 1995-08-01
AU683066B2 (en) 1997-10-30
DE4326656A1 (de) 1995-02-16
TW264506B (ko) 1995-12-01
CZ192994A3 (en) 1995-03-15
EP0638591B1 (de) 1998-01-28
US5596057A (en) 1997-01-21
EP0638591A3 (de) 1995-03-29
CN1106417A (zh) 1995-08-09
DE59405158D1 (de) 1998-03-05
DK0638591T3 (da) 1998-03-16
US5608012A (en) 1997-03-04
ES2114637T3 (es) 1998-06-01
ATE162806T1 (de) 1998-02-15
CA2128657A1 (en) 1995-02-10

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