KR920006266A - 시클로헥사논 유도체들 및 그의 제조방법 - Google Patents
시클로헥사논 유도체들 및 그의 제조방법 Download PDFInfo
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- KR920006266A KR920006266A KR1019910015281A KR910015281A KR920006266A KR 920006266 A KR920006266 A KR 920006266A KR 1019910015281 A KR1019910015281 A KR 1019910015281A KR 910015281 A KR910015281 A KR 910015281A KR 920006266 A KR920006266 A KR 920006266A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/45—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by at least one doubly—bound oxygen atom, not being part of a —CHO group
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/292—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with chromium derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
- C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
- C07C45/58—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in three-membered rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
- C07C49/697—Unsaturated compounds containing a keto groups being part of a ring containing halogen containing six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
- C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/753—Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 하기 일반식(Ⅰ)의 화합물 :(Ⅰ)상기식에서, n은 정수0-5를 나타내고, 각각의 R은 할로겐 원자, 니트로, 시아노, 히드록실, 알킬, 할로알킬, 알콕시, 할로알콕시, 아미노, 알킬아미노, 디알킬아미노, 알콕시카르보닐, 카르복실, 알카노일, 알킬티오, 알킬설피닐, 알킬설포닐, 카르바모일, 알킬아미도, 시클로 알킬 또는 페닐기를 나타내고, R1, R2및 R3는 독립적으로 수소원자 또는 알킬기를 나타내고, R6및 R7은 함께 단일 탄소-탄소 결합 또는 에폭시기를 나타내고, R8은 수소원자 또는 히드록실기를 나타내고, 단, R6및 R7이 함께 에폭시기를 나타낼때, R8은 수소원자를 나타낸다.
- 제1항에 있어서, R1, R2및 R3가 독립적으로 수소원자 또는 C1-4알킬기를 나타내는 화합물.
- 제1항 또는 제2항에 있어서, R1, R2및 R3가 독립적으로 수소원자 또는 메틸기를 나타내는 화합물.
- 제1항 내지 제3항중 어느 한 항에 있어서, R이 할로겐 원자를 나타내는 화합물.
- 제1항 내지 제4항중 어느 한 항에 있어서, n이 1이고, R이 염소원자를 나타내고, R1및 R2모두가 수소원자 또는 메틸기를 나타내고, R3가 수소원자 또는 메틸기를 나타내는 화합물.
- 하기(a)-(c)단계들로 구성되는 제1항 내지 제5항중 어느 한 항에서 정의된 바와 같은 일반식(Ⅰ)화합물의 제조방법 : (a) 하기 일반식(Ⅱ)의 화합물 :(Ⅱ)(상기식에서, n, R, R1, R2및 R3는 앞서 정의된 바와 같다)을 산 존재하에 산화제와 반응시켜, R6및 R7이 함께 단일 탄소-탄소결합을 나타내고, R8이 수소원자를 나타내는 일반식(Ⅰ)의 화합물을 생성시키는 단계: (b) 원한다면, (a)단계에서 형성된 일반식(Ⅰ)의 화합물을 염기 존재하에 과산화수소와 반응시켜, R6및 R7이 함께 에폭시기를 나타내고, R8이 수소원자를 나타내는 일반식(Ⅰ)의 화합물을 생성시키는 단계, 및 (c) 원한다면, (b) 단계에서 형성된 일반식(Ⅰ)화합물을 극성용매 존재하에, 하기 일반식(Ⅲ)의 화합물 :MOR5(Ⅲ)(상기식에서, R5는 수소원자 또는 알킬 또는 시클로알킬기를 나타내고, M은 알킬리 금속 원자를 나타낸다)과 반응시켜, R6및 R7이 함께 단일 탄소-탄소결합을 나타내고, R8이 히드록실기를 나타내는 일반식(Ⅰ)의 화합물을 생성시키는 단계.
- 제6항에 있어서, 단계(a)에서의 산화제가 알칼리 금속 디크로메이트인 방법.
- 제6항에 있어서, 단계(c)에서의 극성용매가 하기 일반식(Ⅳ)의 화합물인 방법:R5OH (Ⅳ)(상기식에서, R5는 제6항에서 정의된 바와 같다)※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9019192.5 | 1990-09-03 | ||
GB909019192A GB9019192D0 (en) | 1990-09-03 | 1990-09-03 | Cyclohexenone derivatives |
GB90191933 | 1990-09-03 | ||
GB909019194A GB9019194D0 (en) | 1990-09-03 | 1990-09-03 | Cyclohexanone derivatives |
GB90191941 | 1990-09-03 | ||
GB909019193A GB9019193D0 (en) | 1990-09-03 | 1990-09-03 | Cyclohexenol derivatives |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920006266A true KR920006266A (ko) | 1992-04-27 |
KR100218139B1 KR100218139B1 (ko) | 1999-09-01 |
Family
ID=27265248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910015281A KR100218139B1 (ko) | 1990-09-03 | 1991-09-02 | 시클로헥사논 유도체들 및 그의 제조방법 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5200535A (ko) |
EP (1) | EP0474301B1 (ko) |
JP (1) | JP3241760B2 (ko) |
KR (1) | KR100218139B1 (ko) |
BR (1) | BR9103785A (ko) |
CA (1) | CA2050466A1 (ko) |
DE (1) | DE69115608T2 (ko) |
HU (1) | HU214552B (ko) |
IL (1) | IL99253A (ko) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5808139A (en) * | 1992-04-21 | 1998-09-15 | Ligand Pharmaceuticals Incorporated | Non-steroid progesterone receptor agonist and antagonist and compounds and methods |
AU5664194A (en) * | 1993-04-16 | 1994-11-08 | Ligand Pharmaceuticals, Inc. | Progesterone receptor agonist and antagonists |
US20020009467A1 (en) | 1997-01-29 | 2002-01-24 | Shozo Koyama | Antigenic substance inductor, vaccine precursor, vaccine, antibody, neutralizing antibody, antitoxin, idiotype antibody and/or anti-idiotype antibody which is induced by its idiotype antibody |
KR20020034258A (ko) * | 2000-10-31 | 2002-05-09 | 최원철 | 홍조류로부터 분리한 신규한 화합물 및 그 제조방법 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4863505A (en) * | 1985-09-12 | 1989-09-05 | Kureha Kagaku Kogyo Kabushiki Kaisha | Novel derivative of azole, and agricultural and horticultural composition containing the same as an active incredient |
JPH0625140B2 (ja) * | 1986-11-10 | 1994-04-06 | 呉羽化学工業株式会社 | 新規アゾール誘導体、その製造方法及び該誘導体の農園芸用薬剤 |
CA1335294C (en) * | 1988-08-31 | 1995-04-18 | Paul Howard Briner | Fungicidal compositions |
-
1991
- 1991-08-19 US US07/746,977 patent/US5200535A/en not_active Expired - Lifetime
- 1991-08-21 IL IL9925391A patent/IL99253A/en not_active IP Right Cessation
- 1991-08-30 CA CA002050466A patent/CA2050466A1/en not_active Abandoned
- 1991-09-02 EP EP91202226A patent/EP0474301B1/en not_active Expired - Lifetime
- 1991-09-02 BR BR919103785A patent/BR9103785A/pt not_active Application Discontinuation
- 1991-09-02 DE DE69115608T patent/DE69115608T2/de not_active Expired - Fee Related
- 1991-09-02 KR KR1019910015281A patent/KR100218139B1/ko not_active IP Right Cessation
- 1991-09-02 JP JP24656191A patent/JP3241760B2/ja not_active Expired - Fee Related
- 1991-09-02 HU HU912841A patent/HU214552B/hu not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2050466A1 (en) | 1992-03-04 |
JPH04316531A (ja) | 1992-11-06 |
EP0474301A3 (en) | 1992-07-08 |
IL99253A (en) | 1995-06-29 |
EP0474301B1 (en) | 1995-12-20 |
HU214552B (hu) | 1998-08-28 |
US5200535A (en) | 1993-04-06 |
DE69115608D1 (de) | 1996-02-01 |
HUT58678A (en) | 1992-03-30 |
BR9103785A (pt) | 1992-05-19 |
EP0474301A2 (en) | 1992-03-11 |
DE69115608T2 (de) | 1996-09-19 |
KR100218139B1 (ko) | 1999-09-01 |
HU912841D0 (en) | 1992-01-28 |
JP3241760B2 (ja) | 2001-12-25 |
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