KR890006755A - 수-기제 실리콘-유기 중합체 조성물 및 이의 제조방법 - Google Patents

수-기제 실리콘-유기 중합체 조성물 및 이의 제조방법 Download PDF

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KR890006755A
KR890006755A KR1019880014132A KR880014132A KR890006755A KR 890006755 A KR890006755 A KR 890006755A KR 1019880014132 A KR1019880014132 A KR 1019880014132A KR 880014132 A KR880014132 A KR 880014132A KR 890006755 A KR890006755 A KR 890006755A
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radicals
nonionic
organic polymer
silicon compound
weight
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KR1019880014132A
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KR960016131B1 (ko
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나룰라 디팩
존 스위하트 테렌스
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노만 에드워드 루이스
다우 코닝 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/28—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Medicinal Preparation (AREA)

Abstract

내용 없음

Description

수-기제 실리콘-유기 중합체 조성물 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. (A) 수성 규소 화합물 유액 조성물 및 (B) 수성 유기 중합체 조성물을 함유하는 성분들을 혼합하여, 유기 중합체에 대한 규소 화합물의 중량비가 1/100 내지 100/1인 실리콘-유기 중합체 조성물을 제공하며, 여기서 수성 규소 화합물 유액 조성물 (i) 필수적으로 물 10중량부 이상으로 이루어지는 수성상 및 (ii) 필수적으로 일반식 RaSio(4-a)/2(여기서, R은 각각, 수소원자, 알콕시 라디칼, 하이드록시 라디칼, 탄화수소 라디칼, 및 질소, 산소, 황 및 할로겐으로 이루어진 그룹중에서 선택된 하나 이상의 원자를 함유하는 라디칼 중에서 선택된 치환제로 치환된 탄화수소 라디칼로 이루어진 그룹중에서 선택된 1가의 규소-결합된 라디칼이고, a는 1 내지 4이다)의 규소 화합물 100중량부로 이루어지는 오일상을 함유하며; 수성상 및/또는 오일상은 추가로, 전체적으로 (1) HLB수가 13 내지 15인 비이온성 1급 계면활성제 3밀리몰 이상, (2) 비이온성 1급 계면활성제 밀리몰당, HLB수가 7 내지 9인 비이온성 2급 계면활성제 1 내지 5밀리몰 및 (3) HLB수가 16이상인 비이온성 3급 계면활성제 0.05밀리몰 이상을 함유함을 특징으로 하여, 실리콘-유기중합체 조성물을 제조하는 방법.
  2. 제1항의 방법에 의해 제조된 실리콘-유기 중합체 조성물.
  3. 일반식 RaSio(4-a)/2(여기서, R은 각각, 수소원자, 알콕시 라디칼, 하이드록시 라디칼, 탄화수소 라디칼 및 질소, 산소 황 및 할로겐으로 이루어진 그룹 중에서 선택된 하나 이상의 원자를 함유하는 라디칼 중에서 선택된 치환체로 치환된 탄화수소 라디칼로 이루어진 그룹 중에서 선택된 1가의 규소-결합된 라디칼이고, 하이드록시 라디칼 및 알콕시 라디칼로 이루어진 그룹 중에서 선택된 R 라디칼이 규소 화합물 분자당 하나 이상 존재하며, a는 1 내지 4이다)의 규소 화합물 100중량부; 유기 중합체 1 내지 10,000중량부; HLB수가 16이상인 비이온성 3급 계면활성제 0.05 밀리몰 이상; HLB수가 13 내지 15인 비이온성 1급 계면활성제 3밀리몰 이상; 1급 계면활성제 밀리몰당, HLB수가 7 내지 9인 비이온성 2급 계면활성제 1 내지 5밀리몰; 및 물 10중량부 이상을 함유함을 특징으로 하는 실리콘-유기 중합체 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880014132A 1987-10-30 1988-10-29 수성 실리콘-유기 중합체 조성물 및 이의 제조방법 KR960016131B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/115,493 US4803233A (en) 1987-10-30 1987-10-30 Water-based silicone-organic polymer compositions and method therefor
US115,493 1987-10-30

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KR890006755A true KR890006755A (ko) 1989-06-15
KR960016131B1 KR960016131B1 (ko) 1996-12-04

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US (1) US4803233A (ko)
EP (1) EP0317057B1 (ko)
JP (1) JPH0637591B2 (ko)
KR (1) KR960016131B1 (ko)
AU (1) AU608086B2 (ko)
CA (1) CA1330245C (ko)
DE (1) DE3854715T2 (ko)

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Publication number Publication date
US4803233A (en) 1989-02-07
AU2442588A (en) 1989-05-04
EP0317057B1 (en) 1995-11-22
EP0317057A2 (en) 1989-05-24
EP0317057A3 (en) 1990-10-24
KR960016131B1 (ko) 1996-12-04
JPH01161057A (ja) 1989-06-23
AU608086B2 (en) 1991-03-21
DE3854715T2 (de) 1996-05-30
CA1330245C (en) 1994-06-14
DE3854715D1 (de) 1996-01-04
JPH0637591B2 (ja) 1994-05-18

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