KR830005097A - N-치환된-2-할로아세트아닐리드의 제조방법 - Google Patents

N-치환된-2-할로아세트아닐리드의 제조방법 Download PDF

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Publication number
KR830005097A
KR830005097A KR1019810000880A KR810000880A KR830005097A KR 830005097 A KR830005097 A KR 830005097A KR 1019810000880 A KR1019810000880 A KR 1019810000880A KR 810000880 A KR810000880 A KR 810000880A KR 830005097 A KR830005097 A KR 830005097A
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South Korea
Prior art keywords
alkyl
alkoxy
alkenyl
halo
formula
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KR1019810000880A
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KR840000238B1 (ko
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호르스트 알트 게르하르트
폴 츄프 죤
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죤 엠머 마우리
몬산토 캄파니
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Publication of KR830005097A publication Critical patent/KR830005097A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/04—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D309/06—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/15—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Pyrane Compounds (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

내용 없음

Description

N-치환된-2-할로아세트아닐리드의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 다음 구조식(Ⅱ)의 화합물을 산할라이드 및 용매의 존재하에 구조식(Ⅲ)의 화합물과 반응시켜 다음 구조식(Ⅰ)의 할로알킬 에테르를 제조하는 방법.
    상기 구조식에서
    R1은 수소 또는 탄소수 1내지 4의 알킬;
    X는 클로로, 브로모 또는 요도이며;
    R은 탄소수 1내지 10의 알킬, 탄소수 3내지 10의 알케닐, 탄소수 3내지 10의 사이클로알킬, 탄소수 3 내지 10의 알키닐, (C1-5)알콕시(C2-5)알킬, 모노-할로(C2-5)알킬, 모노-할로(C3-5) 알케닐 또는로서, 여기서 y는 정수 2,3 또는 4이며
    단, R이 알케닐 또는 알키닐일 때 산소원자에 결합된 탄소는 인접한 탄소원자와 2중 결합 또는 3중 결합될 수 없다.
  2. 구조식(Ⅴ)의 알콜, 포름알데히드 및 구조식(Ⅵ)의 산할라이드를 상전이촉매 존재하에 용매내에서 반응시키고 이어서 과량의 염기를 첨가하여 다음 구조식(Ⅳ)의 화합물을 제조하는 방법.
    상기 구조식에서
    X1은 클로로, 브로모 또는 요도이며
    R은 C1-10알킬, C3-10알케닐, C3-10사이클로알킬, C3-10알키닐, C1-5알콕시(C2-5)알킬, 모노-할로(C3-5)알키닐, 모노-할로(C3-5) 알케닐 또는그룹으로서 y는 정수 2,3 또는 4이며
    단, R이 알케닐 또는 알키닐일 때 산소원자와 결합된 탄소원자는 인접한 탄소원자의 2중결합 또는 3중 결합될 수 없으며;
    R2는 C1-8알킬, C2-8알케닐, C3-8알키닐, C1-8알콕시, C1-8알콕시(C1-5)알킬, 할로(C1-5)알킬, 할로겐, NO2, C1-5알콕시(C1-5)알콕시, 또는 C1-5알콕시(C1-5)알콕시(C1-5)알콕시이며,
    R3는 수소, C1-8알킬, C2-8알케닐, C1-8알콕시, C1-8알콕시(C1-5)알킬, 할로(C1-5)알킬, 할로겐 또는 NO2이며
    R4는 C1-8알킬, 할로(C1-5)알킬, 할로겐 또는 NO2이며
    n은 0,1 또는 2이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019810000880A 1980-03-25 1981-03-18 N-치환된-2-할로 아세트아닐리드의 제조 방법 KR840000238B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US133,720 1980-03-25
US06/133,720 US4284564A (en) 1980-03-25 1980-03-25 Process for the in-solvent, in-situ generation of haloalkyl alkyl ethers useful to produce N-substituted-2-haloacetanilides
US133720 1993-10-08

Publications (2)

Publication Number Publication Date
KR830005097A true KR830005097A (ko) 1983-07-23
KR840000238B1 KR840000238B1 (ko) 1984-03-07

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KR1019810000880A KR840000238B1 (ko) 1980-03-25 1981-03-18 N-치환된-2-할로 아세트아닐리드의 제조 방법

Country Status (21)

Country Link
US (1) US4284564A (ko)
EP (1) EP0037656B1 (ko)
JP (1) JPS56150032A (ko)
KR (1) KR840000238B1 (ko)
AR (1) AR229509A1 (ko)
AT (1) ATE7291T1 (ko)
AU (1) AU536552B2 (ko)
BG (1) BG35895A3 (ko)
BR (1) BR8101607A (ko)
CA (1) CA1165325A (ko)
CS (1) CS219305B2 (ko)
DE (1) DE3163356D1 (ko)
ES (2) ES8202531A1 (ko)
HU (1) HU188545B (ko)
IL (1) IL62408A (ko)
MX (1) MX157884A (ko)
MY (1) MY8600462A (ko)
NZ (1) NZ196539A (ko)
PL (1) PL129317B1 (ko)
YU (1) YU42388B (ko)
ZA (1) ZA811810B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HU177876B (en) * 1979-04-24 1982-01-28 Nitrokemia Ipartelepek Process for preparing 2,6-dialkyl-n-/alkoxy-methyl/-chloro-acetanilide derivatives
US4798618A (en) * 1981-12-10 1989-01-17 Agro-Kanesho Co., Ltd. Novel chloroacetanilide derivatives and herbicides containing the same for use in paddy field
HU190681B (en) * 1982-01-15 1986-10-28 Eszakmagyar Vegyimuevek Process for production of n-alcoxi-alkyl-2,6-dialkylchlor-acetanilids
JPH042552U (ko) * 1990-04-24 1992-01-10
JPH05228796A (ja) * 1992-02-13 1993-09-07 Nippon Avionics Co Ltd 位置決め制御装置

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2863752A (en) * 1953-10-30 1958-12-09 Monsanto Chemicals Herbicides
BE622131A (ko) * 1961-08-28
US3442945A (en) * 1967-05-22 1969-05-06 Monsanto Co Phytotoxic alpha-halo-acetanilides
US3547620A (en) * 1969-01-23 1970-12-15 Monsanto Co N-(oxamethyl)alpha-halo-acetanilide herbicides
US3952056A (en) * 1972-02-07 1976-04-20 Ciba-Geigy Corporation Plant growth regulating agent
US4160660A (en) * 1972-02-07 1979-07-10 Ciba-Geigy Corporation Acetanilide plant growth regulating agent
US4200451A (en) * 1972-06-06 1980-04-29 Ciba-Geigy Corporation Plant growth regulating agent
US4168965A (en) * 1972-06-06 1979-09-25 Ciba-Geigy Corporation 2,6-Diethyl-n-(2'-N-propoxyethyl)-chloroacetanilide for selectively combating weeds
US3937730A (en) * 1972-06-06 1976-02-10 Ciba-Geigy Corporation Plant growth regulating agent
US4070179A (en) * 1973-02-07 1978-01-24 Ciba-Geigy Corporation Plant growth regulation with N-(2-alkoxy-ethyl)-N-chloroacetyl-2,3,6-trimethyl-anilines
SU643488A1 (ru) * 1976-08-04 1979-01-25 Предприятие П/Я Р-6462 Способ получени -хлорэтиловых эфиров замещенных спиртов

Also Published As

Publication number Publication date
MX157884A (es) 1988-12-19
JPH027940B2 (ko) 1990-02-21
US4284564A (en) 1981-08-18
PL230203A1 (ko) 1981-11-13
JPS56150032A (en) 1981-11-20
MY8600462A (en) 1986-12-31
BR8101607A (pt) 1981-09-29
AR229509A1 (es) 1983-09-15
AU6849281A (en) 1981-10-01
ES500463A0 (es) 1982-02-01
EP0037656B1 (en) 1984-05-02
IL62408A (en) 1985-10-31
ZA811810B (en) 1982-04-28
ES8202531A1 (es) 1982-02-01
AU536552B2 (en) 1984-05-10
ES500464A0 (es) 1982-02-01
KR840000238B1 (ko) 1984-03-07
BG35895A3 (en) 1984-07-16
DE3163356D1 (en) 1984-06-07
IL62408A0 (en) 1981-05-20
HU188545B (en) 1986-04-28
YU42388B (en) 1988-08-31
ES8202536A1 (es) 1982-02-01
CS219305B2 (en) 1983-03-25
ATE7291T1 (de) 1984-05-15
EP0037656A1 (en) 1981-10-14
YU70781A (en) 1983-09-30
NZ196539A (en) 1983-06-17
CA1165325A (en) 1984-04-10
PL129317B1 (en) 1984-04-30

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