KR950703514A - 유성 조성물(oleaginous compositions) - Google Patents

유성 조성물(oleaginous compositions) Download PDF

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KR950703514A
KR950703514A KR1019950701319A KR19950701319A KR950703514A KR 950703514 A KR950703514 A KR 950703514A KR 1019950701319 A KR1019950701319 A KR 1019950701319A KR 19950701319 A KR19950701319 A KR 19950701319A KR 950703514 A KR950703514 A KR 950703514A
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KR100313182B1 (ko
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그라함 잭슨
레이첼 에벌린 메리 켄워드
바바라 캐써린 브룩
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케이쓰 로드니 만셀
엑손 케미칼 패턴츠 인코포레이티드
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Abstract

본 발명은 유성 조성물의 첨가제로서 유용한 하기 일반식(Ⅰ)의 화합물에 관한 것이다;
상기식에서, B는 방향족 시시템을 나타내고, A는 하이드로카빌 그룹을 나타내고, R1및 R2는 같거나 다르며, 각각 독립적으로 탄소 원자 1 내지 40 개를 함유하는 지방족 하이드로카빌 그룹이나, R1및 R2중 하나는 수소원자를 나타낼 수 있고, z는 적어도 1이고, 방향족 시스템은 고리 시스템에 대한 활성화 그룹 또는 이의 유도체인 적어도 하나의 치환 그룹을 운반한다.

Description

유성 조성물(OLEAGINOUS COMPOSITIONS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (22)

  1. 유성 조성물질과 첨가제로 하기 일반식(Ⅰ)을 갖는 화합물 또는 이들의 염을 포함하는 조성물;
    상기식에서, B는 방향족 시시템을 나타내고, A는 하이드로카빌 그룹을 나타내고, R1및 R2는 같거나 다르며, 각각 독립적으로 탄소 원자 10 내지 40 개를 함유하는 지방족 하이드로카빌이나, 단 R1및 R2중 하나는 수소원자를 나타낼 수 있으며, z는 적어도 1이고, 방향족 시스템은 고리 시스템에 대한 활성화 그룹 또는 이의 유도체인 적어도 하나의 치환 그룹을 갖는다.
  2. 제1항에 있어서 상기 방향족 시스템이 또한 하기 일반식(Ⅱ)의 치환체를 갖는 조성물:
    상기식에서, R1및 R2는 제1항에서 정의한 바와 같으며, Q는 하이드로카빌 그룹을 나타내고, w는 0 또는 1이다.
  3. 제1 또는 제2항에 있어서, 상기 활성화 그룹이 만니히(Mannich) 반응에 대한 활성화 그룹인 조성물.
  4. 제1항 내지 제3항중 어느 한 항에 있어서, 상기 활성화 그룹이 하이드록실 그룹인 조성물.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, 상기 활성화 그룹의 유도체가 아세틸 유도체인 조성물.
  6. 제1항 내지 제5항중 어느 한 항에 있어서, A가 메틸렌 그룹을 나타내는 조성물.
  7. 제1항에 있어서, 일반식(Ⅰ)의 화합물이 하기 일반식(Ⅲ)을 갖는 조성물:
    상기식에서, X는 수소 또는 하이드로카빌 그룹 또는 하이드카빌이 아닌 그룹 또는 하기 일반식(Ⅳ)의 그룹이고;
    Y는 이가 그룹이고, a는 1, 2, 3, 4 또는 5이고, b는 1, 2, 3 또는 4이고, c는 0, 1 또는 2이고, d는 0, 1, 2, 3 또는 4이고, e는 0, 1, 2, 3 또는 4이고, R3, R4, R7및 R8은 수소 또는 하이드로카빌 그룹이고, R1또는 R2은 독립적으로 C10-C40지방족 하이드로카빌 그룹이고, D는 하이드록실 그룹 또는 하이드록실그룹의 유도체를 나타낸다.
  8. 제1항 내지 제7항중 어느 한 항에 있어서, R1또는 R2가 독립적으로 C12내지 C24지방족 하이드로카빌 그룹인 조성물.
  9. 제8항에 있어서, R1또는 R2가 독립적으로 C16내지 C22지방족 하이드로카빌 그룹인 조성물.
  10. 제7항 제9항 중 어느 한 항에 있어서, R3R4R7및 R8이 수소인 조성물.
  11. 제1항 내지 제10항 중 어느 한 항에 있어서, 상기 유성 물질이 연료유이고, 상기 화합물이 연료의 10 내지 2000 중량 ppm의 농도로 존재하는 조성물.
  12. 제11항에 있어서, 상기 화합물이 25 내지 500 중량ppm의 비율로 존재하는 조성물.
  13. 제12항에 있어서, 상기 화합물이 100 내지 500 중량ppm의 비율로 존재하는 조성물.
  14. 제11항 내지 제13항중 어느 한 항에 있어서, 제1항 내지 제10항중 어느 한 항에 정의된 첨가제이외의 첨가제 또는 이 첨가제의 혼합물을 포함하고 상기 기타 첨가제들이 하나 이상의 하기 화합물인 조성물: 극성 N 화합물, 빗형 중합체(comb polymer), 폴리옥시알킬렌 에스테르, 에테르, 에스테르/에테르, 아미드/에스테르, 에틸렌-불포화 에스테르 공중합체 탄화수소 중합체, 및 황 카복시 화합물.
  15. 제1항 내지 제10항중 어느 한 항에 있어서, 상기 유성 물질이 윤활유이고, 상기 화합물이 조성물의 총 중량을 기준으로 0.01 내지 약 15중량%의 비율로 존재하는 조성물.
  16. 연료유 또는 연료유와 혼화되는 용매중에 제1항 내지 제10항 중 어느 한 항에 정의된 바와 같은 화합물 3 내지 75 중량%를 포함하는 첨가제 농축물.
  17. 윤활유 또는 윤활유와 혼화되는 용매중에 제1항 내지 제10항 중 어느 한 항에 정의된 바와 같은 화합물 10 내지 80 중량%를 포함하는 첨가제 농축물.
  18. 유성 물질중의 첨가제로서 제1항 내지 제10항중 어느 한 항에 정의된 화합물의 용도.
  19. 연료유중의 왁스 첨가제 결정 개질제로의 제1항 내지 제10항 중 어느 한항에 정의된 화합물의 용도.
  20. 활성화 그룹이 하이드록실 그룹인, 제1항에 정의된 바와 같은 일반식(Ⅰ)을 갖는 화합물.
  21. 제20항에 있어서, R1및 R2가 탄소 원자 12개 내지 40개를 함유하는 화합물.
  22. 하이드록시방향족 화합물, 포름알데하이드 또는 알데하이드와 C1-C40지방족 하이드로카빌 그룹을 포함하는 2급 아민을 만니히 축합 조건하에 함께 반응시키는, 제20항 또는 제21항에 청구한 바와 같은 화합물의 제조 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950701319A 1992-10-05 1993-10-05 유성조성물 KR100313182B1 (ko)

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GB929220876A GB9220876D0 (en) 1992-10-05 1992-10-05 Compounds useful in oleaginous compositions
PCT/EP1993/002739 WO1994007842A1 (en) 1992-10-05 1993-10-05 Oleaginous compositions

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GB9426290D0 (en) * 1994-12-28 1995-02-22 Zeneca Ltd Composition,compound and use
GB9621263D0 (en) * 1996-10-11 1996-11-27 Exxon Chemical Patents Inc Lubricity additives for fuel oil compositions
US6495496B2 (en) * 2000-12-22 2002-12-17 Infineum International Ltd. Hydroxy aromatic mannich base condensation products and the use thereof as soot dispersants in lubricating oil compositions
US6855674B2 (en) 2000-12-22 2005-02-15 Infineum International Ltd. Hydroxy aromatic Mannich base condensation products and the use thereof as soot dispersants in lubricating oil compositions
EP1357168A1 (en) * 2002-04-16 2003-10-29 Infineum International Limited Jet fuel compositions
CA2520174C (en) 2004-09-17 2013-07-23 Infineum International Limited Additive composition for improving conductivity in fuel oils
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US2570377A (en) * 1949-08-30 1951-10-09 Tide Water Associated Oil Comp Fuel compositions
US3060210A (en) * 1960-05-12 1962-10-23 Petrolite Corp Polyaminomethyl phenols
US4142980A (en) * 1977-09-09 1979-03-06 Standard Oil Company (Indiana) Mannich reaction products made with alkyphenol substituted aliphatic unsaturated carboxylic acids
US4211534A (en) * 1978-05-25 1980-07-08 Exxon Research & Engineering Co. Combination of ethylene polymer, polymer having alkyl side chains, and nitrogen containing compound to improve cold flow properties of distillate fuel oils
US4396517A (en) * 1981-08-10 1983-08-02 Mobil Oil Corporation Phenolic-containing mannich bases and lubricants containing same
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KR100313182B1 (ko) 2002-10-11
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