KR910014347A - 티오알칸산-치환된 n.n-디알킬히드록시아민 및 안정화된 윤활제 조성물 - Google Patents

티오알칸산-치환된 n.n-디알킬히드록시아민 및 안정화된 윤활제 조성물 Download PDF

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KR910014347A
KR910014347A KR1019910001351A KR910001351A KR910014347A KR 910014347 A KR910014347 A KR 910014347A KR 1019910001351 A KR1019910001351 A KR 1019910001351A KR 910001351 A KR910001351 A KR 910001351A KR 910014347 A KR910014347 A KR 910014347A
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compound
alkyl
lubricant composition
dialkylhydroxyamines
substituted
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KR1019910001351A
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KR0156260B1 (ko
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에반스 사무엘
케이산 데이비드
셀처 레이몬드
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베르너 발데크
시바-가이기 아게
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/32—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
    • C07C327/34—Esters of monothiocarboxylic acids having sulfur atoms of esterified thiocarboxyl groups bound to carbon atoms of hydrocarbon radicals substituted by carboxyl groups with amino groups bound to the same hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/20—Thiols; Sulfides; Polysulfides
    • C10M135/22—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M135/26—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/60—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton with the carbon atom of at least one of the carboxyl groups bound to nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C327/00—Thiocarboxylic acids
    • C07C327/20—Esters of monothiocarboxylic acids
    • C07C327/22—Esters of monothiocarboxylic acids having carbon atoms of esterified thiocarboxyl groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

티오알칸산-치환된 N.N-디알킬히드록시아민 및 안정화된 윤활제 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 일반식(Ⅰ)의 화합물 :
    상기 식에서, R, R1, R3및 R4은 독립적으로 H, C1-C18-알킬, 또는 C6-C10-아릴이고, X는 OR2, SR2또는 NR3R4이고, R2는 H, C1-C24-알킬, C5-C12-시클로알킬, C7-C9-아랄킬 또는 -(CH2CH2O)nCH2CH2OR5이며, m은 0내지 6이고, R5는 C1-C18알킬이고, n은 1 또는 2이다.
  2. 제1항에 있어서, R 및 R1이 H인 화합물.
  3. 제2항에 있어서, X가 OR2또는 SR2인 경우 R2가 C8-알킬이고, n이 1인 화합물.
  4. 제1항에 있어서, N,N-비스(2-에틸헥실옥시카르보닐메틸티오메틸)히드록시아민인 화합물.
  5. 제1항에 있어서, N,N-비스(이소옥틸옥시카르보닐메틸티오메틸)히드록시아민인 화합물.
  6. 광물유 또는 합성 유체 또는 이들의 혼합물, 및 하기 일반식(Ⅰ)의 화합물 안정화 유효량을 포함하는 윤활제 조성물.
    상기 식에서, R, R1, R3및 R4은 독립적으로 H, C1-C18-알킬, 또는 C6-C10-아릴이고, X는 OR2, SR2또는 NR3R4이고, R2는 H, C1-C24-알킬, C5-C12-시클로알킬, C7-C9-아랄킬 또는 -(CH2CH2O)nCH2CH2OR5이며, m은 0내지 6이고, R5는 C1-C18알킬이고, n은 1 또는 2이다.
  7. 제6항에 있어서, R 및 R1이 H인 일반식(Ⅰ)의 화합물을 함유하는 윤활제 조성물.
  8. 제7항에 있어서, X가 OR2또는 SR2인 경우 R2가 C8-알킬이고, n이 1인 일반식(Ⅰ)의 화합물을 함유하는 윤활제 조성물.
  9. 제6항에 있어서, 일반식(Ⅰ)의 화합물이 N,N-비스(2-에틸헥실옥시카르보닐메틸티오메틸)히드록시아민인 윤활제 조성물.
  10. 제1항에 따른 일반식(Ⅰ)의 화합물 안정화 유효량을 첨가하는 것을 포함하는, 산화로 인한 열화에 대해 윤활제를 안정화시키는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910001351A 1990-01-26 1991-01-24 티오알칸산-치환된 n,n-디알킬히드록시아민 및 안정화된 윤활제 조성물 KR0156260B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/471,167 US5019285A (en) 1990-01-26 1990-01-26 Thioalkanoic acid substituted N,N-dialkylhydroxylamines and stabilized lubricant compositions
US471,167 1990-01-26

Publications (2)

Publication Number Publication Date
KR910014347A true KR910014347A (ko) 1991-08-31
KR0156260B1 KR0156260B1 (ko) 1998-12-01

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KR1019910001351A KR0156260B1 (ko) 1990-01-26 1991-01-24 티오알칸산-치환된 n,n-디알킬히드록시아민 및 안정화된 윤활제 조성물

Country Status (8)

Country Link
US (1) US5019285A (ko)
EP (1) EP0439431B1 (ko)
JP (1) JP2896386B2 (ko)
KR (1) KR0156260B1 (ko)
BR (1) BR9100315A (ko)
CA (1) CA2034891A1 (ko)
DE (1) DE69100632T2 (ko)
ES (1) ES2060338T3 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5405545A (en) * 1993-03-02 1995-04-11 Mobil Oil Corporation Antiwear and antioxidant additives
US20020088574A1 (en) * 1998-10-22 2002-07-11 Raymond Seltzer Inhibition of pulp and paper yellowing using hydroxylamines and other coadditives
US6599326B1 (en) 1999-01-20 2003-07-29 Ciba Specialty Chemicals Corporation Inhibition of pulp and paper yellowing using hydroxylamines and other coadditives
US20020198297A1 (en) * 2001-03-02 2002-12-26 Odorisio Paul A. Polyester and polyamide compositions of low residual aldehyde content
US6908650B2 (en) * 2001-03-02 2005-06-21 Ciba Specialty Chemicals Corporation Polyester and polyamide compositions of low residual aldehyde content
KR100822007B1 (ko) * 2001-03-20 2008-04-15 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 방염성 조성물
WO2016109789A1 (en) 2014-12-31 2016-07-07 Basf Se Candle wax compositions stabilized with uv absorbers and select hindered amine light stabilizers

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3408422A (en) * 1964-11-04 1968-10-29 Shell Oil Co Stabilization of unsaturated polyesters and resulting products
US3644278A (en) * 1968-03-04 1972-02-22 Ciba Geigy Corp Substituted hydroxylamine stabilizers
US3778464A (en) * 1972-10-10 1973-12-11 P Klemchuk Substituted hydroxylamine anti-oxidants
US4242224A (en) * 1979-08-17 1980-12-30 The Goodyear Tire & Rubber Company Color stabilization of amine antioxidant and antiozonant emulsions
US4316996A (en) * 1980-11-17 1982-02-23 The Goodyear Tire & Rubber Company Discoloration prevention of phenolic antioxidants
US4547532A (en) * 1982-04-02 1985-10-15 M&T Chemicals Inc. Antifouling paint
US4590231A (en) * 1983-10-11 1986-05-20 Ciba-Geigy Corporation Polyolefin compositions stabilized against degradation using hydroxylamine derivatives
US4612393A (en) * 1985-04-29 1986-09-16 Ciba-Geigy Corporation Bis(substituted thioalkyl)hydroxylamines and stabilized polyolefin compositions
US4720517A (en) * 1986-11-24 1988-01-19 Ciba-Geigy Corporation Compositions stabilized with N-hydroxyiminodiacetic and dipropionic acids and esters thereof
ATE92916T1 (de) * 1987-04-08 1993-08-15 Ciba Geigy Ag Schwefelhaltige verbindungen als antioxidantien fuer schmiermittel und elastomere.
FR2633618B1 (fr) * 1988-06-29 1991-03-22 M & T Chemicals Inc Nouveaux esters renfermant un groupement dithioacetal, leur preparation et leur application a la stabilisation des matieres organiques

Also Published As

Publication number Publication date
KR0156260B1 (ko) 1998-12-01
ES2060338T3 (es) 1994-11-16
CA2034891A1 (en) 1991-07-27
BR9100315A (pt) 1991-10-22
DE69100632D1 (de) 1993-12-23
JP2896386B2 (ja) 1999-05-31
EP0439431A1 (en) 1991-07-31
EP0439431B1 (en) 1993-11-18
DE69100632T2 (de) 1994-05-11
JPH04342563A (ja) 1992-11-30
US5019285A (en) 1991-05-28

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