KR910018476A - 메타 아크릴 수지 조성물 - Google Patents

메타 아크릴 수지 조성물 Download PDF

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Publication number
KR910018476A
KR910018476A KR1019910006093A KR910006093A KR910018476A KR 910018476 A KR910018476 A KR 910018476A KR 1019910006093 A KR1019910006093 A KR 1019910006093A KR 910006093 A KR910006093 A KR 910006093A KR 910018476 A KR910018476 A KR 910018476A
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KR
South Korea
Prior art keywords
methacrylic resin
weight
methacrylic
resin composition
inner layer
Prior art date
Application number
KR1019910006093A
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English (en)
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KR0173986B1 (ko
Inventor
데루히사 고야마
히데아끼 마쓰우라
Original Assignee
모리 히데오
스미또모가가꾸고요교 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority claimed from JP10079390A external-priority patent/JP2969770B2/ja
Priority claimed from JP03049434A external-priority patent/JP3111487B2/ja
Application filed by 모리 히데오, 스미또모가가꾸고요교 가부시끼가이샤 filed Critical 모리 히데오
Publication of KR910018476A publication Critical patent/KR910018476A/ko
Application granted granted Critical
Publication of KR0173986B1 publication Critical patent/KR0173986B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/22—Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

내용 없음

Description

메타 아크릴 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 메타아크릴수지 20내지 99중량%와 하기 (a) 내지(e)에서 규정되는 메타아크릴제2층구조 중합체 1내지 80중량%와의 혼합물로 이루어진 메타아크릴수지 조성물.
    (a)1분자중에 탄소-탄소 2중결합을 2개 이상 갖는 다관능 단량체 0.1내지 10중량%를 함유하는 메타 아크릴산메틸을 주성분으로 하는 다관능 단량체를 중합하여 얻어지는 내층, (b)메타 아크릴산 메틸을 주성분으로 하는 단관능 단량체를 이 내층의 존재하에 중합하여 이루어진 외층, (c)내층과 외층의 중량비가 1:9내지 9:1, (d)유리전이온도가 50℃내지 120℃, (e) 평균입경이 200내지 5000A
  2. 제1항에 있어서, 메타아크릴수지가 메타아크릴산 메틸 70중량%이상 및 이것과 공중합 가능한 다른 에틸렌계 불포화 단량체로 이루어진 공중합체인 것을 특징으로 메타아크릴 수지조성물.
  3. 제1항에 있어서, 메타아크릴수지가 아크릴계고무 또는 부타디엔계 고무를 함유하는 고무변성 메타아크릴수지인 것을 특징으로 하는 메타아크릴수지 조성물.
  4. 제1항에 있어서, 메타아크릴수지와 메타아크릴계 2층구조 중합체의 비가 메타아크릴수지 50내지 95중량%와 메타아크릴계 2층구조 중합체 5내지 50중량%인 메타아크릴 수지조성물.
  5. 제1항에 있어서, 메타아크릴계 2중 구조체가 하기 (a)내지 (e)에서 규정되는 것을 특징으로 하는 메타아크릴 수지조성물.
    (a)1분자중에 탄소-탄소2중결합을 2개 이상 갖는 다관능 단량체 0.2내지 5중량%를 함유하는 메타아크릴산메틸을 주성분으로 하는 당관능 단량체를 중합하여 얻어지는 내층, (b) 메타아크릴산메틸을 주성분으로 하는 단고안능 단량체를 이 내층의 존재하에 중합하여 이루허지는 외층, (c)내층과 외층의 중량비가 1:9내지 9:1, (d)유리전이 온도가 80℃내지 120℃, (e)평균입경이 1000내지 4500A.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910006093A 1990-04-16 1991-04-16 메타아크릴수지 조성물 KR0173986B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2-100793 1990-04-16
JP10079390A JP2969770B2 (ja) 1990-04-16 1990-04-16 アクリル樹脂組成物
JP03049434A JP3111487B2 (ja) 1991-03-14 1991-03-14 メタアクリル樹脂組成物
JP3-049434 1991-03-14

Publications (2)

Publication Number Publication Date
KR910018476A true KR910018476A (ko) 1991-11-30
KR0173986B1 KR0173986B1 (ko) 1999-04-01

Family

ID=26389828

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910006093A KR0173986B1 (ko) 1990-04-16 1991-04-16 메타아크릴수지 조성물

Country Status (6)

Country Link
US (1) US5236911A (ko)
EP (1) EP0453198B1 (ko)
KR (1) KR0173986B1 (ko)
CA (1) CA2040481A1 (ko)
DE (1) DE69120852T2 (ko)
TW (1) TW202470B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100497169B1 (ko) * 2002-07-31 2005-06-23 주식회사 엘지화학 고무중합체의 제조방법 및 이를 포함하는 ａｂｓ계 수지

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3396240B2 (ja) * 1992-05-25 2003-04-14 住友化学工業株式会社 メタアクリル樹脂組成物
FR2743078B1 (fr) * 1995-12-28 1998-01-30 Atohaas Holding Cv Composition de resine methacrylique thermoplastique rigide et articles presentant une resistance amelioree aux agents fissurants, obtenus a partir de cette composition
TW476772B (en) * 1996-04-30 2002-02-21 Kureha Chemical Ind Co Ltd Acrylic copolymer, process for producing same and vinyl chloride resin composition containing same
JP3664575B2 (ja) 1997-08-19 2005-06-29 株式会社カネカ メタクリル酸エステル系樹脂組成物及びそれを成形してなるフィルム
DE19859544A1 (de) * 1997-12-25 1999-07-01 Sumitomo Chemical Co Struktur mit hochwertigem Aussehen und Verfahren zu ihrer Herstellung
US6306520B1 (en) * 1997-12-25 2001-10-23 Sumitomo Chemical Company, Limited Laminated film or sheet process for producing same and laminated structure formed using same
GB9919304D0 (en) 1999-08-17 1999-10-20 Ici Plc Acrylic composition
DE10060410A1 (de) * 2000-12-05 2002-06-06 Bayer Ag Thermoplastische Formmassen
DE10145773A1 (de) * 2001-09-17 2003-04-03 Bayer Ag ABS-Zusammensetzungen mit verbesserten Eigenschaftskombinationen
KR101560024B1 (ko) * 2010-10-14 2015-10-16 주식회사 엘지화학 용융 가공 수지 성형품

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2159882A6 (en) * 1970-04-13 1973-06-22 Rohm & Haas Transparent or translucent impact-resistant polyalkylmethacrylate blends
US3793402A (en) * 1971-11-05 1974-02-19 F Owens Low haze impact resistant compositions containing a multi-stage,sequentially produced polymer
JPS537792A (en) * 1976-07-12 1978-01-24 Asahi Chem Ind Co Ltd Solvent-resistant acrylic resins
US4180529A (en) * 1977-12-08 1979-12-25 E. I. Du Pont De Nemours And Company Acrylic multistage graft copolymer products and processes
JPS5815489B2 (ja) * 1978-01-20 1983-03-25 旭化成株式会社 耐溶剤性アクリル系樹脂成形材及びその製造方法
US4385152A (en) * 1979-11-06 1983-05-24 Boyack Robert M Acrylic polymer emulsion
JPS58180413A (ja) * 1982-04-16 1983-10-21 Mitsubishi Metal Corp 化粧料
JPS5910745A (ja) * 1982-07-08 1984-01-20 Mitsubishi Motors Corp 休筒エンジンの制御方法
JPS6160749A (ja) * 1984-08-31 1986-03-28 Mitsubishi Rayon Co Ltd 耐溶剤性メタクリル樹脂組成物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100497169B1 (ko) * 2002-07-31 2005-06-23 주식회사 엘지화학 고무중합체의 제조방법 및 이를 포함하는 ａｂｓ계 수지

Also Published As

Publication number Publication date
EP0453198B1 (en) 1996-07-17
EP0453198A2 (en) 1991-10-23
CA2040481A1 (en) 1991-10-17
DE69120852T2 (de) 1997-02-06
KR0173986B1 (ko) 1999-04-01
EP0453198A3 (en) 1992-02-05
US5236911A (en) 1993-08-17
DE69120852D1 (de) 1996-08-22
TW202470B (ko) 1993-03-21

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