KR930016140A - 미세캡슐, 그의 제조방법과 그의 용도 - Google Patents
미세캡슐, 그의 제조방법과 그의 용도 Download PDFInfo
- Publication number
- KR930016140A KR930016140A KR1019920027601A KR920027601A KR930016140A KR 930016140 A KR930016140 A KR 930016140A KR 1019920027601 A KR1019920027601 A KR 1019920027601A KR 920027601 A KR920027601 A KR 920027601A KR 930016140 A KR930016140 A KR 930016140A
- Authority
- KR
- South Korea
- Prior art keywords
- water
- salt
- styrene
- maleic anhydride
- anhydride copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003094 microcapsule Substances 0.000 title claims abstract 8
- 238000002360 preparation method Methods 0.000 title claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 13
- 239000000463 material Substances 0.000 claims abstract 12
- 150000003839 salts Chemical class 0.000 claims abstract 11
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims abstract 10
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims abstract 10
- 239000002775 capsule Substances 0.000 claims abstract 10
- 150000002148 esters Chemical class 0.000 claims abstract 10
- 239000000203 mixture Substances 0.000 claims abstract 8
- 239000007787 solid Substances 0.000 claims abstract 7
- 239000007900 aqueous suspension Substances 0.000 claims abstract 5
- 239000000126 substance Substances 0.000 claims abstract 5
- 239000012736 aqueous medium Substances 0.000 claims abstract 3
- 229920000642 polymer Polymers 0.000 claims abstract 3
- 239000004094 surface-active agent Substances 0.000 claims abstract 3
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims 13
- 239000000575 pesticide Substances 0.000 claims 8
- ZDOOQPFIGYHZFV-ROUUACIJSA-N (2s,4s)-2-ethyl-4-[(4-phenoxyphenoxy)methyl]-1,3-dioxolane Chemical compound O1[C@@H](CC)OC[C@@H]1COC(C=C1)=CC=C1OC1=CC=CC=C1 ZDOOQPFIGYHZFV-ROUUACIJSA-N 0.000 claims 2
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 229920002396 Polyurea Polymers 0.000 claims 2
- 239000005822 Propiconazole Substances 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 2
- 150000003863 ammonium salts Chemical group 0.000 claims 2
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 claims 2
- 239000005648 plant growth regulator Substances 0.000 claims 2
- 229920000768 polyamine Polymers 0.000 claims 2
- 229920001228 polyisocyanate Polymers 0.000 claims 2
- 239000005056 polyisocyanate Substances 0.000 claims 2
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 claims 1
- 230000000895 acaricidal effect Effects 0.000 claims 1
- 239000000642 acaricide Substances 0.000 claims 1
- 239000003905 agrochemical Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 235000011114 ammonium hydroxide Nutrition 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000004985 diamines Chemical class 0.000 claims 1
- 239000003974 emollient agent Substances 0.000 claims 1
- 239000000417 fungicide Substances 0.000 claims 1
- 239000004009 herbicide Substances 0.000 claims 1
- 239000002917 insecticide Substances 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 159000000003 magnesium salts Chemical class 0.000 claims 1
- 239000005645 nematicide Substances 0.000 claims 1
- 239000007764 o/w emulsion Substances 0.000 claims 1
- 230000003071 parasitic effect Effects 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical class 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract 2
- 239000008346 aqueous phase Substances 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000003205 fragrance Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Medicinal Preparation (AREA)
- Formation And Processing Of Food Products (AREA)
- Catching Or Destruction (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81802992A | 1992-01-03 | 1992-01-03 | |
| US07/818,0290 | 1992-01-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR930016140A true KR930016140A (ko) | 1993-08-26 |
Family
ID=25224465
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019920027601A Withdrawn KR930016140A (ko) | 1992-01-03 | 1992-12-30 | 미세캡슐, 그의 제조방법과 그의 용도 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5310721A (https=) |
| EP (1) | EP0551796B1 (https=) |
| JP (1) | JPH05269367A (https=) |
| KR (1) | KR930016140A (https=) |
| AT (1) | ATE156728T1 (https=) |
| AU (1) | AU651511B2 (https=) |
| BR (1) | BR9205208A (https=) |
| CA (1) | CA2086583A1 (https=) |
| DE (1) | DE69221601T2 (https=) |
| DK (1) | DK0551796T3 (https=) |
| HU (1) | HUT65767A (https=) |
| IL (1) | IL104286A (https=) |
| MX (1) | MX9207569A (https=) |
| RU (1) | RU2089062C1 (https=) |
| TW (1) | TW273499B (https=) |
| ZA (1) | ZA9210100B (https=) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5958463A (en) * | 1991-07-29 | 1999-09-28 | Agri-Tek, Inc. | Agricultural pesticide formulations |
| IL110662A0 (en) * | 1993-08-23 | 1994-11-11 | Ciba Geigy Ag Ciba Geigy Ag | Process for the manufacture of phenoxyphenoxyalkyl derivatives |
| MX245101B (es) | 1994-11-16 | 2007-04-19 | Fmc Corp | Formulaciones de clomazone de baja volatilidad. |
| US5705174A (en) * | 1995-06-07 | 1998-01-06 | American Cyanamid Company | Process for the preparation of microcapsule compositions |
| WO1997023133A1 (en) * | 1995-12-21 | 1997-07-03 | Basf Corporation | Low rate application of inhibitors of ethylene biosynthesis or action |
| CA2193714A1 (en) * | 1995-12-21 | 1997-06-22 | Wilhelm Rademacher | Encapsulated plant growth regulator formulations and applications |
| WO1997022252A1 (en) * | 1995-12-21 | 1997-06-26 | Basf Corporation | Aminoethoxyvinylglycine in combination with mepiquat chloride |
| US5837653A (en) * | 1995-12-21 | 1998-11-17 | Basf Corporation | Encapsulated plant growth regulator formulations |
| US5843203A (en) * | 1996-03-22 | 1998-12-01 | Grantek, Inc. | Agricultural carrier |
| ZA974359B (en) * | 1996-05-23 | 1998-05-12 | Zeneca Ltd | Microencapsulated compositions. |
| GB9615158D0 (en) * | 1996-07-19 | 1996-09-04 | Dowelanco | Process for preparing storage-stable pesticide dispersion |
| DE19646880A1 (de) * | 1996-11-13 | 1998-05-14 | Hoechst Schering Agrevo Gmbh | Endosulfan-Mikrokapseldispersion |
| AU5727498A (en) | 1996-12-20 | 1998-07-17 | Basf Corporation | Plant growth regulators in pyrrolidone solvents |
| WO2000010392A1 (en) * | 1998-08-18 | 2000-03-02 | Fmc Corporation | Combination of two or more active ingredients using microencapsulated formulations |
| KR100598211B1 (ko) * | 1998-11-12 | 2006-07-07 | 에프엠씨 코포레이션 | 미세캡슐화된 배합물의 신규한 제조 방법 |
| US6218339B1 (en) * | 1999-03-18 | 2001-04-17 | Fmc Corporation | Microencapsulated clomazone in the presence of fat and resin |
| AU778192B2 (en) | 1999-11-12 | 2004-11-18 | M-I L.L.C. | Method and composition for the triggered release of polymer-degrading agents for oil field use |
| US6818594B1 (en) | 1999-11-12 | 2004-11-16 | M-I L.L.C. | Method for the triggered release of polymer-degrading agents for oil field use |
| DE10022989A1 (de) † | 2000-05-11 | 2001-11-22 | Aventis Cropscience Gmbh | Kombinationen von Pflanzenschutzmitteln mit organischen oder anorganischen Trägermaterialien |
| ES2251487T3 (es) | 2000-06-05 | 2006-05-01 | Syngenta Limited | Nuevas emulsiones. |
| CA2311194A1 (en) * | 2000-06-12 | 2001-12-12 | Anna Shulkin | Encapsulation process using anhydride moieties |
| CA2311192A1 (en) * | 2000-06-12 | 2001-12-12 | Harald D. H. Stover | Encapsulation process using isocyanate moieties |
| JP2004503513A (ja) * | 2000-06-12 | 2004-02-05 | 呉羽化学工業株式会社 | マイクロカプセル懸濁液およびその方法 |
| DE10117784A1 (de) * | 2001-04-10 | 2002-10-17 | Bayer Ag | Mikrokapseln |
| US6992047B2 (en) * | 2001-04-11 | 2006-01-31 | Monsanto Technology Llc | Method of microencapsulating an agricultural active having a high melting point and uses for such materials |
| US6719053B2 (en) | 2001-04-30 | 2004-04-13 | Bj Services Company | Ester/monoester copolymer compositions and methods of preparing and using same |
| KR100425549B1 (ko) * | 2001-06-14 | 2004-04-03 | 주식회사 마이크로폴 | 마이크로캡슐을 이용한 훈증기용 패드 및 그 제조방법 |
| PT1524902E (pt) * | 2002-07-22 | 2007-03-30 | Basf Corp | Métodos de utilizar compostos de dinitroanilina na forma de formulações de microcapsula |
| AU2003297683A1 (en) * | 2002-12-13 | 2004-07-09 | Monsanto Technology Llc | Microcapsules with amine adjusted release rates |
| US9079152B2 (en) * | 2003-05-11 | 2015-07-14 | Ben Gurion University Of The Negev Research And Development Authority | Encapsulated essential oils |
| US7101617B2 (en) * | 2003-07-10 | 2006-09-05 | Motorola, Inc. | Silicone dispensing with a conformal film |
| BRPI0512102A (pt) * | 2004-06-14 | 2008-02-06 | Monsanto Technology Llc | microcápsulas tendo liberação ativada de material de núcleo dentro delas |
| MY146405A (en) | 2005-03-01 | 2012-08-15 | Basf Ag | Fast-release microcapsule products |
| CN101272849A (zh) * | 2005-09-23 | 2008-09-24 | 巴斯夫欧洲公司 | 新型农用化学品配制剂 |
| CN101557705B (zh) | 2006-11-30 | 2015-01-07 | 巴斯夫欧洲公司 | 包含基于烯属不饱和二羧酸单酯和二酯的共聚物的农业化学配制剂 |
| JP5323715B2 (ja) | 2006-11-30 | 2013-10-23 | ビーエーエスエフ ソシエタス・ヨーロピア | 1−ビニル−2−ピロリジノンコポリマーを含む農薬製剤 |
| CN102112219A (zh) * | 2008-07-31 | 2011-06-29 | 溶胶凝胶技术公司 | 包含有效成分和金属氧化物壳的微胶囊,其制备方法及其用途 |
| AU2009329535B2 (en) | 2008-12-19 | 2015-08-13 | Basf Se | Aqueous flowable concentrate compositions of a microencapsulated dinitroaniline herbicide |
| RU2420350C2 (ru) * | 2009-02-09 | 2011-06-10 | Общество С Ограниченной Ответственностью "Делси" | Микрокапсулы, содержащие воду или водный раствор, (варианты) и способы их получения (варианты) |
| EP2395843B1 (en) | 2009-02-13 | 2017-08-09 | Monsanto Technology LLC | Encapsulation of herbicides to reduce crop injury |
| HUE030498T2 (en) | 2009-03-20 | 2017-05-29 | Basf Se | A method of treating sowing with an encapsulated pesticide |
| UA107670C2 (en) * | 2009-08-07 | 2015-02-10 | Dow Agrosciences Llc | Meso-sized capsules useful for the delivery of agricultural chemicals |
| PE20130566A1 (es) | 2010-01-22 | 2013-04-28 | Basf Se | Un metodo para controlar artropodos, que comprende la aplicacion de un gel en forma de manchas |
| AU2011212201B2 (en) * | 2010-02-03 | 2014-09-25 | Upl Limited | An improved formulation |
| US9913469B2 (en) | 2010-08-18 | 2018-03-13 | Monsanto Technology Llc | Early applications of encapsulated acetamides for reduced injury in crops |
| WO2012130823A1 (en) | 2011-03-30 | 2012-10-04 | Basf Se | Suspension concentrates |
| IN2014CN00795A (https=) | 2011-08-19 | 2015-04-03 | Basf Se | |
| US9801377B2 (en) | 2012-07-27 | 2017-10-31 | Fmc Corporation | Formulations of clomazone |
| GB2496330B (en) * | 2013-01-21 | 2016-06-29 | Rotam Agrochem Int Co Ltd | Preparation of an agrochemical active composition encapsulated in cross linked polyurea |
| US9364422B2 (en) | 2013-12-19 | 2016-06-14 | Avon Products, Inc | Styrene maleic anhydride polymers in cosmetics and personal care products |
| CA3181871A1 (en) | 2014-01-27 | 2015-07-30 | Monsanto Technology Llc | Aqueous herbicidal concentrates comprising an acetanilide herbicide, a protoporphyrinogen oxidase inhibitor, and a pseudoplastic thickener |
| WO2015167988A1 (en) | 2014-04-28 | 2015-11-05 | Basf Se | Method of forming an encapsulated fertilizer |
| MX2019015014A (es) | 2017-06-13 | 2020-02-26 | Monsanto Technology Llc | Herbicidas microencapsulados. |
| EP3651756B1 (en) | 2017-07-12 | 2025-09-03 | Sol-Gel Technologies Ltd. | Compositions comprising encapsulated tretinoin |
| UA129154C2 (uk) | 2019-01-30 | 2025-01-29 | Монсанто Текнолоджі Ллс | Мікрокапсульовані ацетамідні гербіциди |
| JP7692268B2 (ja) * | 2020-02-03 | 2025-06-13 | 日本化薬株式会社 | マイクロカプセル農薬組成物 |
| EP4056038A1 (en) * | 2021-03-10 | 2022-09-14 | Basf Se | Microparticles containing active substances |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3577515A (en) * | 1963-12-13 | 1971-05-04 | Pennwalt Corp | Encapsulation by interfacial polycondensation |
| JPS602100B2 (ja) * | 1977-09-28 | 1985-01-19 | 三菱製紙株式会社 | 微小カプセルの製造方法 |
| US4280833A (en) * | 1979-03-26 | 1981-07-28 | Monsanto Company | Encapsulation by interfacial polycondensation, and aqueous herbicidal composition containing microcapsules produced thereby |
| JPS59177129A (ja) * | 1983-03-25 | 1984-10-06 | Mitsubishi Paper Mills Ltd | 微小カプセルの製法 |
| US4563212A (en) * | 1983-12-27 | 1986-01-07 | Monsanto Company | High concentration encapsulation by interfacial polycondensation |
| US4601863A (en) * | 1984-02-09 | 1986-07-22 | Kanzaki Paper Manufacturing Co., Ltd. | Process for producing powder of microcapsules |
| US4630079A (en) * | 1984-04-21 | 1986-12-16 | Mitsubishi Paper Mills, Ltd. | Pressure sensitive copying paper |
| US4640709A (en) * | 1984-06-12 | 1987-02-03 | Monsanto Company | High concentration encapsulation by interfacial polycondensation |
| ATE77916T1 (de) * | 1985-09-13 | 1992-07-15 | Ciba Geigy Ag | Verfahren zur herstellung von mikrokapseln. |
| US4681806A (en) * | 1986-02-13 | 1987-07-21 | Minnesota Mining And Manufacturing Company | Particles containing releasable fill material and method of making same |
| FR2610537A1 (fr) * | 1987-02-11 | 1988-08-12 | Rhone Poulenc Chimie | Procede ameliore de microencapsulation par polyaddition interfaciale |
| DE69027717T2 (de) * | 1989-08-11 | 1996-11-28 | Fuji Photo Film Co Ltd | Licht- und wärmeempfindliches Aufzeichnungsmaterial |
-
1992
- 1992-12-22 DK DK92811017.0T patent/DK0551796T3/da active
- 1992-12-22 DE DE69221601T patent/DE69221601T2/de not_active Expired - Fee Related
- 1992-12-22 AT AT92811017T patent/ATE156728T1/de not_active IP Right Cessation
- 1992-12-22 EP EP92811017A patent/EP0551796B1/en not_active Expired - Lifetime
- 1992-12-24 TW TW081110341A patent/TW273499B/zh active
- 1992-12-24 MX MX9207569A patent/MX9207569A/es not_active IP Right Cessation
- 1992-12-30 BR BR9205208A patent/BR9205208A/pt not_active Application Discontinuation
- 1992-12-30 KR KR1019920027601A patent/KR930016140A/ko not_active Withdrawn
- 1992-12-30 HU HU9204183A patent/HUT65767A/hu unknown
- 1992-12-30 ZA ZA9210100A patent/ZA9210100B/xx unknown
- 1992-12-30 AU AU30465/92A patent/AU651511B2/en not_active Ceased
- 1992-12-30 RU RU9292016247A patent/RU2089062C1/ru active
- 1992-12-31 IL IL10428692A patent/IL104286A/en not_active IP Right Cessation
- 1992-12-31 CA CA002086583A patent/CA2086583A1/en not_active Abandoned
-
1993
- 1993-01-04 JP JP5015828A patent/JPH05269367A/ja active Pending
- 1993-04-27 US US08/052,510 patent/US5310721A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| HU9204183D0 (en) | 1993-04-28 |
| EP0551796A3 (en) | 1993-08-11 |
| IL104286A (en) | 1996-10-31 |
| ZA9210100B (en) | 1996-03-06 |
| IL104286A0 (en) | 1993-05-13 |
| TW273499B (https=) | 1996-04-01 |
| DE69221601D1 (de) | 1997-09-18 |
| DK0551796T3 (da) | 1998-03-23 |
| DE69221601T2 (de) | 1998-01-15 |
| ATE156728T1 (de) | 1997-08-15 |
| JPH05269367A (ja) | 1993-10-19 |
| BR9205208A (pt) | 1993-07-06 |
| EP0551796B1 (en) | 1997-08-13 |
| HUT65767A (en) | 1994-07-28 |
| MX9207569A (es) | 1993-07-01 |
| EP0551796A2 (en) | 1993-07-21 |
| AU3046592A (en) | 1993-07-08 |
| US5310721A (en) | 1994-05-10 |
| AU651511B2 (en) | 1994-07-21 |
| CA2086583A1 (en) | 1993-07-04 |
| RU2089062C1 (ru) | 1997-09-10 |
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