KR870005021A - Pvc용의 투명한 내충격성 개량제 - Google Patents
Pvc용의 투명한 내충격성 개량제 Download PDFInfo
- Publication number
- KR870005021A KR870005021A KR860009241A KR860009241A KR870005021A KR 870005021 A KR870005021 A KR 870005021A KR 860009241 A KR860009241 A KR 860009241A KR 860009241 A KR860009241 A KR 860009241A KR 870005021 A KR870005021 A KR 870005021A
- Authority
- KR
- South Korea
- Prior art keywords
- styrene
- weight
- parts
- acrylonitrile
- butadiene
- Prior art date
Links
- 239000004609 Impact Modifier Substances 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 16
- 239000000203 mixture Substances 0.000 claims 11
- 229920000578 graft copolymer Polymers 0.000 claims 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 8
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 8
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims 6
- 229920000638 styrene acrylonitrile Polymers 0.000 claims 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 4
- 238000004132 cross linking Methods 0.000 claims 2
- 238000010559 graft polymerization reaction Methods 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/932—Blend of matched optical properties
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 필수적으로 부타디엔 78 내지 95중량%, 스티렌 22 내지 5중량% 및 공중합 가능한 다가의 교차 결합 단량체 2중량% 이하로 이루어진 스티렌 부타디엔 공중합체 100중량부의 존재하에 스티렌/아크릴로니트릴 중량비가 3.8/1 내지 4.2/1인 스티렌과 아크릴로니트릴과의 혼합물 약 42 내지 67중량부를 그래프트 중합시켜 제조한 그래프트 공중합체.
- 제1항에 있어서, 스티렌- 아크릴로니트릴 혼합물의 양이 스티렌 부타디엔 공중합체 100중량부당 47 내지 61중량부인 그래프트 공중합체.
- 제1항에 있어서, 스티렌- 아크릴로니트릴 혼합물의 양이 스티렌- 부타디엔 공중합체 100중량부당 47내지 61중량부이고 스티렌- 아크릴로니트릴 중량비가 4.0/1인 그래프트 공중합체.
- 제1항에 있어서, 스티렌- 부타디엔 공중합체가 부타디엔 78 내지 95중량% 및 스티렌 22 내지 5중량%로 이루어진 그래프트 공중합체.
- 제1항에 있어서, 겉보기 굴절률이 1.5500 내지 1.5400인 그래프트 공중합체.
- PVC : 및 필수적으로 부타디엔 78 내지 95중량%, 스티렌 22 내지 5중량% 및 공중합 가능한 다가의 교차 결합 단량체 2중량% 이하로 이루어진 스티렌- 부타디엔 공중합체 100중량부의 존재하에 스티렌/아크릴로니트릴 중량비가 3.8/1 내지 4.2/1인 스티렌과 아크릴로니트릴과의 혼합물 42 내지 67중량부를 그래프트 중합시켜 제조한 그래프트 공중합체로 PVC를 이루어진 내충격성이 개량된 투명한 PVC 조성물.
- 제6항에 있어서, 그래프트 공중합체의 굴절률이 1.5500 내지 1.5400인 내충격성이 개량된 투명한 PVC 조성물.
- 제6항에 있어서, 그래프트 공중합체 중의 스티렌- 아크릴로니트릴 혼합물의 양이 스티렌-부타디엔 공중합체 100중량부당 47 내지 61중량부인 내충격성이 개량된 투명한 PVC 조성물.
- 제6항에 있어서, 스티렌-부타디엔 공중합체가 부타디엔 78 내지 95중량% 및 스티렌 22 내지 5중량%로 이루어진 내충격성이 개량된 투명한 PVC 조성물.
- 제6항에 있어서, 공중합체 중의 스티렌-아크릴로니트릴 혼합물의 양이 스티렌- 부타디엔 공중합체 100중량부당 47 내지 61중량부이고 스티렌-아크릴로니트릴 중량비가 4.0/1인 내충격성이 개량된 투명한 PVC 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US79436285A | 1985-11-04 | 1985-11-04 | |
US794,362 | 1985-11-04 | ||
US794.362 | 1985-11-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870005021A true KR870005021A (ko) | 1987-06-04 |
KR940003859B1 KR940003859B1 (ko) | 1994-05-04 |
Family
ID=25162432
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860009241A KR940003859B1 (ko) | 1985-11-04 | 1986-11-03 | Pvc용의 투명한 내충격성 개량제 |
Country Status (10)
Country | Link |
---|---|
US (1) | US4764563A (ko) |
EP (1) | EP0221456B1 (ko) |
JP (1) | JPH0788415B2 (ko) |
KR (1) | KR940003859B1 (ko) |
CN (1) | CN1005983B (ko) |
AR (1) | AR242812A1 (ko) |
AU (1) | AU604219B2 (ko) |
BR (1) | BR8605428A (ko) |
CA (1) | CA1315906C (ko) |
DE (1) | DE3687509T2 (ko) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX168323B (es) * | 1986-10-21 | 1993-05-18 | Rohm & Haas | Modificadores de impacto de nucleo cubierto para resinas estirenicas |
DE3831853A1 (de) * | 1988-09-20 | 1990-03-29 | Bayer Ag | Zur herstellung transparenter thermoplastischer formmassen geeignete pfropfpolymerisate |
JPH07116340B2 (ja) * | 1989-03-10 | 1995-12-13 | 鐘淵化学工業株式会社 | 射出成形用難燃性樹脂組成物 |
DE4006643A1 (de) * | 1990-03-03 | 1991-09-05 | Basf Ag | Teilchenfoermiges pfropfpolymerisat mit verbesserter haftung zwischen pfropfgrundlage und pfropfhuelle |
DE4011163A1 (de) * | 1990-04-06 | 1991-10-10 | Basf Ag | Teilchenfoermiges pfropfpolymerisat und daraus hergestellte thermoplastische formmasse mit verbesserter zaehigkeit |
US5486562A (en) * | 1990-07-12 | 1996-01-23 | General Electric Company | Modifications of poly(alkylene cyclohexanedicarboxylate) blends |
DE4142910A1 (de) * | 1991-12-24 | 1993-07-01 | Basf Ag | Schlagzaehmodifier und diesen enthaltende formmasse |
US5614589A (en) * | 1993-11-15 | 1997-03-25 | Kawasaki Chemical Holding Co., Inc. | Transparent, antistatic thermoplastic composition and methods of making the same |
CN1489522A (zh) * | 2000-12-22 | 2004-04-14 | 艾弗里・丹尼森公司 | 顺从的薄膜和由其制得的制品 |
JP2003064233A (ja) * | 2001-08-27 | 2003-03-05 | C I Kasei Co Ltd | 農業用塩化ビニル系樹脂フィルム及び塩化ビニル系樹脂組成物 |
CN100404241C (zh) * | 2002-04-17 | 2008-07-23 | 屠林华 | 一种超薄软面abs塑料箱包及其生产方法 |
EP1517945A4 (en) * | 2002-06-27 | 2006-04-05 | Avery Dennison Corp | CONFORMABLE CALANDER FILM AND ARTICLES THEREOF |
US7302915B2 (en) * | 2005-02-23 | 2007-12-04 | Pawplunger Llc | Portable device for cleaning an animal's paw |
CN109504027A (zh) * | 2018-11-23 | 2019-03-22 | 谢岳贤 | 一种耐老化的abs和pvc混合塑料配方 |
CN109734979A (zh) * | 2019-01-11 | 2019-05-10 | 张海涛 | 一种耐冲击品质稳定的塑胶材料的制备方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB841849A (ko) * | ||||
DE1420576A1 (de) * | 1956-07-25 | 1968-12-19 | Monsanto Co | Verfahren zur Herstellung von Mischpolymerisaten |
FR2008612A1 (ko) * | 1968-05-15 | 1970-01-23 | Polymer Corp | |
US3636138A (en) * | 1968-08-05 | 1972-01-18 | Monsanto Co | Process for impact modification of vinyl halide polymers and impact modifiers and vinyl halide blends produced therewith |
GB1267984A (en) * | 1968-08-31 | 1972-03-22 | Kureha Chemical Ind Co Ltd | Polyvinyl chloride resin composition of improved transparency and impact resistance and preparation therefor |
US3657391A (en) * | 1969-03-12 | 1972-04-18 | Borg Warner | Graft copolymers of styrene acrylonitrile and methyl acrylate onto diene polymers and blends thereof with vinyl chloride resins |
US3792125A (en) * | 1971-12-02 | 1974-02-12 | Uniroyal Inc | Transparent heat resistant gum plastic |
US3900529A (en) * | 1973-10-09 | 1975-08-19 | Monsanto Co | Rubber modified high nitrile polymers and polymer blends produced thereby |
US3900528A (en) * | 1973-10-09 | 1975-08-19 | Monsanto Co | Process for impact modification of high nitrile polymers |
JPS54140503A (en) * | 1978-04-24 | 1979-10-31 | Kureha Chemical Ind Co Ltd | Transparent resin composition for information disk |
JPS57212246A (en) * | 1981-06-23 | 1982-12-27 | Kureha Chem Ind Co Ltd | Vinyl chloride resin composition |
DE3217874A1 (de) * | 1982-05-12 | 1983-11-17 | Bayer Ag, 5090 Leverkusen | Pfropfkautschuke zur modifizierung thermoplastischer formmassen |
JPS5984912A (ja) * | 1982-11-04 | 1984-05-16 | Mitsui Toatsu Chem Inc | ゴム変性耐衝撃性樹脂の連続的製造方法 |
US4507435A (en) * | 1983-12-27 | 1985-03-26 | Mobil Oil Corporation | Blends of polyvinyl chloride and copolymers containing para-methyl styrene and acrylonitrile having improved clarity |
-
1986
- 1986-10-16 CA CA000520618A patent/CA1315906C/en not_active Expired - Fee Related
- 1986-10-23 DE DE8686114706T patent/DE3687509T2/de not_active Expired - Fee Related
- 1986-10-23 EP EP86114706A patent/EP0221456B1/en not_active Expired - Lifetime
- 1986-10-30 AU AU64532/86A patent/AU604219B2/en not_active Ceased
- 1986-11-03 KR KR1019860009241A patent/KR940003859B1/ko not_active IP Right Cessation
- 1986-11-04 JP JP61262594A patent/JPH0788415B2/ja not_active Expired - Lifetime
- 1986-11-04 AR AR86305782A patent/AR242812A1/es active
- 1986-11-04 BR BR8605428A patent/BR8605428A/pt not_active IP Right Cessation
- 1986-11-04 CN CN86107555.2A patent/CN1005983B/zh not_active Expired
-
1987
- 1987-02-27 US US07/020,283 patent/US4764563A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPS62106915A (ja) | 1987-05-18 |
KR940003859B1 (ko) | 1994-05-04 |
US4764563A (en) | 1988-08-16 |
CN1005983B (zh) | 1989-12-06 |
BR8605428A (pt) | 1987-08-11 |
JPH0788415B2 (ja) | 1995-09-27 |
AU604219B2 (en) | 1990-12-13 |
CN86107555A (zh) | 1987-04-29 |
EP0221456B1 (en) | 1993-01-13 |
CA1315906C (en) | 1993-04-06 |
EP0221456A3 (en) | 1990-01-03 |
EP0221456A2 (en) | 1987-05-13 |
DE3687509D1 (de) | 1993-02-25 |
AR242812A1 (es) | 1993-05-31 |
DE3687509T2 (de) | 1993-08-26 |
AU6453286A (en) | 1987-05-07 |
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