KR920016493A - 중합체 발포물 제조방법 및 이에 사용되는 화학적 조성물 - Google Patents

중합체 발포물 제조방법 및 이에 사용되는 화학적 조성물 Download PDF

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KR920016493A
KR920016493A KR1019920001594A KR920001594A KR920016493A KR 920016493 A KR920016493 A KR 920016493A KR 1019920001594 A KR1019920001594 A KR 1019920001594A KR 920001594 A KR920001594 A KR 920001594A KR 920016493 A KR920016493 A KR 920016493A
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reactive
isocyanate
cyclic
compound
metal salt
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KR1019920001594A
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KR100213557B1 (ko
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허버트 러셀 길리스
더크 스탄센스
릭 데 보스
알드릭 뢸프 포스테마
데이비드 랜댈
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수잔 제인 젠틀
임페리알 케미칼 인더스트리스 피엘씨
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0028—Use of organic additives containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3218—Polyhydroxy compounds containing cyclic groups having at least one oxygen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/3848—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2330/00—Thermal insulation material
    • C08G2330/50—Evacuated open-celled polymer material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

내용 없음

Description

중합체 발포물 제조방법 및 이에 사용되는 화학적 조성물.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 반응이 마이크로에멀젼 또는 유체의 분산상으로서 존재하는 불활성이고 불용성인 유기 액체 존재내에서 행해지고, 이소시아네이트 반응성 물질이 최소한 하나의 다음 구조식을 갖는 이소시아네이트와 반응성이 있는 환식 화합물로 이루어지는 것을 특징으로 하는, 발포 촉진제 및 금속염 촉매 존재내에서 유기 플리이소시아네이트를 이소시아네이트 반응성 물질과 반응시켜 경질 발포물을 제조하는 방법.
    식중 Y는 -O-또는 -NR1-, 각 R1은 독립적으로 C1-C6저급 알킬라디칼 또는 이소시아네이트 반응성 그룹으로 치환된 저급 알킬 라디칼; 각 R은 독립적으로 H, C1-C6저급 알킬 라디칼 또는 X가 OH또는 NH2인 이소시아네이트 반응성 그룹이고 m이 0,1또는2인 -(CH2)m-X인데 단, m은 최소한 하나의 R1또는 R이 이소시아네이트 반응성 그룹으로 이루어진다는 조건으로 1또는 2임.
  2. 제1항에 있어서 금속염이 Ia족 및 Ⅱa족 금속염중에서 선택되는 방법.
  3. 제1항에 있어서, 금속염이 금속 카복실레이트인 방법.
  4. 제1항에 있어서, 금속염이 아세트산 칼륨 또는 포타슘-2-에틸-헥소에이트인 방법.
  5. 제1항에 있어서, 이소시아네이트와 반응성이있는 환식 화합물이 글리세롤 카보네이트인 방법.
  6. 제1항에 있어서, 이소시아네이트와 반응성이 있는 환식 화합물이 다음 구조식의 환식 우레아인 방법.
  7. 제1항에 있어서, 불용성이고 불활성인 유기 액체가 비등점이 최소한 40℃인 매우 불화되었거나 과불화된 화합물인 방법.
  8. 제1항에 있어서, 이소시아네이트 반응성 물질이 MW가 62-1500이고 기능도가 2-8인 폴리올을 더 포함하는 방법.
  9. a)폴리올, 폴리아민, 아미노-또는 엔아미노 화합물로부터 선택된 최소한 하나의 이소시아네이트 반응성 화합물;b) 이소시아네이트와 반응성이 있는 환식 탄산염 또는 이소시아네이트와 반응성이 잇는 환식 우레아, C) 마이크로에멀젼 또는 유제의 분산상으로서 존재하고 조성물내에 용해되지 않는, 비등점이 최소한 40℃인 과불화된 액체 화합물, 및 d)Ia족 및 Ⅱa족 메탈 카복실레이트로부터 선택된 촉매 작용을 하기에 효과적인 양의 촉매로 이루어진 이소시아네이트 반응성 조성물.
  10. 제9항에 있어서, 1-60중량%의 이소시아네이트와 반응성이 있는 환식 탄산염 또는 환식 우레아를 함유하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920001594A 1991-02-04 1992-02-01 중합체 발포물 제조방법 및 이에 사용되는 화학적 조성물 KR100213557B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB919102362A GB9102362D0 (en) 1991-02-04 1991-02-04 Polymeric foams
GB9102362.2 1991-02-04

Publications (2)

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KR920016493A true KR920016493A (ko) 1992-09-24
KR100213557B1 KR100213557B1 (ko) 1999-08-02

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KR1019920001595A KR100207943B1 (ko) 1991-02-04 1992-02-01 다공성 엘라스토머의 제조방법 및 이에 사용된 화학적 조성물
KR1019920001594A KR100213557B1 (ko) 1991-02-04 1992-02-01 중합체 발포물 제조방법 및 이에 사용되는 화학적 조성물

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Country Status (12)

Country Link
US (1) US5578656A (ko)
EP (2) EP0498628B1 (ko)
JP (2) JP3133128B2 (ko)
KR (2) KR100207943B1 (ko)
AU (2) AU642335B2 (ko)
CA (2) CA2060530A1 (ko)
DE (2) DE69203104T2 (ko)
ES (2) ES2074819T3 (ko)
FI (1) FI920472A (ko)
GB (3) GB9102362D0 (ko)
HK (2) HK191696A (ko)
ZA (2) ZA92673B (ko)

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Also Published As

Publication number Publication date
FI920472A (fi) 1992-08-05
JP3133127B2 (ja) 2001-02-05
GB9102362D0 (en) 1991-03-20
HK191596A (en) 1996-10-25
AU642335B2 (en) 1993-10-14
EP0498628B1 (en) 1996-07-24
KR100207943B1 (ko) 1999-07-15
EP0498629A1 (en) 1992-08-12
AU649772B2 (en) 1994-06-02
CA2060590A1 (en) 1992-08-05
KR920016494A (ko) 1992-09-24
ES2074819T3 (es) 1995-09-16
EP0498629B1 (en) 1995-06-28
JPH0570548A (ja) 1993-03-23
US5578656A (en) 1996-11-26
KR100213557B1 (ko) 1999-08-02
CA2060530A1 (en) 1992-08-05
JP3133128B2 (ja) 2001-02-05
GB9202310D0 (en) 1992-03-18
FI920472A0 (fi) 1992-02-04
JPH0570547A (ja) 1993-03-23
ZA92727B (en) 1992-11-25
HK191696A (en) 1996-10-25
ZA92673B (en) 1992-11-25
DE69203104D1 (de) 1995-08-03
DE69203104T2 (de) 1995-10-26
GB9202320D0 (en) 1992-03-18
ES2089384T3 (es) 1996-10-01
DE69212342T2 (de) 1996-12-05
AU1071792A (en) 1992-08-06
EP0498628A1 (en) 1992-08-12
AU1059392A (en) 1992-08-06
DE69212342D1 (de) 1996-08-29

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