KR950000647A - 방향족 아민을 수소화시켜 이들의 고리 수소화된 대응물을 제조하는 방법 - Google Patents

방향족 아민을 수소화시켜 이들의 고리 수소화된 대응물을 제조하는 방법 Download PDF

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Publication number
KR950000647A
KR950000647A KR1019940014720A KR19940014720A KR950000647A KR 950000647 A KR950000647 A KR 950000647A KR 1019940014720 A KR1019940014720 A KR 1019940014720A KR 19940014720 A KR19940014720 A KR 19940014720A KR 950000647 A KR950000647 A KR 950000647A
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KR
South Korea
Prior art keywords
catalyst
weight
rhodium
aromatic amine
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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KR1019940014720A
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English (en)
Korean (ko)
Inventor
아난다 베다지 가미니
넬슨 아모어 존
Original Assignee
윌리암 에프. 마쉬
에어 프로덕츠 앤드 케미칼스, 인코오포레이티드
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Publication of KR950000647A publication Critical patent/KR950000647A/ko
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
    • C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1019940014720A 1993-06-25 1994-06-25 방향족 아민을 수소화시켜 이들의 고리 수소화된 대응물을 제조하는 방법 Ceased KR950000647A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/083,843 1993-06-25
US08/083,843 US5360934A (en) 1993-06-25 1993-06-25 Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts

Publications (1)

Publication Number Publication Date
KR950000647A true KR950000647A (ko) 1995-01-03

Family

ID=22181053

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940014720A Ceased KR950000647A (ko) 1993-06-25 1994-06-25 방향족 아민을 수소화시켜 이들의 고리 수소화된 대응물을 제조하는 방법

Country Status (6)

Country Link
US (1) US5360934A (cg-RX-API-DMAC10.html)
EP (1) EP0630882B1 (cg-RX-API-DMAC10.html)
KR (1) KR950000647A (cg-RX-API-DMAC10.html)
BR (1) BR9402488A (cg-RX-API-DMAC10.html)
DE (1) DE69406594T2 (cg-RX-API-DMAC10.html)
TW (1) TW250475B (cg-RX-API-DMAC10.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100418023B1 (ko) * 2001-03-07 2004-02-14 에스케이 주식회사 방향족 아민의 수소화 반응에 의한 환상의 지방족 아민의제조방법

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DE4328007A1 (de) * 1993-08-20 1995-02-23 Huels Chemische Werke Ag Katalysator zur Herstellung von Bis-Para-aminocyclohexylmethan mit niedrigem Anteil an trans-trans-Isomer durch Hydrierung von Methylendiamin
DE19533718A1 (de) * 1995-09-12 1997-03-13 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Aminogruppe an einen aromatischen Kern gebunden ist
DE19641688A1 (de) * 1996-10-10 1998-04-16 Bayer Ag Katalysatoren und Verfahren zur Herstellung von cycloaliphatischen Aminen
DE19824906A1 (de) * 1998-06-04 1999-12-09 Bayer Ag Verfahren zur Herstellung von variablen Gemischen aus Cyclohexylamin und Dicyclohexylamin
DE19827282A1 (de) * 1998-06-19 1999-12-23 Bayer Ag Verfahren zur Herstellung von cycloaliphatischen Aminen
DE19845641A1 (de) * 1998-10-05 2000-04-06 Bayer Ag Verfahren zur Herstellung von dicycloaliphatischen Aminen
US6184416B1 (en) * 2000-04-28 2001-02-06 Air Products And Chemicals, Inc. Lithium aluminate as a catalyst support for hydrogenation of aromatic amines
US6429338B1 (en) * 2002-01-17 2002-08-06 Air Products And Chemicals, Inc. Hydrogenation of single ring aromatic diamines
EP1366812B1 (de) 2002-05-31 2009-02-18 Evonik Degussa GmbH Geträgerter Rutheniumkatalysator und Verfahren zur Hydrierung eines aromatischen Amins in Gegenwart dieses Katalysators
DE10231119A1 (de) * 2002-07-10 2004-02-05 Degussa Ag Verfahren zur Selektivitätserhöhung der Hydrierung von 4,4'-Diaminodiphenylmethan zu 4,4'-Diaminodicyclohexylmethan in Gegenwart eines N-Alkyl-4,4'-Diaminodiphenylmethans
US7038088B2 (en) * 2004-05-19 2006-05-02 Air Products And Chemicals, Inc. Hydrogenation of highly contaminated methylenedianiline
DE102008002002A1 (de) 2008-05-27 2009-12-03 Evonik Degussa Gmbh Chlor armes mehrstufiges Verfahren zur Herstellung von cycloaliphatischen Diisocyanaten
CN102216254A (zh) * 2008-11-18 2011-10-12 因温斯特技术公司 1,2-二氨基环己烷和化学方法
CN102688757A (zh) * 2011-03-22 2012-09-26 中国科学院大连化学物理研究所 一种在临氨条件下苯二胺加氢制备环己二胺的催化剂
ES2614356T3 (es) * 2014-02-05 2017-05-30 Covestro Deutschland Ag Procedimiento de hidrogenación de poliaminas y dipoliaminas aromáticas a poliaminas y dipoliaminas cicloalifáticas
EP2905273B1 (en) 2014-02-05 2018-06-06 Covestro Deutschland AG Process for hydrogenating aromatic di- and polyamines
TWI534131B (zh) 2014-11-27 2016-05-21 財團法人工業技術研究院 氫化４，４’－二胺基二苯甲烷的觸媒與方法
CN109562355A (zh) 2016-08-18 2019-04-02 芝加哥大学 用于高效有机转化的金属氧化物负载的地球丰富的金属催化剂
CN112898184A (zh) * 2021-01-25 2021-06-04 河北工业大学 一种连续合成脂环族氨基甲酸酯方法
WO2023275038A1 (de) * 2021-07-02 2023-01-05 Evonik Operations Gmbh Hydrierung von aromatischen aminen aus pu-zersetzungsprozessen
EP4685129A1 (de) 2024-07-26 2026-01-28 Evonik Operations GmbH Verfahren zur hydrierung von mda
EP4685130A1 (de) 2024-07-26 2026-01-28 Evonik Operations GmbH Verfahren zur herstellung von methylenbis(cyclohexylamin)

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DD69585A (cg-RX-API-DMAC10.html) *
US2606928A (en) * 1947-11-18 1952-08-12 Du Pont Preparation of amino alicyclic compounds
US2511028A (en) * 1947-12-04 1950-06-13 Du Pont 4-[(para-aminophenyl) alkyl] cyclo-hexylamine
US2606924A (en) * 1949-06-09 1952-08-12 Du Pont Bis (4-aminocyclohexyl)-methane
US2606925A (en) * 1949-12-15 1952-08-12 Du Pont Ruthenium catalyzed hydrogenation process for obtaining aminocyclohexyl compounds
US3347917A (en) * 1961-12-29 1967-10-17 Du Pont Process for the preparation of di (paraaminocyclohexyl) methane
US3155724A (en) * 1961-12-29 1964-11-03 Du Pont Process for bringing stereoisomeric mixture of bis-(4-aminocyclohexane) methane close to the equilibrium concentration
CH515882A (de) * 1965-12-23 1971-11-30 Du Pont Verfahren zur Herstellung von 4,4'-Methylen-di-(cyclohexylamin)
US3591635A (en) * 1968-09-25 1971-07-06 Upjohn Co Catalytic hydrogenation process for preparing di(4 - aminocyclohexyl) methane
US3644522A (en) * 1969-04-04 1972-02-22 Du Pont Catalytic hydrogenation of nitrogen containing compounds over supported ruthenium catalysts
US3679746A (en) * 1969-10-27 1972-07-25 Du Pont Isomer enrichment of bicyclohexyl-4,4{40 -diamine
JPS4830603B1 (cg-RX-API-DMAC10.html) * 1969-12-24 1973-09-21
US3711550A (en) * 1970-02-16 1973-01-16 Du Pont Isomerization of 4,4'-methylenedi (cyclohexylamine) over moderated ruthenium catalyst
US3766272A (en) * 1972-08-25 1973-10-16 Du Pont 4,4'-methylenedi(cyclohexylamine)isomerization over a supported catalyst
US4034061A (en) * 1972-11-16 1977-07-05 Union Oil Company Of California Aluminum borate catalyst compositions and use thereof in chemical conversions
US4220559A (en) * 1978-02-14 1980-09-02 Engelhard Minerals & Chemicals Corporation High temperature-stable catalyst composition
US4754070A (en) * 1986-01-23 1988-06-28 Air Products And Chemicals, Inc. Hydrogenation of methylenedianiline to produce bis(para-aminocyclohexyl)methane
US4960941A (en) * 1988-03-30 1990-10-02 Air Products And Chemicals, Inc. Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts
US5116879A (en) * 1988-12-28 1992-05-26 Den Norske Stats Oljeselskap A.S. Process using a supported catalyst for hydrocarbon synthesis

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100418023B1 (ko) * 2001-03-07 2004-02-14 에스케이 주식회사 방향족 아민의 수소화 반응에 의한 환상의 지방족 아민의제조방법

Also Published As

Publication number Publication date
EP0630882A1 (en) 1994-12-28
BR9402488A (pt) 1995-03-14
DE69406594T2 (de) 1998-03-05
EP0630882B1 (en) 1997-11-05
US5360934A (en) 1994-11-01
DE69406594D1 (de) 1997-12-11
TW250475B (cg-RX-API-DMAC10.html) 1995-07-01

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