KR920701376A - 폴리스티렌-폴리이소프렌-폴리스티렌 블록 공중합체, 고온-용융 접착제 조성물, 및 이로부터 제조된 제품 - Google Patents

폴리스티렌-폴리이소프렌-폴리스티렌 블록 공중합체, 고온-용융 접착제 조성물, 및 이로부터 제조된 제품

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Publication number
KR920701376A
KR920701376A KR1019910700348A KR910700348A KR920701376A KR 920701376 A KR920701376 A KR 920701376A KR 1019910700348 A KR1019910700348 A KR 1019910700348A KR 910700348 A KR910700348 A KR 910700348A KR 920701376 A KR920701376 A KR 920701376A
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hot
melt adhesive
weight
adhesive composition
component
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KR1019910700348A
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English (en)
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KR0150188B1 (ko
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에프. 디일 찰스
오. 마이어스 마이클
엠. 탕크레드 진
Original Assignee
리차드 지. 워터맨
더 다우 케미칼 캄파니
벤 씨. 케이든헤드
엑손 케미칼 패턴츠 인코포레이티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/58—Adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/10—Polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00—Personal care
    • B32B2555/02—Diapers or napkins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y10T428/2817—Heat sealable
    • Y10T428/2826—Synthetic resin or polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
    • Y10T428/2883—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer of diene monomer [e.g., SBR, SIS, etc.]

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Hematology (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

폴리스티렌-폴리이소프렌-폴리스티렌 블록 공중합체, 고온-용융 접착제 조성물, 및 이로부터 제조된 제품
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. B성분이 평균분자량 30,000내지 70,000의 폴리이소프렌이고, A성분이 평균 분자량 12,000내지 20,000의 폴리스티렌이며, 블록 공중합체의 총 분자량이 60,000내지 110,000이고, A성분이 블록 공중합체 100중량부당 적어도 27내지 50부의 양으로 존재하는 A-B-A블록 공중합체를 함유하는, 고온-용융 접착제를 형성시키는데 유용한 물질의 조성물.
  2. 제1항에 있어서, A-B-A블록 공중합체의 B성분의 평균분자량이 35,000내지 60,000이고, A성분의 평균 분자량이 14,000내지 19,000이며, 공중합체의 총 분자량이 70,000내지 95,000이고, A성분이 공중합체 100중량부당 35내지 45부의 양으로 존재하는 조성물.
  3. 제1항에서 청구한 A-B-A블록 공중합체 15내지 35%(고온-용융 접착제 조성물 중량 기준), 상용성 일차 접착부여 수지 45내지 70%(고온-용융 접착제 조성물 중량 기준), 가소화 오일 또는 이차 점착부여 수지 0내지 30%(고온-용융 접착제 조성물 중량 기준) 및 안정화제 0.1내지 2%(고온-용융 접착제 조성물 중량 기준)를 함유하는 일회용 제품의 조립에 유용한 고온-용융 접착제 조성물.
  4. 제3항에 있어서, 고온-용융 접착제 조성물이 20내지 30%의 공중합체를 함유하는 조성물.
  5. 제3항에 있어서, 잡지 또는 책을 라이닝하는데 유용한 접착제 조성물을 형성시키기에 충분한 탄화수소왁스 약 5%이하(고온-용융 접착제 조성물 중량 기준)를 추가로 함유하는 조성물.
  6. 제1항에 있어서 청구한 A-B-A블록 공중합체 15내지 35%(고온-용융 접착제 조성물 중량 기준), 상용성 일차 접착부여 수지 45내지 70%(고온-용융 접착제 조성물 중량 기준), 가소화 오일 또는 이차 점착부여 수지 0내지 30%(고온-용융 접착제 조성물 중량 기준) 및 안정화제 0.1내지 2%(고온-용융 접착제 조성물 중량 기준)을 함유하는 고온-용융 접착제 조성물을 사용하여 티슈, 부직 폴리에틸렌 또는 폴리프로필렌 기질에 결합시킨 폴리에틸렌 또는 폴리프로필렌 기질을 함유하는 일회용 제품.
  7. 제6항에 있어서, A-B-A블록 공중합체의 B성분의 평균 분자량이 35,000내지 60,000이고, A성분의 평균 분자량이 14,000내지 19,000이며, 공중합체의 총 분자량이 70,000내지 95,000이고, A성분이 공중합체 100중량부당 35내지 45부의 양으로 존재하는 일회용 제품.
  8. 제6항에 있어서, 일차 점착부여 수지가(1)천연 및 개질 로신; (2)천연 및 개질 로신의 글리세롤 및 펜타에리트리톨 에스테르; (3)천연화된 테르펜의 공중합체 및 터폴리머; (4)ASTM방법 E28-58T에 의해 측정한 연화점이 약 80내지 150℃인 폴리테르펜 수지; (5)페놀성 개질된 테르펜 수지 및 이의 수소화 유도체; (6)환구(Ball and Ring)연화점이 70내지 135℃인 지방족 석유 탄화수소 수지; (7)방향족 석유 탄화수소 수지, 및 혼합 방향족 및 지방족 파라핀 탄화수소 수지, 및 이의 수소화 유도체; (8)방향족 개질된 지환족 석유 탄화수소 수지 및 이의 수소화 유도체; 및 (9)지환족 석유 탄화수소 수지 및 이의 수소화 유도체 중에서 선택된 상용성 수지 또는 이의 혼합물인 일회용 제품.
  9. 제6항에 있어서, 기저귀, 위생 내프킨 및 침대 패드 중에서 선택된 일회용 제품.
  10. 제6항에 있어서, 접착 성분을 불연속상, 연속상, 미세한 평행 세로 스트립 또는 접착제 소적의 다점(multi-dot)패턴으로 적용시킨 일회용 제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910700348A 1989-08-11 1990-08-07 폴리스티렌-폴리이소프렌-폴리스티렌 블록 공중합체를 포함하는 열용융형 접착제 조성물 KR0150188B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/393,545 US5143968A (en) 1989-08-11 1989-08-11 Polystyrene-polyisoprene-polystyrene block copolymers, hot melt adhesive compositions, and articles produced therefrom
US393545 1989-08-11
US393,545 1989-08-11
PCT/US1990/004408 WO1991002039A1 (en) 1989-08-11 1990-08-07 Polystyrene-polyisoprene-polystyrene block copolymers, hot-melt adhesive compositions, and articles produced therefrom

Publications (2)

Publication Number Publication Date
KR920701376A true KR920701376A (ko) 1992-08-11
KR0150188B1 KR0150188B1 (ko) 1998-10-01

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KR1019910700348A KR0150188B1 (ko) 1989-08-11 1990-08-07 폴리스티렌-폴리이소프렌-폴리스티렌 블록 공중합체를 포함하는 열용융형 접착제 조성물

Country Status (11)

Country Link
US (2) US5143968A (ko)
EP (1) EP0438576B1 (ko)
JP (1) JPH04501285A (ko)
KR (1) KR0150188B1 (ko)
AT (1) ATE112795T1 (ko)
AU (1) AU635559B2 (ko)
CA (1) CA2037926C (ko)
DE (1) DE69013321T2 (ko)
ES (1) ES2061060T3 (ko)
FI (1) FI911716A0 (ko)
WO (1) WO1991002039A1 (ko)

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FI911716A0 (fi) 1991-04-10
EP0438576B1 (en) 1994-10-12
ATE112795T1 (de) 1994-10-15
JPH04501285A (ja) 1992-03-05
KR0150188B1 (ko) 1998-10-01
EP0438576A1 (en) 1991-07-31
WO1991002039A1 (en) 1991-02-21
DE69013321D1 (de) 1994-11-17
US5143968A (en) 1992-09-01
DE69013321T2 (de) 1995-03-30
US5292806A (en) 1994-03-08
ES2061060T3 (es) 1994-12-01
AU6186890A (en) 1991-03-11
CA2037926A1 (en) 1991-02-12
AU635559B2 (en) 1993-03-25
CA2037926C (en) 2002-06-18

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