KR920702912A - 고분자 전해질 착제 항균제 및 항균성 재료 - Google Patents
고분자 전해질 착제 항균제 및 항균성 재료Info
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- KR920702912A KR920702912A KR1019920701786A KR920701786A KR920702912A KR 920702912 A KR920702912 A KR 920702912A KR 1019920701786 A KR1019920701786 A KR 1019920701786A KR 920701786 A KR920701786 A KR 920701786A KR 920702912 A KR920702912 A KR 920702912A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
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- A—HUMAN NECESSITIES
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
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- A—HUMAN NECESSITIES
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
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- A—HUMAN NECESSITIES
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- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/0226—Quaternisation of polyalkylene(poly)amines
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- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/026—Wholly aromatic polyamines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/028—Polyamidoamines
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/246—Intercrosslinking of at least two polymers
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- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2203/00—Applications
- C08L2203/02—Applications for biomedical use
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
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Abstract
내용 없음
Description
고분자 전해질 착제 항균제 및 항균성 재료
[도면의 간단한 설명]
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (11)
- 반복 단위중에 N+원자를 함유한 양이온 중합체와 반복 단위중에 -COO- 기, -SO3- 기 또는 -PO3- 기를 합유한 음이온 중합체를 반응시킴으로써 수득되는 고분자 전해질 착체를 함유하는 것을 특징으로 하는 항균제.
- 제1항에 있어서, 양이온 중합체의 양이온 자리와 중합체의 음이온 자리의 농도비(양이온 자리/옴이온 자리)가 0.25 내지 4.0인 항균제.
- 제1항에 있어서, 양이온 중합체로서, (al)하기 일반식(I)로 표시되는 화합물. (a2)하기 일반식(II)로 표시되는 화합물, (a3)하기 일반식(III)으로 표시되는 화합물, 및 (a4)양이온성 다당류로 이루어진 군으로부터 선택된 화합물 1종 이상을 사용하는 항균제:상기식에서, R1및 R4는 각각 독립적으로 탄소수 1 내지 10개의 알킬렌기, 일반식(여기서, R11및 R12는 각각 독립적으로 탄소수 1또는 2개의 알킬렌기이다)로 표시되는 기 또는 아릴렌기이고, R2, R3, R5및 R6는 각각 독립적으로 탄소수 1 내지 3개의 알킬기이거나, 또는 R1은 상기식중의 2개의 질소윈자 및 R2, R3, R5및 R6와 함께 일반식으로 표시되는 기를 형성하고, R4는 상기한 바와 같으며, X1 -는 쌍이온이고, m은 5이상의 수이며, A는 일반식(여기서, B는 탄소수 1 또는 2개의 알킬렌기이며, R21, R22및 R23은 각각 독립적으로 수소원자 또는 탄소수 1 내지 3개의 알킬기이고, X2 -는 쌍이온이다)로 표시되는 기이거나, 또는 일반식(여기서, R24는 탄소수 1 내지 3개의 알킬기 또는 벤질기이며, X3는 쌍이온이다)로 표시되는 기이거나, 또는 일반식(여기서, R25는 탄소수 1 또는 2개의 알킬기이며, R26, R27및 R28은 각각 독립적으로 수소원자 또는 탄소수 1 내지 3개의 알킬기이고, X4는 쌍이온이다)로 표시되는 기이며, n은 10이상의 수이고, v는 3 또는 4이며, R91은 수소원자; 탄소수 1 내지 4개의 알킬기; 하이드록시기. 머캅토기 또는 탄소수 1 내지 3개의 알킬티오기로 치환된 탄소수 1 내지 4개의 알킬기; 또는 이미다졸릴 메틸기 또는 인돌릴메틸기이고, R92,는 -N+H2X5 -또는 -N+HC(NH)NH2X6 -이며, X- 5및 X- 6는 각각 독립적으로 쌍이온이고, t는 20 내지 100이며, r은 10이상의 정수이다.
- 제1항에 있어서, 음이온 중합체로서, (b1)하기 일반식(IV)로 표시되는 화합물, (b2)하기 일반시(V)로 표시되는 화합물. 및 (b3)음이온성 다당류로 이루어진 군으로부터 선택된 화합물 1종 이상을 사용하는 항균제:상기식에서, u는 1 또는 2이고, R81은 수소윈자; 탄소수 1 내지 4개의 알킬기; 하이드록시기, 머캅토기 또는 탄소수 1 내지 3개의 알킬티오기로 치환된 탄소수 1 내지 4개의 알킬기 또는 이미다졸릴메틸기 또는 인돌릴메틸기이며; s는 20 내지 100이고, q는 10 이상의 정수이며, R31은 수소원자 또는 메틸기이고, R32는 탄소수 6 내지 18개의 알킬기이며, Y는 카복실기 또는 그의 염, 설폰산기 또는 그의 염, 또는 설폰산기 또는 그의 염을 함유하는 아릴기이고, a는 20 내지 100의 수이며, p는 10 이상의 수이다.
- 제3항에 있어서, 상기 일반식(I)의 화합물중, R1및 R4가 각각 독립적으로 탄소수 2 내지 8개의 직쇄 또는 측쇄 알킬렌기이며, R11및 R12가 p위치에서 결합되어 있는 상기 일반식(I)로 표시되는 화합물(a1)을 사용하는 항균제.
- 제3항에 있어서, 상기 일반식(III)의 화합물중, R91이 수소원자, 메틸기, 이소프로필기, 이소부틸기, s-부틸기. 하이드록시메틸기, 하이드록시에틸기, 메틸티오에틸기, 머캅토메틸기, 5-이미다졸릴메틸기 또는 3-이미다졸릴메틸기인 상기 일반식(III)으로 표시되는 화합물(a3)를 사용하는 항균제.
- 제3항에 있어서, 양이온성 다당류(a4)로서, 키토산, 키토산의 유도체, 또는 중성 다당류의 디에틸아미노 에틸 유도체를 사용하는 항균제.
- 제4항에 있어서, 상기 일반식(IV)의 화합물중, R81이 수소원자, 메틸기, 이소프로필기, 이소부틸기, s-부틸기, 하이드록시메틸기. 하이드록시에틸기, 메틸티오에틸기, 머캅토메틸기, 5-이미다졸릴 메틸기 또는 3-이미다졸틸메틸기인 상기 일반식(IV)로 표시되는 화합물(b1)을 사용하는 항균제.
- 제4항에 있어서, 상기 일반식(V)의 화합물중, R32가 탄소수 6 내지 14개의 직쇄 또는 측쇄 알킬기이며, a가 50 내지 100인 상기 일반식(V)로 표시되는 화합물(b2)을 사용하는 항균제.
- 제4항에 있어서, 음이온성 다당류로서, 히알루론산 및 그의 유도체, 아르긴산 및 그의 유도체, 콘드로이틴 황산 A, 콘드로이틴 황산 C, 콘드로이틴 황산 B(델마탄황산) 및 그의 유도체, 콘드로이틴 황산 D 및 그의 유도체, 콘드로이틴 황산 E 및 그의 유도체 헤파란 황산 및 그의 유도체, 헤파린 및 그의 유도체 k-카라게난 및 그의 유도체, λ-카라게난 및 그의 유도체, 카복시메틸화. 황산화 또는 인산화된 셀룰로오스 유도체, 카복시메틸화, 황산화 또는 인산화된 키틴 유도체, 카복시메틸 전분 및 그의 유도체, 카복시메틸화, 황산화 또는 인산화된 아밀로오스 유도체, 카복시메틸화, 황산화 또는 인산화된 아밀로펙틴 유도체, 카복시메틸화, 황산화 또는 인산화된 β-1,3'-글루칸 유도체, 카복시메틸화, 황산화 또는 인산화된 β-1,2'-글루칸유도체. 카복시메틸화, 황산화 또는 인산화된 β-1,3', β-1,6'-글루칸유도체, 카복시메틸화, 황산화 또는 인산화된 덱스트란유도체, 카복시메틸화. 황산화 또는 인산화된 플루란유도체, 카복시메틸화, 황산화 또는 인산화된 아가로오스유도체, 카복시메틸화. 황산화 또는 인산화된 β-1,4'-갈락탄유도체, 카복시메틸화, 황산화 또는 인산화된 만난유도체, 및 카복시메틸화, 황산화 또는 인산화된 이누린유도체로 이루어진 군으로 부터 선택된 음이온성다당류(b3) 1종 이상을 사용하는 항균제.
- 제1항 내지 제10항중 어느 한 항에 기재된 고분자 전해질 착체를 담체상에 담지시키는 것을 특징으로 하는 항균재료.※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP90-325405 | 1990-11-29 | ||
JP32540690 | 1990-11-29 | ||
JP32540590 | 1990-11-29 | ||
JP90-325406 | 1990-11-29 | ||
JP30685791A JPH05117106A (ja) | 1991-10-26 | 1991-10-26 | 高分子電解質錯体抗菌剤及び抗菌性材料 |
JP30685891A JPH05117111A (ja) | 1991-10-26 | 1991-10-26 | 高分子電解質錯体抗菌剤及び抗菌性材料 |
JP91-306858 | 1991-10-26 | ||
JP91-306857 | 1991-10-26 | ||
PCT/JP1991/001639 WO1992009198A1 (en) | 1990-11-29 | 1991-11-28 | Polyelectrolyte complex antibacterial agent and antibacterial material |
Publications (1)
Publication Number | Publication Date |
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KR920702912A true KR920702912A (ko) | 1992-12-17 |
Family
ID=27479925
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019920701786A KR920702912A (ko) | 1990-11-29 | 1991-11-28 | 고분자 전해질 착제 항균제 및 항균성 재료 |
Country Status (8)
Country | Link |
---|---|
US (2) | US5578598A (ko) |
EP (1) | EP0528035B1 (ko) |
KR (1) | KR920702912A (ko) |
AU (1) | AU655445B2 (ko) |
CA (1) | CA2074509A1 (ko) |
DE (1) | DE69126972T2 (ko) |
ES (1) | ES2106093T3 (ko) |
WO (1) | WO1992009198A1 (ko) |
Families Citing this family (61)
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US9642360B2 (en) * | 2015-06-25 | 2017-05-09 | International Business Machines Corporation | Antimicrobial polymers formed by bulk polyaddition |
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JP7031890B2 (ja) | 2016-07-28 | 2022-03-08 | イクシオン ラブス インコーポレイテッド | ポリマーベースの抗菌性組成物及びその使用方法 |
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TWI725542B (zh) * | 2018-09-25 | 2021-04-21 | 日商東洋紡股份有限公司 | 水分散性之微粒子、抗微生物劑及生物膜去除劑 |
CN112521597B (zh) * | 2020-11-25 | 2021-08-20 | 吉林大学 | 一种含有巯基的聚芳醚化合物及其制备方法和应用、抗菌超滤膜及其制备方法 |
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US5260002A (en) * | 1991-12-23 | 1993-11-09 | Vanderbilt University | Method and apparatus for producing uniform polymeric spheres |
-
1991
- 1991-11-28 KR KR1019920701786A patent/KR920702912A/ko not_active Application Discontinuation
- 1991-11-28 ES ES91920778T patent/ES2106093T3/es not_active Expired - Lifetime
- 1991-11-28 DE DE69126972T patent/DE69126972T2/de not_active Expired - Lifetime
- 1991-11-28 AU AU89319/91A patent/AU655445B2/en not_active Ceased
- 1991-11-28 WO PCT/JP1991/001639 patent/WO1992009198A1/ja active IP Right Grant
- 1991-11-28 EP EP19910920778 patent/EP0528035B1/en not_active Expired - Lifetime
- 1991-11-28 CA CA 2074509 patent/CA2074509A1/en not_active Abandoned
-
1994
- 1994-10-03 US US08/317,288 patent/US5578598A/en not_active Expired - Lifetime
-
1995
- 1995-08-25 US US08/519,298 patent/US5658915A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0528035A1 (en) | 1993-02-24 |
DE69126972D1 (de) | 1997-09-04 |
EP0528035A4 (en) | 1993-03-10 |
ES2106093T3 (es) | 1997-11-01 |
US5658915A (en) | 1997-08-19 |
AU8931991A (en) | 1992-06-25 |
CA2074509A1 (en) | 1992-05-30 |
DE69126972T2 (de) | 1997-11-27 |
EP0528035B1 (en) | 1997-07-23 |
WO1992009198A1 (en) | 1992-06-11 |
AU655445B2 (en) | 1994-12-22 |
US5578598A (en) | 1996-11-26 |
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