KR910006331A - 점성 중합체의 제조방법 - Google Patents

점성 중합체의 제조방법 Download PDF

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KR910006331A
KR910006331A KR1019900015340A KR900015340A KR910006331A KR 910006331 A KR910006331 A KR 910006331A KR 1019900015340 A KR1019900015340 A KR 1019900015340A KR 900015340 A KR900015340 A KR 900015340A KR 910006331 A KR910006331 A KR 910006331A
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ethylene
ethylene propylene
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silica
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리 성준
채프맨 베이커 에드가
니콜라스 에드워즈 데이비드
리 규희
헨리 무어하우스 존
세바스챤 스카롤라 레오나드
존 캐롤 프레드릭
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티모시 엔. 비숍
유니온 카바이드 케미칼즈 앤드 플라스틱스 캄파니 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2019/00—Use of rubber not provided for in a single one of main groups B29K2007/00 - B29K2011/00, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00—Use of unspecified rubbers as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/16—EPM, i.e. ethylene-propylene copolymers; EPDM, i.e. ethylene-propylene-diene copolymers; EPT, i.e. ethylene-propylene terpolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

점성 중합체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 점성 중합체 제조용의 대표적인 기체 유동층 반응기 구조를 예시한 것이다.
제2도는 밀도가 상이한 중합체의 연화점을 상호 연관시킨 그래프이다.
제3도는 중합체의 밀도와 프로필렌 함량을 상호 연관시킨 그래프이다.

Claims (27)

  1. 평균입자크기가 약 0.01내지 약 10μ인 불활성 입상물질 약 0.3 내지 약 80 중량%(최종 생성물의 중량기준)의 존재하에 점성 중합체의 연화점 이상에서 중합 반응시킴으로써, 점성 중합체의 중합체 응집물을 점성 중합체의 연속 제조에 적합한 크기로 유지시킴을 특징으로 하여, 유동상 반응기에서 촉매의 존재하에서 점성 중합체의 연화점을 초과하는 중합반응온도에서 점성 중합체를 제조하는 방법.
  2. 제1항에 있어서, 카본블랙, 실리카 및 점토 중에서 불활성 입상물질을 선택하는 방법.
  3. 제1항에 있어서, 불활성 입상물질이, 주요 입자크기가 약 10내지 약 100㎜이고, 평균 응집물 크기는 약 0.1 내지 약 10μ이고, 비표면적은 약 30 내지 약 1,500㎡/ｇ이고, 디부틸프탈레이트 흡수율은 약 80 내지 약 350cc/100g인 카본블랙인 방법.
  4. 제1항에 있어서, 불활성 입상물질이, 주요 입자크기가 약 5내지 50㎚이고, 평균응집물 크기는 약 0.1 내지 약 10μ이고, 비표면적은 약 50내지 500㎡/g이고, 디부틸프탈레이트 흡수율은 약 100 내지 400cc/100g인 실리카인 방법.
  5. 제1항에 있어서, 불활성 입상물질이, 평균 입자크기가 약 0.01 내지 약 10μ이고, 비표면적은 약 3 내지 약 30㎡/g이고, 오일흡수율은 100g당 약 20 내지 약 100g인 점토인 방법.
  6. 제1항에 있어서, 점성중합체가 (a)에틸렌 프로필렌고무, (b)에틸렌프로필렌 디엔 삼원궁중합체 고무, (c)폴리부타디엔 고무, 및 (d)에틸렌 고함량 프로필렌 에틸렌 블럭 공중합체인 방법.
  7. 제6항에 있어서, 에틸렌 프로필렌 디엔 삼원 공중합체가 에틸렌/프로필렌/에틸리덴노르보넨 삼원 공중합체인 방법.
  8. 제6항에 있어서, 에틸렌 프로필렌 디엔 삼원 공중합체가 에틸렌/프로필렌/헥사디엔 삼원공중합체인 방법.
  9. 제1항에 있어서, 불활성 입상물질을 최종 중합체 생성물의 중량을 기준으로 약 5 내지 약 75%의 양으로 사용하는 방법.
  10. 제1항에 있어서, 불활성 입상물질을 가열하고 질소에 의해 퍼징시킨 후, 반응기에 도입시키는 방법.
  11. 제3항에 있어서, 카본블랙을 최중 중합체 생성물의 중량을 기준으로 하여 약 0.3 내지 약 50%의 양으로 사용하는 방법.
  12. 제3항에 있어서, 카본블랙을 최종 중합체 생성물의 중량을 기준으로 하여 약 5 내지 약 30%의 양으로 사용하는 방법.
  13. 제4항에 있어서 실리카를 최종생성물의 중량을 기준으로하여 약 0.3 내지 약 50%의 양으로 사용하는 방법.
  14. 제4항에 있어서, 실리카를 최종생성물의 중량을 기준으로하여 약 5 내지 약 30%의 양으로 사용하는 방법.
  15. 제5항에 있어서, 점토를 최종 중합체 생성물의 중량을 기준으로 하여 약 12 내지 약 75%의 양으로 사용하는 방법.
  16. 주요 입자크기가 약 10 내지 약 100㎚이고, 평균 응집물 크기는 약 0.1 내지 약 10μ이고, 비표면적은 약 30 내지 약 1,500㎡/g이고, 디부틸프탈레이트 흡수율은 약 80 내지 약 350cc/100g인 카본블랙 약 0.3 내지 약 50중량% (최종생성물의 중량 기준)의 존재하에 에틸렌/프로필렌/에틸리덴노르보넨 삼원공중합체의 연화점 이상에서 중합 반응시킴으로써, 에틸렌/프로필렌/에틸리덴노르보넨 삼원공중합체의 중합체 응집물을 에틸렌/프로필렌/에틸레딘노르보넨 삼원공중합체의 연속 제조에 적합한 크기로 유지시킴을 특징으로 하여, 전이금속촉매에 의해 촉매화되는 유동상 반응기에서 에틸렌 프로필렌 에틸리덴 노르보넨 삼원공중합체의 연화점을 초과하는 중합반응 온도에서 에틸렌 프로필렌 에틸리덴노르보넨 삼원공중합체를 제조하는 방법.
  17. 제16항에 있어서, 카본블랙을 최종생성물의 중량을 기준으로 하여 약 5 내지 약 30%의 양으로 사용하는 방법.
  18. 제16항에 있어서, 카본블랙을 가열하고 질소에 의해 퍼징시킨후, 반응기에 도입시키는 방법.
  19. 주요 입자크기가 약 10 내지 약 100㎚이고, 평균 응집물 크기는 약 0.1내지 약 10μ이고, 비표면적은 약 30 내지 약 1,500㎡/g이고, 디부틸프탈레이트 흡수율은 약 10 내지 약 350cc/100g인 카본블랙 약 0.3 내지 약 50중량% (최종생성물의 중량 기준)의 존재하에 에틸렌 프로필렌 고무 공중합체의 연화점 이상에서 중합 반응시킴으로써, 에틸렌 프로필렌 고무의 중합체 응집물을 에틸렌 고무의 연속 제조에 적합한 크기로 유지 시킴을 특징으로 하여, 전이금속촉매에 의해 촉매화되는 유동상 반응기에서 에틸렌 프로필렌 고무의 연화점을 초과하는 중합반응온도에서 에틸렌 프로필렌 고무를 제조하는 방법.
  20. 제19항에 있어서, 카본블랙을 최종생성물의 중량을 기준으로 하여 약 5 내지 약 30%의 양으로 사용하는 방법.
  21. 제19항에 있어서, 카본블랙을 가열하고 질소에 의해 퍼징시킨후, 반응기에 도입시키는 방법.
  22. 주요 입자크기가 약 5 내지 약 50㎚이고, 평균 응집물 입자는 약 0.1 내지 약 10μ이고, 비표면적은 약 50내지 약 500㎡/g이고, 디부틸프탈레이트 흡수율은 약 100 내지 약 400cc/100g인 실리카 약 0.3 내지 약 50중량%(최종생성물의 중량 기준)의 존재하에 에틸렌/프로필렌/에틸리덴노르보넨 삼원공중합체의 연화점 이상에서 중합 반응시킴으로써, 에틸렌/프로필렌/에틸리덴노르보넨 삼원공중합체의 중합체 응집물을 에틸렌/프로필렌/에틸레딘노르보넨 삼원공중합체의 연속 제조에 적합한 크기로 유지시킴을 특징으로 하여, 전이금속촉매에 의해 촉매화되는 유동상 반응기에서 에틸렌 프로필렌 에틸리덴노르보넨 삼원공중합체의 연화점을 초과하는 중합반응 온도에서 에틸렌 프로필렌 에틸리덴노르보넨 삼원공중합체를 제조하는 방법.
  23. 제22항에 있어서, 실리카를 최종생성물의 중량을 기준으로 하여 약 5 내지 약 30%의 양으로 사용하는 방법.
  24. 제22항에 있어서, 실리카를 가열하고 질소에 의해 퍼징시킨후 반응기에 도입시키는 방법.
  25. 주요 입자크기가 약 5 내지 약 50㎚이고, 평균 응집물 크기는 약 0.1 내지 약 10μ이고, 비표면적은 약 50 내지 약 500㎡/g이고, 디부틸프탈레이트 흡수율은 약 100 내지 약400cc/100g인 실리카 약 0.3 내지 약 50중량% (최종생성물의 중량 기준)의 존재하에 에틸렌 프로필렌 고무의 연화점 이상에서 중합 반응시킴으로써, 에틸렌 프로필렌 고무의 중합체 응집물을 에틸렌 프로필렌 고무의 연속 제조에 적합한 크기로 유지시킴을 특징으로 하여, 전이금속촉매에 의해 촉매화되는 유동상 반응기에서 에틸렌 프로필렌 고무의 연화점을 초과하는 중합반응온도에서 에틸렌 프로필렌 고무를 제조하는 방법.
  26. 제25항에 있어서, 실리카를 최종생성물의 중량을 기준으로 하여 약 5 내지 약 30%의 양으로 사용하는 방법.
  27. 제25항에 있어서, 실리카를 가열하고 질소에 의해 퍼징시킨후 반응기에 도입시키는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900015340A 1989-09-28 1990-09-27 점착성 중합체 및 이의 제조방법 KR950006119B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US413,704 1989-09-28
US413704 1989-09-28
US07/413,704 US4994534A (en) 1989-09-28 1989-09-28 Process for producing sticky polymers

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KR910006331A true KR910006331A (ko) 1991-04-29
KR950006119B1 KR950006119B1 (ko) 1995-06-09

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US (1) US4994534A (ko)
EP (1) EP0422452B1 (ko)
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MX22641A (es) 1993-04-01
CA2026338A1 (en) 1991-03-29
US4994534A (en) 1991-02-19
EP0422452A2 (en) 1991-04-17
MX167157B (es) 1993-03-08
ZA907745B (en) 1991-07-31
BR9004882A (pt) 1991-09-10
ATE190069T1 (de) 2000-03-15
DE69033470T2 (de) 2000-08-10
PH26958A (en) 1992-12-28
NZ235485A (en) 1992-03-26
ES2142788T3 (es) 2000-05-01
PT95453A (pt) 1991-05-22
AU6316190A (en) 1991-04-11
EP0422452A3 (en) 1992-02-05
FI904765A0 (fi) 1990-09-27
JPH0647606B2 (ja) 1994-06-22
AR244251A1 (es) 1993-10-29
JPH03217402A (ja) 1991-09-25
NO904203L (no) 1991-04-02
EP0422452B1 (en) 2000-03-01
NO904203D0 (no) 1990-09-27
AU620736B2 (en) 1992-02-20
TR24892A (tr) 1992-07-01
DE69033470D1 (de) 2000-04-06
KR950006119B1 (ko) 1995-06-09
BG92915A (bg) 1993-12-24
HUT63640A (en) 1993-09-28
CN1051737A (zh) 1991-05-29
HU906245D0 (en) 1991-03-28

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