KR920017995A - 방향족 화합물, 그의 제조방법 및 그의 해충 억제용 조성물 - Google Patents

방향족 화합물, 그의 제조방법 및 그의 해충 억제용 조성물 Download PDF

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KR920017995A
KR920017995A KR1019920004545A KR920004545A KR920017995A KR 920017995 A KR920017995 A KR 920017995A KR 1019920004545 A KR1019920004545 A KR 1019920004545A KR 920004545 A KR920004545 A KR 920004545A KR 920017995 A KR920017995 A KR 920017995A
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aromatic compound
chloro
benzene
butoxy
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아끼라 스또
노리야스 사까모또
히로시 기시다
히로아끼 후지모또
기미또시 우메다
노리따다 마쓰노
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모리 히데오
스미또모가가꾸고오교 가부시끼가이샤
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Publication of KR920017995A publication Critical patent/KR920017995A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/18—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C07C323/19—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton with singly-bound oxygen atoms bound to acyclic carbon atoms of the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14—Ethers
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/27—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups
    • C07C205/35—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/54—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and etherified hydroxy groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/225—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
    • C07D317/54—Radicals substituted by oxygen atoms

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Abstract

내용 없음

Description

방향족 화합물, 그의 제조방법 및 그의 해출 억제용 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 하기 일반식(1)의 방향족 화합물:
    (상기식에서, R1은 C3~C8알킬기, C3~C8알콕시기, C3~C8알콕시알킬기,C3~C8알케닐기, C3~C8알케닐옥시기, C3~C8알케닐옥시알킬기,C3~C|8할로알킬기, C3~C8할로알콕시기,C3~C8할로알콕시알킬기, C3~C8할로알케닐기,C3~C|8할로알케닐옥시기, C3~C8할로케닐옥시알킬기 또는C3~C8알키닐옥시기이고, R2는 할로겐 원자이며, R3는 동일하거나 상이하여 수소원자, 할로겐원자 또는 메틸기이고, R4는 수소원자 또는 메틸기이며, R5는 동일하거나 상이하며, 수소원자, 할로겐원자, C1~C4알킬기, C1~C4할로알킬기, C1~C4알콕시기, C1~C4할로알콕시기, C1~C4알킬티오기, C1~C4할로알킬티오기, 3,4-메틸렌디옥시기, 메톡시메틸기, 시아노기 또는 니트로기이고, m은 1~3의 저수이며, n은 1~5의 정수이다).
  2. 제1항에 있어서, R2가 염소원자인 방향족 화합물.
  3. 제1항에 있어서, R2가 염소원자이며 R5가 동일하거나 상이한 할로겐원자인 화합물.
  4. 제1항에 있어서, R2가 염소원자이며 R5가 에틸기인 방향족 화합물.
  5. 제1항에 있어서, 1-sec-부톡시-3-클로로-4-(4-클로로벤질옥시)벤젠인 방향족 화합물.
  6. 제1항에 있어서, 1-sec-부톡시-4-(4-브로모벤질옥시)-3-클로로벤젠인 방향족 화합물.
  7. 제1항에 있어서, 1-sec-부톡시-3-클로로-4-(4-요오드벤질옥시)벤젠인 방향족 화합물.
  8. 제1항에 있어서, 1-sec-부톡시-3-클로로-4-(4-에틸벤질옥시)벤젠인 방향족 화합물.
  9. 제1항에 있어서, 1-sec-부톡시-3-클로로-4-(4-메틸벤질옥시)벤젠인 방향족 화합물.
  10. 제1항에 있어서, 1-sec-부톡시-3-클로로-4-(4-트리플루오로메틸벤질옥시)벤젠인 방향족 화합물.
  11. 제1항에 있어서, 3-클로로-4-(4-클로로벤진옥시)-1-이소부톡시메틸벤젠인 방향족 화합물.
  12. 제1항에 있어서, 3-클로로-4-(4-클로로벤진옥시)-1-(2-에틸부틸)벤젠인 방향족 화합물.
  13. 제1항에 있어서, 3-클로로-4-(4-클로로벤진옥시)-1-(1-메틸부톡시)벤젠인 방향족 화합물.
  14. 제1항에 있어서, 1-sec-부톡시-3-클로로-4-(3,4-디플루오로벤질옥시)벤젠인 방향족 화합물.
  15. 제1항에 있어서, 1-sec-부톡시-3-클로로-4-〔1-(4-클로로페닐)에톡시〕벤젠인 방향족 화합물.
  16. 제1항에 있어서, 1-sec-부톡시-3-클로로-4-(3-클로로벤질옥시)벤젠인 방향족 화합물.
  17. 제1항에 있어서, 3-클로로-1-(2-에틸부틸)-4-(4-메틸벤조일옥시)벤젠인 방향족 화합물.
  18. 제1항에 있어서, 3-클로로-1-이소부톡시메틸-4-(4-메틸벤조일옥시)벤젠인 방향족 화합물.
  19. (a)하기 일반식(Ⅱ)의 페놀을 하기 일반식(Ⅲ)의 할로겐 화합물과 반응시키거나, 또는 (b)하기 일반식 (Ⅳ)의 페놀 화합물을 하기 일반식(Ⅴ)의 알콜과 반응시킴을 특징으로 하는 일반식(Ⅰ)의 방향족 화합물의 제조방법.
    (상기식에서, R1은 C3~C8알킬기,C3~C8알콕시기, C3~C8알콕시알킬기,C3~C8알케닐기, C3~C8알케닐옥시기,C3~C8알케닐옥시알킬기, C3~C|8할로알킬기,C3~C8할로알콕시기, C3~C8할로알콕시알킬기,C3~C8할로알케닐기, C3~C|8할로알케닐옥시기,C3~C8할로케닐옥시알킬기 또는 C3~C8알키닐옥시기이고, R2는 할로겐 원자이며, R3는 동일하거나 상이하며 수소원자, 할로겐원자 또는 메틸기이고, R4는 수소원자 또는 메틸기이며, R5는 동일하거나 상이하며, 수소원자, 할로겐원자, C1~C4알킬기, C1~C4할로알킬기,C1~C4알콕시기, C1~C4할로알콕시기,C1~C4알킬티오기, C1~C4할로알킬티오기, 3,4-메틸렌디옥시기, 메톡시메틸기, 시아노기 또는 니트로기이고, m은 1~3의 정수이며, n은 1~5의 정수이고, M은 알킬리 금속원자 또는 수소원자이며, A는 할로겐원자이다).
  20. 제19항에 있어서, (a)단계의 반응이 염기 존재하에 -20℃ 내지 불활성 용매의 비점인 불활성 용매 내에서 수행되는 제조방법.
  21. 제19항에 있어서, (b)단계의 반응이 탈수소화 촉매 또는 탈수소화제의 존재하에 -20℃ 내지 200℃ 또는 불활성 용매의 비점인 불활성 용매내에서 수행되는 제조방법.
  22. 제1항에 따른 방향족 화합물의 유효량과 불활성 담체를 함유하는 해충 억제용 조성물.
  23. 제1항에 따른 방향족 화합물의 유효량을 해충 또는 해충이 번식하고 있는 지역에 사용함을 특징으로 하는 해충의 억제방법.
  24. 제1항에 따른 방향족 화합물의 해충 억제용 약제로서의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920004545A 1991-03-19 1992-03-19 방향족 화합물, 그의 제조방법 및 그의 해충 억제용 조성물 KR920017995A (ko)

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DE69505490T2 (de) * 1994-08-04 1999-06-24 Sumitomo Chemical Co., Ltd., Osaka Dihalopropenverbindungen, sie enthaltende insektizide/akarizide mittel, und zwischenprodukte
US6177412B1 (en) 1999-05-28 2001-01-23 Valent U.S.A. Corporation Insecticidal composition and method for the use thereof
US20050065577A1 (en) * 2003-09-23 2005-03-24 Mcarthur Frank G. Low level laser tissue treatment
BRPI0508545A (pt) * 2004-06-29 2007-08-14 Univ Florida análogos de hormÈnio juvenil para controle de pragas de cigarrinha da folha e cigarrinha arborìcola
WO2006119876A1 (en) * 2005-05-07 2006-11-16 Merial Ltd. Pesticidal substituted phenylethers

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JPS6341451A (ja) * 1986-08-06 1988-02-22 Nippon Kayaku Co Ltd エ−テル誘導体およびそれを有効成分とする殺ダニ、殺虫組成物

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DE69204505D1 (de) 1995-10-12
EP0504812A3 (en) 1992-10-28
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