KR910004703A - 방향족 폴리에테르의 제조방법 - Google Patents

방향족 폴리에테르의 제조방법 Download PDF

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Publication number
KR910004703A
KR910004703A KR1019900012118A KR900012118A KR910004703A KR 910004703 A KR910004703 A KR 910004703A KR 1019900012118 A KR1019900012118 A KR 1019900012118A KR 900012118 A KR900012118 A KR 900012118A KR 910004703 A KR910004703 A KR 910004703A
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KR
South Korea
Prior art keywords
condensation
reaction
bis
dihalo
phenol
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KR1019900012118A
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English (en)
Inventor
쉬넬러 아르놀드
Original Assignee
벡크, 테르가우
훽스트 아크티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 벡크, 테르가우, 훽스트 아크티엔게젤샤프트 filed Critical 벡크, 테르가우
Publication of KR910004703A publication Critical patent/KR910004703A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • C08G65/4087—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group characterised by the catalyst used

Abstract

내용 없음.

Description

방향족 폴리에테르의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 축합 보조제로서 주기율표 제1족 금속의 탄산염의 존재하에, 임의로 하나 이상의 용매의 존재하에 2가 페놀을 활성화된 방향족 디할로 화합물과 축합시키거나 다핵 활성화 할로페놀을 자가 축합시키고, 축합 보조제로서 탄산나트륨과 탄산수소나트륨의 혼합물을 사용하는 것을 특징으로 하여, 방향족 폴리에테르를 제조하는 방법.
  2. 제1항에 있어서, 중탄산나트륨의 양이 사용된 탄산나트륨 몰당 0.001 내지 0.5몰, 바람직하게는 0.3몰 이하인 방법.
  3. 제1항 또는 2항에 있어서, 반응에 사용된 페놀 성분의 하이드록실 그룹 몰당 하나 이상의 금속원자가 존재하는 양으로 탄산염을 사용하는 방법.
  4. 제1항 내지 3항중 어느 한 항에 있어서, 축합 반응을 방향족 설폰, 특히 디페닐 설폰중에서 수행하는 방법.
  5. 제1항 내지 4항중 어느 한 항에 있어서, 일반식(4)의 벤제노이드 디할로 화합물을 사용하는 방법.
    상기식에서, Hal은 p-또는 o-위치의 동일하거나 상이한 할로겐 원자이고, Q및 Q′는 -CO- 및/또는 SO2- 그룹이며, u는 0.1 또는 2이다.
  6. 제1항 내지 5항중 어느 한 항에 있어서, 벤제노이드 디하이드록시 화합물이 일반식(1)의 페놀인 방법.
    상기식에서, X는 직접결합, -O-, -S-, -SO2-, -CO-, -CH2-, -C(CH3)2- 또는 -C(CF3)2- 이고, m 및 n이 0이며, k는 0 또는 1이다.
  7. 제1항 내지 6항중 어느 한 항에 있어서, 탄산나트륨과 탄산수소나트륨의 혼합물을 승온에서 용매중에 용해시킨 디할로 화합물중에 현탁시키고난 다음, 디할로 화합물을 승온, 바람직하게는 200 내지 350℃에서 가하는 방법.
  8. 제1항 내지 7항중 어느 한 항에 있어서, 고유점도 (농황산 100㎖중의 중합체 0.5g의 용액중에서 측정함)가 50 내지 500, 바람직하게는 75 내지 300㎖/g이 될때까지 축합반응을 수행하는 방법.
  9. 제1항 내지 8항중 어느 한 항에 있어서, 사용된 2가 페놀이 하이드로퀴논 또는 2,2-비스 (4′-하이드록시페닐) 프로판이고 사용된 디할로 화합물이 1,4-비스(4′-클로로벤조일)벤젠 또는 1,4-비스(4′-플루오로벤조일) 벤젠이며, 디페닐 설폰이 존재하는 방법.
  10. 제1항 내지 9항중 어느 한 항에 있어서, 반응을 조절제, 바람직하게는 메틸 클로라이드, t-부틸 클로라이드, 4-클로로디페닐 설폰 또는 4-플루오로벤존페논의 존재하에 수행하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900012118A 1989-08-09 1990-08-08 방향족 폴리에테르의 제조방법 KR910004703A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3926263A DE3926263A1 (de) 1989-08-09 1989-08-09 Verfahren zur herstellung eines aromatischen polyethers
DEP39262634 1989-08-09

Publications (1)

Publication Number Publication Date
KR910004703A true KR910004703A (ko) 1991-03-29

Family

ID=6386772

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900012118A KR910004703A (ko) 1989-08-09 1990-08-08 방향족 폴리에테르의 제조방법

Country Status (8)

Country Link
US (1) US5081214A (ko)
EP (1) EP0412498A3 (ko)
JP (1) JPH03174445A (ko)
KR (1) KR910004703A (ko)
CA (1) CA2022910A1 (ko)
DE (1) DE3926263A1 (ko)
IE (1) IE902868A1 (ko)
PT (1) PT94942A (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0388358B1 (de) * 1989-03-17 1996-09-25 Sumitomo Chemical Company Limited Neue Polyarylenether
US5268444A (en) * 1993-04-02 1993-12-07 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Phenylethynyl-terminated poly(arylene ethers)
FR2843399B1 (fr) * 2002-08-06 2004-09-03 Commissariat Energie Atomique Polymeres de type polyphenylenes, leur procede de preparation, membranes et dispositif de pile a combustible comprenant ces membranes
DE102005002084A1 (de) * 2005-01-14 2006-07-20 Degussa Ag Verfahren zur Herstellung von Polyarylenetherketonen
GB0513621D0 (en) * 2005-07-02 2005-08-10 Victrex Mfg Ltd Polymeric materials
CN100374483C (zh) * 2006-03-29 2008-03-12 长春吉大高科技股份有限公司 聚醚醚砜和聚醚醚酮三元共聚物的制备方法
CN102257033B (zh) * 2008-10-24 2014-01-29 索维高级聚合物股份有限公司 用于制造聚(芳基醚酮)的改进的方法以及用于提供适合于制造聚(芳基醚酮)的碳酸钠的改进的方法
CN101580583B (zh) * 2009-06-26 2011-03-30 金发科技股份有限公司 采用四元共聚技术制备聚芳醚酮类共聚物的方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA847963A (en) * 1970-07-28 Zutty Nathan Process for preparing polyarylene polyethers
US3065205A (en) * 1959-10-27 1962-11-20 Du Pont Aromatic polyketones and preparation thereof
DE1545106C3 (de) * 1963-07-16 1979-05-31 Union Carbide Corp., New York, N.Y. (V.St.A.) Verfahren zur Herstellung von linearen Polyarylenpolyäthern
GB1586972A (en) * 1977-02-01 1981-03-25 Ici Ltd Production of aromatic polyethers
DE2861696D1 (en) * 1977-09-07 1982-04-29 Ici Plc Thermoplastic aromatic polyetherketones, a method for their preparation and their application as electrical insulants
EP0010868A3 (en) * 1978-10-27 1980-06-11 Imperial Chemical Industries Plc Production of aromatic polyethers
DE3342433A1 (de) * 1983-11-24 1985-06-05 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von aromatischen polyaethern
US4638044A (en) * 1985-03-20 1987-01-20 Amoco Corporation Process for preparing poly(aryl ether ketone)s
US4891167A (en) * 1985-05-02 1990-01-02 Amoco Corporation Block polymers containing a poly(aryl ether ketone) and methods for their production
US4731429A (en) * 1985-06-17 1988-03-15 Amoco Corporation Novel poly(aryl ether ketones)
CA1276743C (en) * 1986-03-10 1990-11-20 Isaburo Fukawa Crystalline aromatic polyketone copolymer and manufacturing the same
US4774314A (en) * 1986-04-25 1988-09-27 Amoco Corporation Preparing poly(aryl ethers) using alkaline earth metal carbonates, organic acid salts, and optionally copper compounds, as catalysts
JPS6465129A (en) * 1987-09-04 1989-03-10 Mitsubishi Gas Chemical Co Production of aromatic polyether
JPH01204928A (ja) * 1988-02-10 1989-08-17 Daicel Chem Ind Ltd 芳香族ポリエーテルの製法
DE3907474A1 (de) * 1989-03-08 1990-09-13 Bayer Ag Verfahren zur herstellung von aromatischen polyetherketonen

Also Published As

Publication number Publication date
EP0412498A3 (en) 1992-02-26
CA2022910A1 (en) 1991-02-10
PT94942A (pt) 1991-04-18
EP0412498A2 (de) 1991-02-13
IE902868A1 (en) 1991-02-27
US5081214A (en) 1992-01-14
DE3926263A1 (de) 1991-02-14
JPH03174445A (ja) 1991-07-29

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