KR940703789A - 고무 보강용 유리섬유(rubber-reinforcing glass fiber product) - Google Patents

고무 보강용 유리섬유(rubber-reinforcing glass fiber product)

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Publication number
KR940703789A
KR940703789A KR1019940702427A KR19940702427A KR940703789A KR 940703789 A KR940703789 A KR 940703789A KR 1019940702427 A KR1019940702427 A KR 1019940702427A KR 19940702427 A KR19940702427 A KR 19940702427A KR 940703789 A KR940703789 A KR 940703789A
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South Korea
Prior art keywords
latex
rubber
butadiene
glass fiber
rubber latex
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KR1019940702427A
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English (en)
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KR0160183B1 (ko
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아끼노부 오까무라
마사또 세끼구찌
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이데하라 요오조
닛뽕가라스셍이 가부시끼가이샤
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Publication of KR940703789A publication Critical patent/KR940703789A/ko
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Publication of KR0160183B1 publication Critical patent/KR0160183B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/27—Rubber latex
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/465—Coatings containing composite materials
    • C03C25/47—Coatings containing composite materials containing particles, fibres or flakes, e.g. in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/48—Coating with two or more coatings having different compositions
    • C03C25/50—Coatings containing organic materials only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C08L15/005—Hydrogenated nitrile rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C08L21/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/16—Solid spheres
    • C08K7/18—Solid spheres inorganic
    • C08K7/20—Glass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10S156/91—Bonding tire cord and elastomer: improved adhesive system
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
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    • Y10T428/249934—Fibers are aligned substantially parallel
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    • Y10T428/2904—Staple length fiber
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    • Y10T428/2918—Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/2927—Rod, strand, filament or fiber including structurally defined particulate matter
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    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/2938—Coating on discrete and individual rods, strands or filaments
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    • Y10T428/294—Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
    • Y10T428/296—Rubber, cellulosic or silicic material in coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer
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    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926—Coated or impregnated inorganic fiber fabric
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    • Y10T442/2992—Coated or impregnated glass fiber fabric

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  • Geochemistry & Mineralogy (AREA)
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Abstract

요오드가가 120 이하인 니트릴기 함유 고포화 중합체 고무 라텍스(A), 상기 고포화 중합체 고무 라텍스 이외의 고무 라텍스(B), 및 수용성 레조르시놀/포름알데히드 축합물을 각각 고형분 중량비로서 15 내지 80중량%, 5 내지 70중량% 및 2 내지 15중량%의 양으로 함유하는 처리제, 이 처리제로 피복 처리된 고무 고강용 유리 섬유, 및 이 고무 보강용 유리 섬유를 사용하여 만들어진 톱니형 벨트, 타이어 등의 고무 제품이 개시되어 있다. 상기 처리제로 피복된 유리 섬유는 2차 처리제로서의 할로겐 함유 중합체계 접착제로 더욱 피복 처리될 수 있다.
상기 처리제는 보강 섬유와 마트릭스 간의 결합력이 크다. 따라서 고무 제품을 반복하여 굴곡 응력을 가할때라도, 그의 강도는 저하되지 않으며, 또한 보강 섬유와 고무 아트릭스 사이에서 박리가 발생하지 않는다. 또한 고무 제품은 내열성 내수성이 충분하다.

Description

고무 보강용 유리섬유(RUBBER-REINFORCING GLASS FIBER PRODUCT)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 1 구현예에 따른 유리 섬유로 보강된 톱니형 벨트의 열 주행 시험 성능을 측정하기 위한 시험기의 개략적인 측면도,
제2도는 본 발명의 1 구현예에 따른 유리 섬유로 보강된 톱니형 벨트의 열 주행 시험 성능을 측정하기 위한 물 주입 주행 시험기의 개략적인 단면도.

Claims (25)

  1. 요오드가가 120 이하인 니트릴기 함유 고포화 중합체 고무 라텍스(A), 상기 고포화 중합체 고무 라텍스 이외의 고무 라텍스(B), 및 수용성 레조르시놀/포름알데히드 축합물을 각각 고형분 중량비로서 15 내지 80중량%, 5 내지 70중량% 및 2 내지 15중량%의 양으로 함유함을 특징으로 하는 유리 섬유 피복 조성물.
  2. 제1항에 있어서, 상기 고무 라텍스(B)가 부타디엔/스티렌 공중합체 라텍스, 디카르복실화 부타디엔/스테린 공중합체 라텍스, 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스, 클로로술폰화 폴리에틸렌 라텍스, 및 아클릴로니트릴/부타디엔 공중합체 라텍스로 구성된 군에서 선택되는 1종 이상임을 특징으로 하는 유리 섬유 피복 조성물.
  3. 제2항에 있어서, 상기 고무 라텍스(B)가 피닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스와 클로로술폰화 폴리에틸렌 라텍스의 혼합물임을 특징으로 하는 유리 섬유 피복 조성물.
  4. 요오드가가 120 이하인 니트릴기 함유 고포화 중합체 고무 라텍스(A), 상기 고포화 중합체 고무 라텍스 이외의 고무 라텍스(B), 및 수용성 레조르시놀/포름알데히드 축합물을 각각 고형분 중량비로서 15 내지 80중량%, 5 내지 70중량% 및 2 내지 15중량%의 양으로 함유하는 처리제로 피복됨을 특징으로 하는 고무 보강용 유리 섬유.
  5. 제4항에 있어서, 상기 고무 라텍스(B)가 부타디엔/스티렌 공중합체 라텍스, 디카르복실화 부타디엔/스티렌 공중합체 라텍스, 비닐피리딘/부타디엔/스티렌 상원공중합체 라텍스, 클로로술폰화 폴리에틸렌 라텍스, 및 아크릴로니트릴/부타디엔 공중합체 라텍스로 구성된 군에서 선택된는 1종 이상임을 특징으로 하는 고무 보강용 유리 섬유.
  6. 제4항에 있어서, 상기 고무 라텍스(B)가 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스와 클로로술폰화 폴리에틸렌 라텍스의 혼합물임을 특징으로 하는 고무 보강용 유리 섬유.
  7. 요오드가가 120 이하인 니트릴기 함유 고포화 중합체 고무 라텍스(A), 상기 고포화 중합체 고무 라텍스 이외의 고무 라텍스(B), 및 수용성 레조르시놀/포름알데히드 축합물을 각각 고형분 중량비로서 15 내지 80중량%, 5 내지 70중량% 및 2 내지 15중량%의 양으로 함유하는 처리제로 피복되고, 또한 할로겐 함유 중합체계 접착제 용액으로 더욱 피복됨을 특징으로 하는 고무 보강용 유리 섬유.
  8. 제7항에 있어서, 상기 고무 라텍스(B)가 부타디엔/스티렌 공중합체 라텍스, 디카르복실화 부타디엔/스티렌 공중합체 라텍스, 비닐피리딘/부타디엔/스티렌 상원공중합체 라텍스, 클로로술폰화 폴리에틸렌 라텍스, 및 아클릴로니트릴/부타디엔 공중합체 라텍스로 구성된 군에서 선택되는 1종 이상임을 특징으로 하는 고무 보강용 유리 섬유.
  9. 제7항에 있어서, 상기 고무 라텍스(B)가 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스와 클로로술폰화 폴리에틸렌 라텍스의 혼합물임을 특징으로 하는 고무 보강용 유리 섬유.
  10. 요오드가가 120 이하인 니트릴기 함유 고포화 중합체 고무 라텍스(A), 상기 고포화 중합체 고무 라텍스 이외의 고무 라텍스(B), 및 수용성 레조르시놀/포름알데히드 축합물을 각각 고형분 중량비로서 15 내지 80중량%, 5 내지 70중합체 및 2 내지 15중량%의 양으로 함유하는 처리제로 피복된 유리 섬유를 사용하여 만들어진 고무 제품.
  11. 제10항에 있어서, 상기 고무 라텍스(B)가 부타디엔/스티렌 공중합체 라텍스, 디카르복실화 부타디엔/스티렌 공중합체 라텍스, 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스, 클로로술폰화 폴리에틸렌 라텍스, 및 아클릴로니트릴/부타디엔 공중합체 라텍스로 구성된 군에서 선택되는 1종 이상임을 특징으로 하는 고무 제품.
  12. 제10항에 있어서, 상기 고무 라텍스(B)가 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스와 클로로술폰화 폴리에틸렌 라텍스의 혼합물임을 특징으로 하는 고무 제품.
  13. 제10항, 제11항 또는 제12항에 있어서, 상기 고무 제품이 톱니형 벨트임을 특징으로 하는 고무 제품.
  14. 제10항, 제11항 또는 제12항에 있어서, 상기 고무 제품이 고무 타이어임을 특징으로 하는 고무 제품.
  15. 요오드가가 120 이하인 니트릴기 함유 고포화 중합체 고무 라텍스(A), 상기 고포화 중합체 고무 라텍스 이외의 고무 라텍스(B), 및 수용성 레조르시놀/포름알데히드 축합물을 각각 고형분 중량비로서 15 내지 80중량%, 5 내지 70중량% 및 2 내지 15중량%의 양으로 함유하는 처리제로 피복되고 또한 할로겐 함유 중합체계 접착제 용액으로 더욱 피복된 유리 섬유를 사용하여 만들어진 고무 제품.
  16. 제15항에 있어서, 상기 고무 라텍스(B)가 부타디엔/스티렌 공중합체 라텍스, 디카르복실화 부타디엔/스티렌 공중합체 라텍스, 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스, 클로로술폰화 폴리에틸렌 라텍스, 및 아클릴로니트릴/부타디엔 공중합체 라텍스로 구성된 군에서 선택되는 1종 이상임을 특징으로 하는 고무 제품.
  17. 제15항에 있어서, 상기 고무 라텍스(B)가 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스와 클로로술폰화 폴리에틸렌 라텍스의 혼합물임을 특징으로 하는 고무 제품.
  18. 제15항, 제16항 또는 제17항에 있어서, 상기 고무 제품이 톱니형 벨트임을 특징으로 하는 고무 제품.
  19. 제15항, 제16항 또는 제17항에 있어서, 상기 고무 제품이 고무 타이어임을 특징으로 하는 고무 제품.
  20. 요오드가가 120 이하인 니트릴기 함유 고포화 중합체 고무 라텍스(A), 상기 고포화 중합체 고무 라텍스 이외의 고무 라텍스(B), 및 수용성 레조르시놀/포름알데히드 축합물을 각각 고형분 중량비로서 15 내지 80중량%, 5 내지 70중량% 및 2 내지 15중량%의 양으로 함유하는 처리제로 고무 보강용 유리 섬유를 피복 처리함을 특징으로 하는 고무 보강용 유리 섬유의 피복 처리 방법.
  21. 제20항에 있어서, 상기 고무 라텍스(B)가 부타디엔/스티렌 공중합체 라텍스, 디카르복실화 부타디엔/스티렌 공중합체 라텍스, 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스, 클로로술폰화 폴리에틸렌 라텍스, 및 아클릴로니트릴/부타디엔 공중합체 라텍스로 구성된 군에서 선택되는 1종 이상임을 특징으로 하는 고무 보강용 유리 섬유의 피복 처리 방법.
  22. 제20항에 있어서, 상기 고무 라텍스(B)가 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스와 클로로술폰화 폴리에틸렌 라텍스의 혼합물임을 특징으로 하는 고무 보강용 유리 섬유의 피복 처리 방법.
  23. 요오드가가 120 이하인 니틀릴기 함유 고포화 중합체 고무 라텍스(A), 상기 고포화 중합체 고무 라텍스 이외의 고무 라텍스(B), 및 수용성 레조르시놀/포름알데히드 축합물을 각각 고형분 중량비로서 15 내지 80중량%, 5 내지 70중량% 및 2 내지 15중량%의 양으로 함유하는 처리제로 고무 보강용 유리 섬유를 피복 처리한후, 또한 할로겐 함유 중합체계 접착제 용액으로 더욱 피복 처리함을 특징으로 하는 고무 보강용 유리 섬유의 피복 처리 방법.
  24. 제23항에 있어서, 상기 고무 라텍스(B)가 부타디엔/스티렌 공중합체 라텍스, 디카르복실화 부타디엔/스티렌 공중합체 라텍스, 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스, 클로로술폰화 폴리에틸렌 라텍스, 및 아클릴로니트릴/부타디엔 공중합체 라텍스로 구성된 군에서 선택되는 1종 이상임을 특징으로 하는 고무 보강용 유리 섬유의 피복 처리 방법.
  25. 제23항에 있어서, 상기 고무 라텍스(B)가 비닐피리딘/부타디엔/스티렌 삼원공중합체 라텍스와 클로로술폰화 폴리에틸렌 라텍스의 혼합물임을 특징으로 하는 고무 보강용 유리 섬유의 피복 처리 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940702427A 1992-12-01 1993-11-29 고무 보강용 유리섬유 KR0160183B1 (ko)

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JP92-321504 1992-12-01
JP32150492 1992-12-01
PCT/JP1993/001731 WO1994012443A1 (en) 1992-12-01 1993-11-29 Glass fiber for rubber reinforcement

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KR0160183B1 KR0160183B1 (ko) 1998-11-16

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JP3754132B2 (ja) * 1996-07-09 2006-03-08 日本板硝子株式会社 ゴム補強用繊維処理剤、補強用繊維、およびゴム補強物
JP3427714B2 (ja) * 1998-01-23 2003-07-22 日本板硝子株式会社 ゴム補強用ガラス繊維コード
US6132870A (en) * 1998-03-27 2000-10-17 Lord Corporation Reinforced composite and adhesive
JP2003253569A (ja) * 2002-02-27 2003-09-10 Nippon Sheet Glass Co Ltd ゴム補強用ガラス繊維処理剤、それを用いたゴム補強用コードおよびゴム製品
US20050158531A1 (en) * 2002-02-27 2005-07-21 Nippon Sheet Glass Company, Limited Rubber-reinforcing glass fiber treatment agent, rubber-reinforcing cord using the fiber treatment agent, and rubber product
JP2003268678A (ja) * 2002-03-14 2003-09-25 Nippon Sheet Glass Co Ltd ゴム補強用ガラス繊維処理剤、それを用いたゴム補強用コードおよびゴム製品
EP1371618B1 (en) * 2002-06-14 2014-01-22 OCV Intellectual Capital, LLC Fiber for reinforcing rubber products and process for its production
JP2005009010A (ja) 2003-06-18 2005-01-13 Asahi Fiber Glass Co Ltd ゴム製品の補強用繊維
JP4354791B2 (ja) * 2003-12-12 2009-10-28 オーシーヴィー インテレクチュアル キャピタル エルエルシー ゴム製品の補強用繊維
US20080107913A1 (en) * 2004-03-30 2008-05-08 Nippon Sheet Glass Company, Limited Composition for Cord Coating, Cord for Rubber Reinforcement Made with the Same, and Rubber Product Made with the Same
EP1818443A4 (en) * 2004-11-11 2009-06-10 Nippon Sheet Glass Co Ltd RUBBER SHRIMP SCORD, METHOD OF MANUFACTURING THEREFOR AND SOFTENING SUBSTANCE BASED ON IT
JP6000124B2 (ja) 2009-11-24 2016-09-28 オムノバ ソリューソンズ インコーポレーティッド 窒素含有モノマーを含むビニルピリジンラテックスポリマーを含むゴム接着剤組成物
JP5816397B2 (ja) * 2011-04-26 2015-11-18 住友精化株式会社 クロロスルホン化ポリエチレンゴムラテックス
TWI778447B (zh) * 2019-11-07 2022-09-21 墨西哥商帝納梭艾拉托梅羅斯公司 經改質二烯共聚物及其用途

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US5077127A (en) * 1987-03-31 1991-12-31 Nippon Zeon Co., Ltd. Adhesive for bonding rubber to fibers
JP2752744B2 (ja) * 1989-11-27 1998-05-18 日本硝子繊維株式会社 ゴム補強用繊維の処理剤
JPH0725898B2 (ja) * 1990-08-24 1995-03-22 本田技研工業株式会社 ゴムの補強用織維
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KR0160183B1 (ko) 1998-11-16
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DE69310717T2 (de) 1997-09-04
EP0624557B1 (en) 1997-05-14
EP0624557A1 (en) 1994-11-17
US5885718A (en) 1999-03-23
WO1994012443A1 (en) 1994-06-09
US6468654B1 (en) 2002-10-22
US5523154A (en) 1996-06-04

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