KR910000589A - 비닐기전이 반응 - Google Patents

비닐기전이 반응 Download PDF

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KR910000589A
KR910000589A KR1019890009030A KR890009030A KR910000589A KR 910000589 A KR910000589 A KR 910000589A KR 1019890009030 A KR1019890009030 A KR 1019890009030A KR 890009030 A KR890009030 A KR 890009030A KR 910000589 A KR910000589 A KR 910000589A
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에우겐 머레이 렉스
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티모시 엔. 비숍
유니온 카바이드 코포레이션
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Abstract

내용 없음

Description

비닐기전이 반응
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (80)

  1. 비닐기전이(transvinylation)가 발생하는 온도하에 루테늄 화합물의 존재하에서 비닐 유도체 및 브론스테드산(Bronsted acid)을 함유하는 액상 혼합물을 제공하고, 비닐기전이 반응의 생성물로서 전자와 다른 브론스테드산의 비닐 유도체를 회수함을 특징으로 하여, 브론스테드 산의 비닐 유도체를 전자와 다른 브론스테드 산으로 비닐기전이 시키는 방법.
  2. 제1항에 있어서, 루테늄 화합물이 액체 혼합물 중에서 가용성인 방법.
  3. 제1항에 있어서, 비닐 유도체가 카복실산의 비닐 에스테르인 방법.
  4. 제3항에 있어서, 비닐기전이 반응의 생성물이 카복실산의 비닐 에스테르인 방법.
  5. 제3항에 있어서, 카복실산의 비닐 에스테르가 비닐 아세테이트인 방법.
  6. 제3항에 있어서, 카복실산의 비닐 에스테르가 비닐 피발레이트인 방법.
  7. 제4항에 있어서, 카복실산의 비닐 에스테르가 비닐 피발레이트인 방법.
  8. 제3항에 있어서, 카복실산의 비닐 에스테르가 비닐 벤조에이트인 방법.
  9. 제4항에 있어서, 카복실산의 비닐 에스테르가 비닐 벤조에이트인 방법.
  10. 제3항에 있어서, 카복실산의 비닐 에스테르가 비닐 아크릴레이트인 방법.
  11. 제10항에 있어서, 카복실산의 비닐 에스테르가 비닐 아크릴레이트인 방법.
  12. 제10항에 있어서, 카복실산의 비닐 에스테르가 비닐 메타크릴레이트인 방법.
  13. 제4항에 있어서, 비닐 에스테르가 하이드록시 알킬 카복실레이트인 비닐 에테르인 방법.
  14. 제1항에 있어서, 액상 혼합물중의 물이 실질적으로 제거된 방법.
  15. 제14항에 있어서, 액상 혼합물이 필수적으로 무수물인 방법.
  16. 제14항에 있어서, 반응에서 물의 양이 혼합물 중량의 약 25%미만인 방법.
  17. 제16항에 있어서, 반응에서 물의 양이 혼합물 중량의 약 15%미만인 방법.
  18. 제15항에 있어서, 반응에서 물의 양이 혼합물 중량의 약 10%미만인 방법.
  19. 제1항에 있어서, 브론스테드 산이 질소 함유 화합물인 방법.
  20. 제19항에 있어서, 질소 함유 화합물이 아미노함유 화합물인 방법.
  21. 제1항에 있어서, 일산화탄소의 존재하에 수행되는 방법.
  22. 제2항에 있어서, 일산화탄소의 존재하에 수행되는 방법.
  23. 제1항에 있어서, 약 20℃내지 약 300℃온도하에서 수행되는 방법.
  24. 제2항에 있어서, 약 20℃내지 약 300℃온도하에서 수행되는 방법.
  25. 제23항에 있어서, 약 50℃내지 약 200℃온도하에서 수행되는 방법.
  26. 제24항에 있어서, 약 50℃내지 약 200℃온도하에서 수행되는 방법.
  27. 제1항에 있어서, 반응압력이 부압(subatmospheric), 대기 또는 초대기성(superatmospheric)인 방법.
  28. 제2항에 있어서, 반응압력이 부압, 대기 또는 초대기성인 방법.
  29. 제27항에 있어서, 반응압력이 약 10-6토르내지 약 5,000psia인 방법.
  30. 제28항에 있어서, 반응압력이 약 10-6토르내지 약 5,000psia인 방법.
  31. 제29항에 있어서, 반응압력이 약 10-5토르내지 약 800psia인 방법.
  32. 제30항에 있어서, 반응압력이 약 10-5토르내지 약 800psia인 방법.
  33. 제31항에 있어서, 반응압력이 약 10-4토르내지 약 550psia인 방법.
  34. 제32항에 있어서, 반응압력이 약 10-4토르내지 약 550psia인 방법.
  35. 제1항에 있어서, 브론스테드산대 루테늄의 몰비가 적어도 0.5대 1인 방법.
  36. 제2항에 있어서, 브론스테드산대 루테늄의 몰비가 적어도 0.5대 1인 방법.
  37. 제35항에 있어서, 브론스테드산 대 루테늄의 몰비가 약 50대 1내지 약 1,000,000대 1인 방법.
  38. 제36항에 있어서, 브론스테드산 대 루테늄의 몰비가 약 50대 1내지 약 1,000,000대 1인 방법.
  39. 제1항에 있어서, 루테늄 촉매농도가 액상 반응혼합물의 중량을 기준하여 루테늄 밀리온당 약30,000부 내지 약 0.5부인 방법.
  40. 제27항에 있어서, 적어도 하나의 반응물에 대해 용매 비-반응물이 존재하는 방법.
  41. 제28항에 있어서, 적어도 하나의 반응물에 대해 용매 비-반응물이 존재하는 방법.
  42. 제29항에 있어서, 압력범위가 무수물 평방인치당 약 16내지 약 5,000파운드인 방법.
  43. 제30항에 있어서, 압력범위가 무수물 평방인치당 약 16내지 약 5,000파운드인 방법.
  44. 제27항에 있어서, 압력이 부압인 방법.
  45. 제28항에 있어서, 압력이 부압인 방법.
  46. 제1항에 따른 루테늄 촉매.
  47. 제2항에 따른 루테늄 촉매.
  48. 제4항에 있어서, 비니기전이 반응이 생성물이 디비닐 아디페이트인 방법.
  49. 제4항에 있어서, 비니기전이 반응이 생성물이 디비닐 이소프탈레이트인 방법.
  50. 제4항에 있어서, 비니기전이 반응이 생성물이 디비닐 테레프탈레이트인 방법.
  51. 제4항에 있어서, 비니기전이 반응이 생성물이 비닐 프로피오네이트인 방법.
  52. 제4항에 있어서, 비니기전이 반응이 생성물이 비닐 스테아레이트인 방법.
  53. 제4항에 있어서, 비니기전이 반응이 생성물이 비닐 살리실레이트인 방법.
  54. 제4항에 있어서, 비니기전이 반응이 생성물이 비닐 신나메이트인 방법.
  55. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐 2-에틸헥사노에이트인 방법.
  56. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐 사이클로헥사노에이트인 방법.
  57. 제4항에 있어서, 비니기전이 반응의 생성물이 N-비닐 피롤리디논인 방법.
  58. 제4항에 있어서, 비니기전이 반응의 생성물이 N-비닐 석신이미디인 방법.
  59. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐 페닐 에테르인 방법.
  60. 제4항에 있어서, 비니기전이 반응의 생성물이 N-비닐 2-옥사졸리디논인 방법.
  61. 제4항에 있어서, 비니기전이 반응의 생성물이 N-비닐 에틸렌우레아인 방법.
  62. 제4항에 있어서, 비니기전이 반응의 생성물이 2-비닐옥시에틸 아세테이트인 방법.
  63. 제4항에 있어서, 비니기전이 반응의 생성물이 2-비닐옥시에틸 아크릴레이트인 방법.
  64. 제4항에 있어서, 비니기전이 반응의 생성물이 2-비닐옥시에틸 메타크릴레이트인 방법.
  65. 제4항에 있어서, 비니기전이 반응의 생성물이 2-비닐옥시에틸 피발레이트인 방법.
  66. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐 팔미테이트인 방법.
  67. 제4항에 있어서, 비니기전이 반응의 생성물이 2-하이드록시에틸 5-비닐 에틸렌우레아인 방법
  68. 제4항에 있어서, 비니기전이 반응의 생성물이 1-(2-아세톡시에틸)-2-비닐옥시-이미다졸린인 방법
  69. 제4항에 있어서, 비니기전이 반응의 생성물이 2-아세톡시에틸- 5-비닐 에틸렌우레아인 방법
  70. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐(1,1,1,3,3,3-헥사플루오로-2-프로필)에테르인 방법
  71. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐(2,2-디페닐 아세테이트)인 방법.
  72. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐 2-벤조일 벤조에이트인 방법.
  73. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐 네오-헵타노에이트인 방법.
  74. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐 네오-노나노에이트인 방법.
  75. 제4항에 있어서, 비니기전이 반응의 생성물이 헥실 비닐 에테르인 방법.
  76. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐(N-아세틸아미노-카프로애이트)인 방법.
  77. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐(n-피보일아미노-카프로에이트)인 방법.
  78. 제4항에 있어서, 비니기전이 반응의 생성물이 비닐옥시(트리-n-프로필)실란인 방법.
  79. 제4항에 있어서, 비니기전이 반응의 생성물이 5-이소벤조푸란-카복실산, 1,3-디하이드로-1,3-디옥소-에테닐 에스테르인 방법.
  80. 제4항에 있어서, 비니기전이 반응의 생성물이 N-비닐 0-톨루엔 설폰아미드인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890009030A 1988-06-30 1989-06-29 비닐기전이 반응 KR950000643B1 (ko)

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US07/213,697 US4981973A (en) 1988-06-30 1988-06-30 Transvinylation reaction

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JPH0684317B2 (ja) 1994-10-26
AU3717789A (en) 1990-01-04
FI893186A0 (fi) 1989-06-29
ES2064385T3 (es) 1995-02-01
KR950000643B1 (ko) 1995-01-26
DK324889D0 (da) 1989-06-29
NO892717D0 (no) 1989-06-29
HUT50754A (en) 1990-03-28
FI893186A (fi) 1989-12-31
DE68919766D1 (de) 1995-01-19
RU2051143C1 (ru) 1995-12-27
MC2036A1 (fr) 1990-05-30
EP0351603A3 (en) 1991-11-21
JPH0256438A (ja) 1990-02-26
EP0351603A2 (en) 1990-01-24
HU208519B (en) 1993-11-29
MY105046A (en) 1994-07-30
DK324889A (da) 1989-12-31
ZA894954B (en) 1990-04-25
ATE115113T1 (de) 1994-12-15
CA1337869C (en) 1996-01-02
US4981973A (en) 1991-01-01
RO105609B1 (ro) 1992-10-30
DE68919766T2 (de) 1995-05-04
NO173275B (no) 1993-08-16
AU623151B2 (en) 1992-05-07
NO173275C (no) 1993-11-24
BR8903207A (pt) 1990-02-13
EP0351603B1 (en) 1994-12-07

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