KR920008016A - 살리실산 유도체 - Google Patents

살리실산 유도체 Download PDF

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KR920008016A
KR920008016A KR1019910018914A KR910018914A KR920008016A KR 920008016 A KR920008016 A KR 920008016A KR 1019910018914 A KR1019910018914 A KR 1019910018914A KR 910018914 A KR910018914 A KR 910018914A KR 920008016 A KR920008016 A KR 920008016A
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alkyl
formula
substituted
alkoxy
alkylthio
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KR1019910018914A
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KR100218655B1 (ko
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라인하이머 요아힘
아이켄 카알
요제프 포겔바허 우베
베스트팔렌 카알-오토
겔버 마티아스
발터 헬무트
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라이싱어, 바르츠
바스프 악티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
    • C07D251/22—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to two ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/34—One oxygen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/60—Three or more oxygen or sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/30—Only oxygen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Pyridine Compounds (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

내용 없음

Description

살리실산 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 일반식( I )의 살리실산 유도체
    I
    식중에서 R1은 숙신이미독시; 2개 또는 3개의 질소원자를 포함하고 그리고 1개 또는 2개의 할로겐 원자 및/또는 1개 또는 2개의 다음 : C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시 및/또는 C1-C4-알킬티오를 치환할 수 있는 5원 헤테로방향족 기; R2가 1개 내지 3개의 C1-C4-알킬기를 치환할 수 있는 C3-C12-시클로알킬, 1개 내지 5개의 할로겐원자 및/또는 방향기는 차례로 1개 내지 5개의 할로겐원자 및/또는 1개 내지 3개의 C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시, C1-C4-알콕시, C1-C4-할로알콕시 및/또는 C1-C4-알킬티오를 치환할 수 있는, 다음 : C1-C4-알콕시, C1-C4-알킬티오, 시아노, C1-C8-알킬카르보닐, C3-C12-시클로알킬, C1-C8-알콕시카르보닐, 페닐, 페녹시 또는 페닐카르보닐중 하나와 치환할 수 있는 C1-C10-알킬, 2위치에서 1개의 다음 : C1-C8-알콕시이미노, C3-C6-알켄일옥시이미노, C3-C6-할로알켄일옥시이미노 또는 벤질옥시이미노, 또는 벤질옥시이미노를 치환할 수 있는 C2-C6-알킬, 차례로 1개 내지 5개의 할로겐 원자를 치환할 수 있는 각각의 C3-C6-알켄일 또는 C3-C6-알킨일, C1-C6-알킬 또는 C1-C6-알콕시에 의해 1내지 3회로 또는 할로겐에 의해 1내지 5회로 비치환 또는 치환되는 페닐, 또는 R6및 R7이 각각 페닐, C1-C4-알콕시 및/또는 C1-C4-알킬티오를 치환할 수 있는 C1-C20-알킬이거나 또는 페닐이거나 또는 결합하여 1개 내지 3개의 C1-C8-알킬 그룹을 치환할 수 있는 C3-C12-알킬렌 사슬을 함께 형성할 수 있는 -N=CR6R7인 -OR5이고 또한 R1은 R8이 수소, 알칼리 금속 양이온, 동가의 알킬린토금속 양이온, 암모늄 또는 유기 암모늄 이온인 -OR8이며, R2및 R3는 각각 C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시 및/또는 C1-C4-알킬티오이고, R4는 에틴일 또는 1개 내지 3개의 할로겐원자를 치환할 수 있는 비닐이고, X는 산소 또는 황이고, Z는 질소 또는 =CH- 이다.
  2. 통상적인 방법으로, 염기의 존재하에 하기 일반식(Ⅱ)의 화합물과 하기 일반식(Ⅲ)의 헤테로 고리를 반응시키는 것으로 이루어지는 제1항에 청구된 바와같은 일반식( I )의 화합물을 제조하는 방법.
    Ⅱ
    Ⅲ
    식중에서 R9는 핵배척 이탈기이다.
  3. 통상적인 방법으로 하기 일반식( I' )의 화합물을 할로겐화물 또는 카르복실 그룹의 다른 활성화 형태로 전환시키고 이 형태를 알코올 R5OH, 디아졸 또는 트리아졸 또는 N-히드록시숙신이미드와 반응시키는 것으로 이루어지는 것을 특징으로 하는 제1항에 청구된 바와같은 일반식( I )의 화합물을 제조하는 방법 :
    I'
  4. 통상적인 방법으로 하기 유리 카르복실산(1")을 염으로 전환하고, 그리고 이 염을 하기 화합물(A)와 반응시키는 것으로 이루어지는 것을 특징으로 하는 제1항에 청구된 바와 같은 일반식( I )의 화합물을 제조하는 방법 :
    I"
    R10-R5(A)
    식중에서, R10은 핵배척 이탈 그룹이고 그리고 R5는 다음의 1개 내지 3개의 C1-C4-알킬기를 치환할 수 있는 C3-C12-시클로알킬; 1개 내지 5개의 할로겐원자를 치환할 수 있고, 및/또는 방향족기가 차례로 1개 내지 5개의 할로겐원자 및/또는 1개 내지 3개의 다음의 C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시 및/또는 C1-C4-알킬티오를 치환할 수있는 다음의 : C1-C4-알콕시, C1-C4-알킬티오, 시아노, C1-C8-알킬카르보닐, C3-C12-시클로알킬, C1-C8-알콕시카르보닐, 페닐, 페녹시, 또는 페닐카르보닐중 하나를 치환할 수 있는 C1-C10-알킬; 2위치에서 다음 C1-C6-알콕시이미노, C3-C6-알켄일옥시이미노, C3-C6-할로알켄일옥시이미노 또는 벤질옥시이미노중 하나를 치환할 수 있는 C2-C6-알킬; 그들중 각각 이 차례로 1개 내지 5개의 할로겐 원자를 치환할 수 있는 C3-C6-알켄일 또는 C3-C6-알킨일이다.
  5. 하기 일반식(Ⅳ)의 화합물 :
    Ⅳ
    식중에서 R11은 수소, 아세틸 또는 메틸이다.
  6. 제1항에서 청구된 바와같은 일반식( I )의 화합물과, 통상적인 비활성 첨가물을 포함하는 제초제.
  7. 제거할 식물 및/또는 그들의 서식지를 제1항에 청구된 바와같은 유도체( I )의 제초적 양으로 처리하는 것으로 이루어지는 것을 특징으로 하는 제거할 식물성장을 조절하는 방법.
  8. 제초제로서 제1항에 청구된 바와같은 일반식( I )의 살리실산 유도체의 용도.
  9. 제1항에 청구된 바와같은 일반식( I )의 살리실산 유도체, 및 통상적인 비활성 첨가물을 포함하는 식물성장에 영향을 미치는 제제.
  10. 종자, 식물 및/또는 그들의 서식지를 제1항에 청구된 바와같은 일반식( I )의 살리실산 유도체의 성장-조절 양으로 처리하는 것으로 이루어지는 식물성장을 조절하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910018914A 1990-10-26 1991-10-25 살리실산 유도체 KR100218655B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4034045A DE4034045A1 (de) 1990-10-26 1990-10-26 Salicylsaeurederivate
DEP4034045.7 1990-10-26

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KR920008016A true KR920008016A (ko) 1992-05-27
KR100218655B1 KR100218655B1 (ko) 1999-09-01

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US (2) US5201937A (ko)
EP (1) EP0490060B1 (ko)
JP (1) JP3040558B2 (ko)
KR (1) KR100218655B1 (ko)
AT (1) ATE132142T1 (ko)
CA (1) CA2054143C (ko)
DE (2) DE4034045A1 (ko)
DK (1) DK0490060T3 (ko)
ES (1) ES2082088T3 (ko)
HU (1) HU207855B (ko)

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DE4034045A1 (de) * 1990-10-26 1992-04-30 Basf Ag Salicylsaeurederivate
US5401711A (en) * 1991-07-31 1995-03-28 Kumiai Chemical Industry Co., Ltd. Pyrimidine derivatives and herbicidal composition
JPH0532638A (ja) * 1991-07-31 1993-02-09 Kumiai Chem Ind Co Ltd ピリミジンまたはトリアジン誘導体及び除草剤
BR9307115A (pt) * 1992-09-29 1999-03-30 Sumitomo Chemical Co Derivado de naftol processo para a preparação do derivado de naftol composição herbicida processo para controlar ervas daninhas indesejadas e uso do derivado de naftol como um herbicida
DE4337321A1 (de) * 1993-11-02 1995-05-04 Basf Ag Cyclische Acetale, Verfahren zu deren Herstellung und deren Umsetzung zu Pflanzenschutzmitteln
US5962685A (en) * 1994-08-02 1999-10-05 Nippon Soda Co., Ltd. Oxazole derivatives, process for producing the same, and herbicide
US6649566B2 (en) 2001-12-13 2003-11-18 Morse Enterprises Limited, Inc. Stabilized concentrated formulations for enhancing plant defensive responses
WO2010034153A1 (zh) * 2008-09-25 2010-04-01 沈阳化工研究院 2-嘧啶氧（硫）基苯甲酸基烯酸酯类化合物及其应用
HUP0900407A2 (en) 2009-06-26 2011-01-28 Biopure Kft Plant conditioning composition of natural origin and process for using it
DE102015111314B4 (de) 2015-07-13 2019-05-02 Oget Innovations Gmbh Pflanzenstärkungsmittel, Verfahren zu dessen Herstellung und dessen Verwendungen
LU92774B1 (en) 2015-07-13 2017-01-31 Oget Innovations Gmbh Plant conditioning composition, method of preparation and uses thereof
CN105272925A (zh) * 2015-11-25 2016-01-27 常州大学 一种水稻田除草剂嘧草醚的制备方法
CN109111405B (zh) * 2018-10-22 2021-07-30 南开大学 一种芳香硫醚类化合物及其农药和医药用途

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* Cited by examiner, † Cited by third party
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JPH0651684B2 (ja) * 1985-10-15 1994-07-06 クミアイ化学工業株式会社 ピリミジン誘導体および除草剤
JPH082883B2 (ja) * 1986-06-06 1996-01-17 クミアイ化学工業株式会社 ２−フエノキシピリミジン誘導体および除草剤
EP0287079B1 (en) * 1987-04-14 1994-10-12 Kumiai Chemical Industry Co., Ltd. 2-Phenoxypyrimidine derivatives and herbicidal compositions
DE3854099T2 (de) * 1987-04-14 1996-04-04 Kumiai Chemical Industry Co 2-Phenoxy-pyrimidin-Derivate und herbizide Zusammensetzung.
EP0346789B1 (de) * 1988-06-16 1994-04-20 BASF Aktiengesellschaft Salicylsäurederivate und deren Schwefelanaloge
DE3832237A1 (de) * 1988-09-22 1990-03-29 Basf Ag Aromatische carbonsaeurederivate, verfahren zu ihrer herstellung und ihre verwendung als herbizide
US5185027A (en) * 1989-06-14 1993-02-09 Basf Aktiengesellschaft Salicylaldehyde derivatives and salicyclic acid derivatives and their sulfur analogs, and their use as herbicides and bioregulators
DE4034045A1 (de) * 1990-10-26 1992-04-30 Basf Ag Salicylsaeurederivate

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ES2082088T3 (es) 1996-03-16
JP3040558B2 (ja) 2000-05-15
EP0490060A1 (de) 1992-06-17
HUT59914A (en) 1992-07-28
JPH04305569A (ja) 1992-10-28
EP0490060B1 (de) 1995-12-27
HU913373D0 (en) 1992-01-28
CA2054143A1 (en) 1992-04-27
DE4034045A1 (de) 1992-04-30
HU207855B (en) 1993-06-28
CA2054143C (en) 2001-10-23
US5360913A (en) 1994-11-01
US5201937A (en) 1993-04-13
DK0490060T3 (da) 1996-01-29
ATE132142T1 (de) 1996-01-15
KR100218655B1 (ko) 1999-09-01
DE59107157D1 (de) 1996-02-08

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