KR870006070A - 스피로디포스페이트-함유 작용성 조성물 - Google Patents

스피로디포스페이트-함유 작용성 조성물 Download PDF

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KR870006070A
KR870006070A KR860011179A KR860011179A KR870006070A KR 870006070 A KR870006070 A KR 870006070A KR 860011179 A KR860011179 A KR 860011179A KR 860011179 A KR860011179 A KR 860011179A KR 870006070 A KR870006070 A KR 870006070A
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composition
group
spirodiphosphate
residues
aliphatic
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KR860011179A
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KR940009417B1 (ko
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리처니
유우발하펀
케이스 니버트 로저
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케이스 디. 슐쯔
보오그-워너 케미칼스 인코퍼레이티드
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/657154Cyclic esteramides of oxyacids of phosphorus
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • C10M137/10Thio derivatives
    • C10M137/105Thio derivatives not containing metal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/16Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-nitrogen bond
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/042Metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/047Thioderivatives not containing metallic elements
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/049Phosphite
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/08Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-nitrogen bonds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/042Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/046Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Lubricants (AREA)

Abstract

내용 없음

Description

스피로디포스페이트-함유 작용성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 31℃, 98℃ 및 160℃에서 실시예 2에 대한 시험 결과를 그래프로 나타낸 도면이다.
제2도는 31℃, 98℃ 및 160℃에서 비교 실시예 C3에 대한 시험 결과를 나타낸 도면이다.
제3도는 160℃에서 0,2,1,2,4 및 6시간 후의 실시예 2에 대한 시험 결과를 그래프로 나타낸 도면.

Claims (14)

  1. 담체 매질 및 하기 일반식(Ⅰ)의 스피로디포스페이트로 이루어진 조성물
    상기식에서, X 및 X'는 독립적으로 산소 및 황으로 이루어진 그룹중에서 선택되며;
    Z 및 Z'는 독립적으로 산소, 황, 질소 및 탄소를 통하여 인에 결합하는 유기 잔기로 이루어진 그룹중에서 선택된다.
  2. 제1항에 있어서, Z 및 Z'가 옥시알킬, 폴리옥시알킬, 옥시알케닐, 옥시아릴, 티오알킬, 티오알케닐, 티오아릴, 치환된 아미노, 알크아릴 및 지방족 잔기로 이루어진 그룹중에서 선택되는 조성물.
  3. 제1항에 있어서, X 및 X'가 황인 조성물.
  4. 제1항에 있어서, Z 및 Z'가 티오알킬, 틸오아릴 및 치환된 아미노 잔기 중에서 선택되는 조성물.
  5. 제4항에 있어서, Z 및 Z'가 기의 정의가 다음과 같은 일반식 -NRR'의 아미노 잔기로 이루어진 그룹 중에서 선택되는 조성물;
    R 및 R'는 지방족, 옥시지방족, 폴리옥시지방족, 지환족 및 아릴잔기로 이루어진 그룹중에서 선택되고 또한 R'는 수소로 이루어진 그룹중에서 선택된다.
  6. 제5항에 있어서, R'가 수소인 조성물.
  7. 제5항에 있어서, R이 C6-C30지방족 및 치환족 잔기, 및 C7-C30지방족 치환된 아릴잔기로 이루어진 그룹중에서 선택되는 조성물.
  8. 제6항에 있어서, R이 C13-C24지방족 잔기로 이루어진 그룹중에서 선택되는 조성물.
  9. 제8항에 있어서, R이 알케닐 잔기인 조성물.
  10. 제5항에 있어서, R이 옥시지방족 또는 폴리옥시지방족 잔기인 조성물.
  11. 제1항에 있어서, 언급된 담체 매질이 광물성유 및 광물섬유-기본 그리이스로 이루어진 그룹 중에서 선택되는 조성물.
  12. 제1항에 있어서, 스피로디포스페이트가 조성물의 중량에 대해 10중량% 이하로 존재하는 조성물.
  13. 제12항에 있어서, 스피로디포스페이트가 윤활조성물의 중량에 대해 약 0.01 내지 약 5중량%로 존재하는 조성물.
  14. 제13항에 있어서, 스피로디포스페이트가 조성물에 대해 약 0.1 내지 약 2.5중량%로 존재하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860011179A 1985-12-24 1986-12-24 스피로디포스페이트-함유 작동 조성물 KR940009417B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/813,296 US4778613A (en) 1985-12-24 1985-12-24 Spirodiphosphate-containing working substances
US813,296 1985-12-24
US813296 1985-12-24

Publications (2)

Publication Number Publication Date
KR870006070A true KR870006070A (ko) 1987-07-09
KR940009417B1 KR940009417B1 (ko) 1994-10-13

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KR1019860011179A KR940009417B1 (ko) 1985-12-24 1986-12-24 스피로디포스페이트-함유 작동 조성물

Country Status (6)

Country Link
US (1) US4778613A (ko)
EP (1) EP0227101B1 (ko)
JP (1) JPH086112B2 (ko)
KR (1) KR940009417B1 (ko)
CA (1) CA1256091A (ko)
DE (1) DE3689751T2 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1293737C (en) * 1985-12-24 1991-12-31 Lee Cherney Spirodiphosphoamidate type compounds and process for their preparation
US5230816A (en) * 1992-05-05 1993-07-27 Ciba-Geigy Corporation 3,9-bis(dialkylamino)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecanes and stabilized compositions
US6541430B1 (en) * 2000-03-24 2003-04-01 E. I. Du Pont De Nemours And Company Fluorinated lubricant additives
CN1293134C (zh) * 2005-07-05 2007-01-03 四川大学 具有双螺环结构的含磷阻燃剂及其制备方法
US8466096B2 (en) 2007-04-26 2013-06-18 Afton Chemical Corporation 1,3,2-dioxaphosphorinane, 2-sulfide derivatives for use as anti-wear additives in lubricant compositions

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US3192243A (en) * 1962-04-10 1965-06-29 Delaware Chemicals Inc Phosphorous derivatives of pentaerythritol
US3141032A (en) * 1963-01-23 1964-07-14 Union Carbide Corp Dialkyl pentaerythritol diphosphonates and phosphite phosphonates
US3325566A (en) * 1964-04-20 1967-06-13 Olin Mathieson Diphosphaspiro compound and process of making same
US3597503A (en) * 1967-12-06 1971-08-03 Hooker Chemical Corp Cyclic phosphoroamidates and process for making same
DE2206933A1 (de) * 1971-02-16 1972-08-24 Shell Internationale Research Maatschappij N.V., Den Haag (Niederlande) Phosphorinane und diese Verbindungen enthaltende Schmiermittel
US3819748A (en) * 1972-05-05 1974-06-25 Texaco Nv Sa Phosphorus derivatives of tetrafunctional aromatic compounds
US3839506A (en) * 1973-04-16 1974-10-01 Borg Warner Hindered phenol pentaerythritol phosphonate
US3978167A (en) * 1974-01-02 1976-08-31 Michigan Chemical Corporation Pentaerythritol cyclic diphosphates and diphosphoramidates
US4290976A (en) * 1975-03-24 1981-09-22 Borg-Warner Chemicals, Inc. Process for the preparation of phenol-free phosphites
CA1075257A (en) * 1975-09-26 1980-04-08 James A. Albright Pentaerythritol cyclic diphosphates and diphosphoramidates
US4086205A (en) * 1976-09-03 1978-04-25 Monsanto Company Hydrogen phosphonates
US4154721A (en) * 1976-09-21 1979-05-15 Borg-Warner Corporation Flame-retardant phosphonate compositions
US4162278A (en) * 1978-04-28 1979-07-24 American Cyanamid Company Flame retardant polyphenylene ether resin compositions containing a pentaerythrityl phosphonate
US4348291A (en) * 1979-07-02 1982-09-07 Stauffer Chemical Company Novel phosphoramides, lubricating compositions and method of improving wear and extreme pressure characteristics of lubricating oil
US4341722A (en) * 1979-07-06 1982-07-27 Ciba-Geigy Corporation 2-Thiono-(2H) [1,3,2] dioxaphosphorinanes (phospholanes)
DE3585120D1 (de) * 1984-10-03 1992-02-20 Hitachi Ltd Schmiermittel fuer die plastische verformung von metallen.
US4664828A (en) * 1985-04-25 1987-05-12 Stauffer Chemical Company Antiwear additives for functional fluids
CA1293737C (en) * 1985-12-24 1991-12-31 Lee Cherney Spirodiphosphoamidate type compounds and process for their preparation

Also Published As

Publication number Publication date
EP0227101A3 (en) 1988-01-27
EP0227101A2 (en) 1987-07-01
DE3689751D1 (de) 1994-05-05
KR940009417B1 (ko) 1994-10-13
US4778613A (en) 1988-10-18
JPH086112B2 (ja) 1996-01-24
DE3689751T2 (de) 1994-10-20
EP0227101B1 (en) 1994-03-30
CA1256091A (en) 1989-06-20
JPS62158796A (ja) 1987-07-14

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