KR900008166B1 - 올레핀의 하이드로시안화 방법 - Google Patents

올레핀의 하이드로시안화 방법 Download PDF

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Publication number
KR900008166B1
KR900008166B1 KR1019830000098A KR830000098A KR900008166B1 KR 900008166 B1 KR900008166 B1 KR 900008166B1 KR 1019830000098 A KR1019830000098 A KR 1019830000098A KR 830000098 A KR830000098 A KR 830000098A KR 900008166 B1 KR900008166 B1 KR 900008166B1
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KR
South Korea
Prior art keywords
nickel
catalyst
molar ratio
ligand
promoter
Prior art date
Application number
KR1019830000098A
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English (en)
Korean (ko)
Other versions
KR840003236A (ko
Inventor
라포포오트 모리스
Original Assignee
이.아이.듀퐁 드 네모아 앤드 캄파니
에이. 엔. 리디
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이.아이.듀퐁 드 네모아 앤드 캄파니, 에이. 엔. 리디 filed Critical 이.아이.듀퐁 드 네모아 앤드 캄파니
Publication of KR840003236A publication Critical patent/KR840003236A/ko
Application granted granted Critical
Publication of KR900008166B1 publication Critical patent/KR900008166B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1019830000098A 1982-01-13 1983-01-13 올레핀의 하이드로시안화 방법 KR900008166B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US339059 1982-01-13
US339,059 1982-01-13
US06/339,059 US4371474A (en) 1982-01-13 1982-01-13 Hydrocyanation of olefins

Publications (2)

Publication Number Publication Date
KR840003236A KR840003236A (ko) 1984-08-20
KR900008166B1 true KR900008166B1 (ko) 1990-11-05

Family

ID=23327312

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019830000098A KR900008166B1 (ko) 1982-01-13 1983-01-13 올레핀의 하이드로시안화 방법

Country Status (11)

Country Link
US (1) US4371474A (fr)
JP (1) JPS58159452A (fr)
KR (1) KR900008166B1 (fr)
BE (1) BE895583A (fr)
CA (1) CA1181428A (fr)
DE (1) DE3300969A1 (fr)
FR (1) FR2519632B1 (fr)
GB (1) GB2113218B (fr)
IT (1) IT1160169B (fr)
LU (1) LU84579A1 (fr)
NL (1) NL8300119A (fr)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4539302A (en) * 1984-04-30 1985-09-03 E. I. Du Pont De Nemours And Company Recovery of zerovalent nickel complexes
US4705881A (en) * 1986-11-17 1987-11-10 E. I. Du Pont De Nemours And Company Continuous hydrocyanation process using zinc halide promoter
DK0730574T3 (da) * 1993-11-23 1999-05-25 Du Pont Fremgangsmåder og katalysatorsammensætninger til hydrocyanering af monoolefiner
EP0755302B1 (fr) 1994-04-14 2000-10-04 E.I. Du Pont De Nemours And Company Compositions de catalyseur a base de phosphite bidendate et de nickel pour l'hydrocyanation de mono-olefines
US5512695A (en) * 1994-04-14 1996-04-30 E. I. Du Pont De Nemours And Company Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
TW315370B (fr) * 1994-10-07 1997-09-11 Du Pont
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
US5449807A (en) * 1994-11-18 1995-09-12 E. I. Du Pont De Nemours And Company Catalyzed vapor phase hydrocyanation of diolefinic compounds
IN187044B (fr) * 1995-01-27 2002-01-05 Du Pont
US5821378A (en) * 1995-01-27 1998-10-13 E. I. Du Pont De Nemours And Company Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
FR2850966B1 (fr) * 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
FR2854892B1 (fr) * 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
EP1948591A1 (fr) * 2005-10-18 2008-07-30 INVISTA Technologies S.à.r.l. Procede de preparation de 3-aminopentanenitrile
US7629484B2 (en) * 2006-03-17 2009-12-08 Invista North America S.A.R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7709674B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7880028B2 (en) * 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7659422B2 (en) * 2006-07-14 2010-02-09 Invista North America S.A.R.L. Hydrocyanation process with reduced yield losses
WO2009075692A2 (fr) 2007-05-14 2009-06-18 Invista Technologies S.A.R.L. Réacteur et procédé à haut rendement
WO2008157218A1 (fr) * 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Procédé pour améliorer la qualité de l'adiponitrile
US7977502B2 (en) * 2008-01-15 2011-07-12 Invista North America S.A R.L. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
CN101918356B (zh) * 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
JP2011515411A (ja) * 2008-03-19 2011-05-19 インビスタ テクノロジーズ エス エイ アール エル シクロドデカトリエンの製造方法およびラウロラクトンの製造方法
US8247621B2 (en) * 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
KR20120047251A (ko) * 2009-08-07 2012-05-11 인비스타 테크놀러지스 에스.에이.알.엘. 디에스테르를 형성하기 위한 수소화 및 에스테르화
EP2614070B1 (fr) * 2010-09-07 2017-07-26 Invista Technologies S.à r.l. Compositions de nickel pour préparer un métal nickel et des complexes à base de nickel
CN103229778B (zh) * 2013-05-07 2015-05-06 江苏辉丰农化股份有限公司 一种防治禾谷类作物病害的杀菌剂

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853948A (en) * 1965-11-23 1974-12-10 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentene-nitriles
GB1112539A (en) * 1965-11-26 1968-05-08 Du Pont Preparation of organic nitriles
US3766237A (en) * 1972-01-25 1973-10-16 Du Pont Hydrocyanation of olefins
US3818067A (en) * 1972-07-20 1974-06-18 Du Pont Preparation of organic dinitriles
US3903120A (en) * 1973-06-19 1975-09-02 Du Pont Preparation of zerovalent nickel complexes from elemental nickel
US4330483A (en) * 1981-02-24 1982-05-18 E. I. Du Pont De Nemours And Company Hydrocyanation of olefins

Also Published As

Publication number Publication date
KR840003236A (ko) 1984-08-20
NL8300119A (nl) 1983-08-01
JPH0251901B2 (fr) 1990-11-08
BE895583A (fr) 1983-07-12
LU84579A1 (fr) 1983-09-08
FR2519632A1 (fr) 1983-07-18
IT8319081A0 (it) 1983-01-12
GB2113218B (en) 1986-06-04
IT1160169B (it) 1987-03-04
US4371474A (en) 1983-02-01
CA1181428A (fr) 1985-01-22
JPS58159452A (ja) 1983-09-21
FR2519632B1 (fr) 1987-05-07
GB2113218A (en) 1983-08-03
DE3300969C2 (fr) 1991-09-12
DE3300969A1 (de) 1983-07-21
GB8300786D0 (en) 1983-02-16

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KR900008166B1 (ko) 올레핀의 하이드로시안화 방법
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EP0268448B1 (fr) Procédé continu d'hydrocyanisation employant un halogènure de zinc comme promoteur
US7709673B2 (en) Process for making 3-pentenenitrile by hydrocyanation of butadiene
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US20080015382A1 (en) Hydrocyanation process with reduced yield losses
US4382038A (en) Hydrocyanation of olefins
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EP1344770A1 (fr) Procédé pour la hydrocyanisation du butadiène

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