KR920002713A - 필름성형 중합체 바인더로서 유용한 중합체 혼합물 - Google Patents

필름성형 중합체 바인더로서 유용한 중합체 혼합물 Download PDF

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KR920002713A
KR920002713A KR1019910011321A KR910011321A KR920002713A KR 920002713 A KR920002713 A KR 920002713A KR 1019910011321 A KR1019910011321 A KR 1019910011321A KR 910011321 A KR910011321 A KR 910011321A KR 920002713 A KR920002713 A KR 920002713A
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polymer
soft
hard
emulsion
glass transition
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KR1019910011321A
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KR100221675B1 (ko
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마이클 프리엘 죤
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윌리암 이 램버트 3세
롬 앤드 하스 캄파니
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical

Abstract

내용 없음

Description

필름성형 중합체 바인더로서 유요한 중합체 혼합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 20℃이상의 유리전이 온도를 갖는 최소한 하나의 경성 유화 중합체 20-60wt% 및 15℃이하의 유리전이 온도를 갖는 최소한 하나의 연성 유화 중합세 40-80wt%의 중합체 혼합물로 된, 휘발성 유기용매를 함유하지 않는 수성 도료 조성물에 유용한 필름 성형 중합체 바인더(film forming polymeric binder).
  2. 제1항에 있어서, 중합체 혼합물이 20-40wt%의 경성 유화 중합체 및 60-80wt%의 연성 유화중합체로 구성되는 것인, 필름성형 중합체 바인더.
  3. 제1항에 있어서, 경성 유화중합체는 25-65℃의 유리전이 온도를 갖는 것이고, 연성 유화 중합체는 -5-10℃ 유리전이 온도를 갖는 것인, 필름성형 중합체 바인더.
  4. 제1항에 있어서, 연성 유화 중합체는 5℃의 유리전이 온도를 갖고 혼합물의 60wt%를 구성하며, 경성 유화 중합체는 65℃의 유리전이 온도를 갖고 40wt%를 구성하며, 상기 연성 유화 중합체 및 경성 유화 중합체 모두가 각각 부틸 아크릴레이트, 스티렌, 메타크릴산 및 메틸메타크릴레이트로 부터 형성된 공중합체인, 필름성형 중합체 바인더.
  5. 제1항에 있어서, 경성 유화중합체 및 연성 유화 중합체가 각각 동일한 단량체들로부터 형성된 공중합체인, 필름 성형 중합체 바인더.
  6. 제1항에 있어서, 경성 유화중합체가 부틸아크릴레이트, 스티렌, 메타크릴산, 메틸메타크릴레이트, 2-에틸헥실 아크릴레이트 및 아크릴로니트릴로 구성된 군으로부터 선택된 단량체들로부터 형성된 공중합체인, 필름성형 중합체 바인더.
  7. 제1항에 있어서, 연성 유화 중합체가 부틸아크릴레이트, 스티렌 메타크릴산 및 메틸 메타크릴레이트로 구성된 군으로 부터 선택된 단량체들로부터 형성된 공중합체인, 필름성형 중합체 바인더.
  8. 제5항에 있어서, 경성 유화 중합체 및 연성 유화 중합체가 각각 부틸아크릴레이트 및 메틸 메타크릴레이트 단량체들로부터 형성된 공중합체인, 필름 성형 중합체 바인더.
  9. 제8항에 있어서, 연성 유화 중합체와 경성 유화 중합체의 평균입자크기 직경 상이의 차이가 최대화된 것인, 필름성형 중합체 바인더.
  10. 제8항에 있어서, 연성 유화중합체의 평균입자크기 직경은 530nm이고 경성 유화중합체의 평균 입자크기직경은 120nm인, 필름성형 중합체 바인더.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910011321A 1990-07-05 1991-07-04 필름성형 중합체 바인더로서 유용한 중합체 혼합물 KR100221675B1 (ko)

Applications Claiming Priority (2)

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US54803590A 1990-07-05 1990-07-05
US548,035 1990-07-05

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KR920002713A true KR920002713A (ko) 1992-02-28
KR100221675B1 KR100221675B1 (ko) 1999-09-15

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US (1) US5731377A (ko)
EP (1) EP0466409B1 (ko)
JP (1) JPH05112758A (ko)
KR (1) KR100221675B1 (ko)
CN (1) CN1058605A (ko)
AT (1) ATE157691T1 (ko)
AU (1) AU653943B2 (ko)
CA (1) CA2045366C (ko)
DE (1) DE69127523T2 (ko)
DK (1) DK0466409T3 (ko)
ES (1) ES2106055T3 (ko)
FI (1) FI102289B (ko)
GR (1) GR3024871T3 (ko)
HK (1) HK1001592A1 (ko)
IE (1) IE912349A1 (ko)
MX (1) MX9203531A (ko)
NO (1) NO912603L (ko)
NZ (1) NZ238836A (ko)
PT (1) PT98209B (ko)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100491428B1 (ko) * 2002-05-21 2005-05-25 (주)한맥기술 사면의 교각 시공 방법
KR102477117B1 (ko) * 2022-07-14 2022-12-13 (주)유주 해저 연약지반에서의 침하 방지를 위한 수중 콘크리트 구조물 및 그 시공 방법
WO2024014729A1 (ko) * 2022-07-14 2024-01-18 (주)유주 해저 연약지반에서의 침하 방지를 위한 수중 콘크리트 구조물 및 그 시공 방법

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EP0466409B1 (en) 1997-09-03
IE912349A1 (en) 1992-01-15
ES2106055T3 (es) 1997-11-01
NO912603L (no) 1992-01-06
CA2045366C (en) 1998-11-24
AU8014991A (en) 1992-01-09
NO912603D0 (no) 1991-07-03
GR3024871T3 (en) 1998-01-30
JPH05112758A (ja) 1993-05-07
DK0466409T3 (da) 1997-09-29
US5731377A (en) 1998-03-24
PT98209B (pt) 1998-12-31
FI913259A (fi) 1992-01-06
CN1058605A (zh) 1992-02-12
DE69127523D1 (de) 1997-10-09
HK1001592A1 (en) 1998-06-26
CA2045366A1 (en) 1992-01-06
NZ238836A (en) 1993-05-26
DE69127523T2 (de) 1998-04-02
KR100221675B1 (ko) 1999-09-15
PT98209A (pt) 1992-06-30
FI102289B1 (fi) 1998-11-13
EP0466409A1 (en) 1992-01-15
AU653943B2 (en) 1994-10-20
ATE157691T1 (de) 1997-09-15
FI913259A0 (fi) 1991-07-04
MX9203531A (es) 1992-07-01
FI102289B (fi) 1998-11-13

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