KR910003078A - 윤활제 조성물 - Google Patents

윤활제 조성물 Download PDF

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KR910003078A
KR910003078A KR1019890010211A KR890010211A KR910003078A KR 910003078 A KR910003078 A KR 910003078A KR 1019890010211 A KR1019890010211 A KR 1019890010211A KR 890010211 A KR890010211 A KR 890010211A KR 910003078 A KR910003078 A KR 910003078A
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South Korea
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hydrogen
composition
methyl
alkyl
compound
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KR1019890010211A
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English (en)
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KR970007781B1 (en
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슈마커 롤프
에반스 사무엘
둠스 포일
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베르니 발데크
시바-가이기 아게
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Publication of KR910003078A publication Critical patent/KR910003078A/ko
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Publication of KR970007781B1 publication Critical patent/KR970007781B1/ko

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Abstract

내용 없음.

Description

윤활제 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (74)

  1. 하기 성분(A), (B) 및 (C)를 포함하는 윤활제 조성물: (A)광물성 또는 합성 베이스오일, 혹은 그러한 오일들의 혼합물, (B) 하기 일반식(Ⅰ) 또는 (Ⅱ)를 갖는 한가지 이상의 방향족 아민:
    (상기식에서, R1은 C1-C18알킬, C7-C9페닐알킬, C5-C12시클로알킬, 페닐, C7-C18알킬페닐, C7-C18알콕시페닐 또는 나프틸이고, R2은 페닐, C7-C18알킬페닐, C7-C18알콕시페닐 또는 나프틸이고, R3은 수소 C1-C12알킬, 벤질, 알릴, 메탈릴, 페닐 또는 -CH2SR4기이고, R4은 C4-C18알킬, -CH2COO(C4-C18알킬) 또는 -CH2CH2COO(C4-C18알킬)이며, R5와 R6는 서로 독립적으로 H, C1-C18알킬 또는 C1-C18알킬 또는 C7-C8페닐알킬이다.) (C)한가지 이상의 입체 장해아민.
    (상기식에서, R1은 C1-C18알킬, C7-C9페닐알킬, C5-C12시클로알킬, 페닐, C7-C18알킬페닐, C7-C18알콕시페닐 또는 나프틸이고, R2은 페닐, C7-C18알킬페닐, C7-C18알콕시페닐 또는 나프틸이고, R3은 수소 C1-C12알킬, 벤질, 알릴, 메탈릴, 페닐 또는 -CH2SR4기이고, R4은 C4-C18알킬, -CH2COO(C4-C18알킬) 또는 -CH2CH2COO(C4-C18알킬)이며, R5와 R6는 서로 독립적으로 H, C1-C18알킬 또는 C1-C18알킬 또는 C7-C8페닐알킬이다.) (C)한가지 이상의 입체 장해아민.
    (상기식에서, R1은 C1-C18알킬, C7-C9페닐알킬, C5-C12시클로알킬, 페닐, C7-C18알킬페닐, C7-C18알콕시페닐 또는 나프틸이고, R2은 페닐, C7-C18알킬페닐, C7-C18알콕시페닐 또는 나프틸이고, R3은 수소 C1-C12알킬, 벤질, 알릴, 메탈릴, 페닐 또는 -CH2SR4기이고, R4은 C4-C18알킬, -CH2COO(C4-C18알킬) 또는 -CH2CH2COO(C4-C18알킬)이며, R5와 R6는 서로 독립적으로 H, C1-C18알킬 또는 C7-C8페닐알킬이다.) (C)한가지 이상의 입체 장해아민.
  2. 제1항에 있어서, R1은 C1-C4알킬, C7-C9페닐알킬, 시클로헥실, 페닐, C10-C18알킬페닐 또는 나프틸이고, R2가 C10-C18알킬페닐 또는 페닐이고, R3은 수소, C1-C8알킬, 벤질, 알릴, 또는 -CH2SR4이며, R4가 C8-C18알킬 또는 -CH2COO(C8-C18알킬)이고 R5와 R6는 서로 독립적으로 H, C1-C12알킬 또는 C7-C9페닐알킬인 일반식(Ⅰ) 또는 (Ⅱ)의 화합물 한가지 이상을 성분(B)로서 포함하는 조성물.
  3. 제1항에 있어서, R1과 R2가 서로 독립적으로 페닐 또는 C10-C18알킬페닐이고 R3가 수소인 일반식(Ⅰ)의 화합물 한가지 이상을 성분(B)로서 포함하는 조성물.
  4. 제1항에 있어서, R3가 수소이고 R5과 R6가 서로 독립적으로 H 또는 C1-C12알킬인 일반식(Ⅱ)의 화합물 한가지 이상을 성분(B)로서 포함하는 조성물.
  5. 제1항에 있어서, 4.4′-디-3차-옥틸디페닐아민, 3.7-디-3차-억틸페노티아진, 또는 디페닐아민을 디이소부틸렌과 반응시킴으로써 얻어진 공업용 혼합물을 성분(B)로서 포함하는 조성물.
  6. 제1항에 있어서, 하기 일반식(Ⅲ)의 기를 한개 이상 함유하는 화합물을 성분(C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이다.
  7. 제1항에 있어서, R3가 수소이고 R5과 R6가 서로 독립적으로 H 또는 C1-C12알킬인 일반식(Ⅱ)의 화합물 한가지 이상을 성분(B)로서 포함하는 조성물.
  8. 제1항에 있어서, 4.4′-디-3차-옥틸디페닐아민, 3.7-디-3차-억틸페노티아진, 또는 디페닐아민을 디이소부틸렌과 반응시킴으로써 얻어진 공업용 혼합물을 성분(B)로서 포함하는 조성물.
  9. 제1항에 있어서, 하기 일반식(Ⅲ)의 기를 한개 이상 함유하는 화합물을 성분(C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이다.
  10. 제1항에 있어서, 4.4′-디-3차-옥틸디페닐아민, 3.7-디-3차-억틸페노티아진, 또는 디페닐아민을 디이소부틸렌과 반응시킴으로써 얻어진 공업용 혼합물을 성분(B)로서 포함하는 조성물.
  11. 제1항에 있어서, 하기 일반식(Ⅲ)의 기를 한개 이상 함유하는 화합물을 성분(C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이다.
  12. 제1항에 있어서, 하기 일반식(Ⅲ)의 기를 한개 이상 함유하는 화합물을 성분(C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이다.
    상기식에서 R은 수소 또는 메틸이다.
    상기식에서 R은 수소 또는 메틸이다.
  13. 제6항에 있어서, R이 수소인 조성물.
  14. 제6항에 있어서, 하기 일반식(Ⅳ)의 화합물을 성분(C)로서 포함하는 조성물.
    상기식에서, R은 수소이고, R11은 수소 또는 메틸이고, n은 2이며, R12는 탄소수 4~12인 지방족 디카르복실산의 디아실디칼이다.
  15. 제6항에 있어서, 하기 일반식(Ⅴ)의 화합물을 성분(C)로서 포함하는 조성물.
    상기식에서, n은 1 또는 2이고, R는 소수이고 R11은 수소 또는 메틸이고, R13은 수소, C1-C12알콜 또는 하기 일반식의 기이고.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  16. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  17. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  18. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  19. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
  20. 제6항에 있어서, 하기 일반식(Ⅳ)의 화합물을 성분(C)로서 포함하는 조성물.
    상기식에서, R은 수소이고, R11은 수소 또는 메틸이고, n은 2이며, R12는 탄소수 4~12인 지방족 디카르복실산의 디아실디칼이다.
  21. 제6항에 있어서, 하기 일반식(Ⅴ)의 화합물을 성분(C)로서 포함하는 조성물.
    상기식에서, n은 1 또는 2이고, R는 소수이고 R11은 수소 또는 메틸이고, R13은 수소, C1-C12알콜 또는 하기 일반식의 기이고.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  22. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  23. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  24. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  25. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
    상기식에서, R은 수소이고, R11은 수소 또는 메틸이고, n은 2이며, R12는 탄소수 4~12인 지방족 디카르복실산의 디아실디칼이다.
  26. 제6항에 있어서, 하기 일반식(Ⅴ)의 화합물을 성분(C)로서 포함하는 조성물.
    상기식에서, n은 1 또는 2이고, R는 소수이고 R11은 수소 또는 메틸이고, R13은 수소, C1-C12알콜 또는 하기 일반식의 기이고.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  27. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  28. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  29. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  30. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
    상기식에서, R은 수소이고, R11은 수소 또는 메틸이고, n은 2이며, R12는 탄소수 4~12인 지방족 디카르복실산의 디아실디칼이다.
  31. 제6항에 있어서, 하기 일반식(Ⅴ)의 화합물을 성분(C)로서 포함하는 조성물.
    상기식에서, n은 1 또는 2이고, R는 소수이고 R11은 수소 또는 메틸이고, R13은 수소, C1-C12알콜 또는 하기 일반식의 기이고.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  32. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  33. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  34. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  35. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
  36. 제6항에 있어서, 하기 일반식(Ⅴ)의 화합물을 성분(C)로서 포함하는 조성물.
    상기식에서, n은 1 또는 2이고, R는 소수이고 R11은 수소 또는 메틸이고, R13은 수소, C1-C12알콜 또는 하기 일반식의 기이고.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  37. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  38. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  39. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  40. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
    상기식에서, n은 1 또는 2이고, R는 소수이고 R11은 수소 또는 메틸이고, R13은 수소, C1-C12알콜 또는 하기 일반식의 기이고.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  41. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  42. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  43. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  44. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
    상기식에서, n은 1 또는 2이고, R는 소수이고 R11은 수소 또는 메틸이고, R13은 수소, C1-C12알콜 또는 하기 일반식의 기이고.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  45. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  46. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  47. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  48. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  49. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  50. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  51. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  52. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
    n이 1일때 R14는 수소 또는 C1-C12알킬이고, n이 2일때는 R14가 C2-C8알킬렌이다.
  53. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  54. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  55. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  56. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
  57. 제6항에 있어서, 하기 일반식(Ⅸ)의 화합물을 성분 (C)로서 포함하는 조성물:
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  58. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  59. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  60. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  61. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  62. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  63. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
    상기식에서 R은 수소 또는 메틸이고, R11은 수소 또는 메틸이다.
  64. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  65. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  66. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
  67. 제1항에 있어서, (B)와 (C)의 합량이 (A)를 기준으로 0.1내지 2중량%인 조성물.
  68. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  69. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
  70. 제1항에 있어서, (C)에 대한 (B)의 비가 중량부 기준으로 3내지 5인 조성물.
  71. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
  72. 제1항에 있어서, 페놀류 황산화제 (D)를 포함하는 조성물.
  73. 제1항에 있어서, 지방족 또는 방향족 포스파이트 또는 포스포나이트(E)를 포함하는 조성물.
  74. 자동차 오일로서 제1항에 따른 조성물의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR89010211A 1988-07-18 1989-07-18 Lubricating oil composition KR970007781B1 (en)

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EP0356677A1 (de) 1990-03-07
EP0356677B1 (de) 1993-06-09
KR970007781B1 (en) 1997-05-16
US5073278A (en) 1991-12-17
ZA895408B (en) 1990-03-28
MX169536B (es) 1993-07-09
AU621910B2 (en) 1992-03-26
CN1020748C (zh) 1993-05-19
JP2832541B2 (ja) 1998-12-09
AU3817489A (en) 1990-01-18
CN1041610A (zh) 1990-04-25
CA1334532C (en) 1995-02-21
DE58904610D1 (de) 1993-07-15
BR8903526A (pt) 1990-03-13
JPH0273894A (ja) 1990-03-13
SU1736343A3 (ru) 1992-05-23
ES2055762T3 (es) 1994-09-01

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